Compounds Having The Group -c(=x)-x-nx-, Wherein The X's May Be The Same Or Diverse Chalcogens, Nx Is A Divalent Chalcogen Or A Chain Of Divalent Chalcogens Single Bonded To Each Other, And The Terminal X Is Bonded Directly To Carbon, Which Carbon May Be Single Bonded To Any Atom But May Be Multiple Bonded Only To Carbon (e.g., Percarboxylate Esters, Etc.) Patents (Class 560/302)
  • Patent number: 4874846
    Abstract: Process for the preparation of aryloxy-benzoic acids containing a sulphonamide group by the direct reaction of a phenoxy-benzoic acid with a sulphonamide, in the presence of a halogenating agent such as P(O)Cl.sub.3.
    Type: Grant
    Filed: May 26, 1987
    Date of Patent: October 17, 1989
    Assignee: Rhone-Poulenc Agrochimie S.A.
    Inventor: Alain Chene
  • Patent number: 4859794
    Abstract: New dialkyl esters of monoperoxyoxalic acid which have a tertiary alkyl group in the perester part of the molecule while the other alkyl group is a long-chain, primary alkyl group. The compounds give rise to radicals at heating and are useful as initiators for the polymerization of ethylenically unsaturated monomers, particularly for the polymerization of vinyl chloride.
    Type: Grant
    Filed: December 3, 1987
    Date of Patent: August 22, 1989
    Assignee: Berol Nobel Nacka AB
    Inventors: Claes O. A. Lundin, Erik M. Larsson, Bjorn J. E. Akermark
  • Patent number: 4859356
    Abstract: Disclosed are products derived from the reaction of amine or metal salts of N,N-diorganodithiocarbamic acids with alkylthiosulfinyl halides. These compositions are useful as antioxidants and antiwear additives in lubricating oil compositions.
    Type: Grant
    Filed: August 24, 1988
    Date of Patent: August 22, 1989
    Assignee: Mobil Oil Corporation
    Inventor: Abraham O. M. Okorodudu
  • Patent number: 4831188
    Abstract: Peresters of the formula: R.sub.1 Ar COOOR wherein R is an alkyl group; Ar is selected from the group including phenyl (unsubstituted or substituted) groups, naphthyl groups, anthryl groups, pyryl groups, phenanthryl groups, or heterocyclic groups; and R.sub.1 is any group absorbing radiation between 250 and 800 nm such that R.sub.1 produces an excited state of sufficient lifetime to cause the decomposition to free radicals of the appended perester or peroxidic function.
    Type: Grant
    Filed: January 20, 1987
    Date of Patent: May 16, 1989
    Assignee: Bowling Green State University
    Inventor: Douglas C. Neckers
  • Patent number: 4786746
    Abstract: A method of preparing a compound useful as a brightener in aqueous copper electroplating solutions comprising reacting a compound of the following formula: ##STR1## with a compound of the formula:HS--R.sub.2 --Z.sub.nwherein:R.sub.1 and R.sub.2 each is an alkyl containing from 2 to 8 carbon atoms, an aryl, an alkylaryl, an arylalkyl or a heterocyclic group containing at least one nitrogen atom in its ring;X, Y and Z each is hydrogen or a water-solubilizing group; andn is an integer of from 1 to 4; provided that:when R.sub.1 is a heterocyclic group, X, Y and Z are hydrogen and R.sub.2 is an alkyl containing from 2 to 8 carbon atoms, an aryl, an alkylaryl or an arylalkyl;when R.sub.2 is a heterocyclic group, X, Y and Z are hydrogen and R.sub.1 is an alkyl containing from 2 to 8 carbon atoms, an aryl, an alkylaryl or an arylalkyl;when X or Y is a water-solubilizing group, R.sub.
    Type: Grant
    Filed: September 18, 1987
    Date of Patent: November 22, 1988
    Assignee: Pennsylvania Research Corporation
    Inventor: Momcilo Miljkovic
  • Patent number: 4777191
    Abstract: Photopolymerization initiators of the general formula: ##STR1## wherein R.sub.1 and R.sub.1 ' independently stand for a tertiary alkyl group or a tertiary aralkyl group and R.sub.2 and R.sub.2 ' independently stand for a hydrogen atom, a tertiary alkoxy group, or a tertiary aralkyloxy group are disclosed. They are useful for effecting polymerization of radically polymerizable unsaturated compounds. Tetra peroxy esters of benzophenone are preferred.
    Type: Grant
    Filed: November 5, 1987
    Date of Patent: October 11, 1988
    Assignee: Nippon Oil & Fats Co., Ltd.
    Inventors: Takeshi Komai, Mamoru Shimizu
  • Patent number: 4752649
    Abstract: Peresters of the formula: ROOC--R.sub.1 --COOOR wherein R is an alkyl group; R.sub.1 is selected from the group including ketone (unsubstituted or substituted) groups, and R.sub.1 is any group absorbing radiation between 250 and 800 nm such that R.sub.1 produces an excited state of sufficient lifetime to cause the decomposition to free radicals of the appended perester or peroxidic function.
    Type: Grant
    Filed: August 27, 1984
    Date of Patent: June 21, 1988
    Assignee: Bowling Green State University
    Inventor: Douglas Neckers
  • Patent number: 4705888
    Abstract: This disclosure relates to novel peroxy esters carrying a t-alkenyl, e.g. 2-methyl-3-butene-2-yl, peroxy group. These peroxy esters have shorter half-life periods of decomposition and are more reactive polymerization initiators and unsaturated polyester resin curing agents than the corresponding prior art peroxy esters carrying a t-alkyl, e.g. t-amyl, peroxy group.
    Type: Grant
    Filed: September 4, 1986
    Date of Patent: November 10, 1987
    Assignee: Akzo NV
    Inventors: John Meijer, Hans Westmijze, Eltjo Boelema
  • Patent number: 4604295
    Abstract: Compounds represented by the formula: ##STR1## wherein R.sup.1 is alkyl, aralkyl, alkoxyalkyl, alkenyl, alkynyl, carboxyalkyl or carboxyaryl;R.sup.2 is any group which does not cause spontaneous decomposition of the peroxy group; andx and y are integers between 0 and 4 with x+y great than or equal to 1, are disclosed.The inventive compounds are useful as visible and UV photoinitiators and as thermal or chemical initiators for curing compositions of ethylenically unsaturated monomers and prepolymers.
    Type: Grant
    Filed: December 22, 1983
    Date of Patent: August 5, 1986
    Assignee: Loctite Corporation
    Inventor: Robert W. R. Humphreys