Patent number: 9085505
Abstract: This invention provides a method for highly efficient catalytic conversion of cellulosic raw materials to glycols. In the process, cellulosic compounds such as crop stalk, wood powder and etc., as feedstock are subjected to one-step catalytic conversion with a ternary composite catalyst composed of organic acid or inorganic acid which does not contain tungsten, a transition metal from Groups 8, 9 or 10 such as iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum, or a mixture thereof, and a tungsten oxide, a tungsten sulfide, a tungsten chloride, a tungsten hydroxide, tungsten bronze, tungstic acid, a tungstate, a metatungstate acid, a metatungstate, a paratungstate acid, a paratungstate, a peroxotungstic acid, pertungstate and heteropoly tungstate, or a mixture thereof. The reaction is carried out under hydrothermal conditions at a temperature between 120-300° C. with hydrogen pressure between 1-13 MPa.
Type:
Grant
Filed:
May 16, 2013
Date of Patent:
July 21, 2015
Assignee:
DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES
Inventors:
Tao Zhang, Jifeng Pang, Mingyuan Zheng, Yu Jiang, Aiqin Wang
Publication number: 20140249334
Abstract: Ethylene glycol and propylene glycol may be made by hydrogenolysis of a polyol comprising the steps of reacting a polyol with hydrogen in the presence of a hydrogenolysis catalyst. The hydrogenolysis comprises nickel, one or more promoter, and one or more support. The promoter is selected from bismuth, silver, tin, antimony, gold, lead, thallium, cerium, lanthanum, and manganese. The support is selected from zirconia and carbon. A zirconia support comprises a zirconia textual promoter, which is selected from Cr, Mo, W, Nb, Ce, Ca, Mg, La, Pr, Nd, Al, and P. If the support comprises carbon, then the promoter is selected from bismuth and antimony. In another embodiment, if the support comprises carbon, then both the promoter is selected from bismuth and antimony, and the catalyst comprises copper. In another embodiment, the catalyst additionally comprises copper.
Type:
Application
Filed:
March 1, 2013
Publication date:
September 4, 2014
Applicant:
Clariant Corporation
Inventors:
Aaron B. MILLER, Malati RAGHUNATH, Valery SOKOLOVSKII, Claus G. LUGMAIR, Anthony F. VOLPE, JR., Wenqin SHEN, Wayne TURBEVILLE