Aldehyde Reactant Patents (Class 568/433)
  • Patent number: 4284823
    Abstract: There is disclosed a process comprising reacting a compound having the general structural Formula II: ##STR1## with a compound having the general Formula III: ##STR2## in the presence of a basic catalyst while dissolved in an organic solvent to yield an aldehyde having the structural Formula I: ##STR3## wherein R.sub.1 and R.sub.2 are the same or different radicals selected from the group consisting of tertiary alkyl radicals having from 4 to 12 carbon atoms, R.sub.3 and R.sub.4 are the same or different radicals selected from the group consisting of alkyl radicals containing from 1 to 12 carbon atoms, cycloalkyl radicals containing from 5 to 12 carbon atoms, phenyl and substituted phenyl radicals or R.sub.3 and R.sub.4 with the carbon atom to which they are joined may form a cycloalkyl ring of from 5 to 12 carbon atoms, R.sub.5 is selected from the group consisting of hydrogen, alkyl radicals containing from 1 to 12 carbon atoms, or a cycloalkyl radical containing 5 or 6 carbon atoms.
    Type: Grant
    Filed: October 15, 1979
    Date of Patent: August 18, 1981
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Richard H. Kline
  • Patent number: 4281207
    Abstract: Disclosed herein are monomeric compounds having the formula (I): ##STR1## wherein: R, R.sup.1, R.sup.2 and R.sup.3 are independently hydrogen or alkyl having from 1 to 4 carbon atoms;R.sup.4 is arylene having 6 to 18 carbon atoms;m is an integer from 1 to 4; andn is an integer from 0 to 4.These monomers can be homopolymerized or copolymerized with one or more other polymerizable monomers, and can particularly be copolymerized with those monomers having substituents which are susceptible to attack or degradation by a base. The resulting crosslinkable polymers are useful in relief image materials, such as photoresists and lithographic plates.
    Type: Grant
    Filed: October 26, 1979
    Date of Patent: July 28, 1981
    Assignee: Eastman Kodak Company
    Inventor: John C. Wilson
  • Patent number: 4275242
    Abstract: A process for preparing 2-methylenealdehydes by reacting aldehydes with formaldehyde in the presence of enamines is disclosed.
    Type: Grant
    Filed: December 21, 1979
    Date of Patent: June 23, 1981
    Assignee: Ruhrchemie Aktiengesellschaft
    Inventors: Jurgen Weber, Wolfgang Bernhagen, Helmut Springer
  • Patent number: 4268444
    Abstract: A process for the preparation of polyene-aldehydes, derived from 2,6-dimethyl-2,4,6,8-nonatetraen-1-al by substitution in the 9-position, by means of the Wittig ylide synthesis. The process is based on the observation, contrary to all expectation, that on reacting 2,6-dimethyl-octa-2,4,6-triene-1,8-dial with an equimolar amount of an ylide, it is exclusively the 8-al group of the dialdehyde which reacts. This specificity of the reaction is of particular importance for the preparation of the food dye .beta.-apo-8'-carotinal.
    Type: Grant
    Filed: November 16, 1979
    Date of Patent: May 19, 1981
    Assignee: BASF Aktiengesellschaft
    Inventor: Hagen Jaedicke
  • Patent number: 4263212
    Abstract: The present invention relates to a process for the preparation of aromatic or furyl substituted olefins, which comprises reacting an olefinic compound with an aromatic compound or furan compound in the presence of carbon monoxide by using a rhodium carbonyl complex as a catalyst to form a corresponding aromatic or furyl substituted olefin.
    Type: Grant
    Filed: February 14, 1980
    Date of Patent: April 21, 1981
    Assignee: Rikagaku Kenkyusho
    Inventors: Pangbu Hong, Hiroshi Yamazaki
  • Patent number: 4239657
    Abstract: Aldehydes or ketones of not less than 4 or 5 carbon atoms, respectively, are manufactured in a one stage process in the liquid phase by subjecting aldehydes and/or ketones of not less than 2 or 3 carbon atoms, respectively, to an aldol condensation and hydrogenating the resulting olefinically unsaturated aldehyde, the catalyst used for the aldol condensation and hydrogenation containing nickel or cobalt or their mixtures, zinc oxide and at least one of the elements iron, arsenic, antimony, bismuth, gallium, indium, thallium, germanium, tin, lead, cadmium and mercury or compounds of the said elements.
    Type: Grant
    Filed: February 12, 1979
    Date of Patent: December 16, 1980
    Assignee: BASF Aktiengesellschaft
    Inventors: Axel Nissen, Gerd Heiien, Ekkehard Sapper, Werner Fliege, Arnold Wittwer
  • Patent number: 4231967
    Abstract: Salicylaldehydes useful for perfumes, agricultural chemicals, chelating agents and the like are produced in high yield with high selectivity by reacting formaldehyde or its derivative with a corresponding phenol in a solvent using as a catalyst chromium or iron compounds.
    Type: Grant
    Filed: June 8, 1979
    Date of Patent: November 4, 1980
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Teruo Matsuda, Tetsuo Murata
  • Patent number: 4218567
    Abstract: A process for the preparation of aromatic ethers by the bromination of a compound of the formula ##STR1## wherein R.sub.1, independently, is hydrogen, hydroxy, lower alkoxy, lower alkyl; m is an integer from 1-4, and A is --CHO, --COOR.sub.3 or lower alkyl, and subsequently treating the reaction product of the bromination step with an alkali metal alkoxide in the presence of cuprous halide or oxide, is described.
    Type: Grant
    Filed: May 30, 1978
    Date of Patent: August 19, 1980
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Percy S. Manchand, John M. Townsend
  • Patent number: 4215044
    Abstract: Process for preparing an organic compound of the formula R.sup.2 R.sup.2 CFC(O)R.sup.3, which process comprises contacting and reacting in a reaction mixture which includes an inert solvent, at a temperature of -40.degree. C. to -100.degree. C., ROF and ##STR1## R is polyfluoroperhaloalkyl of 1-6 carbon atoms or FOCF.sub.2 ; R.sup.1 is hydrocarbyl of 1-6 carbon atoms;each R.sup.2 is selected from H, alkyl of 1-17 carbon atoms, cycloalkyl of 3-6 carbon atoms, aryl, heteroaryl and such alkyl, cycloalkyl, aryl and heteroaryl substituted by halogen or alkoxy of 1-6 carbon atoms;R.sup.3 is selected from H, alkyl and haloalkyl of 1-16 carbon atoms, cycloalkyl of 3-10 carbon atoms, aryl and haloaryl, OSi(R.sup.1).sub.3, OH, NH.sub.2, alkoxy of 1-6 carbon atoms, aryloxy, NHR.sup.1 and NR.sup.1.sub.2 wherein R.sup.1 is alkyl of 1-6 carbon atoms, N-arylamino and nitrogen or sulfur heterocyclic of 4-5 carbon atoms;R.sup.3 and one R.sup.2 taken together is a diradical which with the C.dbd.
    Type: Grant
    Filed: April 23, 1979
    Date of Patent: July 29, 1980
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: William J. Middleton
  • Patent number: 4212829
    Abstract: A process for preparing m-(p-bromophenoxy)benzaldehyde of the formula, ##STR1## characterized by brominating m-phenoxybenzaldehyde with bromine or bromine chloride as a brominating agent.
    Type: Grant
    Filed: January 22, 1979
    Date of Patent: July 15, 1980
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tadashi Ohsumi, Nobushige Itaya
  • Patent number: 4211726
    Abstract: There is provided a process for the manufacture of substituted 9,10-anthracenedicarboxaldehydes and substituted 9,10-dihydro-9,10-anthracenedicarboxaldehydes useful as intermediates in the preparation of antibacterial agents.
    Type: Grant
    Filed: February 16, 1979
    Date of Patent: July 8, 1980
    Assignee: American Cyanamid Company
    Inventors: Yang-I Lin, Stanley A. Lang, Jr.
  • Patent number: 4203980
    Abstract: Benzylpyrimidines of the formula ##STR1## wherein R.sup.1 and R.sup.2, independently, are C.sub.1-6 -alkyl, R.sup.3 isC.sub.1-3 -alkyl and R.sup.4 is methylene or C.sub.2-4 -alkylideneand physiologically compatible acid addition salts thereof, are described. The compounds of formula I are useful as antibacterial agents and as potentiators of sulfonamides.
    Type: Grant
    Filed: April 26, 1978
    Date of Patent: May 20, 1980
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Ivan Kompis, Alexander E. Wick