Plural Chalcogens Bonded Directly To Ring Carbons Of The Five-membered Hetero Ring (e.g., Cyclic Imides, Etc.) Patents (Class 548/435)
  • Patent number: 4742166
    Abstract: Imides of the formula I ##STR1## in which E is allyl or methallyl, R is hydrogen, alkyl, alkenyl, cycloalkyl, aryl, benzyl, alkylene or arylene, and n is 1 or 2, are intermediates for the preparation of crosslinked polymers having excellent physical properties. The polymers can be used, in particular, for the preparation of glass fibre-reinforced and carbon fibre-reinforced plastics and heat-resistant composite materials, and as electrical insulation materials and whirl-sintered powder paints.
    Type: Grant
    Filed: April 17, 1986
    Date of Patent: May 3, 1988
    Assignee: Ciba-Geigy Corporation
    Inventor: Alfred Renner
  • Patent number: 4739075
    Abstract: Disclosed in an alicyclic end-capping agent for a heterocyclic compound, which is represented by the formula [I]: ##STR1## wherein X is CO, O, S, CH.sub.2 or substituted CH.sub.2, Y.sub.1 -Y.sub.6 are halo, H, NO.sub.2, aryl, alkaryl, arylalkyl or alkyl ether, and Z is ##STR2## (Q.sub.1 is --NH.sub.2, --SH, --OH or ##STR3## (Q.sub.2 is H, or monovalent aliphatic or amomatic group). Also disclosed is an addition-curable quinoxaline resin oligomer having the above-mentioned alicylic end-capping agents at both terminals of oligomer. This oligomer is useful especially for an intermediate material for a fiber-reinforced composite.
    Type: Grant
    Filed: February 13, 1987
    Date of Patent: April 19, 1988
    Assignee: Director-General of Agency of Industrial Science & Technology
    Inventors: Nobuyuki Odagiri, Kuniaki Tobukuro
  • Patent number: 4739030
    Abstract: The solvent resistance of polysulfone, polyether sulfone, and polyesters is enhanced by using difunctional end-cap monomers of the present invention to provide improved crosslinking. The imidophenol monomers include two unsaturated functionalities capable of crosslinking upon thermal or chemical activation. Oligomer, oligomer blends, pregregs, and composites using the novel end caps are also described.
    Type: Grant
    Filed: January 6, 1986
    Date of Patent: April 19, 1988
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard
  • Patent number: 4728742
    Abstract: Imides of the formula I ##STR1## wherein R.sup.1, R.sub.2, R.sup.3 and n have the meanings defined in claim 1, are intermediates for producing polymers having excellent physical properties, and for producing sulfonic acid esters.
    Type: Grant
    Filed: June 19, 1985
    Date of Patent: March 1, 1988
    Assignee: Ciba-Geigy Corporation
    Inventor: Alfred Renner
  • Patent number: 4714768
    Abstract: A new compound is disclosed, N-(chlorocarbonyloxy-5-norbornene-2,3-dicarboximide I, in addition to processes for its production and employment of the compound as starting product for the manufacture of non-symmetrical carbonate, urethane-protected amino acid or peptide, activated carrier and carrier-ligand-complexes. The new compound is reacted with alcohols as well as with hydroxyl-group-containing or amino-group-containing polymers.
    Type: Grant
    Filed: August 27, 1984
    Date of Patent: December 22, 1987
    Assignee: Akademie Der Wissenschaften Der DDR
    Inventors: Peter Henklein, Manfred Becker, Werner Buttner, Fritz Loth, Horts Dautzenberg, Klaus Forner, Rudolf Dolling, Karl-Heinz Graul, Wolf-Rainer Halatsch, Christian Rupprich
  • Patent number: 4709047
    Abstract: Imides of formula I ##STR1## wherein R.sup.1 and R.sup.2 are independently hydrogen or methyl, R.sup.3 is a direct bond, alkylene, oxaalkylene, cycloalkylene, arylene or arylene-T-arylene where T is methylene or isopropylidene, and R.sup.4 alkyl, cycloalkyl, aryl, benzyl or alkaryl are suitable as catalysts for the crosslinking of specific unsaturated imides.
    Type: Grant
    Filed: January 17, 1986
    Date of Patent: November 24, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Alfred Renner, Christian Vonlanthen
  • Patent number: 4661604
    Abstract: Resins are prepared from polysulfone and polyethersulfone polymers that bear functional groups derived from compounds that are condensation products of amino-phenols and acid anhydrides. The polymers are prepared by coreacting aromatic compounds holding two hydroxyl groups, aromatic compounds holding two active halogen groups, and the condensation product of amino-phenol and acid anhydride, the condensation product holding one hydroxyl group. The resulting product has a molecular weight between about 1,000 and 40,000, preferably between about 5,000 and 30,000, and can be cross-linked to form a resin that is thermoplastic and solvent resistant.
    Type: Grant
    Filed: August 12, 1983
    Date of Patent: April 28, 1987
    Assignees: TRW, Inc., The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard
  • Patent number: 4661630
    Abstract: Described herein are novel carboxylic acid amide compounds or carboximide compounds represented by the general formula: ##STR1## wherein Z represents either the monoamido radical of an aromatic or cycloaliphatic ortho dicarboxylic acid or the amide of the corresponding anhydride, and their pharmaceutically acceptable salts; processes for the production thereof; and medicines containing the same. The novel compounds are useful as treating, preventing and improving agents for diseases attended with cerebral dysfunction as well as various symptoms caused by the said diseases.
    Type: Grant
    Filed: December 2, 1985
    Date of Patent: April 28, 1987
    Assignee: Eisai Co., Ltd.
    Inventors: Yasuji Harigaya, Hiroo Ogura, Mitsuo Mihara, Motosuke Yamanaka, Kiyomi Yamatsu
  • Patent number: 4604437
    Abstract: Imides of the formula I ##STR1## in which E is allyl or methallyl, R is hydrogen, alkyl, alkenyl, cycloalkyl, aryl, benzyl, alkylene or arylene, and ni is 1 or 2, are intermediates for the preparation of crosslinked polymers having excellent physical properties. The polymers can be used, in particular, for the preparation of glass fibre-reinforced and carbon fibre-reinforced plastics and heat-resistant composite materials, and as electrical insulation materials and whirl-sintered powder paints.
    Type: Grant
    Filed: January 22, 1985
    Date of Patent: August 5, 1986
    Assignee: Ciba-Geigy Corporation
    Inventor: Alfred Renner
  • Patent number: 4560768
    Abstract: Polyimido-ester compounds having the formula RO--C(O)--R.sub.1 --C(O)--OR are disclosed wherein R is an alkylene N-dicarboximido radical containing cycloolefinic unsaturation and R.sub.1 is the divalent residue of an unsaturated polycarboxylic acid such as fumaric, itaconic, aconitic, mesaconic, or glutaconic acid. These compounds are blended with unsaturated resins such as unsaturated polyester resin or vinyl ester resin, and polymerizable unsaturated monomers such as styrene to provide thermosettable resin compositions which can be cured to provide castings or laminates with improved resistance to thermal aging.
    Type: Grant
    Filed: December 16, 1983
    Date of Patent: December 24, 1985
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Douglas L. Hunter
  • Patent number: 4555563
    Abstract: Imide functional polyphenols are prepared by reacting an excess of a phenol with an unsaturated diimide which is prepared by reacting an unsaturated polycycloaliphatic dicarboxylic acid anhydride with a diamine.These materials are useful in the preparation of castings, coatings, laminates and the like.
    Type: Grant
    Filed: December 7, 1984
    Date of Patent: November 26, 1985
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Mary N. White
  • Patent number: 4515962
    Abstract: Imides of the formula I ##STR1## in which E is allyl or methallyl, R is hydrogen, alkyl, alkenyl, cycloalkyl, aryl or benzyl when n is 1, and R is alkylene or arylene when n is 2, are intermediates for the preparation of crosslinked polymers with excellent physical properties. The polymers can be used, in particular, for the preparation of glass fiber-reinforced and carbon fiber-reinforced plastics and as electrical insulating materials.
    Type: Grant
    Filed: July 25, 1983
    Date of Patent: May 7, 1985
    Assignee: Ciba Geigy Corporation
    Inventor: Alfred Renner
  • Patent number: 4514533
    Type: Grant
    Filed: September 27, 1983
    Date of Patent: April 30, 1985
    Assignee: Canusa Coating Systems Limited
    Inventor: Ralph H. Hansen
  • Patent number: 4476184
    Abstract: Resins are prepared from polymers that bear monofunctional or difunctional groups derived from compounds that are condensation products of amino-phenols and acid anhydrides. The polymers are prepared by coreacting aromatic compounds holding two hydroxyl groups, aromatic compounds holding two active halogen groups, and the condensation product of amino-phenol and acid anhydride, the condensation product holding one hydroxyl group. The resulting product has a molecular weight between about 1,000 and 40,000, preferably between about 5,000 and 30,000, and can be cross-linked to form a resin that is thermoplastic and solvent resistant.
    Type: Grant
    Filed: August 9, 1983
    Date of Patent: October 9, 1984
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard
  • Patent number: 4460783
    Abstract: An ether imide of the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and D are as defined in the specification produced by reacting a diamine with an ethylenically unsaturated dicarboxylic acid can give a composition together with one or more unsaturated polyesters, epoxy compounds, amines, and the like to give shaped articles excellent in flexibility and heat resistance.
    Type: Grant
    Filed: January 19, 1981
    Date of Patent: July 17, 1984
    Assignee: Hitachi, Ltd.
    Inventors: Akio Nishikawa, Masashi Shitara, Susumu Era, Toshiaki Fukushima, Hiroshi Suzuki, Hisashi Kohkame
  • Patent number: 4414269
    Abstract: Resins are prepared from polysulfone and polyethersulfone polymers that bear functional groups derived from compounds that are condensation products of amino-phenols and acid anhydrides. The polymers are prepared by coreacting aromatic compounds holding two hydroxyl groups, aromatic compounds holding two active halogen groups, and the condensation product of amino-phenol and acid anhydride, the condensation product holding one hydroxyl group. The resulting product has a molecular weight between about 1,000 and 40,000, preferably between about 5,000 and 30,000, and can be cross-linked to form a resin that is thermoplastic and solvent resistant.
    Type: Grant
    Filed: June 16, 1981
    Date of Patent: November 8, 1983
    Assignees: TRW, Inc., The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard
  • Patent number: 4374220
    Abstract: Flame retardants having good stability at the processing temperatures of high melting polymers are described. The flame retardants are halogen-containing bis-imides, for example, those of the formula ##STR1## R being defined in the specification.
    Type: Grant
    Filed: May 14, 1981
    Date of Patent: February 15, 1983
    Assignee: Raychem Corporation
    Inventor: Joseph Sonnenberg
  • Patent number: 4365068
    Abstract: New crosslinkable bis-imidyl derivatives are described which can be produced by reaction of imidylphthalic acid derivatives, such as maleimidyl-phthalic acid anhydrides, with monomeric, oligomeric or polymeric diamines. The new crosslinkable bis-imidyl derivatives can be used for producing crosslinked polymers which are distinguished, in particular, by their stability to oxidation and to heat.
    Type: Grant
    Filed: November 14, 1980
    Date of Patent: December 21, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Roland Darms, Vratislav Kvita, Gerd Greber