Abstract: A dry liquid propane substantially free from HF, organic fluorides and water is produced by bringing into intimate contact with a sodium hydroxide solution containing not more than about 5 percent by weight NaOH a liquid propane stream obtained by heating a stream of the propane containing organic fluoride and bringing said stream in contact with a defluorinating agent, e.g., aluminum fluoride, to produce a stream of propane containing HF, the stream of propane containing organic fluorides having been obtained from a hydrogen fluoride stripper operated in conjunction with a depropanizing zone wherein an HF alkylation hydrocarbon product stream or effluent is depropanized. In an embodiment only a relatively small volume of propane containing HF is contacted with the aqueous sodium hydroxide solution whereupon the intermingled fluids are immediately passed into a body of settling propane and aqueous sodium hydroxide solution in a settling zone or vessel.

Abstract: An improved HF alkylation process comprising, in series, HF and isoparaffin flow and parallel injection of at least two different olefins into a vertically extended reaction zone coupled with recycle of some of the alkylation hydrocarbon effluent to each point of olefin introduction into the alkylation zone. The improved alkylation system allows minimum sized fractionation and extremely high isoparaffin/olefin ratios with temperature control of the reaction at each olefin injection.