Abstract: Fibrous material webs and methods of making the fibrous material webs. Binderless webs can be formed in a continuous process where fiber material, such as glass is melted and formed into fibers. The fibers are formed into a web of binderless glass fibers or a web with a dry binder. The binderless web or the web with dry binder can be layered and/or the fibers that make up the web can be mechanically entangled, for example, by needling.

Abstract: Light diffusing optical fibers for use in ultraviolet illumination applications and which have a uniform intensity that is angularly independent are disclosed herein along with methods for making such fibers. The light diffusing fibers are composed of a silica-based glass core that is coated with a number of layers including a scattering layer. According to some embodiments multiple light diffusing fibers are bundle together and are situated inside a jacket. The jacket may incorporate scattering sites, or may include a scattering layer situated thereon.

Abstract: Provided is an inorganic fiber containing silica and magnesia as the major fiber components which further includes a phosphate additive to the melt of fiber ingredients, or as a coating on the surfaces of the fiber, or both. The inorganic fiber exhibits improved thermal performance properties and is non-durable in physiological fluids. Also provided are methods of preparing the inorganic fiber and of thermally insulating articles using thermal insulation prepared from a plurality of the inorganic fibers.

Abstract: Methods for producing a coated optical fiber may include drawing an optical fiber from a draw furnace along a first pathway and redirecting the optical fiber along a second, different pathway which is non-parallel with the first pathway. The optical fiber may be coated as it travels along the second pathway.

Abstract: Glass compositions and high-modulus, and high-strength glass fibers made therefrom, being capable of economical, continuous processing and suitable for the production of high-strength and/or high stiffness, low-weight composites, such as windturbine blades, the glass composition comprises the following constituents in the limits defined below, expressed as weight percentages: between about 56 to about 61 weight percent SiO2; between about 16 to about 23 weight percent Al2O3, wherein the weight percent ratio of SiO2/Al2O3 is between about 2 to about 4; between about 8 to about 12 weight percent MgO; between about 6 to about 10 weight percent CaO, wherein the weight percent ratio of MgO/CaO is between about 0.7 to about 1.5; between about 0 to about 2 weight percent Na2O; less than about 1 weight percent Li2O; and total residual transition metal oxides of less than about 2 weight percent.

Abstract: The invention relates to an optical fiber, in particular a laser fiber, containing a doped glass fiber core (1) and cladding (2) around the latter with a refraction index profile which decreases outwards from the fiber core. The optical fiber is distinguished by at least one intermediate layer (3, 4, 5) being disposed between the glass fiber core and the cladding to reduce the mechanical tension therebetween. In one advantageous embodiment, the intermediate layer is doped in such a way as to ensure a stepped mechanical tension distribution between the glass fiber core and the cladding, and is co-doped in such a way as to reduce the refractive index and counteract the refraction index-increasing effect of the intermediate layer doping.

Abstract: The present invention relates to a process for producing glass strands coated with a hot-melt size, whereby molten glass streams, flowing out of orifices located in the base of one or more bushings, are drawn in the form of one or more sheets of continuous filaments, the filaments are then assembled into one or more strands that are collected on one or more moving supports, this process consisting in depositing a first composition containing a coupling agent on the glass filaments and then in depositing a second composition comprising a hot-melt polymer in the melt state, at the latest during assembly of the filaments into one or more strands. It also relates to the glass strands obtained according to this process and to the composites containing said strands.

Abstract: Provided is a fiberglass binder composition which comprises epoxidized oil and a multifunctional carboxylic acid or anhydride. The resultant binder provides minimal processing difficulties and a fiberglass product which exhibits minimal water absorption. The cure time of the binder is also exceptional.

Abstract: Methods for producing a coated optical fiber may include drawing an optical fiber from a draw furnace along a first pathway and redirecting the optical fiber along a second, different pathway which is non-parallel with the first pathway. The optical fiber may be coated as it travels along the second pathway.

Abstract: The present invention is directed to sizing compositions for glass fibers and glass fiber reinforced thermoplastic resins. The sizing composition comprises a maleic anhydride copolymer. Thermoplastic polyamide resin articles reinforced with glass fibers at least partially coated with a residue of the sizing composition can demonstrate a surprising improvement in strength of the reinforced polyamide resin when lubricated with a fatty acid metal salt and in the hydrolysis resistance when exposed to boiling water/ethylene glycol medium.

Abstract: The present invention relates to a composition for reinforcing strands, characterized in that it includes at least one additive capable of acting at the strands/matrix interface so as to improve the fire resistance of the strands/matrix composite, and it also relates to the strands and composites obtained.

Abstract: The subject of the invention is a unit for manufacturing felts (6) which are formed from crosslinked mineral fibers, comprising at least one pair of conveyors formed by a lower conveyor (11) and an upper conveyor (12) which are placed opposite each other and intended to compress said felt (6) in at least one direction, a means (13) for heat treating the felt (6) after it has passed through the conveyors (11, 12) comprising at least one means (14) placed between the conveyors (11, 12) and the heat treatment means (13), intended to prevent decompression of the felt (6) in this region, said means comprising at least one cam (14) having a profile suitable for keeping a constant and minimum distance between the conveyors (11, 12) and the heat treatment means (13), and in that at least one of the conveyors is rigidly connected to one element of the heat treatment means (13).

Abstract: A two-part sizing composition including a precursor size composition and a binder composition, the binder composition being substantially free of any aminosilane coupling agent for is provided for the production of reinforcing fiber materials that exhibit little or no coloration. The two-part sizing composition may be advantageously employed to make substantially colorless, densified fiber pellets of a reinforcing fiber material. The densified fiber pellets may be produced by applying the sizing composition to reinforcing fiber strands, chopping the reinforcing fiber strands to form chopped strand segments, applying the binder composition, and palletizing and densifying the coated chopped strand segments to form flowable densified fiber pellets.

Abstract: The invention relates to a sizing composition composed of a solution comprising at least 5% by weight of solvent and comprising a thermally curable base system, said system comprising at least 60% by weight of components with a molecular mass of less than 750 and at least 60% by weight of components of a mixture exhibiting at least one epoxy reactive functional group, at least one amine, preferably primary or secondary amine, reactive functional group, and at least one hydroxyl reactive functional group. Another subject matter of the invention relates to the glass strands coated with the abovementioned sizing composition. The glass strands obtained are capable of being used to reinforce organic or inorganic materials.

Abstract: A two-part sizing composition that imparts improved resistance to hydrolysis of reinforced composites including a size composition and a binder composition is provided. The size composition may include one or more coupling agents, one or more lubricants, and at least one wetting agent. The binder composition may include a copolymer formed from maleic anhydride and at least one other copolymerizable monomer, at least one crosslinking agent, and a surfactant or mixture of surfactants. In at least one exemplary embodiment, the maleic anhydride copolymer is a maleic anhydride-butadiene copolymer partial ammonium salt. The size composition may be applied to a reinforcing fiber material before the binder size material is applied. The two-part size composition may be applied to a reinforcing fiber material to form a reinforcing fiber product which may then be densified or compacted to form a densified reinforcing fiber product, such as a pellet.

Abstract: A binder slurry for a continuous filament mat used in a phenolic pultrusion system comprising a phenolic compatible silane, a non-ionic surfactant, a defoamer, water, an organic acid and a bisphenol epoxy powdered resin having a thermally active dicyandiamide cross-linking resin. The binder slurry resin is unique in that the bisphenol epoxy powdered resin having a thermally active dicyandiamide cross-linking resin is compatable with presently available phenolic resins, and as such pultruded parts made have improved surface and mechanical properties as compared with traditional polyester type binder slurries which are not compatable with phenolic resins. Continuous filament mats made with the new binder slurry also may also be made into epoxy prepreg that can be used to make composite parts.

Abstract: A roll coater for placing binder on the fibers prior to being wound around a rotating drawing drum. The drawing drum draws fibers out of orifices in the bottom of a slowly reciprocating furnace. The fibers form a mat on the drawing drum that is later removed and expanded. The roll coater includes a graphite or other material coating drum that rotates in a bath of liquid binder and/or wetting agents, and reciprocates with the furnace. The fibers scrape over the surface of the coating drum after being formed but before winding around the drawing drum. The binder and/or wetting agent picked up on the surface of the coating drum coats the fibers with binder and/or wetting agent. Liquid binder and/or wetting agent is replenished in the bath in which the coating drum is partially submerged by a float, sensor, pump and large container of binder/wetting agent.

Abstract: A filter medium for an air filter, characterized in that it comprises a filter material having a glass fiber as its primary component and an alkyl ketene dimer adhered to the surface of the glass fiber; and a method for producing the filter medium which comprises a step of subjecting a dispersed slurry of a raw material fiber to a wet papermaking to form a wet paper, a step of immersing the wet paper in an aqueous dispersion or solution of the dimer or a liquid mixture of the dimer and a binder resin, or applying or spraying any of the above-mentioned liquids to the wet paper, to thereby allow the dimer to adhere onto the surface of the glass fiber, and a step of drying the resultant wet paper having the dimer adhered thereto. The filter medium exhibits a reduced amount of an out gas generated when it is used with ventilation and also exhibits high water-repellency and satisfactory strength in various applications such as air conditioning of a building and semiconductor manufacturing.

Abstract: A coated optical fiber includes a fiber coating having an unblended primary portion on the optical fiber, an unblended secondary portion, and a blended portion intermediate the unblended primary and secondary portions. The thickness of the blended portion is greater than or equal to about 10% but less than 100% of the thickness of the fiber coating. An optical fiber ribbon includes a ribbon matrix similarly having an unblended primary portion, an unblended secondary portion, and a blended portion between the unblended primary portion and unblended secondary portion. A method for fabricating a coated optical fiber or optical fiber ribbon includes applying a primary portion material to the optical fiber or plurality of coated optical fibers, and applying a secondary portion material in a manner selected to provide a blend of the primary portion material and the secondary portion material. An applicator apparatus includes means for performing the described steps.

Abstract: A method of measuring the twist imparted to an optical fibre includes the steps of advancing the optical fibre in a predetermined direction and at a predetermined velocity, imparting to the optical fibre, during the step of advancing, a twist about its axis, measuring the diameter of the optical fibre during the step of advancing, to generate a time-based signal indicating the diameter, and processing this signal to find a value indicating the imparted twist. The step of processing includes the principal steps of transforming in the frequency domain the signal relating to the measurement of the diameter, calculating the power spectrum of the signal thus obtained, distinguishing in this power spectrum the signal peaks correlated with the imparted twist, determining the maximum frequency associated with these signal peaks, and dividing the value of this maximum frequency by the value of the velocity of advance of the fibre to find the value indicating the imparted twist.

Abstract: A roll coater for placing binder on the fibers prior to being wound around a rotating drawing drum. The drawing drum draws fibers out of orifices in the bottom of a slowly reciprocating furnace. The fibers form a mat on the drawing drum that is later removed and expanded. The roll coater includes a graphite or other material coating drum that rotates in a bath of liquid binder and/or wetting agents, and reciprocates with the furnace. The fibers scrape over the surface of the coating drum after being formed but before winding around the drawing drum. The binder and/or wetting agent picked up on the surface of the coating drum coats the fibers with binder and/or wetting agent. Liquid binder and/or wetting agent is replenished in the bath in which the coating drum is partially submerged by a float, sensor, pump and large container of binder/wetting agent.

Abstract: A roll coater for placing binder on the fibers prior to being wound around a rotating drawing drum. The drawing drum draws fibers out of orifices in the bottom of a slowly reciprocating furnace. The fibers form a mat on the drawing drum that is later removed and expanded. The roll coater includes a graphite or other material coating drum that rotates in a bath of liquid binder and/or wetting agents, and reciprocates with the furnace. The fibers scrape over the surface of the coating drum after being formed but before winding around the drawing drum. The binder and/or wetting agent picked up on the surface of the coating drum coats the fibers with binder and/or wetting agent. Liquid binder and/or wetting agent is replenished in the bath in which the coating drum is partially submerged by a float, sensor, pump and large container of binder/wetting agent.

Abstract: The invention relates to a method of applying a protective organic coating to an optical glass fiber, said glass fiber is drawn from a preform and passed through a liquid which contains the material for forming said organic coating, once the amount of liquid coating material to be applied to the fiber has been adjusted, said coating matrial is hardened, while a gas is passed along the liquid wherein nitrous oxide (an N2O-containing gas) is used as said gas. The invention also relates to the coated optical glass fiber, produced by that method.

Abstract: A forming bucket for use in the preparation of gas attenuated fiber insulation products includes a tubular member having a fiber inlet and a fiber outlet. The tubular member has a conical portion disposed between the fiber inlet and the fiber outlet. The conical portion has a smooth curvilinear surface for minimizing turbulence in a fiber stream flowing through the forming bucket during the gas attenuation process.

Abstract: Provided herewith is a fiberglass binder comprising an aqueous solution of a polycarboxy polymer, a polyol and at least 30 weight percent of a filler material, preferably clay. The clay filler material is generally present in the aqueous solution as a suspension of particles having an average size of 3 &mgr;m or less. The clay filler extended fiberglass binder of the present invention is more cost effective without significantly altering the appearance or function of the binder.

Abstract: The present invention relates to a method for improving the thermal performance of fibrous glass insulation in the admix recycling of the insulation, which includes the use of corrugated hose in the recycling process.

Abstract: A coated optical fiber adjusted to operate at a predetermined temperature range. The coated fiber includes an optical fiber, a first polymer coating generally concentrically surrounding the optical fiber and a second polymer coating generally concentrically surrounding the first polymer coating, wherein the first polymer coating includes substantially no coefficient of thermal expansion stresses when the optical fiber is placed at a lower end of the temperature range.

Abstract: A method for manufacturing an optical fiber (100) having low PMD, comprises the steps of: a) heating at least one end portion (3a) of a preform (3); b) drawing an optical fiber (100) from a free end of said heated end portion (3a) along a fiber drawing axis (I—I); c) coating said optical fiber (100) with a suitable coating material; d) applying to said coated optical fiber (100) a torque about said fiber drawing axis (I—I), e) winding said coated optical fiber (100) onto a collecting spool (9). According to the invention, step d) is carried out by means of a pulley (16) supported upstream of said collecting spool (9) and rotated about the fiber drawing axis (I—I), said optical fiber (100) being wound up onto said pulley (16) for an angle of at least about 360°. Advantageously, such method also allows to notably increase the amount of optical fiber produced per unit of time with respect to the prior art.

Abstract: A roll coater for placing binder on the fibers prior to being wound around a rotating drawing drum. The drawing drum draws fibers out of orifices in the bottom of a slowly reciprocating furnace. The fibers form a mat on the drawing drum that is later removed and expanded. The roll coater includes a graphite or other material coating drum that rotates in a bath of liquid binder and/or wetting agents, and reciprocates with the furnace. The fibers scrape over the surface of the coating drum after being formed but before winding around the drawing drum. The binder and/or wetting agent picked up on the surface of the coating drum coats the fibers with binder and/or wetting agent. Liquid binder and/or wetting agent is replenished in the bath in which the coating drum is partially submerged by a float, sensor, pump and large container of binder/wetting agent.

Abstract: Cooling systems and the methods of cooling filaments using the cooling systems are disclosed. One embodiment of the cooling system includes a layer of nozzles that spray air on the filaments above a pre-pad water spray. Alternatively, another cooling system utilizes air-atomizing nozzles to spray a mixture of air and water on the filaments.

Abstract: A method for manufacturing an optical fiber (100) having low PMD, comprises the steps of:

Abstract: A sizing composition for coating glass and carbon fibers. The composition comprises low concentrations of a cationic and nonionic lubricant, a film-forming polymer, and preferably a coupling agent and a hydrolyzing agent. Use of the sizing composition reduces fuzz development, increases wettability, and improves roving package stability.

Abstract: A method is disclosed for forming coated fibers suitable for making a composite article. A plurality of fibers are coated with an aqueous- or non-aqueous-based chemical treatment containing a curable resin such that the resin on the fibers is in a partially cured or uncured state. The coated fibers may then be formed into a composite article in a subsequent forming operation, for example, by filament winding, pultrusion, weaving, knitting, or extrusion coating. The strand of fibers may also be shaped into a preform which can be used in resin transfer molding (RTM) and injection molding processes.

Abstract: A method for high velocity coating optical fibers includes passing a fiber with diameter l at velocity V through a coating container to which liquid coating material with viscosity .mu. is supplied under pressure p. Unwanted bubble formation in the coating is prevented by adjusting one or more of the parameters V, l, .mu., and p using the relationship:S=pl/.mu.Vwhere S is a constant characteristic of the coating container/die structure.

Abstract: A method for coating an optical fiber (1) has the optical fiber (1) exiting the longitudinal direction through a coating nozzle (10) from a volume (11) which is filled with a liquid hardenable coating material (6). The surface of the fiber is spaced from the wall (12) of the coating nozzle (10). The viscosity of the coating material (6) at room temperature is greater than 2500 mPa.multidot.s and the temperature of the coating material (6) is adjusted high enough for the coating material (6) to have a viscosity of less than 2000 mPa.multidot.s.

Abstract: In the process of drawing optical fibers, a protective plastic coating is applied to the fiber by applying a curable liquid coating material thereto and the subsequently curing the liquid coating to a protective plastic layer. At high fiber draw speeds, air entrained with the fiber enters the liquid coating material and causes bubbles in the cured coating. The incidence of bubbles in the coating is reduced by replacing air adjacent the fiber surface with helium.

Abstract: A process is provided for making filled mineral fiber products which comprises applying mineral melt to a rotating fiberizing rotor and thereby throwing from the rotor as fibers and forming a substantially annular cloud of fibers, spraying binder into the annular cloud of fibers, carrying the fibers axially from the rotor towards a collector surface and collecting the fibers on the collector surface as a web. The process includes spraying into the substantially annular cloud a slurry which has specific gravity of at least 1.1, preferably at least 1.2, and which comprises a substantially stable liquid dispersion of particulate material in an aqueous binder.

Abstract: A sizing applicator is provided for applying a coating of sizing composition to glass fibers. The sizing applicator includes a housing and a roll applicator which is rotatably coupled to the housing. The housing has a supply port adapted to receive sizing composition from a sizing supply source, an exit slot and a passageway extending from the supply port to the exit slot. The passageway receives sizing composition from the supply port and delivers the sizing composition to the exit slot such that the sizing composition exits the housing and is received on an outer surface of the roll applicator. The roll applicator is spaced from the housing such that the housing does not substantially contact the sizing composition once it is received on the roll applicator.

Abstract: A method and apparatus are provided for producing uniformly sized glass fibers. A heated bushing supplies streams of molten glass to be drawn into continuous fibers, and a drawing device attenuates the streams into fibers. A sizing applicator has a coating element engaging the drawn fibers, which applies a coating of sizing composition to the fibers. A shoe spaced from the applicator engages the fibers and causes the fibers to sweep back and forth across the element.

Abstract: A method is disclosed for forming pre-impregnated fibers suitable for making a composite article. A plurality of fibers (14) are pre-impregnated with about 50% by weight of an aqueous-based chemical treatment containing a curable resin, and then contacted with a drying device (41) which effects drying of the chemical treatment without effecting full curing of the resin. The pre-impregnated fibers may then be formed into a composite article in a subsequent forming operation, for example, by filament winding, pultrusion, weaving, knitting, or extrusion coating.

Abstract: A process and device for manufacturing cut threads according to which glass threads composed of continuous filaments are coated with a liquid non-aqueous size, which can react under the effect of actinic radiation. The threads are cut by a member which is also used to draw or entrain the threads mechanically before they are subjected to actinic radiation.

Abstract: A bubble stripping and coating apparatus for stripping entrained gas from the surface of a fiber, then coating the fiber with a coating material having a bubble stripping and coater body and a die assembly. The bubble stripping and coater body has a bubble stripping gas entrance for providing a bubble stripping argon gas to a bubble stripping gas chamber for stripping entrained gas from the fiber and having a die assembly bore. The die assembly is arranged in the die assembly bore, and has a guide die having a lower guide die opening with a diameter of less than 0.016 inches.

Abstract: A thread is formed of one or a plurality of fans of continuous filaments on which a sizing composition is deposited. The moisture content on the thread is controlled by subjecting the fans of filaments to a current of air transversely to the direction of movement of the filaments between the zone in which the size is deposited and the zone in which the filaments are gathered together.

Abstract: A loose-fill insulation product having irregularly shaped glass fibers is provided. The loose-fill insulation product shows improved recovery, lower thermal conductivity and requires lower product densities than prior art loose-fill insulation at equivalent fiber diameters.

Abstract: An apparatus is provided for producing a glass fiber package. The apparatus includes a heated bushing for supplying streams of molten glass to be drawn into continuous fibers, a rotatable member adapted to draw the streams into fibers and to wind the fibers into a package, an applicator for applying a size to the fibers, and a drying device including a heated element maintained at a temperature of between about 1000.degree. F. and 1500.degree. F. for contacting and transferring energy in the form of heat to the sized fibers to dry the fibers before they are wound into the package. The heating member is stationary while contacting the sized fibers.

Abstract: This invention is a strand of silicate glass fibers with a carbon skin or sheath around each glass fiber of the strand. The invention uses hydrocarbon pyrolysis with silicate fiber glass manufacturing to produce fibers using conventional melt-bushing technology. The formation of a carbon skin or sheath on the silicate glass fibers offers numerous advantages. For example, pyrolyzing hydrocarbons is endothermic. Heat is removed in the process and fibers are cooled faster. This helps to achieve higher throughput.

Abstract: In a process for producing insulating materials with environmentally safe binding components, a long-chain starch is used as binder, besides silicone. The starch is heated up to 50.degree. to 60.degree. C., held at this temperature and sprayed on the glass fibers separately from the silicone; 6 to 8% binder, consisting of starch and silicone, are used, then a spun-glass mat or slab may be shaped and dried at about 180.degree. C. A spun-glass mat (16), insulating mat or slab or adsorber is thus obtained which surprisingly is water-proofed and held together exclusively by starch, resin and silicone, which may be used without any problems and has a uniform bulk density throughout. In the plant (1) provided for that purpose, supply rings for water (9), for starch (10) and for silicone (11) are provided. The nozzles (13) for the supply ring 10 have a larger opening and separation edges. The premixing container (17) and the supply pipe (15) are heatable or heat-insulated.

Abstract: An optical cable reinforcement in the form of glass fiber strands ?30! having a first coating ?32! of a binding agent such as a latex mixture and a second coating ?34! of particles ?36! of a water blocking agent such as a polyacrylate salt. The particles ?36! of water blocking agent are adhered to the glass fiber strands ?30! by the binding agent without the binding agent entirely coating the particles of water blocking agent. The unoccluded surface areas of water blocking agent thus provided serve to rapidly absorb/desorb water and protect the optical cable from moisture. A unique powder coating station ?60! is used to apply the particles ?36! of water blocking agent to glass fiber strands ?30! which have been coated with wet binding agent so that the proper adherence of the particles ?36! of water blocking agent without complete embodiment, is obtained.

Abstract: A process and apparatus are provided for coating a sizing composition onto glass fibers. The apparatus includes an applicator for applying a liquid sizing composition to the glass fibers and a treatment station for treating the sized fibers to increase the viscosity of the sizing composition, thereby improving the adherence of the sizing composition to the fibers.

Abstract: A method and apparatus are provided for producing composite strands. The apparatus comprises a heated bushing for supplying streams of molten glass to be drawn into continuous first fibers; a drawing device adapted to draw the streams into the first fibers; supply equipment for supplying one or more second fibers of a second material; one or more applicators for applying a size to the first and second fibers; and a device for gathering the first and second fibers into one or more composite strands. The composite stands are made by drawing glass fibers from the bushing; applying sizing to the glass fibers and the second fibers; contacting the fibers with a heated contact plate to dry the fibers; and then commingling the fibers to form one or more composite strands.