Two Silicons Bonded Directly To The Same Oxygen Patents (Class 556/425)
  • Patent number: 5914420
    Abstract: Compositions of unstrained perfluorinated organo substituted cyclosiloxanes of formula (I): ##STR1## wherein m is an integer of 1 to 12; n is an integer of 1 to 4; X is a divalent radical which may include O, NH, N(CH.sub.3), OC(O), NHC(O), N(CH.sub.3)C(O)CH.sub.2 ; and R.sup.F is a perfluorinated straight chain or branched chain monovalent alkyl radical of 1 to 25 carbon atoms; or R.sup.F is a perfluorinated ether radical of the general formula (II): ##STR2## wherein p is an integer of 1 to 10 are described, along with copolymer compositions prepared from these cyclopolysiloxanes and from mixtures of these cyclosiloxanes and other siloxanes.
    Type: Grant
    Filed: May 29, 1998
    Date of Patent: June 22, 1999
    Assignee: PCR, Inc.
    Inventors: Mark A. Buese, John Scott Shaffer
  • Patent number: 5892086
    Abstract: Compositions of unstrained perfluorinated ether organo substituted cyclosiloxanes of formula (I): ##STR1## wherein m is an integer of 1 to 12; n is an integer of 1 to 4; X is a divalent radical which may include O, NH, N(CH.sub.3), OC(O), NHC(O), N(CH.sub.3)C(O)CH.sub.2 ; and R.sup.F is a perfluorinated ether radical of the general formula (II): ##STR2## wherein p is an integer of 1 to 10 are described, along with copolymer compositions prepared from these cyclopolysiloxanes and from mixtures of these cyclosiloxanes and other siloxanes.
    Type: Grant
    Filed: May 29, 1998
    Date of Patent: April 6, 1999
    Assignee: PCR, Inc.
    Inventors: Mark A. Buese, John Scott Shaffer
  • Patent number: 5892084
    Abstract: The invention provides high purity 3-aminopropylmethylsiloxanes of the general formulae: ##STR1## wherein each R may be the same or different aryl group, or monovalent straight or branched chain alkyl group having from 1 to about 18 carbon atoms, Me is methyl, and x may range from about 3 to about 5, the process comprisinghydrosilylating allylamine with a monohydridomethylsiloxane of the general formulae: ##STR2## wherein each R may be the same or different aryl group, or monovalent straight or branched chain alkyl group with 1 to about 18 carbon atoms, and x may range from about 3 to about 5, in the presence of a neutral platinum catalyst.
    Type: Grant
    Filed: February 3, 1998
    Date of Patent: April 6, 1999
    Assignee: PCR, Inc.
    Inventors: Benigno A. Janeiro, Mark A. Buese
  • Patent number: 5863509
    Abstract: An aqueous alcoholic fluoroalkyl functional group containing organopolysiloxane-composition, comprising:organopolysiloxanes of formula I:RO?Si(A)(CH.sub.3).sub.z (OR).sub.1-z O!.sub.a ?Si(B)(R.sup.2).sub.y (OR).sub.1-y O!.sub.b ?Si(C)(CH.sub.3)O!.sub.c ?Si(D)(OR)O!.sub.d R.multidot.(HX) (I)wherein A is an aminoalkyl radical derived from the compound of formula II:H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II)wherein 0.ltoreq.f.ltoreq.6, 9=0 if f=0 and g=1 if f>0, 0.ltoreq.h.ltoreq.6 and 0.ltoreq.z.ltoreq.1, and B is a fluoroalkyl radical derived from the compound of formula III:R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y (III)wherein R.sup.1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH.sub.2, O or S group, R.sub.2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0.ltoreq.y.ltoreq.
    Type: Grant
    Filed: June 10, 1998
    Date of Patent: January 26, 1999
    Assignee: Huels Aktiengesellschaft
    Inventors: Burkhard Standke, Roland Edelmann, Albert-Johannes Frings, Ralf Laven, Michael Horn, Peter Jenkner, Helmut Mack, Jaroslaw Monkiewicz
  • Patent number: 5856544
    Abstract: Aminopolysiloxanes of the following structure Q.sub.2 RSiO-- (SiR.sub.2 O).sub.x -(SiRR.sup.1 O).sub.y -SiRQ.sub.2 wherein R is a monovalent hydrocarbon group having 1 to 10 carbon atoms including alkyl, aryl and aralkyl groups; R.sup.1 is CH.sub.2 --CH.sub.2 --C--(CH.sub.3).sub.2 --CH.sub.2 --NHR.sup.2, R.sup.2 is hydrogen, an alkyl of C.sub.1 -C.sub.6, an alkyl amine of C.sub.1 -C.sub.6, or an alkanolamine of C.sub.1 -C.sub.6 ; Q is R, R.sup.1, hydroxyl, or an alkoxy of C.sub.1 -C.sub.4. x can be zero or integer; y is an integer, with x+y being less than 1,100, for use in various applications, including softening textiles.
    Type: Grant
    Filed: April 14, 1997
    Date of Patent: January 5, 1999
    Assignee: OSi Specialties, Inc.
    Inventors: Anna Czech, Gerald J. Murphy, Curtis L. Schilling, Jr.
  • Patent number: 5849942
    Abstract: An aqueous alcoholic fluoroalkyl functional group containing organopolysiloxane- composition, comprising:organopolysiloxanes of formula I:RO?Si(A)(CH.sub.3).sub.z (OR).sub.1-z O!.sub.a ?Si(B)(R.sup.2).sub.y (OR).sub.1-y O!.sub.b?Si(C)(CH.sub.3)O!.sub.c ?Si(D)(OR)O!.sub.d R.multidot.(HX)(I)wherein A is an aminoalkyl radical derived from the compound of formula II:H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II)wherein 0.ltoreq.f.ltoreq.6, 9=0 if f=0 and g=1 if f>0, 0.ltoreq.h.ltoreq.6 and 0.ltoreq.z.ltoreq.1, and B is a fluoroalkyl radical derived from the compound of formula III:R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2)y(OR).sub.3-y (III)wherein R.sup.1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH.sub.2, O or S group, R.sub.2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0.ltoreq.y.ltoreq.
    Type: Grant
    Filed: December 3, 1997
    Date of Patent: December 15, 1998
    Assignee: Huels Aktiengesellschaft
    Inventors: Burkhard Standke, Roland Edelmann, Albert-Johannes Frings, Ralf Laven, Michael Horn, Peter Jenkner, Helmut Mack, Jaroslaw Monkiewicz
  • Patent number: 5840951
    Abstract: Organosilicon compounds containing amino groups, their preparation and their useOrganosilicon compounds containing amino groups and comprisinga) siloxane units of the formulaR.sub.a Si(OR.sup.1).sub.b O.sub.(4-a-b)/2 (I)andb) at least one unit per molecule selected from the group consisting of units of the formulaeAR.sub.C SiO.sub.(4-c-1)/2 (II),O.sub.(4-c-1)/2 R.sub.C Si--A.sup.1 --R.sub.C SiO.sub.(4-c-1)/2 (III)or ##STR1## where R is an identical or different hydrocarbon radical which has from 1 to 18 carbon atoms, optionally substituted by halogen atoms, alkoxy groups or hydroxy groups where the hydrocarbon radical is optionally interrupted by oxygen atoms,R.sup.1 is an identical or different alkyl radical which is optionally interrupted by oxygen atoms,a is 0, 1, 2 or 3 andb is 0, 1, 2 or 3, with the proviso that the sum a+b is not greater than 3, andc is 0, 1 or 2,A is a radical of the formula--R.sup.2 R.sup.3.sub.z N(--CR.sup.4.sub.2 --R.sup.5).sub.(2-z) (V),A.sup.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: November 24, 1998
    Assignee: Wacker-Chemie GmbH
    Inventors: Thomas Hierstetter, Jochen Dauth, Joerg Pfister, Bernward Deubzer
  • Patent number: 5834613
    Abstract: Chemically stable, perfluorinated, linear or cyclic polyorganosiloxanes (POS), and a process for the preparation thereof. Antifoams, agents for lowering surface tension, dirt repellents, antiadhesives, lubricants, oleophobic and/or hydrophobic agents, coatings and other compositions containing the perfluorinated POS are disclosed.
    Type: Grant
    Filed: July 25, 1996
    Date of Patent: November 10, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventors: Philippe Jost, Philippe Karrer, Gerard Mignani, Philippe Olier
  • Patent number: 5808125
    Abstract: An aqueous organopolysiloxane-containing composition comprising organopolysiloxanes of formula I:HO?Si(A) (CH.sub.3).sub.z (OH).sub.1-z O!.sub.a ?Si(B) (R.sup.2).sub.y (OH).sub.1-y O!.sub.b ?Si(C) (CH.sub.3)O!.sub.c ?Si(D) (OH)O!.sub.d H.multidot.(HX).sub.e (I),wherein A is an aminoalkyl group of formula II:H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II),in which 0.ltorsim.f.ltorsim.6, g=0 if f=0 and g=1 if f>0, 0.ltorsim.h.ltorsim.6 and 0.ltorsim.z.ltorsim.1;B is a fluoroalkyl group of formula III:R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2)y(OR).sub.3-y (III),wherein R.sup.1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms, or a mono-, oligo- or perfluorinated aryl group, Y is a CH.sub.2, O or S group, R.sup.2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0.ltorsim.y.ltorsim.1;C is an alkyl group of formula IV:R.sup.3 --Si(CH.sub.3) (OR).sub.2 (IV),and D is an alkyl group of formula V:R.sup.3 --Si(OR).sub.
    Type: Grant
    Filed: December 3, 1997
    Date of Patent: September 15, 1998
    Assignee: Huels Aktiengesellschaft
    Inventors: Burkhard Standke, Roland Edelmann, Albert-Johannes Frings, Michael Horn, Peter Jenkner, Ralf Laven, Helmut Mack, Jaroslaw Monkiewicz
  • Patent number: 5807956
    Abstract: The present invention discloses non-hydrolyzable, block, (AB).sub.n A type, copolymers comprising alternating units of polysiloxane and amino-polyalkyleneoxide and provides a method for the preparation of these copolymers. Also provided is the use of these copolymers as softeners, in particular durable, hydrophilic textile softeners, which improve tactile properties of the textiles substrates treated with the commercial soil release finishes, without substantially detracting from their properties.The copolymers of the present invention have alternating units of polysiloxane ?X(C.sub.a H.sub.2a O).sub.b R.sup.2 ?(SiO(R.sup.1).sub.2 !.sub.c Si(R.sup.1).sub.2 R.sup.2 (C.sub.a H.sub.2a O).sub.b X!and polyalkyleneoxides ?YO(C.sub.a H.sub.2a O).sub.d Y!wherein R.sup.1 is a C.sub.1 to C.sub.4 alkyl, preferably methyl, R.sup.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: September 15, 1998
    Assignee: OSi Specialties, Inc.
    Inventor: Anna Czech
  • Patent number: 5776658
    Abstract: Compounds of the general formula I: (SIL--X--).sub.m IN (I), in which SIL is a radical of the formula Si(R.sup.1)(R.sup.2)(R.sup.3), where R.sup.1 is an alkyl, haloalkyl or alkoxy radical of 1 to 8 carbon atoms, an alkenyl radical, an alkenyloxy or acyloxy radical of 2 to 8 carbon atoms, an aryl or aryloxy radical of 6 to 10 carbon atoms, or a dialkyl-, diaryl- or alkylaryl-methyleneaminooxy radical having C.sub.1 -C.sub.4 -alkyl or C.sub.6 -aryl groups; and R.sup.2 and R.sup.3 are identical or different radicals with the meaning of R.sup.1 or X--IN; X is a group C.sub.n H.sub.2n ; IN is the radical of a compound which is active as a photoinitiator or photosensitizer and which has at least one carbonyl group located on an aromatic nucleus; m is a number from 1 to 4; and n is a number from 2 to 12, or of the formula II: Si.sub.o O.sub.o-1 (--X--IN).sub.p R.sup.4.sub.2o+2-p (II), in which R.sup.4 is a radical with the meaning of R.sup.1, and two or more radicals R.sup.
    Type: Grant
    Filed: September 29, 1995
    Date of Patent: July 7, 1998
    Assignee: AGFA-Gevaert AG
    Inventors: Claus-Peter Niesert, Georg Pawlowski, Willi-Kurt Gries, Klaus-Juergen Przybilla
  • Patent number: 5747625
    Abstract: The present invention provides a novel silicate group-containing polyimide which is excellent in mechanical properties, heat resistance and electrical properties and has an excellent film forming ability. Further, the present invention provides a film-formable heat resistant material having an excellent solvent resistance, elasticity and adhesive property. The silicate group-containing polyimide has a repeated unit represented by the following Formula (1): ##STR1## wherein Ar.sub.1 represents a tetravalent organic group; R.sub.1 and R.sub.2 each are a single bond or represent an alkylene group having 1 to 4 carbon atoms or a phenylene group; R.sub.3 to R.sub.7, R.sub.9 and R.sub.10 each represent a hydrocarbon group having 1 to 6 carbon atoms; R.sub.8 represents an ethylene group or an alkylene group having 3 to 6 carbon atoms; m and n represent independently an integer of 1 to 10; and k represents an integer of 0 to 2.
    Type: Grant
    Filed: November 26, 1996
    Date of Patent: May 5, 1998
    Assignee: Nippon Steel Chemical Co., Ltd.
    Inventors: Nobuyuki Furukawa, Takeshi Fujiyama, Masatoshi Yuasa
  • Patent number: 5739369
    Abstract: A surface treating agent comprising a reaction product of (A) a fluoroalkyl group-containing alkoxysilane with (B) an amino group-containing alkoxysilane and optionally further with (C) an alkyl group-containing alkoxysilane is water soluble. The agent is diluted with water to form a solution for treating glass and other substrates to impart durable water repellency and other improved properties to the substrates.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: April 14, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Kazuyuki Matsumura, Mitsuo Asai, Shoji Ichinohe
  • Patent number: 5725790
    Abstract: Provided are an organopolysiloxane represented by the following formula (I), which has at least one norbornane skeleton and at least one amino group, and a fiber finishing composition containing as a main component the aforesaid organopolysiloxane: ##STR1## wherein R groups are the same or different, and each of them represents an alkyl group containing 1 to 20 carbon atoms or an aryl group containing 6 to 20 carbon atoms; X is a group represented by the following formula (II); A groups are the same or different, and each of them represents an alkoxy group containing 1 to 10 carbon atoms, a hydroxyl group, R or X; m is from 10 to 10,000; and n is from 0 to 500, wherein when n is 0 at least one A group represents X; ##STR2## wherein Q.sup.1 and Q.sup.2 are the same or different, and each represents a divalent organic group containing 1 to 20 carbon atoms.
    Type: Grant
    Filed: January 10, 1997
    Date of Patent: March 10, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshihito Osawa, Satoshi Kuwata
  • Patent number: 5714524
    Abstract: A photocurable silicone composition easy to manufacture, free of variations in adhesion and effective as a potting material or the like is provided. The composition is prepared by adding a silanol terminated organosiloxane to an amino group-containing organodialkoxysilane, then reacting the resulting amino group-containing organopolysiloxane with a vinyl group-containing isocyanate, acrylic anhydride, methacrylic anhydride, acrylic halide or methacrylic halide and combining the resulting photocurable organopolysiloxane with a photopolymerization catalyst.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: February 3, 1998
    Assignee: Three Bond Co., Ltd.
    Inventors: Osamu Hara, Kunihiko Nakashima
  • Patent number: 5698725
    Abstract: This invention relates to treating agents, glass fiber substrates treated with such agents, and the use of such treated glass fiber substrates in molded, glass fiber reinforced resins that are suited to copper clad laminates, composite base materials, printed wiring boards such as mass lamination boards, and, in particular, multilayer printed wiring boards.
    Type: Grant
    Filed: September 4, 1996
    Date of Patent: December 16, 1997
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Masayuki Hayashi, Makoto Iwai
  • Patent number: 5686641
    Abstract: A method for the preparation of very pure organopentasiloxane having the hydrogen atom or an aliphatically unsaturated monovalent hydrocarbon group bonded to the silicon atom at one molecular chain terminal and having a hydrolyzable group or groups bonded to the silicon atom at the other molecular chain terminal.
    Type: Grant
    Filed: January 15, 1997
    Date of Patent: November 11, 1997
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventor: Tadashi Okawa
  • Patent number: 5627253
    Abstract: A polyimide resin having excellent storage stability which cures to give a highly adherent, highly heat-resistant, and highly moisture-resistant film is disclosed, said resin being prepared by reacting(A) a tetracarboxylic dianhydride and(B) a diamino-functional siloxane compound having the general formula ##STR1## in which each R.sup.1 is independently selected from C.sub.1 to C.sub.20 monovalent hydrocarbon radicals, each R.sup.2 is independently selected from C.sub.1 to C.sub.20 divalent hydrocarbon radicals, R.sup.3 is selected from the group consisting of hydrogen and --SiR.sup.1.sub.3 wherein R.sup.1 is defined as above, a is an integer from 1 to 20, b is an integer from 1 to 20, c is an integer from 0 to 20, and d is an integer from 1 to 20.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: May 6, 1997
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventor: Hisataka Nakashima
  • Patent number: 5624680
    Abstract: A hydrosilyl-terminated polyoxyethylene compound of the general formula (I), a quaternary-salt-terminated polyoxyethylene/polyorganosiloxane block copolymer of the general formula (II) derived from the above compound, and a percutaneous drug absorption promoter comprising the above copolymer (II). The copolymer is usable as a percutaneous absorption promoter having a good drug absorption promoting effect and being effective for various drugs.
    Type: Grant
    Filed: January 23, 1996
    Date of Patent: April 29, 1997
    Assignee: Sagami Chemical Research Center
    Inventors: Yu Nagase, Takao Aoyagi, Tomoko Akimoto
  • Patent number: 5616758
    Abstract: A cationic silicone compound which can be employed in a variety of environments, such as a fiber lubricant, textile fabric softener, hair conditioner, and skin conditioner is formed from an aminosilicone compound which has the following Formula (I): ##STR1## wherein a, b, and c are 0-300;d is 0-4, preferably 1 or 2;R.sub.1 comprises hydrogen, an alkyl, aryl, alkynyl, alkenyl, alkyloxyalkylene group which may be unsubstituted or substituted with P, N, or S moieties;R.sub.2 is defined the same as R.sub.1 and can also be a carboxylic acid residue preferably a fatty acid residues, with the proviso that where R.sub.2 is a carboxylic acid residue, the R.sub.1 attached to the terminal N is hydrogen;R.sub.3 is defined the same as R.sub.2 and can also be alkoxy, aryloxy or oxyalkylene groups;R.sub.4 is defined the same as R.sub.3 and can also be an amino-substituted alkyl group;Z.sub.1 and Z.sub.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: April 1, 1997
    Assignee: Karlshamns AB
    Inventors: James P. McCarthy, George H. Greene, Anthony G. DeWar
  • Patent number: 5610258
    Abstract: The crosslinkable nematic polyorganosiloxanes are cyclic polyorganosiloxanes containing at least three different mesogenic side groups per polyorganosiloxane, where at least two mesogenic side groups per polyorganosiloxane each contain at least three radicals selected from aromatic, heteroaromatic and cycloaliphatic radicals. They contain a methacrylic or acrylic group in at least one of the mesogenic side groups. The cyclic polyorganosiloxanes have a broad nematic phase and can be readily aligned.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: March 11, 1997
    Assignee: Consortium f ur elektrochemische Industrie GmbH
    Inventors: Hans-Peter Weitzel, Susanne Weber-Koegl, Sotirios Chatzinerantzis
  • Patent number: 5602224
    Abstract: The invention relates to a series of novel silicone compounds which contain fatty alkyl groups. This class of compounds provides unique solubility in many organic softeners, and increases the effectiveness of the softening of fatty quats. These materials are applied to fibers including textile fibers and hair and skin. The compounds of the present invention contain which contain a fatty substituted quaternary group, a silicone group and a reactive silanol groups. The presence of the positive charge on the nitrogen results in substantivity to many substrates, the presence of a silicone portion results in compatability in silicone fluids and the presence of the fatty tail on the molecule results in fatty solubility. The resulting material is surface active and will allow for the incorporation of silicone into a fatty system or of a fatty quat in a silicone system.
    Type: Grant
    Filed: March 19, 1996
    Date of Patent: February 11, 1997
    Assignee: Siltech Inc.
    Inventors: Richard O. Vrckovnik, Anthony J. O'Lenick, Jr.
  • Patent number: 5599990
    Abstract: A quaternary ammonium halide is prepared by reacting a substituted or unsubstituted haloalkane with a tert-amine in a mol ratio not higher than 1.1/1 in the absence of a solvent and at a temperature such as to maintain the reaction mixture liquid.
    Type: Grant
    Filed: October 27, 1995
    Date of Patent: February 4, 1997
    Assignee: Albemarle Corporation
    Inventors: Joseph H. Miller, Joe D. Sauer, Dru L. DeLaet
  • Patent number: 5591818
    Abstract: Disclosed are organosilane polycondensation products prepared by hydrolysis of an hydrogen salt of an aminosilane compound or by hydrolysis of an aminosilane followed by reaction with an alkyl salt. The compounds are useful in forming stable aqueous solutions and as adhesion promoters between inorganic and organic surfaces.
    Type: Grant
    Filed: March 29, 1995
    Date of Patent: January 7, 1997
    Assignee: Huls Aktiengesellschaft
    Inventors: Burkhard Standke, Hartwig Rauleder, Claus-Dietrich Seiler, Hans-Joachim Kotzsch, Hermann Peeters
  • Patent number: 5567752
    Abstract: Silicon- and nitrogen-containing compositions prepared by the reaction of an aminoalkylsilane such as 3-aminopropyl- or 3-methylaminopropyltrimethoxysilane with a glycidoxyalkylsilane such as 3-glycidoxypropyltrimethoxysilane are useful as adhesion promoters in addition curable polyorganosiloxane compositions. The latter are illustrated by mixtures of vinyl-substituted polyorganosiloxanes and hydride polyorganosiloxanes, also containing at least one platinum group metal compound as a hydrosilylation catalyst.
    Type: Grant
    Filed: November 22, 1995
    Date of Patent: October 22, 1996
    Assignee: General Electric Company
    Inventors: Judith Stein, Jeffrey H. Wengrovius, Paul R. Willey
  • Patent number: 5563231
    Abstract: This invention relates to water-dispersible compounds that are useful as lubricants for textile wet processing having formula (I): ##STR1## wherein R is C.sub.1 -C.sub.10 alkylene;R.sup.1 is an m-functional group having the formula ##STR2## R.sup.2 and R.sup.3 are independently C.sub.1 -C.sub.10 alkyl or groups having the formula ##STR3## R.sup.4 is hydrogen, acyl, or trialkylsilyl; R.sup.5 and R.sup.6 are independently alkyl, alkoxy, --Z--(O--B).sub.s --OR.sup.4, or --Y--(O--A).sub.r --;R.sup.7 and R.sup.8 are independently alkyl, alkoxy, or --Z--(O--B).sub.s --OR.sup.4 ;X is hydrogen, (cyclo)alkyl, (cyclo)alkenyl, --NR.sup.c R.sup.d, --NR.sup.c R.sup.d R.sup.e+ Q.sup.-, --OR.sup.f, --SR.sup.g, --NH--CO--NH--R.sup.h, --O--CO--NH--R.sup.i, --NH--CO--O--R.sup.j, --CN, or halogen;A and B are independently alkylene;Y and Z are independently a direct bond or alkylene;m is from 1 to 20;r and s are independently from 0 to 20; andn and p are from 0 to 100 and the total (n+p) is from 10 to 100.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: October 8, 1996
    Assignee: Bayer Corporation
    Inventors: Lloyd Barringer, Jr., Thomas P. Bellina, Brad A. Ziegler
  • Patent number: 5550272
    Abstract: A method for silating unsaturated monomers by contacting a system having at least one SiH group, an unsaturated monomer, a transition metal catalyst and a free radical polymerization inhibitor is described.
    Type: Grant
    Filed: October 2, 1995
    Date of Patent: August 27, 1996
    Assignee: General Electric Company
    Inventors: Larry N. Lewis, Terrell W. Carothers
  • Patent number: 5536861
    Abstract: Antimicrobial quaternary ammonium group-containing organosilicon polymers, aqueous disinfectant solutions containing such polymers, and lenses produced from such polymers are provided herein.
    Type: Grant
    Filed: July 5, 1994
    Date of Patent: July 16, 1996
    Assignee: Ciba-Geigy Corporation
    Inventor: J. Richard Robertson
  • Patent number: 5534610
    Abstract: A organic solventless two component rapidly curing primer composition comprising a low viscosity dimethylsiloxane oligomer end capped with amino-ethyl-amino-propyl-dimethoxysiloxyl and an organotitanate, a process for the manufacture thereof, and a process for the use therewith said primer particularly suited for use with room temperature vulcanizable silicone sealants and a low viscosity dimethylsiloxane oligomer end capped with amino-ethyl-amino-propyl-dimethoxysiloxyl as a primer for room temperature vulcanizable sealants whereby such sealants may be painted.
    Type: Grant
    Filed: June 30, 1995
    Date of Patent: July 9, 1996
    Assignee: General Electric Company
    Inventors: Brian P. Bayly, Gary M. Lucas, Van W. Stuart
  • Patent number: 5486634
    Abstract: A method for the synthesis of organopolysiloxanes having ##STR1## group, wherein R.sup.1 is an alkyl group with 1 to 4 carbon atoms, is described. The products are obtained by the hydrosilylation of compounds of the formula ##STR2## with hydrogensiloxanes, the addition taking place exclusively in the form of a .gamma. addition.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: January 23, 1996
    Assignee: Th. Goldschmidt AG
    Inventors: Gunter Hahn, Klaus-Dieter Klein, Dietmar Schafer
  • Patent number: 5484950
    Abstract: A process for the selective monoadditon of an olefin or acetylene to a siloxane which contains two reactive Si--H bonds to produce a product in which only one of the two Si--H functions has added across the olefin or acetylene is disclosed. A process for making unsymmetrical siloxanes from symmetrical dihydrosiloxanes and products of both of these processes are also disclosed. Products are represented by the formula I in which R.sup.1 and R.sup.
    Type: Grant
    Filed: December 21, 1992
    Date of Patent: January 16, 1996
    Assignee: Polyset Company, Inc.
    Inventor: James V. Crivello
  • Patent number: 5475124
    Abstract: A composition which is curable to an elastomer comprising:A polymer or mixture of polymers of the formula ##STR1## A composition which is curable to a pressure sensitive adhesive comprising the above polymer and a sufficient amount of tackifier. The invention also relates to fluorosilane compounds useful in the preparation of silicone macromonomer, their preparation and the preparation of silicone macromonomer.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: December 12, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mieczyslaw H. Mazurek, Steven S. Kantner, Charles M. Leir, Audrey A. Sherman
  • Patent number: 5473041
    Abstract: There is disclosed an organopolysiloxane having bifunctional biphenyl groups of the formula I ##STR1## wherein Q is selected from the group consisting of a nitro group, a substituted amino group and an unsubstituted amino group, Z is an organopolysiloxane group represented by the formula II ##STR2## in which R.sup.1 is a divalent organic group having at least 2 carbon atoms, R.sup.2 through R.sup.6 are the same or different monovalent organic groups, n is an integer having a value of at least 1 and m is 0 or 1. The above organopolysiloxane may be reacted with an aromatic tetracarboxylic acid dianhydride and, optionally, with an aromatic diamine to obtain a polyamide acid, which may then be subjected to a thermal imidization step to provide a polyimide having repeating units shown by the formulas VI and VII ##STR3## wherein A.sup.1 is a tetravalent aromatic group, A.sup.3 is a divalent aromatic group and A.sup.
    Type: Grant
    Filed: May 25, 1994
    Date of Patent: December 5, 1995
    Assignee: Dow Corning Corporation
    Inventor: Maki Itoh
  • Patent number: 5457235
    Abstract: The present invention provides liquid crystals that are diphenyldiacetylenes of the general formulas: ##STR1## where W, X, Y and Z are, independently of one another, a halogen atom, a hydrogen atom or a trihalomethyl group, T.sub.1 and T.sub.2, independently of one another can be an alkyl, alkene, alkoxy, alkenoxy, ether, thioalkyl, thioalkenyl, haloalkyl, haloalkoxy or haloalkylether groups having from three to twenty carbon atoms or a silylalkyl, silylalkenyl, silylalkoxy or silylthioalkyl group having from three to twenty-eight carbon atoms and wherein M.sub.1 and M.sub.2 can both be single bonds or one of M.sub.1 or M.sub.2 can be a trans-1,4-cyclohexylene or a --CH.sub.2 CH.sub.2 -trans-1,4-cyclohexylene.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: October 10, 1995
    Assignee: Displaytech, Inc.
    Inventors: Michael D. Wand, Sean D. Monahan, William N. Thurmes, Kundalika M. More
  • Patent number: 5442011
    Abstract: Novel polymeric fluorocarbon siloxane represented by the formula: ##STR1## and corresponding polymeric branched structures wherein R.sub.a is a perfluoroalkyl radical, R.sub.b is an aminoalkyl or substituted aminoalkyl radical and R.sub.c hydrocarbyl, substituted hydrocarbyl phenyl, substituted phenyl or cyanoalkyl radical are shown to form stable aqueous emulsions without the use of volatile organic solvents and by a low energy processing. These emulsion are found to be highly hydrolyzed in solution without leading to precipitation via intermolecular condensation The emulsions when applied to substrates impart both oil and water repellent properties as well as improved lubricity.
    Type: Grant
    Filed: March 4, 1994
    Date of Patent: August 15, 1995
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Robert A. Halling
  • Patent number: 5399737
    Abstract: Novel quaternary ammonium siloxane compounds and methods for their use are disclosed.
    Type: Grant
    Filed: April 4, 1994
    Date of Patent: March 21, 1995
    Assignee: Alcon Laboratories, Inc.
    Inventors: Joonsup Park, Joseph J. Falcetta
  • Patent number: 5344949
    Abstract: Surface active anion-cation complexes are synthesized where an organic or organosilicon compound with at least one epoxide group is reacted with a quaternary ammonium hydrogen sulfite of the general formulaHN.sup.+ (R.sup.1).sub.3 SO.sub.3 H.sup.- IwhereinR.sup.1 within the molecule is the same or different and can be(1) an alkyl or hydroxyalkyl group with 1 to 18 carbon atoms,(2) a phenyl group, or(3) a group of the formula C.sub.n H.sub.2n+1 CONH--(CH.sub.2).sub.m --, in which n can be a number from 7 to 17 and m is 2 or 3,in the presence of a polar solvent in such amounts so that the molar ratio of the epoxide group to HN.sup.+ (R.sup.1).sub.3 SO.sub.3 H.sup.- is 2:1.
    Type: Grant
    Filed: July 14, 1993
    Date of Patent: September 6, 1994
    Assignee: Th. Goldschmidt AG
    Inventors: Gotz Koerner, Klaus-Dieter Klein, Dietmar Schaefer
  • Patent number: 5342983
    Abstract: Organic silicon compounds which are expressed by the general chemical formulae (I) or (II): ##STR1## wherein R.sup.1 is a monovalent organic group with 1 to 8 carbon atoms; R.sup.2, R.sup.3 and R.sup.4 in each equation are independent and either a monovalent organic group with 1 to 8 carbon atoms or a siloxyl group expressed by ##STR2## wherein R.sup.5, R.sup.6 and R.sup.7 are independent in each equation and they are a monovalent organic group with 1 to 8 carbon atoms; and a is either 0, 1 or 2. The novel organic silicon compounds possess both a polymerizable double bond and organopolysiloxane within the same molecule. These compounds are superior in their polymerizability and copolymerizability and are useful as polymer reforming agents.
    Type: Grant
    Filed: March 5, 1993
    Date of Patent: August 30, 1994
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshio Yamazaki, Hideki Sugahara, Shoji Ichinohe, Toshinobu Ishihara, Tohru Kubota
  • Patent number: 5336419
    Abstract: This invention relates to fabric care compositions comprising a silicone gel for ease of ironing and improved appearance after ironing.
    Type: Grant
    Filed: May 8, 1991
    Date of Patent: August 9, 1994
    Assignee: The Procter & Gamble Company
    Inventors: Timothy W. Coffindaffer, Robert G. Bartolo, Kathleen A. Belfiore
  • Patent number: 5304667
    Abstract: The present invention relates to cyclic siloxanes which have at least one group of formula (1) bonded to a silicon atom--(CH.sub.2).sub.x --R"--[--L--A--].sub.y --(L).sub.z --T (1),in which x is an integer having a value of at least 2, preferably having a value of from 2 to 10, R" is a chemical bond or a divalent radical of the formula --COO--, --OOC--, --CH.sub.2 --CH.sub.2 --, --CH.dbd.CH--, --C.tbd.C--, --N.dbd.N--, --N.dbd.N, --N.dbd.CH--, --CH.dbd.N or --Si(R).sub.
    Type: Grant
    Filed: March 29, 1993
    Date of Patent: April 19, 1994
    Assignee: Consortium fur elektrochemische Industrie GmbH
    Inventors: Norman Haeberle, Wolfgang Haas, Franz-Heinrich Kreuzer
  • Patent number: 5300241
    Abstract: The present invention relates to a polyester-fiber-treatment agent that can impart smoothness and flexibility to polyester fiber at the same time that it also equips the polyester fiber with nonflammability. The treatment agent for the polyester fiber is based on an organosilicon compound that contains an organic group comprising a bromine-containing organic group bonded to silicon via carbon where the organosilicon compound has a bromine content of at least 5 weight percent.
    Type: Grant
    Filed: September 28, 1992
    Date of Patent: April 5, 1994
    Assignee: Dow Corning Toray Silicone Co. Ltd.
    Inventors: Ryuzo Mikami, Isao Ona, Masaru Ozaki
  • Patent number: 5286890
    Abstract: Novel aniline terminated silicone monomers with (a) silane (Si--H) functionalities, (b) silanol (Si--OH) functionalities, or (c) alpha,omega-aniline terminated polydimethyl siloxanes, and a novel synthetic route. The alpha,omega-aniline terminated dimethyl siloxanes are prepared, starting with bromoaniline, in which the amine functionality is protected, such as by reaction with 1,1,4,4-tetramethyl-1,4-bis(N,N-diethylamino)-1,4-disilabutane, to form 1-(bromophenyl)-2,2,5,5-tetramethyl-l-aza-2,5-disilacyclopentane. The protected bromoaniline is then reacted with n-butyllithium and chlorodialkylsilane to form 1-((dialkylsilyl)phenyl)-2,2,5,5-tetramethyl-l-aza-2,5-disilacyclopentane. Next, the protected dimethylsilane aniline is subjected to de-protection to form aminophenyldialkyl silane, which is considered to be novel. This silane is then hydrolyzed to form the corresponding silanol, also considered to be novel. The silanol is then condensed to form bis(amino-phenyl)-1,1,3,3-tetraalkyldisiloxane.
    Type: Grant
    Filed: April 16, 1992
    Date of Patent: February 15, 1994
    Assignee: Hughes Aircraft Company
    Inventor: Thomas K. Dougherty
  • Patent number: 5280099
    Abstract: The present invention relates to a series of novel taurine functional silicone polymers, useful in softening hair, and fiber and conditioning skin.Since the compounds of the present invention are high molecular weight silicone polymers, they have a high degree of oxidative stability, even at elevated temperatures.The compounds of the present invention are prepared by the reaction of chloro silicone intermediate with a taurine derivative. In a preferred embodiment the hydroxy containing silicone polymer has been alkoxylated with ethylene oxide, propylene oxide or mixtures thereof. The ability regulate the type of alkylene oxide and amount present in the silicone polymer results in a series of products ranging in water/oil solubility. The technology used to produce the compounds of the present invention is very flexible and allows us to prepare performance tailored molecules for specific applications.
    Type: Grant
    Filed: April 22, 1993
    Date of Patent: January 18, 1994
    Assignees: Siltech Inc., Phoenix Chemical Co.
    Inventors: John Imperante, Anthony J. O'Lenick, Jr.
  • Patent number: 5276123
    Abstract: An alkoxy endblocked polydiorgansiloxane of the formulaZ--(SiR.sub.2 O).sub.n SiR.sub.2 --Zwhere Z is ##STR1## where Y isR.sub.a (R'O).sub.(3-a) Si--,X is ##STR2## in which a is 0 or 1, d has a value of 1 to 3 inclusive, v is 0 or 1, n.ltoreq.8, p has a value of 3 to 6 inclusive, q has a value of 2 to 6 inclusive, r has a value of 4 to 6 inclusive, w is 0 or 1, Me is methyl, R.sup.1 is an alkyl radical having from 1 to 6 inclusive carbon atoms, each R is a monovalent radical independently selected from the group consisting of hydrocarbon radicals and halogenated hydrocarbon radicals, R' is an alkyl radical of 1 to 3 inclusive carbon atoms, R" is a divalent hydrocarbon radical selected from the group consisting of --(CH.sub.2).sub.b -- and --CH(Me)(CH.sub.2).sub.
    Type: Grant
    Filed: September 3, 1992
    Date of Patent: January 4, 1994
    Assignee: Dow Corning Corporation
    Inventors: Russell K. King, Chi-long Lee
  • Patent number: 5262506
    Abstract: There is described an organopolysiloxane which contains at least 2 amino groups, carboxyl groups, hydroxyl groups, or epoxy-functional organic groups at one and only one molecular chain terminal, as well as a method for the preparation of same. The organopolysiloxane has the formula ##STR1## wherein R is a monovalent hydrocarbon group which is free of aliphatically unsaturated bonds and wherein the groups R may be identical or different; A' is selected from the group consisting of groups, the carboxyl group, the hydroxyl group, and epoxy-functional organic groups; B is the same or a different divalent organic group having at least 2 carbon atoms; m is zero or one; and n is an integer with a value of zero to 200.
    Type: Grant
    Filed: April 20, 1992
    Date of Patent: November 16, 1993
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Tadashi Okawa, Shuji Yamada
  • Patent number: 5262507
    Abstract: This invention relates to certain new high modulus silicones, toughened epoxy thermoset resin systems made from those silicones, and composites that are prepared from the new toughened epoxy resin systems. The silicone resins are specifically monophenyl-containing polysiloxanes.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: November 16, 1993
    Assignee: Dow Corning Corporation
    Inventors: Gary T. Decker, Gerald A. Gornowicz
  • Patent number: 5254335
    Abstract: Novel isothiuronium surfactant salts are useful as hair conditioning agents. Aqueous composition containing such salts, and method of using the salts are disclosed.
    Type: Grant
    Filed: July 23, 1992
    Date of Patent: October 19, 1993
    Assignee: Clairol Incorporated
    Inventors: Thomas M. Deppert, Janusz Z. Jachowicz
  • Patent number: 5246607
    Abstract: Methylpolysiloxanes are disclosed which have quaternary ammonium groups linked to silicon atoms via carbon atoms, wherein the ratio of the number of dimethylsiloxy groups to the number of quaternary ammonium groups has a value of 0.5 to 1.5. The methylpolysiloxanes are useful as corrosion inhibitors for preparations consisting predominantly of water, especially coolants, such as cooling lubricants mixed with water, in an amount of 0.01 to 0.1% by weight, based on the total preparation in the form suitable for use.
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: September 21, 1993
    Assignee: Th. Goldschmidt AG
    Inventors: Dietmar Schaefer, Werner Hohner
  • Patent number: 5235082
    Abstract: Compounds of the formula ##STR1## in which R is an alkyl radical having from one to six carbon atoms, a benzyl radical C.sub.6 H.sub.5 CH.sub.2 --, or the radical --(CH.sub.2).sub.2 OH; X.sup.- is halogen selected from the group consisting of chloride, bromide, and iodide, or CH.sub.3 OSO.sub.3 ; and y is an integer having a value of from four to eleven. The compounds have utility as fabric softening and fabric conditioning agents.
    Type: Grant
    Filed: January 8, 1993
    Date of Patent: August 10, 1993
    Assignee: Dow Corning Corporation
    Inventors: Randal M. Hill, Steven A. Snow
  • Patent number: 5231206
    Abstract: Cyclic organosiloxanes which contain at least one Si-bonded organic radical and have at least one donor/acceptor .pi.-electron system.
    Type: Grant
    Filed: November 23, 1990
    Date of Patent: July 27, 1993
    Assignee: Consortium fur elektrochemische Industrie GmbH
    Inventors: Peter Spes, Mechthild HeBling, Franz-Heinrich Kreuzer