To Prevent Or Reduce Polymerization Patents (Class 570/103)
  • Patent number: 9347446
    Abstract: A refrigerant compressor configured to compress ethylene fluorohydrocarbon or a mixture containing the ethylene fluorohydrocarbon as a refrigerant, the refrigerant compressor including: a compression element configured to compress the refrigerant and including a sliding component that constitutes a sliding portion; and refrigerator oil configured to be supplied to the sliding component so as to lubricate the sliding portion, wherein a polymerization inhibitor configured to suppress polymerization of the refrigerant is contained in the refrigerator oil.
    Type: Grant
    Filed: March 21, 2014
    Date of Patent: May 24, 2016
    Assignee: Mitsubishi Electric Corporation
    Inventors: Hideaki Maeyama, Koichi Sato
  • Patent number: 8118995
    Abstract: A method for inhibiting the formation of fouling materials including contacting hydrocarbon media containing aldehyde compounds with an antifoulant while treating the hydrocarbon media with a basic wash. The antifoulant includes a reducing sugar.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: February 21, 2012
    Assignee: General Electric Company
    Inventors: Mary King, Cato Russell McDaniel
  • Publication number: 20100181524
    Abstract: Disclosed is a combination of hydrofluoroolefins and/or hydrochlorofluoroolefins with stabilizers wherein the stabilizers minimize the degradation of the hydrofluoroolefins and hydrochlorofluoroolefins during storage, handling and use yet allow for atmospheric degradation. The combinations exhibit low or zero ozone depletion potential and lower global warming potential making them of interest as replacements for chlorofluorocarbons and hydrfluorocarbons. The combinations of the present invention comprise hydrofluoroolefins and/or hydrochlorofluoroolefins in combination with a stabilizer or stabilizers selected from free radical scavengers, acid scavengers, oxygen scavengers, polymerization inhibitors and combinations thereof.
    Type: Application
    Filed: June 27, 2008
    Publication date: July 22, 2010
    Applicant: ARKEMA INC.
    Inventors: Maher Y. Elsheikh, Philippe Bonnet, Benjamin Bin Chen, Brett L. Van Horn
  • Patent number: 5932775
    Abstract: To avoid the formation of acidity in an F125 containing olefins, a radical scavenger and/or an acidity scavenger is added to it.
    Type: Grant
    Filed: November 4, 1997
    Date of Patent: August 3, 1999
    Assignee: Elf Atochem S.A.
    Inventors: Eric Lacroix, Jean-Marc Sage
  • Patent number: 5652147
    Abstract: There is provided a precisely quantitative measurement method of a hydrocarbonaceous polymerization inhibitor component in a fluorine-containing olefinic monomer, which inhibitor component is contained in the monomer in such a trace amount that it cannot be detected by a gas chromatography. In the method, an ultraviolet absorption spectrum of a concentrated sulfuric acid is measured after it is contacted with the fluorine-containing olefinic monomer and the concentration of the polymerization inhibitor is obtained based on an absorbance of the spectrum and a calibration curve which has been beforehand obtained.
    Type: Grant
    Filed: March 20, 1996
    Date of Patent: July 29, 1997
    Assignee: Daikin Industries, Ltd.
    Inventors: Takuo Kawamura, Shigeru Ichiba, Tomizo Soda
  • Patent number: 5345013
    Abstract: Tetrafluoroethylene is made safe (non-explosive) to handle by forming a liquid solution of tetrafluoroethylene and carbon dioxide, one in the other, in a pressurized container.
    Type: Grant
    Filed: June 10, 1993
    Date of Patent: September 6, 1994
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: David J. Van Bramer, Mark B. Shiflett, Akimichi Yokozeki
  • Patent number: 5220081
    Abstract: A triethylene glycol derivative is added to p-dichlorobenzene so as to prevent consolidation and improve flowability of p-dichlorobenzene.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: June 15, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Ryuichi Mita, Nobuo Shimuta, deceased, Mamoru Ueda, Yosiro Nagatake, Toyohiro Tajiri
  • Patent number: 5110997
    Abstract: A method of inhibiting fouling in a crude ethylene dichloride stream comprises introducing into the stream an inhibiting amount of an antifoulant selected from (A) an acylated amine (e.g., reaction product of polyisobutylene and maleic anhydride) and a polyamine (B) magnesium alkyl aryl sulfonate, and (C) a mixture of A and B.
    Type: Grant
    Filed: April 19, 1991
    Date of Patent: May 5, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Ghazi B. Dickakian
  • Patent number: 4376221
    Abstract: Dibromostyrene is stabilized against unwanted polymerization by incorporating therein a stabilizing amount of a phenylene diamine such as N,N,N',N'-tetramethylphenylene-p-diamine or N,N'-diethylphenylene-p-diamine.
    Type: Grant
    Filed: March 13, 1980
    Date of Patent: March 8, 1983
    Inventor: Philip F. Jackisch
  • Patent number: 4343956
    Abstract: Dibromostyrene has a marked tendency to polymerize on storage. The induction period can be lengthened with the use of a stabilizing quantity of n-propylgallate. The induction period can be markedly prolonged when the gallate ester is admixed with phenothiazine, N,N,N',N'-tetramethyl-p-phenylenediamine, or 4-tert-butyl catechol.
    Type: Grant
    Filed: June 18, 1981
    Date of Patent: August 10, 1982
    Assignee: Ethyl Corporation
    Inventor: Philip F. Jackisch
  • Patent number: 4276189
    Abstract: Mixing dibromostyrene with a metal oxide such as zinc oxide lengthens the induction period before polymerization of dibromostyrene. Preferably, the dibromostyrene has low levels of 2-bromoethyldibromobenzene and tribromostyrene impurities.
    Type: Grant
    Filed: March 13, 1980
    Date of Patent: June 30, 1981
    Assignee: Ethyl Corporation
    Inventor: Philip F. Jackisch