Cellulose Fibers Patents (Class 8/116.1)
  • Patent number: 6844066
    Abstract: The present invention relates to superabsorbent cellulose fiber including cellulose and at least one ethylenically unsaturated monomer. The invention also relates to a method of producing the superabsorbent fiber, and absorbent articles including the superabsorbent fiber.
    Type: Grant
    Filed: May 19, 2003
    Date of Patent: January 18, 2005
    Assignee: Rayonier Products and Financial Services Company
    Inventor: Othman A. Hamed
  • Patent number: 6837972
    Abstract: Tissue and towel products that include crosslinked cellulosic fibers. Methods for making tissue and towel products that include crosslinked cellulosic fibers.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: January 4, 2005
    Assignee: Weyerhaeuser Company
    Inventor: David G. Marsh
  • Patent number: 6825138
    Abstract: A textile treatment process, treatment bath, and treated fabric are disclosed. The process imparts water repellant, stain resistant, and wrinkle-free properties as well as aesthetically pleasing hand properties to a fabric made in whole or in part of fibers having a hydroxyl group, such as cellulosic fibers, though immersion in an aqueous bath and subsequent heating for curing. The aqueous treatment bath contains a urea resin, polytetrafluorethylene (PTFE) and, preferably, fluoroalkyl acrylate co-polymer.
    Type: Grant
    Filed: April 12, 2002
    Date of Patent: November 30, 2004
    Assignee: Warmkraft, Inc.
    Inventor: Ronnie Franklin Lack
  • Patent number: 6821388
    Abstract: Tissue and towel products that include crosslinked cellulosic fibers. Methods for making tissue and towel products that include crosslinked cellulosic fibers.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: November 23, 2004
    Assignee: Weyerhaeuser Company
    Inventor: David G. Marsh
  • Patent number: 6802869
    Abstract: Disclosed is a novel rayon fiber which possesses characteristics similar to those of a viscose rayon fiber as to be suitable for use in clothes in addition to being produced at an economical cost. The rayon fiber is prepared from a cellulose acetate fiber with a degree of substitution of 2.0 or higher by saponifying 75% or greater of the total acetyl groups of the cellulose acetate fiber into hydroxyl groups and has a composite crystalline structure of cellulose II and IV.
    Type: Grant
    Filed: January 11, 2002
    Date of Patent: October 12, 2004
    Assignee: SK Chemicals Co., Ltd.
    Inventors: Ik Soo Kim, Jong Soo An, Byung Hak Kim
  • Patent number: 6793686
    Abstract: This invention relates to a finishing process for cellulosic textiles which provides a textile having a desirable combination of inherent durable press properties, improved moisture content and improved wicking properties.
    Type: Grant
    Filed: January 18, 2002
    Date of Patent: September 21, 2004
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: A. Levent Cimecioglu, Klein A. Rodrigues
  • Patent number: 6793684
    Abstract: A fabric care composition, which is adapted for use in a domestic laundering process, comprises an anionic polymer which is capable of self cross-linking and/or of reacting with cellulosic fibers, such as cotton, and a textile compatible exhaustion agent which is also a fabric conditioner. The polymer may be a carbamoyl sulphonate terminated poly(ether) urethane or a bunte salt terminated polymer. The polymers can increase the dimensional stability of the fabric, improve its surface color definition after washing, impart a softer handle and improve its crease recovery properties.
    Type: Grant
    Filed: August 29, 2002
    Date of Patent: September 21, 2004
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Anthony Nicholas Jarvis, Andrew Philip Parker, Philip John Sams
  • Publication number: 20040177935
    Abstract: The present invention is directed to cross-linked cellulosic fiber in the sheet from, obtainable by cross-linking a blend of mercerized pulp and conventional pulp. The method includes heating treated cellulosic fibers to promote intra-fiber cross-linking. The cross-linked fibers are characterized by an improved acquisition rate, resiliency, absorbency, and absorbency under load. Moreover, the inventive cross-linked fibers exhibit a reduction in centrifuge retention capacity, and have low knots, nits and fines contents. The cross-linked cellulosic fibers of the invention are useful in the acquisition layer and/or absorbent core of absorbent articles.
    Type: Application
    Filed: March 14, 2003
    Publication date: September 16, 2004
    Inventors: Othman A. Hamed, Harry J. Chmielewski, Tina R. Murguia, Karl Sears
  • Patent number: 6774267
    Abstract: New phenolic compounds of formula (I) R=C3-C17 dialkoxymethyl group, 1,3-dioxolan-2-yl group optionally substituted on peaks 4 and/or 5 by one or more C1-C8 alkyls or 1,3-dioxan-2-yl group optionally substituted on peaks 4 and/or 5 and/or 6 by one or more C1-C8 alkyls. n=1, 2 or 3, the group or groups are in o and/or p position of the OH of the cycle m=from 0 to 4-n, X=functional group such as OH or Hal or C1-C8 alkyl or alkoxy group or C5-C12 aryl group and optionally 1 or 2 heteroatoms such as N or O, or carboxy or —CO—Y group where Y=C1-C8 alkyl or alkoxy or amido or amino or thiol group, on condition that at least one of the ortho or para positions of the phenolic cycle is substituted by a hydrogen, and their salts with the alkali metals, alkaline-earth metals and amines.
    Type: Grant
    Filed: February 7, 2001
    Date of Patent: August 10, 2004
    Assignee: Clariant France
    Inventors: Didier Wilhelm, Florence Esmard
  • Publication number: 20040144507
    Abstract: The present invention is polysiloxane pretreated pulp fibers comprising pulp fibers, and a polysiloxane. The polysiloxane pretreated pulp fibers have a polysiloxane content of about 0.4 percent or greater by weight of dry pulp fibers, a silicone retention factor of about 0.6 or greater, and an initial water drop absorption value of about 180 seconds or less.
    Type: Application
    Filed: December 19, 2003
    Publication date: July 29, 2004
    Inventors: Thomas Gerard Shannon, Dale Alan Burghardt, Lisa Ann Flugge, David Andrew Moline
  • Publication number: 20040140070
    Abstract: The present invention relates to cellulosic fibrous material comprising a radiation activatable resin, structures comprising such fibrous material, and absorbent articles especially disposable absorbent articles, comprising such fibrous materials or structures. It further relates to a process to make such fibrous material, structures or articles.
    Type: Application
    Filed: December 8, 2003
    Publication date: July 22, 2004
    Applicant: The Procter & Gamble Company
    Inventors: Ekaterina Ponomarenko, Ludwig Busam
  • Patent number: 6736933
    Abstract: A multi-ply paperboard comprising at least one ply of conventional cellulose fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent; and at least one ply of chemically intrafiber crosslinked cellulosic high-bulk fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent. The water-borne binding agent may be a starch, a modified starch, a polyvinyl alcohol, a polyvinyl acetate, a polyethylene/acrylic acid copolymer, an acrylic acid polymer, a polyacrylate, a polyacrylamide, a polyamine, guar gum, an oxidized polyethylene, a polyvinyl chloride, a polyvinyl chloride/acrylic acid copolymer, an acrylonitrile/butadiene/styrene copolymer or polyacrylonitrile. A method for making the paperboard is disclosed.
    Type: Grant
    Filed: May 2, 2003
    Date of Patent: May 18, 2004
    Assignee: Weyerhaeuser Company
    Inventors: Richard A. Jewell, Amar N. Neogi
  • Publication number: 20040084159
    Abstract: The present invention relates to cross-linked cellulosic fiber having improved absorbency characteristics when compared to conventional cross-linked fibers. The cross-linked cellulosic fiber is obtainable by reacting pulp in the sheet or fluff form with one or more reagents selected from organic molecule having acid and aldehyde functional groups “acid aldehydes.” The invention also relates to a method of producing the cross-linked fiber. The method includes heating the treated cellulosic fibers to promote intrafiber cross-linking. The cross-linked fibers are characterized by having an improved centrifuge retention capacity, fluid acquisition rate, resiliency, absorbent capacity, absorbency under load, and other absorbent properties. The inventive cross-linked fibers are useful in forming absorbent composites, and in particular absorbent cores for use in absorbent articles.
    Type: Application
    Filed: October 28, 2003
    Publication date: May 6, 2004
    Inventors: Othman A. Hamed, Harry J. Chmielewski, Dana B. McBee
  • Patent number: 6730130
    Abstract: An agent containing a lubricant, a non-ionic surfactant and an amphoteric surfactant of a specified kind in specified amounts is applied at a specified rate to spun synthetic fibers before draft and false-twisting processes are simultaneously carried on these fibers such that false-twisted yarns with a high quality without dyeing specks and without abnormal tension variations can be obtained.
    Type: Grant
    Filed: March 26, 2002
    Date of Patent: May 4, 2004
    Assignee: Takemoto Yushi Kabushiki Kaisha
    Inventors: Shigehiko Sakuraba, Masahiro Nagaya, Yukiko Nagai, Fumihiko Kimura
  • Publication number: 20040074616
    Abstract: The invention provides a method for preparing cross-linked cellulosic fibers. A sheet of mercerized cellulosic fibers with a purity of at least 95% is treated with a solution containing a carboxylic acid cross-linking agent. The treated cellulosic fibrous material is dried and cured in sheet form to promote intrafiber cross-linking. Cross-linked fiber products produced are economic and possess good porosity, bulking characteristics, wet resiliency, absorption characteristics, low fines, low nits and low knots. The invention also includes blended cellulose compositions comprising a minor proportion of cross-linked mercerized cellulosic fibers and a major proportion of other cellulosic fibers. The invention further provides individualized, chemically cross-linked mercerized cellulosic fibers of high purity.
    Type: Application
    Filed: October 16, 2002
    Publication date: April 22, 2004
    Inventors: Karl D. Sears, Michael E. Haeussler, Tina R. Solomon
  • Patent number: 6716306
    Abstract: A multi-ply paperboard comprising at least one ply of conventional cellulose fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent; and at least one ply of chemically intrafiber crosslinked cellulosic high-bulk fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent. The water-borne binding agent may be a starch, a modified starch, a polyvinyl alcohol, a polyvinyl acetate, a polyethylene/acrylic acid copolymer, an acrylic acid polymer, a polyacrylate, a polyacrylamide, a polyamine, guar gum, an oxidized polyethylene, a polyvinyl chloride, a polyvinyl chloride/acrylic acid copolymer, an acrylonitrile/butadiene/styrene copolymer or polyacrylonitrile. A method for making the paperboard is disclosed.
    Type: Grant
    Filed: May 30, 2002
    Date of Patent: April 6, 2004
    Assignee: Weyerhaeuser Company
    Inventors: Richard A. Jewell, Amar N. Neogi
  • Patent number: 6703125
    Abstract: The present invention provides cellulosic fibers having high wet bulk and methods for their preparation. In one embodiment, the invention provides cellulosic fibers catalytically crosslinked with glyoxal and, optionally, a glycol. In another embodiment, cellulosic fibers are crosslinked with a combination of glyoxal and a glyoxal-derived resin selected from the group consisting of a glyoxal/polyol condensate, a cyclic urea/glyoxal/polyol condensate, a cyclic urea/glyoxal condensate, and mixtures thereof.
    Type: Grant
    Filed: January 15, 2003
    Date of Patent: March 9, 2004
    Assignee: Weyerhaeuser.Company
    Inventors: Richard A. Jewell, John A. Westland
  • Patent number: 6691358
    Abstract: The invention refers to a method for an integrated treatment of cellulose pulp. The method includes the steps: providing said cellulose pulp (1), providing a determined quantity of white liquor (2) including alkali and sulphur components, providing an oxygen-containing gas, oxidizing (5) the sulphur components of the white liquor by the supply of a part of said gas in such a way that at least a part of the sulphur is present in the form of sulphate, transporting the cellulose pulp having a certain kappa number to at least one mixing device (4), and supplying the oxidized white liquor from the oxidizing step to the cellulose pulp, supplying a part of said gas to the cellulose pulp in said mixing device, mixing the cellulose pulp with the oxidized white liquor and said gas in said mixing device, and transporting the cellulose pulp from said mixing device to a delignification reactor (6) for oxygen delignification of said cellulose pulp, wherein the kappa number is reduced.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: February 17, 2004
    Assignee: AGA Aktiebolag
    Inventors: Anders Tor Jörgen Engström, Anna Tigerström
  • Patent number: 6685748
    Abstract: A method is provided for bleaching a non-cotton cellulosic fiber, yarn or fabric by contacting said fiber, yarn or fabric with a hemicellulase enzyme for a time and under conditions suitable to produce a whitening of said fiber, yarn or fabric.
    Type: Grant
    Filed: April 4, 2000
    Date of Patent: February 3, 2004
    Assignee: Genencor International, Inc.
    Inventors: Anthony G. Day, Scott D. Power, Doreen Victoria, Deborah S. Winetzky
  • Patent number: 6683031
    Abstract: A method is provided for preparing a multifunctional additive involving irradiating raw cotton plant material with an electron beam source, continually blending the raw cotton plant material during the irradiating and micronizing the irradiated cotton plant material. The invention is improved wherein the irradiating and blending of the raw cotton plant material is performed while the raw cotton plant material is in rope form. Irradiated rope is suitably tensioned before micronizing to compensate for degradability of the rope incurred during irradiation.
    Type: Grant
    Filed: August 28, 2002
    Date of Patent: January 27, 2004
    Assignee: React, LLC of Delafield
    Inventor: Bruce A. Tavares
  • Patent number: 6676710
    Abstract: A process for treating a textile substrate, the process including the steps of providing a textile substrate; providing a treatment bath; entraining a transport material in the treatment bath wherein the transport material further comprises a treatment material dissolved or suspended therein and wherein the transport material is substantially immiscible with the treatment bath; and contacting the textile substrate with the transport material in the treatment bath to thereby treat the textile substrate with the treatment material in the transport material.
    Type: Grant
    Filed: December 4, 2000
    Date of Patent: January 13, 2004
    Assignee: North Carolina State University
    Inventors: Carl Brent Smith, Walter A. Hendrix, Donald L. Butcher
  • Publication number: 20040000012
    Abstract: The present invention relates to a method for treating a mixture containing cellulose, comprising at least one step of adding at least one agent capable of reducing carbonyl groups. The invention further relates to a specialty cellulose pulp, obtained by a method comprising said treatment. Furthermore, the invention relates to the use of the specialty cellulose pulp according to the invention or the specialty cellulose pulp obtained by a method according to the invention for the production of cellulose derivatives or materials containing cellulose molecules, including but not limited to, cellulose ethers or cellulose esters. Cellulose derivatives obtained from the specialty cellulose pulp according to the invention display increased viscosity and/or improved brightness over cellulose derivatives obtained from specialty cellulose pulp not subjected to the inventive treatment.
    Type: Application
    Filed: June 26, 2002
    Publication date: January 1, 2004
    Applicant: Borregaard ChemCell
    Inventors: Justin T. Scarpello, Asbjorn E. Bratekas, Ove Bartholsen, Torgeir Hjerde
  • Publication number: 20030226213
    Abstract: Cellulosic based polymer or oligomer materials for use in textile mill applications. The compositions of the present invention impart appearance and integrity benefits to fabrics and textiles during laundering and in-wear. The applications can be stand alone or incorporated into textile mill processes. The materials can be applied onto yarns/fabrics/textiles/garments via pad-dry processes or exhaustion methods.
    Type: Application
    Filed: June 18, 2003
    Publication date: December 11, 2003
    Applicant: The Procter & Gamble Company
    Inventors: Jiping Wang, Nodie Monroe Washington
  • Patent number: 6652598
    Abstract: The present invention relates to a method for treating a weft knitted fabric containing a regenerated cellulose fiber in order to prevent or eliminate the weft bar of the fabric, as well as to a weft knitted fabric which has been subjected to such a method. A method for treatment of weft knitted fabric, which comprises applying a mellowing treatment to a weft knitted fabric containing a regenerated cellulose fiber and subjecting the resulting weft knitted fabric to an alkali treatment in its spread state.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: November 25, 2003
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Mari Shibata, Masanori Nakagawa
  • Publication number: 20030205342
    Abstract: A multi-ply paperboard comprising at least one ply of conventional cellulose fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent; and at least one ply of chemically intrafiber crosslinked cellulosic high-bulk fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent. The water-borne binding agent may be a starch, a modified starch, a polyvinyl alcohol, a polyvinyl acetate, a polyethylene/acrylic acid copolymer, an acrylic acid polymer, a polyacrylate, a polyacrylamide, a polyamine, guar gum, an oxidized polyethylene, a polyvinyl chloride, a polyvinyl chloride/acrylic acid copolymer, an acrylonitrile/ butadiene/styrene copolymer or polyacrylonitrile. A method for making the paperboard is disclosed.
    Type: Application
    Filed: May 2, 2003
    Publication date: November 6, 2003
    Applicant: Weyerhaeuser Company
    Inventors: Richard A. Jewell, Amar N. Neogi
  • Publication number: 20030192659
    Abstract: This invention provides a dried singulated crosslinked cellulose pulp fiber product as well as an apparatus and a method for forming singulated, crosslinked, and dried fibers. In accordance with the process, a feed pulp containing a crosslinker is delivered to a jet drier. The jet drier singulates and dries the feed pulp. The singulated and dried fibers are collected from the jet drier. The feed pulp may be further treated with a treatment substance. The jet drier may be maintained at negative pressure. The product fibers may have low knot count, a low fines count, as well improved kink, curl and twist. The apparatus for carrying out the process may include a pretreatment station for supplying the treatment substance, a pulp feed device designed for pulp, a pulp feed device designed for pulp and foam suspensions, and/or a fiber separation station having a vacuum conveyor.
    Type: Application
    Filed: January 16, 2002
    Publication date: October 16, 2003
    Inventors: Michael J. Yancey, Brian Wester, Michael David Vrbanac, Ramon Charles Dezutter
  • Publication number: 20030188838
    Abstract: This invention provides a dried singulated crosslinked cellulose pulp fiber product as well as an apparatus and a method for forming singulated, crosslinked, and dried fibers. In accordance with the process, a feed pulp containing a crosslinker is delivered to a jet drier. The jet drier singulates and dries the feed pulp. The singulated and dried fibers are collected from the jet drier. The feed pulp may be further treated with a treatment substance. The jet drier may be maintained at negative pressure. The product fibers may have low knot count, a low fines count, as well improved kink, curl and twist. The apparatus for carrying out the process may include a pretreatment station for supplying the treatment substance, a pulp feed device designed for pulp, a pulp feed device designed for pulp and foam suspensions, and/or a fiber separation station having a vacuum conveyor.
    Type: Application
    Filed: January 16, 2002
    Publication date: October 9, 2003
    Inventors: Michael J. Yancey, Brian Wester, Michael David Vrbanac, Ramon Charles Dezutter
  • Patent number: 6610174
    Abstract: Methods for making high wet performance webs. A polymeric anionic reactive compound is applied heterogenously to a cellulosic fibrous web followed by curing of the compound to crosslink the cellulose fibers. The resulting tissue has high wet resiliency, high wet strength, and a high wet:dry tensile strength ratio.
    Type: Grant
    Filed: June 21, 2001
    Date of Patent: August 26, 2003
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Tong Sun, Jeffrey D. Lindsay
  • Publication number: 20030155087
    Abstract: The invention provides a method for preparing cross-linked cellulosic fibers. A sheet of mercerized cellulosic fibers with a purity of at least 95% is treated with a solution containing carboxylic acid cross-linking agents. The treated cellulosic fibrous material is dried and cured in sheet form to promote intrafiber cross-linking. Cross-linked fiber products of this method, which is economic, that possess good porosity, bulking characteristics, wet resiliency, and absorption, low fines, low nits, and low knots, are also disclosed.
    Type: Application
    Filed: April 11, 2001
    Publication date: August 21, 2003
    Applicant: Rayonier Inc.
    Inventors: Karl D. Sears, Michael E. Haeussler, Tina R. Solomon
  • Patent number: 6607564
    Abstract: Provided are compounds and methods for modifying a material to change properties of the material, as well as a variety of products obtained using the methods. In one embodiment, a material comprising one or more modifiable functional groups is reacted with an activated hydrophobic acyl group in the presence of a hindered base, thereby to covalently attach the hydrophobic acyl group to the modifiable functional groups on the material. The material which is modified may be, for example, a carbohydrate, and the modifiable functional groups on the material may be hydroxyls. For example, materials such as cellulose may be modified by reacting it with a acid chloride or acid anhydride including a hydrophobic acyl group, in the presence of a hindered base, such as tripentylamine, to attach the hydrophobic acyl groups to the hydroxyls on the cellulose, thereby to increase the hydrophobicity of the cellulose.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: August 19, 2003
    Assignee: Nano-Tex, LLC
    Inventors: David S. Soane, David A. Offord
  • Patent number: 6605123
    Abstract: A composition for finishing an article comprising a non-volatile siloxane, and a method for finishing an article with a composition comprising a non-volatile siloxane.
    Type: Grant
    Filed: April 14, 2000
    Date of Patent: August 12, 2003
    Assignee: General Electric Company
    Inventors: Amy-Elizabeth Kasson, Edward T. Simoneau
  • Publication number: 20030141028
    Abstract: This invention provides a dried singulated cellulose pulp fiber product as well as an apparatus and a method for forming singulated and dried fibers. In accordance with the process a feed pulp is delivered to a jet drier. The jet drier singulates and dries the feed pulp. The singulated and dried fibers are collected from the jet drier. The feed pulp may be treated with a treatment substance. The jet drier may be maintained at negative pressure. The product fibers may have low knot count, a low fines count, as well improved kink, curl and twist. The apparatus for carrying out the process may include a pretreatment station for supplying the treatment substance, a pulp feed device designed for pulp, a pulp feed device designed for pulp and foam suspensions, and/or a fiber separation station having a vacuum conveyor.
    Type: Application
    Filed: May 7, 2002
    Publication date: July 31, 2003
    Applicant: Weyerhaeuser Company
    Inventors: Michael David Vrbanac, Ramon Charles Dezutter, Brian Wester, Michael James Yancey
  • Patent number: 6592717
    Abstract: Carboxylated cellulosic fibers are disclosed. The fibers include a polycarboxylic acid covalently coupled to the fibers. Methods for producing the fibers and for producing fibrous products that incorporate the fibers are also disclosed.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: July 15, 2003
    Assignee: Weyerhaeuser Company
    Inventor: Richard A. Jewell
  • Patent number: 6582557
    Abstract: Carboxylated cellulosic fibers are disclosed. The fibers include a polycarboxylic acid covalently coupled to the fibers. Methods for producing the fibers and for producing fibrous products that incorporate the fibers are also disclosed.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: June 24, 2003
    Assignee: Weyerhaeuser Company
    Inventor: Richard A. Jewell
  • Patent number: 6582553
    Abstract: A multi-ply paperboard comprising at least one ply of conventional cellulose fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent; and at least one ply of chemically intrafiber crosslinked cellulosic high-bulk fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent. The water-borne binding agent may be a starch, a modified starch, a polyvinyl alcohol, a polyvinyl acetate, a polyethylene/acrylic acid copolymer, an acrylic acid polymer, a polyacrylate, a polyacrylamide, a polyamine, guar gum, an oxidized polyethylene, a polyvinyl chloride, a polyvinyl chloride/acrylic acid copolymer, an acrylonitrile/butadiene/styrene copolymer or polyacrylonitrile. A method for making the paperboard is disclosed.
    Type: Grant
    Filed: June 21, 2001
    Date of Patent: June 24, 2003
    Assignee: Weyerhaeuser Company
    Inventors: Richard A. Jewell, Amar N. Neogi
  • Patent number: 6579415
    Abstract: Carboxylated cellulosic fibers are disclosed. The fibers include a polycarboxylic acid covalently coupled to the fibers. Methods for producing the fibers and for producing fibrous products that incorporate the fibers are also disclosed.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: June 17, 2003
    Assignee: Weyerhaeuser Company
    Inventor: Richard A. Jewell
  • Patent number: 6579841
    Abstract: The present invention relates to novel variant EGIII or EGIII-like cellulases which have improved stability. The variant cellulases have performance sensitive residues replaced to a residue having modified stability.
    Type: Grant
    Filed: August 4, 2000
    Date of Patent: June 17, 2003
    Assignee: Genencor International, Inc.
    Inventors: Anthony G. Day, Peter Gualfetti, Colin Mitchinson, Andrew Shaw
  • Publication number: 20030106163
    Abstract: A modified cellulosic fiber having superabsorbent properties is described. The modified fiber of the invention has a fibrous structure substantially identical to the cellulosic fiber from which it is derived. The modified fiber is a water-swellable, water-insoluble fiber that substantially retains its fibrous structure in its expanded, water-swelled state. The modified fiber is a sulfated and crosslinked cellulosic fiber having a liquid absorption capacity of at least about 4 g/g. In one embodiment, the modified fiber is an individual, crosslinked, sulfated cellulosic fiber. In another aspects, the invention provides a rollgood that includes the modified fiber, absorbent composites and articles that include the modified fiber, and methods for making the modified cellulosic fiber.
    Type: Application
    Filed: July 19, 2002
    Publication date: June 12, 2003
    Inventors: Amar N. Neogi, Richard H. Young, Brent A. Petersen
  • Patent number: 6565612
    Abstract: Fabrics containing rayon fibers may exhibit, after the fabric has been aqueous laundered at least one time, changes in dimension in length and in width of less than about 5% each, a durable press value of at least about 2.5, and a water absorbency time of less than about 100 seconds. Fabrics containing rayon fibers may also exhibit, after the fabric has been aqueous laundered at least one time, changes in dimension in length and in width of less than about 8% each, a durable press value of at least about 3.5, and a water absorbency time of less than about 100 second.
    Type: Grant
    Filed: December 8, 2000
    Date of Patent: May 20, 2003
    Assignee: The Procter & Gamble Company
    Inventors: George L. Payet, Michelle F. Mellea
  • Patent number: 6551706
    Abstract: The present invention provides cellulosic fibers having high wet bulk and methods for their preparation. In one embodiment, the invention provides cellulosic fibers catalytically crosslinked with glyoxal and, optionally, a glycol. In another embodiment, cellulosic fibers are crosslinked with a combination of glyoxal and a glyoxal-derived resin selected from the group consisting of a glyoxal/polyol condensate, a cyclic urea/glyoxal/polyol condensate, a cyclic urea/glyoxal condensate, and mixtures thereof.
    Type: Grant
    Filed: October 16, 2000
    Date of Patent: April 22, 2003
    Assignee: Weyerhaeuser Company
    Inventors: Richard A. Jewell, John A. Westland
  • Patent number: 6547832
    Abstract: Process for the yellowing-inhibiting finishing of textile, indigo-dyed, washed and/or stonewashed and/or bleached denim articles, characterized in that the finishing is carried out from aqueous medium with protonated fatty acid ester-aminoamides and/or hydroxyaminoamides of N-(&bgr;-hydroxyethyl)ethylenediamine, in which the fatty acid radicals each contain from 12 to 22 carbon atoms and which have been protonated with at least 1.5 equivalents of ortho-phosphoric acid per equivalent of basic amino groups.
    Type: Grant
    Filed: July 10, 2000
    Date of Patent: April 15, 2003
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Fred Freudemann, Kurt Poppenwimmer
  • Patent number: 6540792
    Abstract: A fiber structure comprising cellulose fibers crosslinked by using a crosslinking agent and synthetic fibers, characterized in that the crosslinking index represented by the following formula of the cellulose fibers is in a range of 1 to 4, and that the synthetic fibers contain an antimicrobial agent having an inorganic value/organic value ratio of 0.3 to 1.4. This structure has antimicrobial property excellent in industrial washing durability and also has shape stability such as crease resistance and shrinkage resistance. Crosslinking index=A−B where A is the coefficient of moisture absorption of the fiber structure after crosslinking in an atmosphere of 30° C. and 90% RH (%), and B is the coefficient of moisture absorption of the fiber structure after crosslinking in an atmosphere of 20° C. and 65% RH (%).
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: April 1, 2003
    Assignee: Toray Industries, Inc.
    Inventors: Masaki Ishii, Atsushi Horiuchi, Katsuya Okajima, Akira Nagahara, Naoaki Ito, Hidenobu Honda, Kouichi Saito, Yukikazu Nanri
  • Patent number: 6537327
    Abstract: A method to prevent the backstaining of denim during a stonewashing process comprising treating the denim with a solution or dispersion of a hydrophobically modified polymer having a hydrophilic backbone and at least one hydrophobic moiety, wherein said hydrophilic backbone is prepared from at least one monomer selected from the group consisting of ethylenically unsaturated hydrophilic monomer selected from the group consisting of amide, ether, alcohol, aldehyde, anhydride, ketone and ester; polymerizable hydrophilic cyclic monomer; non-ethylenically unsaturated polymerizable hydrophilic monomer which is selected from the group consisting of glycerol and other polyhydric alcohols; and combinations thereof, wherein said hydrophilic backbone is optionally substituted with one or more amino, amine, amide, sulfonate, sulfate, phosphonate, hydroxy, carboxyl or oxide groups; wherein said hydrophobic moiety is prepared from at least one hydrophobic monomer or a chain transfer agent, said hydrophobic monomer is selec
    Type: Grant
    Filed: June 14, 2001
    Date of Patent: March 25, 2003
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Klein A. Rodrigues
  • Publication number: 20030051834
    Abstract: The invention is directed to a method of making a heat and light stable carboxylated cellulose fiber whose fiber strength and degree of polymerization is not significantly sacrificed. The method involves the use of a catalytic amount of a hindered cyclic oxammonium salt as a primary oxidant and a peracid and halide salt as a secondary oxidant in an aqueous environment. The oxammonium compounds may be formed in situ from their corresponding amine, hydroxylamine, and nitroxyl compounds. The oxidized cellulose is then stabilized against D.P. loss and color reversion by further treatment with an oxidant such as sodium chlorite, a chlorine dioxide/hydrogen peroxide mixture, or a peracid under acidic conditions. Alternatively it may be treated with a reducing agent such as sodium borohydride. The method results in a high percentage of carboxyl groups located at the fiber surface. The product is especially useful as a papermaking fiber where it contributes strength and has a higher attraction for cationic additives.
    Type: Application
    Filed: June 6, 2001
    Publication date: March 20, 2003
    Inventors: S. Ananda Weerawarna, Joseph Lincoln Komen, Richard A. Jewell
  • Publication number: 20030051835
    Abstract: A multi-ply paperboard comprising at least one ply of conventional cellulose fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent; and at least one ply of chemically intrafiber crosslinked cellulosic high-bulk fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent. The water-borne binding agent may be a starch, a modified starch, a polyvinyl alcohol, a polyvinyl acetate, a polyethylene/acrylic acid copolymer, an acrylic acid polymer, a polyacrylate, a polyacrylamide, a polyamine, guar gum, an oxidized polyethylene, a polyvinyl chloride, a polyvinyl chloride/acrylic acid copolymer, an acrylonitrile/butadiene/styrene copolymer or polyacrylonitrile. A method for making the paperboard is disclosed.
    Type: Application
    Filed: May 30, 2002
    Publication date: March 20, 2003
    Inventors: Richard A. Jewell, Amar N. Neogi
  • Patent number: 6528438
    Abstract: Cellulosic fiber-containing fabrics are made wrinkle resistant by a durable press wrinkle-free process which comprises treating a cellulosic fiber-containing fabric with formaldehyde, a catalyst capable of catalyzing the crosslinking reaction between the formaldehyde and cellulose and a silicone elastomer, heat-curing the treated cellulose fiber-containing fabric, preferably having a moisture content of more than 20% by weight, under conditions at which formaldehyde reacts with cellulose in the presence of the catalyst without a substantial loss of formaldehyde before the reaction of the formaldehyde with cellulose to improve the wrinkle resistance of the fabric in the presence of a silicone elastomeric softener to provide higher wrinkle resistance, and better tear strength after washing, with less treatment.
    Type: Grant
    Filed: March 16, 1999
    Date of Patent: March 4, 2003
    Assignee: The Procter & Gamble Company
    Inventor: George L. Payet
  • Publication number: 20030037890
    Abstract: Carboxylated cellulosic fibers are disclosed. The fibers include a polycarboxylic acid covalently coupled to the fibers. Methods for producing the fibers and for producing fibrous products that incorporate the fibers are also disclosed.
    Type: Application
    Filed: September 27, 2002
    Publication date: February 27, 2003
    Applicant: Weyerhaeuser Company
    Inventor: Richard A. Jewell
  • Publication number: 20030037891
    Abstract: Carboxylated cellulosic fibers are disclosed. The fibers include a polycarboxylic acid covalently coupled to the fibers. Methods for producing the fibers and for producing fibrous products that incorporate the fibers are also disclosed.
    Type: Application
    Filed: September 27, 2002
    Publication date: February 27, 2003
    Applicant: Weyerhaeuser Company
    Inventor: Richard A. Jewell
  • Patent number: 6524348
    Abstract: The invention is directed to a method of making carboxylated cellulose fibers whose fiber strength and degree of polymerization is not significantly sacrificed. The method involves the use of cyclic nitroxide free radical compounds as a primary oxidant and a hypohalite salt as a secondary oxidant in an aqueous environment. Preferably the oxidized cellulose is then stabilized against D.P. loss in alkaline environments and color reversion with a reducing agent such as sodium borohydride. Alternatively it may be treated with an oxidant such as sodium chlorite. The method results in a high percentage of carboxyl groups located at the fiber surface. The product is especially useful as a papermaking fiber where it contributes strength and has a higher attraction for cationic additives. The product is also useful as an additive to recycled fiber to increase strength. The method can be used to improve properties of either virgin or recycled fiber.
    Type: Grant
    Filed: August 17, 2000
    Date of Patent: February 25, 2003
    Assignee: Weyerhaeuser Company
    Inventors: Richard A. Jewell, Joseph Lincoln Komen, Bing Su, S. Ananda Weerawarna, Yong Li
  • Publication number: 20030034136
    Abstract: A modified cellulosic fiber having superabsorbent properties is described. The modified fiber of the invention has a fibrous structure substantially identical to the cellulosic fiber from which it is derived. The modified fiber is a water-swellable, water-insoluble fiber that substantially retains its fibrous structure in its expanded, water-swelled state. The modified fiber is a sulfated and crosslinked cellulosic fiber having a liquid absorption capacity of at least about 4 g/g. In one embodiment, the modified fiber is an individual, crosslinked, sulfated cellulosic fiber. In another aspects, the invention provides a rollgood that includes the modified fiber, absorbent composites and articles that include the modified fiber, and methods for making the modified cellulosic fiber.
    Type: Application
    Filed: July 19, 2002
    Publication date: February 20, 2003
    Inventors: Amar N. Neogi, Richard H. Young, Brent A. Petersen