Organic Silicon Containing (e.g., Coupling Agent, Etc.) Patents (Class 65/448)
  • Patent number: 11932942
    Abstract: A process for depositing a coating on a continuous fibre of carbon or silicon carbide from a precursor of the coating, includes heating a segment of the fibre in the presence of the coating precursor in a microwave field so as to bring the surface of the segment to a temperature allowing the coating to form on the segment from the coating precursor, wherein the segment of fibre is in the presence of a supercritical phase of the precursor of the coating in the reactor and the coating is formed by supercritical phase chemical deposition in the reactor.
    Type: Grant
    Filed: June 16, 2022
    Date of Patent: March 19, 2024
    Assignees: SAFRAN CERAMICS, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE DE BORDEAUX
    Inventors: Arnaud Delehouze, Eric Bouillon, Adrien Delcamp, Cédric Descamps
  • Patent number: 8080171
    Abstract: A sizing composition for reinforcement fibers that includes one or more film forming agents, a silane coupling agent package, and at least one lubricant surfactant is provided. Optional components such as rheology modifiers, fillers, biocides, and pH modifiers may also be included. Preferred film forming polymers are amide-based polymers. Additionally, the sizing composition is free of polyvinyl alcohol. The absence of polyvinyl alcohol in the size composition reduces or eliminates the production of precipitates from white water in wet-laid processes. The size composition is applied to reinforcement fibers and formed into chopped strand, wet-laid mats that can be used for a variety of purposes, including roofing products. Chopped strand mats formed from fibers sized with the inventive sizing composition maintains or improves the dry tear and tensile strengths compared to chopped strand mats made from fibers sized with a commercial sizing composition that does not contain polyvinyl alcohol.
    Type: Grant
    Filed: June 1, 2007
    Date of Patent: December 20, 2011
    Assignee: OCV Intellectual Capital, LLC
    Inventors: Jerry H. C. Lee, Dennis R. Brown, Timothy A. Miller, Timothy R. Gilbert
  • Patent number: 7510703
    Abstract: Topically applicable cosmetic compositions useful for the UV-A photoprotection of the skin and/or hair contain thus effective amounts of at least one silane, siloxane or polysiloxane merocyanine sulfone having at least one of the structural formulae (1), (2) and (3) below:
    Type: Grant
    Filed: March 20, 2007
    Date of Patent: March 31, 2009
    Assignee: L'Oreal
    Inventor: Herve Richard
  • Patent number: 7419721
    Abstract: The present invention is directed to sizing compositions for glass fibers and glass fiber reinforced thermoplastic resins. The sizing composition comprises a maleic anhydride copolymer. Thermoplastic polyamide resin articles reinforced with glass fibers at least partially coated with a residue of the sizing composition can demonstrate a surprising improvement in strength of the reinforced polyamide resin when lubricated with a fatty acid metal salt and in the hydrolysis resistance when exposed to boiling water/ethylene glycol medium.
    Type: Grant
    Filed: December 19, 2003
    Date of Patent: September 2, 2008
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Henri Beerda, Ronald Boelman, Jacob Cornelis Dijt, Bertho van de Heisteeg, Johannes Leonardus Tabak
  • Patent number: 7267782
    Abstract: A two-part sizing composition including a precursor size composition and a binder composition, the binder composition being substantially free of any aminosilane coupling agent for is provided for the production of reinforcing fiber materials that exhibit little or no coloration. The two-part sizing composition may be advantageously employed to make substantially colorless, densified fiber pellets of a reinforcing fiber material. The densified fiber pellets may be produced by applying the sizing composition to reinforcing fiber strands, chopping the reinforcing fiber strands to form chopped strand segments, applying the binder composition, and palletizing and densifying the coated chopped strand segments to form flowable densified fiber pellets.
    Type: Grant
    Filed: June 19, 2003
    Date of Patent: September 11, 2007
    Assignee: Owens-Corning Fiberglas Technology II, LLC
    Inventors: Willy H. Piret, Nadia Masson
  • Patent number: 7129289
    Abstract: A two-part sizing composition that imparts improved resistance to hydrolysis of reinforced composites including a size composition and a binder composition is provided. The size composition may include one or more coupling agents, one or more lubricants, and at least one wetting agent. The binder composition may include a copolymer formed from maleic anhydride and at least one other copolymerizable monomer, at least one crosslinking agent, and a surfactant or mixture of surfactants. In at least one exemplary embodiment, the maleic anhydride copolymer is a maleic anhydride-butadiene copolymer partial ammonium salt. The size composition may be applied to a reinforcing fiber material before the binder size material is applied. The two-part size composition may be applied to a reinforcing fiber material to form a reinforcing fiber product which may then be densified or compacted to form a densified reinforcing fiber product, such as a pellet.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: October 31, 2006
    Assignee: Owens Corning Composites S.P.R.L.
    Inventors: Willy H. Piret, Nadia Masson
  • Patent number: 7083855
    Abstract: A binder slurry for a continuous filament mat used in a phenolic pultrusion system comprising a phenolic compatible silane, a non-ionic surfactant, a defoamer, water, an organic acid and a bisphenol epoxy powdered resin having a thermally active dicyandiamide cross-linking resin. The binder slurry resin is unique in that the bisphenol epoxy powdered resin having a thermally active dicyandiamide cross-linking resin is compatable with presently available phenolic resins, and as such pultruded parts made have improved surface and mechanical properties as compared with traditional polyester type binder slurries which are not compatable with phenolic resins. Continuous filament mats made with the new binder slurry also may also be made into epoxy prepreg that can be used to make composite parts.
    Type: Grant
    Filed: March 7, 2003
    Date of Patent: August 1, 2006
    Assignee: Owens Corning Fiberglass Technology, Inc.
    Inventors: Adrian C. Lane, Jeffrey L. Antle
  • Publication number: 20040244427
    Abstract: A method for producing zero-twist glass yarn employing a special sizing agent for sizing procedure during spinning process that enables a loss on ignition of the special sizing agent which makes up 0.8˜1.6 Wt % of the glass yarn and a moisture content less than 0.2% of the glass yarn after drying the forming package formed through spinning, sizing and winding procedure with which the zero-twist glass yarn is obtained without need of twist fixing process; moreover, the zero-twist glass yarn produced therefrom possesses the tensile strength better than that of the conventional twisted glass yarn, and, when used as weft yarn, may substantially increase the tensile strength of the glass fabric.
    Type: Application
    Filed: June 1, 2004
    Publication date: December 9, 2004
    Applicant: PFG FIBER GLASS CORPORATION
    Inventor: C.F. Charles Lee
  • Publication number: 20040014586
    Abstract: A glass composition to be used for manufacturing inorganic fiber has a composition that entirely or partly eliminates the use of expensive boron oxide that is employed to lower the glass softening point and the viscosity. The glass composition contains 45 to 75 wt % of SiO2, 1 to 6 wt % of Al2O3, 0 to 4 wt % of MgO, 0 to 15 wt % of CaO, 0 to 6 wt % of B2O3, 0.1 to 10 wt % of BaO, 0.1 to 25 wt % of SrO, 5 to 17 wt % of Na2O, 0.5 to 10 wt % of K2O and 0 to 3.5 wt % of Fe2O3.
    Type: Application
    Filed: April 10, 2003
    Publication date: January 22, 2004
    Inventors: Keiji Otaki, Yukiyoshi Shinobu, Naoko Baba
  • Patent number: 6322888
    Abstract: A process for producing sized glass yarns, which entails: a) drawing streams of molten glass from orifices located at a bottom of one or more dies, in a form of one or more fans of continuous filaments, b) assembling the filaments into one or more moving supports, wherein a first stable composition having a viscosity of between 0.5 and 250 cP is deposited onto the surface of the continuous filaments, and a second stable composition, supplied separately from the first and having a viscosity of between 0.5 and 300 cP, is deposited onto the surface of the filaments of the yarns, at the earliest during deposition of the first composition and at the latest during collection of the years, the difference in viscosity between the two compositions deposited being less than 150 cP, the mixture of the deposited compositions functioning as a sizing composition and being polymerizable at room temperature.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: November 27, 2001
    Assignee: Vetrotex France
    Inventors: Patrick Moireau, Bruno Gibello, Marc Roubin
  • Patent number: 6228281
    Abstract: A sizing composition for coating glass and carbon fibers. The composition comprises low concentrations of a cationic and nonionic lubricant, a film-forming polymer, and preferably a coupling agent and a hydrolyzing agent. Use of the sizing composition reduces fuzz development, increases wettability, and improves roving package stability.
    Type: Grant
    Filed: October 30, 1998
    Date of Patent: May 8, 2001
    Assignee: Owens Corning Fiberglas Technology
    Inventor: Donald B. Sage
  • Patent number: 5961685
    Abstract: A sizing applicator is provided for applying a coating of sizing composition to glass fibers. The sizing applicator includes a housing and a roll applicator which is rotatably coupled to the housing. The housing has a supply port adapted to receive sizing composition from a sizing supply source, an exit slot and a passageway extending from the supply port to the exit slot. The passageway receives sizing composition from the supply port and delivers the sizing composition to the exit slot such that the sizing composition exits the housing and is received on an outer surface of the roll applicator. The roll applicator is spaced from the housing such that the housing does not substantially contact the sizing composition once it is received on the roll applicator.
    Type: Grant
    Filed: March 14, 1997
    Date of Patent: October 5, 1999
    Assignee: Owens Corning Fiberglass Technology, Inc.
    Inventors: Arlo F. Streets, Thomas O. Matteson, Martin C. Flautt
  • Patent number: 5916679
    Abstract: A method is disclosed for forming pre-impregnated fibers suitable for making a composite article. A plurality of fibers (14) are pre-impregnated with about 50% by weight of an aqueous-based chemical treatment containing a curable resin, and then contacted with a drying device (41) which effects drying of the chemical treatment without effecting full curing of the resin. The pre-impregnated fibers may then be formed into a composite article in a subsequent forming operation, for example, by filament winding, pultrusion, weaving, knitting, or extrusion coating.
    Type: Grant
    Filed: August 3, 1998
    Date of Patent: June 29, 1999
    Assignee: Owens Corning Fiberglas Technology, Inc.
    Inventors: Andrew B. Woodside, Joan T. Muellerleile, David R. Hartman
  • Patent number: 5841928
    Abstract: Planar waveguides are produced by using radiation to write path regions into a photosensitive layer. Originally, the photosensitive layer had the same refractive index as the confining regions, e.g., it consists of silica doped with oxides of Ge and B. Composite path regions are produced by depositing a glass soot onto a partial region. On sintering the soot melts to fill up the empty spaces and thereby create a composite layer.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: November 24, 1998
    Assignee: British Telecommunications public limited company
    Inventors: Graeme Douglas Maxwell, Benjamin James Ainslie
  • Patent number: 5698000
    Abstract: The invention relates to a process for manufacturing continuous a glass fiber strand.The process consists in depositing on the glass filaments which are in the process of being drawn a sizing composition of which the solvent content is less than 5 wt % of solvent selected from organic solvent and water, the solution comprising at least 70 wt % of a mixture of constituents which can be polymerized and/or crosslinked by heat treatment, at least 60 wt % of the constituents being constituents of which the molecular weight (Mw) is less than 750, less than 10 weight % being film-forming agents and 0 to 25 weight % being coupling agents, lubricants, stabilizers and initiators and/or catalysts, and in winding the strand or strands, formed by collection of the filaments, on a rotating support so as to form a wound package consisting of turns of strand coated with a non-polymerized sizing composition.The strands are intended to reinforce thermoplastic or thermosetting organic substrates or substances of mineral origin.
    Type: Grant
    Filed: December 8, 1994
    Date of Patent: December 16, 1997
    Assignee: Vetrotex France
    Inventors: Patrick Moireau, Timothy Johnson
  • Patent number: 5690715
    Abstract: In a process for producing insulating materials with environmentally safe binding components, a long-chain starch is used as binder, besides silicone. The starch is heated up to 50.degree. to 60.degree. C., held at this temperature and sprayed on the glass fibers separately from the silicone; 6 to 8% binder, consisting of starch and silicone, are used, then a spun-glass mat or slab may be shaped and dried at about 180.degree. C. A spun-glass mat (16), insulating mat or slab or adsorber is thus obtained which surprisingly is water-proofed and held together exclusively by starch, resin and silicone, which may be used without any problems and has a uniform bulk density throughout. In the plant (1) provided for that purpose, supply rings for water (9), for starch (10) and for silicone (11) are provided. The nozzles (13) for the supply ring 10 have a larger opening and separation edges. The premixing container (17) and the supply pipe (15) are heatable or heat-insulated.
    Type: Grant
    Filed: July 24, 1995
    Date of Patent: November 25, 1997
    Inventor: Helmut Schiwek
  • Patent number: 5662776
    Abstract: Glass fiber non-woven fabric for base material of a laminate comprising binder binding glass fibers to each other, said binder including a reactant product formed by reacting a solution of tri-functional epoxy resin, bi-functional epoxy resin and tri-ethylene tetramine and having an acetic solution and phenyl amino-silane coupling agent added thereto. The thus obtained glass fiber non-woven fabric is impregnated with an predetermined amount of epoxy resin and dried to produce prepregs, which are superposed one upon another and formed under heat and pressure of 20 kgf/cm.sup.2 to produce the laminate.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: September 2, 1997
    Assignee: Shin-Kobe Electric Machinery Co.
    Inventors: Masayuki Ushida, Masaru Ogata, Akihiro Hachiya, Yukihiro Yamashita, Masayuki Noda
  • Patent number: 5611836
    Abstract: The invention relates to a method of producing glass strands, the method comprising coating glass strands with a heat-polymerizable composition constituted by a solution with a solvent content of less than 5% by weight and a viscosity of less than 400 cP, the solution comprising a basic structure which can be polymerized or cross-linked thermally, the structure comprising at least 60% by weight of one or more components with molecular weights of less than 750, having at least one acrylic and/or methacrylic and/or vinyl other and/or N-vinylamide and/or N-vinyllactam function, the proportion of polyfunctional components within these components being at least 45% by weight of these components, so as to produce glass strands coated with a non-polymerized, heat-polymerizable composition.
    Type: Grant
    Filed: December 8, 1994
    Date of Patent: March 18, 1997
    Assignee: Vetrotex France
    Inventor: Patrick Moireau
  • Patent number: 5470658
    Abstract: Glass fibers are coated with a sizing composition comprising an aqueous emulsion based on at least one polyolefin having grafted thereon at least one acid or anhydride which is neutralized by at least one alcoholamine, at least one aminosilane coupling agent, and at least one primary, secondary or tertiary aliphatic monoamine stabilizing agent which is miscible with water and which has a pK.sub.b value lower than the pK.sub.b value of the amine group of the coupling agent, plus 1.The glass fibers of the invention are intended more particularly for reinforcing polyolefin matrices such as polypropylene matrices.
    Type: Grant
    Filed: July 22, 1994
    Date of Patent: November 28, 1995
    Assignee: Vetrotex France
    Inventors: Jean-Philippe Gasca, Gerard Tardy
  • Patent number: 5387468
    Abstract: An aqueous size composition for glass fibers is disclosed which includes a thermoplastic polymer resin powder, a coupling agent, and fugitive processing aids, such as binders or film formers. The composition is applied to the glass fiber surfaces during the fiber forming process. A fugitive rheology modifier material may be added to the size composition. One embodiment of the composition includes a polyethylene oxide binder material and a polyphenylene sulfide thermoplastic polymer resin.
    Type: Grant
    Filed: January 21, 1993
    Date of Patent: February 7, 1995
    Assignee: Owens-Corning Fiberglas Technology Inc.
    Inventors: Jean-Claude Pollet, Gary L. Williams, Gordon P. Armstrong, Martin C. Flautt, David L. Shipp