Abstract: A process is disclosed for the production of synthetic hydrocarbon lubricants having high viscosity index by oligomerizing a mixture of alpha-olefins comprising the reaction product from the thermal cracking of refined wax. The oligomerization is carried out with Lewis acid catalyst or reduced chromium oxide on porous support.
Abstract: Blended gasolines are produced by the mixing of a butane-pentane rich component, a natural gasoline component, and at least one octane-enhancing component. The mix is weathered during the blending operation to remove light-weight hydrocarbons comprising two, three and four-carbon components. The light-weight hydrocarbons, which preferably constitute less than 3 percent of the blended gasoline, can be recovered to generate power to run the process. The liquid gasoline mixture is formulated to produce a desired octane rating, an environmentally acceptable vapor pressure, and a mix which, when burned in an internal combustion engine, produces a minimum amount of pollutants.
Abstract: A process for producing substantially linear hydrocarbons by oligomerizing a lower olefin at elevated temperature and pressure which comprises contacting the lower olefin under oligomerization/polymerization conditions with siliceous acidic ZSM-23 zeolite having Bronsted acid activity; wherein the zeolite has acidic pore activity and wherein the zeolite surface is rendered substantially inactive for acidic reactions. The zeolite surface can be neutralized by a bulky pyridine compound having an effective cross-section larger than the zeolite pore. The preferred deactivating agent is 2,4,6-collidine, which may be applied to the zeolite as a pretreatment or added with olefin feed in a continuous process. The olefin oligomers may be used as alkylating agents to prepare biodegradable alkylbenzenes and alkylphenylsulfonates. A preferred catalyst for this alkylation reaction is dealuminized mordenite.
Type:
Grant
Filed:
July 18, 1989
Date of Patent:
June 25, 1991
Assignee:
Mobil Oil Corporation
Inventors:
David A. Blain, Nancy M. Page, Lewis B. Young
Abstract: Hydrocarbyl substituted cyclopentadienes, cyclopentenes, and cyclopentanes and synthetic lubricating compositions. The preferred structures contain 1 to 6 alkyl groups which have 4 to 36 carbon atoms and may have different and varying carbon chain structures. The cyclopentenes and cyclopentanes are prepared by hydrogenation from the corresponding cyclopentadiene intermediates. The cyclopentadienes are prepared by reaction with hydrocarbylating agents or alcohols. Mixtures are also disclosed.
Abstract: Hydrocarbyl substituted cyclopentadienes, cyclopentenes, and cyclopentanes are synthetic lubricating compositions. The preferred structures contain 1 to 6 alkyl groups which have 4 to 36 carbon atoms and may have different and varying carbon chain structures. The cyclopentenes and cyclopentanes are prepared by hydrogenation from the corresponding cyclopentadiene intermediates. The cyclopentadienes are prepared by reaction with hydrocarylating agents or alcohols. Mixtures are also disclosed.
Abstract: Blended gasolines are produced by the mixing of a butane-pentane rich component, a natural gasoline component, and a toluene component. The mix is weathered during the blending operation to remove light-weight hydrocarbons comprising two, three and four-carbon components. The light-weight hydrocarbons, which preferably constitute less than 3 percent of the blended gasoline, can be recovered to generate power to run the process. The liquid gasoline mixture is formulated to produce a desired octane rating, an environmentally acceptable vapor pressure, and a mix which, when burned in an internal combustion engine, produces a minimum amount of pollutants.
Abstract: A high temperature heat transfer and lubricating composition consisting of a mixture of (a) a mixture of mono-, di- and tribenzylated ethyl benzene and (b) a polyphenyl ether. The lubricant has a pour point of -40.degree. C. and does not degrade at temperatures of 300.degree. C. The lubricant is miscible in all proportions but the ratio of component (a) to component (b) is about 10 to 90:90 to 10.
Abstract: A triblock copolymer VI improver comprising terminal hydrogenated polyisoprene blocks and a central polymeric block containing predominantly monoalkenyl aromatic hydrocarbon monomer units. Oil compositions comprising such triblock copolymer VI improvers exhibit a good balance between thickening efficiency and mechanical shear stability combined with relatively high HTHSR viscosities.
Abstract: A process for preparing a fluid for traction drive from a fraction containing compounds having at least four aromatic rings is disclosed. The fraction is a by-product produced at the time of the preparation of alpha-methyl-benzylalkylbenzenes by alkylation of at least one compound selected from C.sub.7 -C.sub.10 alkylbenzenes with styrene in the presence of an acid catalyst. The process comprises the steps of decomposing the fraction in an atmosphere of hydrogen at a predetermined temperature and pressure, collecting a decomposition product having a boiling range not higher than 450.degree. C. and then subjecting the decomposition product to nuclear hydrogenation at aromatic rings thereof in the presence of a catalyst capable of nuclear hydrogenation.
Abstract: Hydrocarbyl substituted cyclopentadienes, cyclopentenes, and cyclopentanes are sythetic lubricating compositions. The preferred structures contain 1 to 6 alkyl groups which have 4 to 36 carbon atoms and may have different and varying carbon chain structures. The cyclopentenes and cyclopentanes are prepared by hydrogenation from the corresponding cyclopentadiene intermediates. The cyclopentadienes are prepared by reaction with hydrocarbylating agents or alcohols. Mixtures are also disclosed.
Abstract: Synthetic hydrocarbon lubricating materials are produced by cross oligomerizing a Dimersol olefin and a linear olefin with a catalyst comprising a metal oxide substrate having tantalum (v) halide/oxide bound to the surface thereof.
Abstract: Synthetic base oils for functional fluids and greases are provided comprising a mixture of monoalkylated naphthalenes and polyalkylated naphthalenes, said naphthalenes represented by the formula: ##STR1## wherein the R' groups are independently selected from H and methyl, the monoalkylated naphthalenes have three R groups which are H and one R group which is a 12-26 carbon alkyl, the polyalkylated naphthalenes have from two to four R groups which are 12-26 carbon alkyl and any remainder R groups H, and the weight ratio of monoalkylated naphthalenes to polyalkylated naphthalenes is from 5:95 to 70:30 when the average alkyl group is C.sub.12 -C.sub.16 and from 5:95 to 99:1 when the average alkyl group is C.sub.17 -C.sub.26. In the preferred mixture, the polyalkylated naphthalenes have a numerical ratio of .alpha./.beta. substitution of from 50/50 to 10/90 when the R' groups are both H.
Abstract: A method for preparing synthetic oils characterized by a high viscosity index and prepared from 1-olefin is described. The method comprises polymerizing a 1-olefin or a mixture of 1-olefins in the presence of(a) at least one transition metal halide catalyst,(b) at least one alkyl aluminum compound containing up to about 15 carbon atoms in each alkyl group and up to about 40 carbon atoms per molecule as a co-catalyst, and(c) a saturated alkyl fluoride.The homopolymers and copolymers prepared in accordance with the method of the invention generally are characterized by a high viscosity index such as between about 100 to 300. The homopolymers and copolymers are useful as synthetic lubricants and as additives to synthetic or mineral oil lubricants for modifying the viscosity index characteristics of the lubricants.
Abstract: A cleansing agent for lithographic printing plates having substantially reduced aromatic components. The plate cleaner comprises an aqueous mixture of substantially aliphatic hydrocarbons, a composition comprising one or more non-ionic emulsifying agents and/or non-ionic surfactants, an alkaline salt electrolyte and an optional organic or inorganic acid.
Abstract: In a central system fluid composition comprising (1) 70 to 95% by weight of a hydrocarbon base oil and (2) 5 to 30% by weight of a viscosity index improver, the improvement wherein said hydrocarbon base oil (1) comprises (a) 25% by weight to less than 50% by weight, based on the weight of the hydrocarbon base oil (1), of an oligomer of 1-decene having an average molecular weight of 200 to 600 and (b) more than 50% by weight to 75% by weight of a petroleum lubricating oil fraction, and said viscosity index improver (2) is a polymethacrylate having a viscosity average molecular weight of 10,000 to 700,000 obtained by polymerizing at least one ester of a saturated monohydric aliphatic alcohol having 1 to 18 carbon atoms with methacrylic acid.
Type:
Grant
Filed:
August 4, 1980
Date of Patent:
November 10, 1981
Assignees:
Nippon Oil Company, Ltd., Nissan Motor Co., Ltd.
Abstract: A liquid composition and method for forming the composition, the composition being intended for use in an oil-filled electrical apparatus to minimize the detrimental effects that can occur during high fault conditions which oil composition is biodegradable and formed from natural hydrocarbons and synthetic hydrocarbons which when combined form a flat pseudo-rectangular molecular weight distribution curve.
Abstract: A radiation resistant working oil for lubricating parts of atomic power facilities which are exposed to radioactive rays consists essentially of alpha-benzyl substituted methylnaphthalene isomers and beta-benzyl substituted methylnaphthalene isomers in the ratio of about 1:0.2-1:1.