From Substance Which Includes Sulfur Or A Sulfur Containing Compound Patents (Class 568/759)
  • Patent number: 11421629
    Abstract: A reforming system includes a vaporizer configured to vaporize liquid fuel to produce fuel gas; a reformer configured to reform the fuel gas produced by the vaporizer to produce a reformed gas containing hydrogen; an air supplier configured to supply air to the reformer; a fuel gas supplier configured to supply the fuel gas to the reformer; a heater configured to increase a temperature of the reformer; a reformed gas flow passage through which the reformed gas produced by the reformer flows; a cooler disposed in the reformed gas flow passage and configured to cool the reformed gas; a circulation passage connecting the vaporizer with the cooler and through which refrigerant flows through the vaporizer and the cooler; and a circulation pump disposed in the circulation passage and configured to circulate the refrigerant through the circulation passage.
    Type: Grant
    Filed: December 23, 2019
    Date of Patent: August 23, 2022
    Assignee: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI
    Inventor: Yoshitaka Takeuchi
  • Patent number: 8501999
    Abstract: The process provided herein is concerned with recovery of hydrocarbons from sulfones using an individual alkali and alkaline-earthy base and a mixture of thereof. As the starting materials are sulfones generated by ODS and commercially inexpensive alkali and alkaline-earth bases, the cost and ecological impact of solid waste disposal is minimized.
    Type: Grant
    Filed: November 4, 2010
    Date of Patent: August 6, 2013
    Assignees: Saudi Arabian Oil Company, The Chancellor, Masters and Scholars of the University of Oxford
    Inventors: Farhan M. Al-Shahrani, Tiancun Xiao, Huahong Shi, Malcolm L. H. Green
  • Patent number: 8088956
    Abstract: The present disclosure enables phenol recovery, purification and recycle in a simple, economic manner from waste streams from, for example, a phenol/acetone production process, e.g., a phenol/acetone plant or an upstream cumene hydroperoxide cleavage process step, and BPA production step, for use in the reaction with acetone to produce BPA. The disclosure therefore reduces the overall consumption of phenol in the production of BPA.
    Type: Grant
    Filed: January 14, 2011
    Date of Patent: January 3, 2012
    Assignee: Stone & Webster, Inc
    Inventor: David P. Palmer
  • Publication number: 20110213187
    Abstract: The process provided herein is concerned with recovery of hydrocarbons from sulfones using an individual alkali and alkaline-earthy base and a mixture of thereof. As the starting materials are sulfones generated by ODS and commercially inexpensive alkali and alkaline-earth bases, the cost and ecological impact of solid waste disposal is minimized.
    Type: Application
    Filed: November 4, 2010
    Publication date: September 1, 2011
    Inventors: Farhan M. Al-Shahrani, Tiancun Xiao, Huahong Shi, Malcolm L.H. Green
  • Publication number: 20110112333
    Abstract: The present disclosure enables phenol recovery, purification and recycle in a simple, economic manner from waste streams from, for example, a phenol/acetone production process, e.g., a phenol/acetone plant or an upstream cumene hydroperoxide cleavage process step, and BPA production step, for use in the reaction with acetone to produce BPA. The disclosure therefore reduces the overall consumption of phenol in the production of BPA.
    Type: Application
    Filed: January 14, 2011
    Publication date: May 12, 2011
    Applicant: STONE & WEBSTER, INC
    Inventor: David P. Palmer
  • Patent number: 7902408
    Abstract: The present disclosure enables phenol recovery, purification and recycle in a simple, economic manner from waste streams from, for example, a phenol/acetone production process, e.g., a phenol/acetone plant or an upstream cumene hydroperoxide cleavage process step, and BPA production step, for use in the reaction with acetone to produce BPA. The disclosure therefore reduces the overall consumption of phenol in the production of BPA.
    Type: Grant
    Filed: May 1, 2008
    Date of Patent: March 8, 2011
    Assignee: Stone & Webster, Inc.
    Inventor: David P. Palmer
  • Publication number: 20080281129
    Abstract: The present disclosure enables phenol recovery, purification and recycle in a simple, economic manner from waste streams from, for example, a phenol/acetone production process, e.g., a phenol/acetone plant or an upstream cumene hydroperoxide cleavage process step, and BPA production step, for use in the reaction with acetone to produce BPA. The disclosure therefore reduces the overall consumption of phenol in the production of BPA.
    Type: Application
    Filed: May 1, 2008
    Publication date: November 13, 2008
    Inventor: David P. Palmer
  • Patent number: 6680413
    Abstract: A process is described for the recovery of phenol and biphenols from their homogeneous mixtures containing benzene, sulfolane and water, which is based on the use of an alkaline solution and benzene for the separation of biphenols from sulfolane, after removing the benzene, H2O and phenol contained in the reaction effluent. The process allows the recovery of phenol and biphenol by-products dissolved in sulfolane, directly obtaining the purified solvent containing the benzene necessary for the feeding to the reactor for the direct oxidation of benzene, as well as the biphenols dissolved in water and pure phenol.
    Type: Grant
    Filed: May 21, 2003
    Date of Patent: January 20, 2004
    Assignee: Polimeri Europa S.p.A.
    Inventors: Rossella Bortolo, Lino Carnelli, Daniele Moscotti, Daniele Bianchi
  • Patent number: 6066767
    Abstract: Purification of cumene hydroperoxide cleavage products from hydroxyacetone and carbonyl compounds is accomplished via extraction of hydroxyacetone and carbonyl compounds from cleavage products with a circulating water-salt solution in an extractor during an extraction stage and subsequent conversion of hydroxyacetone and other carbonyl compounds into deep condensation products in a HAC reactor operating as a plug-flow reactor or mixing reactor or as their combination. The conversion/condensation process is conducted in the water-salt solution by treating the hydroxyacetone and carbonyl compounds with alkaline agents. Various homogenous and/or heterogeneous alkaline catalysts may be used. Optionally multiple sequential extraction stages may be connected to the HAC reactor for improved performance.
    Type: Grant
    Filed: February 10, 1999
    Date of Patent: May 23, 2000
    Assignee: ILLA International, LLC
    Inventors: Vladimir Mikhailovitch Zakoshansky, Irina Ivanovna Vassilieva
  • Patent number: 5491268
    Abstract: A process for purifying phenol, phenol-type compounds, and substituted phenol and phenol-type compounds of contamination by components more acidic than the phenol component comprising treating a phenol containing process stream by contacting the stream with an amphoteric porous inorganic oxide.
    Type: Grant
    Filed: September 23, 1994
    Date of Patent: February 13, 1996
    Assignee: General Electric Company
    Inventor: Michael J. Cipullo
  • Patent number: 5354429
    Abstract: A discrete impure cresylic acid distillate fraction derived by fractional distillation of a natural cresylic acid feedstock from which tar bases and/or neutral oils have not been removed is subjected to extractive distillation with a polyhydric alcohol extractant and subsequent separation of the discrete cresylic acid fraction. The extractive distillation removes tar bases, neutral oils, undesirable phenolic substances, sulfur compounds, color-forming impurities and odor-imparting impurities.
    Type: Grant
    Filed: July 2, 1993
    Date of Patent: October 11, 1994
    Assignee: Dakota Gasification Company
    Inventors: David H. Duncan, Gene G. Baker, Dana J. Maas, Kevin M. Mohl, Robert G. Todd
  • Patent number: 5344528
    Abstract: Phenol plant waste water containing small amounts of phenol and sodium sulfate is successfully distilled through the addition of recovered sodium sulfate to enhance the volatility of the phenol relative to water; at least a portion of the sodium sulfate is recycled, while a significant portion of the phenol can be returned to the phenol plant for recovery.
    Type: Grant
    Filed: August 4, 1993
    Date of Patent: September 6, 1994
    Assignee: Aristech Chemical Corporation
    Inventors: Thomas H. Bossler, Donald Glassman, Michael C. Grebinoski, Howard H. Morgan, Jr., Jennifer L. Voss
  • Patent number: 4992599
    Abstract: Crude phenol and also individual phenol fractions from tars or the hydrogenation of coal are purified from contaminating organic bases and sulfur compounds by treating the phenols with phthalic acid anhydride and optionally a quinone and distillation.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: February 12, 1991
    Assignee: Rutgerswerke AG
    Inventors: Jorg Talbiersky, Bernhard Wefringhaus, Konrad Stolzenberg, Wolfgang Bergins
  • Patent number: 4943665
    Abstract: Novel, self-curing resins are produced by di(hydroxyphenyl) compound and an arylcyclobutenealkyl compound. The resulting di(hydroxyphenyl) compound (di(arylcyclobutenealkyl) ethers cure upon heating to produce rigid thermosets of relatively high glass transition temperature and heat stability.
    Type: Grant
    Filed: May 9, 1989
    Date of Patent: July 24, 1990
    Assignee: Shell Oil Company
    Inventor: Pui-Kwan Wong
  • Patent number: 4443636
    Abstract: There is disclosed a process for removing tar bases and neutral oils from the Lurgi tar acids by treating the tar acids with aqueous sodium bisulfate to change the tar bases to salts and to hydrolyze the neutral oils to hydrolysis products and distilling the tar acids to obtain refined tar acid as the distillate while the tar base salts and neutral oil hydrolysis products remain as residue.
    Type: Grant
    Filed: July 14, 1982
    Date of Patent: April 17, 1984
    Assignee: Koppers Company, Inc.
    Inventor: Nicholas P. Greco
  • Patent number: 4429170
    Abstract: A process is disclosed for purifying the tar acid mixture that is obtained from the Lurgi process of coal gasification. The tar acid is treated with dilute aqueous sulfuric acid solution to form non-volatile tar base salts from the tar base component and to hydrolyze the neutral oil component and then distilling the tar acid component off from the non-volatile tar base salts and the hydrolysis products of the neutral oil component.
    Type: Grant
    Filed: July 14, 1982
    Date of Patent: January 31, 1984
    Assignee: Koppers Company, Inc.
    Inventor: Robert L. Lovell
  • Patent number: 4356330
    Abstract: A method of eliminating color-causing impurities in mixtures of t-butyl alkylphenols by treatment with N-(2-hydroxyethyl)oxazolidine at 90.degree. C. and at atmospheric pressure is described. These phenols are used as peroxide inhibitors in polyoxyalkylene glycols for polyurethane foams. Discoloration of the polyol occurs if the phenol mixture is not treated with N-(2-hydroxyethyl)oxazolidine. The t-butyl alkylphenol mixture is derived from an alkylphenol made over an acid catalyst.
    Type: Grant
    Filed: July 20, 1981
    Date of Patent: October 26, 1982
    Assignee: Texaco Inc.
    Inventors: Michael Cuscurida, George P. Speranza
  • Patent number: 4327229
    Abstract: An improved process is described for recovery of some of the bisphenol-A values present in the waste streams in an acid-catalyzed bisphenol-A synthesis process.
    Type: Grant
    Filed: January 19, 1981
    Date of Patent: April 27, 1982
    Assignee: General Electric Company
    Inventor: Ashok K. Mendiratta
  • Patent number: 4208280
    Abstract: Covers a method of separating a nonionic surfactant from an anionic surfactant by use of cyclohexanone.
    Type: Grant
    Filed: February 13, 1978
    Date of Patent: June 17, 1980
    Assignee: Texaco Development Corp.
    Inventor: Carter G. Naylor
  • Patent number: 4162902
    Abstract: A process for removing phenols from waste water resulting from the gasification or carbonization of coal and containing CO.sub.2, H.sub.2 S and NH.sub.3, comprising mixing the waste water with a low-boiling organic solvent, separating the mixture into a solvent layer and an aqueous layer, stripping off from the aqueous layer under superatmospheric pressure the vapors of CO.sub.2, H.sub.2 S and organic solvent contained therein, then stripping off from the aqueous layer the NH.sub.3 contained therein leaving a refined aqueous product layer suitable for discharge, scrubbing the stripped vapors under superatmospheric pressure with a portion of the cold refined product to remove organic solvent contained therein, condensing part of the solvent and separating it under superatmospheric pressure, and scrubbing the remaining acid gases still containing ammonia and solvent with recirculated cooled raw phenol to remove the ammonia and solvent.
    Type: Grant
    Filed: September 30, 1977
    Date of Patent: July 31, 1979
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Paul Wiesner, Hans-Martin Stonner
  • Patent number: 4113975
    Abstract: A process for the removal of acids and potential acid-forming agents from a composition containing such acids and potential acid-forming agents and an alkylphenol which composition is obtained by reacting phenols with alkenes in the presence of sulfuric acid or a sulfonic acid, and for treating the effluent thereby obtained, the process being characterized by the steps of:(a) extracting a major amount of the acid constituents from the alkylphenol mixture by means of water;(b) treating the alkylphenol mixture with a dilute aqueous alkali solution in an amount such that the alkali is insufficient to neutralize all the acid originally present in the alkylphenol mixture,(c) separating the alkylphenol mixture from the aqueous alkali solution;(d) combining the aqueous phases obtained from steps (a) and (b);(e) heating the combined aqueous phases to a temperature of 100.degree. to 200.degree. C,(f) separating off the organic phase obtained in step (e); and(g) discharging the aqueous phase.
    Type: Grant
    Filed: January 6, 1977
    Date of Patent: September 12, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Fiege, Josef Haydn, Johann Renner, Karlfried Wedemeyer