Abstract: An oxidative composition for the removal of natural and/or synthetic color from keratinaceous fibers may include a pellet or tablet that when added to a sufficient quantity of a peroxide developer solution readily disperses. The composition may include a gas generating agent to facilitate breakdown and dispersion of the pellet or tablet. The composition added to the developer may be agitated to forms homogeneous cream-like mixture for application to keratinaceous fibers.

Abstract: The invention relates to the use of specific glucuronolactone derivatives as self-tanning substances, as tanning enhancers for dihydroxyacetone or for a mixture of self-tanning substances comprising dihydroxyacetone, for modulation of the colour shade achieved in the case of tanning with dihydroxyacetone or by the mixture or preparation comprising dihydroxyacetone, as contrast-reduction agents or for colouring keratin-containing fibres, and to preparations or compositions for colouring keratin-containing fibres comprising these specific glucuronolactone derivatives.

Abstract: Novel systems and methods for performing treatment (e.g., coloration) of keratinous fibers are disclosed. The methods and systems utilize one or more of a dispensing device which is configured to provide customized composition for treating keratinous fibers (e.g., a coloring composition), optionally formed from tablets; an optical reader, for obtaining sufficient characteristics of the keratinous fibers to make a realistic prediction of the outcome of a treatment (e.g., coloring treatment); a computational units for predicting an outcome of a treatment, optionally being interfaced with the dispensing device and for selecting a customized treatment; and tablet formulations which are useful in preparing customized composition for treating keratinous fibers. Further disclosed are rapidly disintegrating tablets for use in the preparation of compositions for treating keratinous fibers.

Abstract: Compositions, kits, and methods for rebuilding the disulfide bonds in hair that is damaged due to a hair coloring treatment are disclosed. The compositions contain one or more compounds that covalently crosslink at least two thiol groups in the hair. The compositions may be applied subsequent to a hair coloring treatment or simultaneously with a hair coloring treatment. Under normal hair washing conditions, the covalent crosslinks formed are not succeptable to reduction or hydrolysis. Use of the crosslinking compositions prevent the reversion of the hair's disulfide bonds to its reduced state, for at least one week, preferably at least three months, more preferably at least one year, most preferably at least greater than one year, after at least one application of the composition.

Abstract: The invention relates to the use of manganese or iron complexes which, as well as a tetraoxolene unit, contain two macrocyclic, N-containing ligands, especially cyclen or cyclam ligands, in washing and cleaning compositions in the form of granules or powder or solution or suspension for bleaching of coloured stains both on textiles and on hard surfaces. The invention also relates to washing and cleaning compositions which comprise such complexes as bleach activators and to the use thereof for textile washing or for dishwashing detergents and other uses in personal care and other areas.

Abstract: Solubility changeable dye compositions include a dye component linked via a linker moiety to a stimulus responsive hydrophobic moiety which modulates the solubility of the dye, wherein the hydrophobic moiety is configured to be de-linked from the dye component on exposure to a stimulus and render the dye component more hydrophilic. A method of dying a substrate with such dye compositions includes contacting the dye with the substrate.

Abstract: Disclosed herein are solubility changeable dye compositions, methods of preparing such compositions and methods of using them. The composition includes a dye component linked via a linker moiety to a stimulus responsive hydrophobic moiety which modulates the solubility of the dye, wherein the hydrophobic moiety is configured to be de-linked from the dye component on exposure to a stimulus and render the dye component more hydrophilic.

Abstract: A composition and system for use in coloring hair and improving color retention properties in colored hair is described. The composition of the present invention preferably includes hair dye and a copolymer of isobutylmethacrylate and silicone grafted acrylate in isoparaffin, whereby these components are combined in an aqueous based, or alternatively, a nonaqueous based solution. The system includes the step of applying the hair coloring solution to the hair.

Abstract: wherein D is a chromophore; L is a linking group selected from SO2, NHCO, and NHSO2; Q is a hydrogen or halogen atom; and R is selected from C1-C4 alkyl, (CH2)nCOOH, (CH2)nCONH2, (CH2)nSO3H, (CH2)nCOOM, (CH2)nPO3H, (CH2)nOH, (CH2)nSSO3?, (CH2)nNR12, (CH2)nN+R1H2, (CH2)nNHCOR1, PhSSO3?, PhSO3H, PhPO3H, PhNR12, PhN+R13, (CH2)2CH(SH)R1(CH2)3COOH, and n is an integer in the range of 1 to 4 wherein within the same molecule each n is not necessarily the same integer; M is a cation of an alkaline earth metal, alkali metal, NH4+ or NR13+; and R1 is C1-C4 alkyl.

Abstract: A (co)polymer structure comprising at least one portion of an acrylic, silicone, polyglycolic, polysaccharide or natural polymeric chain, comprising a plurality of functionalized units of general formula (I): wherein [C-A] is a portion of a polymeric or copolymeric chain selected from an acrylic silicone, polyglycolic, polysaccharide polymeric structure or from a natural polymer, and X is a functional group selected from one or more solfonic, carbossilic, amino acidic or epoxide groups to react at room temperature and in reaction conditions suitable for use on living beings and to form ionic or covalent bonds with keratin in absence of preemptive modifications of the polymer chain itself.

Abstract: Disclosed are dyes of Formula (I) wherein D is the radical of anthraquinone, acridine, azo, azomethine, hydrazomethine, benzodifuranone, coumarine, diketopyrrolopyrrol, dioxaxine, diphenylmethane, formazane, indigoid, indophenol, naphtalimide, naphthaquinone, nitroaryl, merocyanine, methine, oxazine, perinone, perylene, pyrenequinone, phtalocyanine, phenazine, quinoneimine, quinacridone, quinophtalone, stilbene, styryl, triphenylmethane, xanthene, thiazine dye and thioxanthene dye; Q is C1-C30alkylene, —C2-C12alkenylene, C5-C10arylene-, C5-C10cycloalkylene- or —C1-C10alkylene(C5-C10arylene)- which may be interrupted and/or terminated at one or both ends by one or more than one —O—, —S—, —N?, —N(R1)—, SO2, —(CH2CH2-O) 1-5-, —(CH2CH2CH2—O) 1-5-, —C(O)—, —C(O)—C1-C12alkenylene, —C(O)O—, —OCO—, A N+R1R2, —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —CSR1— or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (hetero)cyclic) bivalent radical optionally comprising at least one h

Abstract: The invention relates to the use, for dyeing keratin fibers, of at least one latent pigment, which is soluble in a medium that is suitable for dyeing, and which can be chemically, thermally or photochemically converted in the fibers into water-insoluble pigments, of formula A(B)x with A representing the chromophoric radical of dyes, and B representing a hydrogen atom or a group of formula (II) with Z representing a cationic water-solubilizing group Z+ or a polyethylene glycol residue, Y representing a hetero atom, F and F? representing a linear or branched C1-C14 alkylene chain, which may contain hetero atoms and may be substituted with one or more hydroxyl, amino or halogen groups. The invention also relates to processes for dyeing keratin fibers using latent pigments, to particular compositions containing them and to multi-compartment dyeing devices or “kits”.

Abstract: Disclosed are thiol dyes of formula (1) wherein L1 is hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; X is C1-C12alkylene, C2-C12alkenylene, C5-C10cycloalkylene, C5-C10arylene, or C5-C10arylene-C1-C10alkylene, which may by interrupted by —O—, —NH—, —S—, —CO—, o-SO2—; Y is the residue of an organic dye Z is a group of formula (1b) or —C?N; wherein A is O; S; or N-L2; B is L3; —OL3; —NL3L4; or —SL3; and L2, L3 and L4, independently from other are hydrogen; C1-C12alkyl; C5-C12aryl-C1-C12alkyl. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.

Abstract: Disclosed are thiol dyes of formula (1), wherein R1, R2, R3, R4 and R5 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); A is a residue of an organic dye; and Y1 is the direct bond; C1-C10alkylene; C5-C10cycloalkylene; C5-C12arylene; or C5-C12arylene-(C1-C10alkylene). The compounds are used to dye hair with or without reducing agents. Furthermore, the present invention relates to compositions comprising thiol dyes of formula (1) and to process for the preparation of theses compounds.

Abstract: A subject-matter of the present invention is compositions of use in the dyeing of human keratinous fibres, comprising, in a cosmetically acceptable medium, at least one dye having a hydrophobic nature and at least one compound chosen from those of following formula (I): in which X represents O or CH2, R? represents a hydrogen, a C1-C8 alkyl or a C1-C4 hydroxyalkyl and n has a value of 1, 2 or 3. The compound of formula (I) can in particular be an alkylene carbonate or a lactone, the pH of the composition being between 2 and 6. Another subject-matter of the invention is a method for dyeing keratinous fibres involving such a composition.

Abstract: Disclosed are polymeric dyes of formula (1a); (1b); or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C10alkylene-; —C2-C12alkenylene-; —C5-C10cycloalkylene-; C5-C10arylene; —C5-C10arylene-(C1-C10alkylene)-; —C(O)—; —(CH2CH2—O)1-5—; —C(O)O—; —OCO—; —N(R1)—; —CON(R1)—; —(R1)NC(O)—; -0-; —S—; —S(O)—; —S(O)2—; —S(O)2—N(R1R2); or the direct bond; R1 and R2 independently from each other are hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y1 and Y2 is a residue of an organic dye; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from O to 1

Abstract: The invention relates to methods of preserving artificial color on keratin materials including applying to artificially colored keratin materials a composition containing at least one silicone film forming resin and at least one polysilicone polymer.

Abstract: The present invention discloses methods and kit-of-parts for treating keratinous fibres prior to dyeing to control and modulate dye uptake into the fibre. Organic solvents having log P of from ?4.0 to ?0.5 or from 0.5 to 4.0 are used to manufacture pre-treatment composition to be applied to the hair. When the hair is pre-treated with at least one organic solvent having a log P of from 0.5 to 4.0 the dye penetration into the keratinous fibres is enhanced, while pre-treating the hair with at least one organic solvent having a log P of from ?4.0 to ?0.5 reduces the dye uptake. One or more compositions to pre-treat the keratinous fibres can be effortlessly applied on different zones of the hair and can be left in place or removed prior the application of the dyeing composition.

Abstract: Disclosed are triarylmethane dyes of formula (1) D1-(Z1J)r-Y1—S-A, wherein A is hydrogen; a radical of formula (1b) *—S—Y2-(Z2)-D2; or a radical of formula (1c) *—S—Y3; Y1 and Y2 independently from each other are unsubstituted or substituted, straight-chain or branched, interrupted or uninterrupted C1-C10alkylene; C5-C10cycloalkylene; C5-C10arylene; or —C5-C10arylene-(C1-C10alkylene); Y3 is an unsubstituted or substituted, straight-chain or branched, interrupted or uninterrupted C1C10alkyl; C5-C10cycloalkyl; C5-C10aryl; or —C5-C10aryl-(C1-C10alkyl); Z1 and Z2 independently from each other are *—(CH2)p—C(O)—**; *—(CH2CH2—O)—**; *—(CH2)p—C(O)O—**; *—(CH2)p—OCO—**; —(CH2)p—N(R1)—**; —(CH2)p—CON(R1)—**; —(CH2)p—(R1)NC(O)—**; -0-; —S—; —S(O)—; —S(O)2—; or a cationic biradical of a substituted or unsubstituted aromatic or heteroaromatic compound of the formula (1a); (1b); (1c); (1d); or (1e); wherein the asterix * indicates the linkage to D1 and/or D2; the asterix ** indicates the linkage to Y1 and/or Y2; W1 is N o

Abstract: Disclosed are mixtures of sulfide dyes and dyeing compositions comprising mixtures of sulfide dyes. The dye mixtures are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.

Abstract: The invention relates to keratin-binding effector molecules comprising reactive dyes and keratin-binding polypeptides and to their use in hair-dyeing preparations. The present invention further relates to a method of dyeing hair.

Abstract: Peptides have been identified that bind with high affinity to hair. Peptide-based hair reagents formed by coupling a hair-binding peptide to a benefit agent are described. The peptide-based hair reagents include peptide-based hair conditioners and hair colorants. The peptide-based hair conditioners and hair colorants are comprised of at least one hair-binding peptide coupled to a hair conditioning agent or a coloring agent, respectively.

Abstract: The present invention is related to an aqueous colouring composition for keratin fibres especially human hair based on hair direct dyes and optionally oxidative dyes and comprising at least one arylated silicone.

Abstract: Formula (I) wherein R1 and R2 each independently from each other are a residue of an organic dye: Y1 and Y2 each independently from each other are unsubstituted or substituted, straightchain or branched, interrupted or uninterrupted —C1-C10alkylene-; —C5-C10cycloalkylene-; C5-C10arylene; or —C5-C10arylene-(C1C10alkylene)-; Z1 and Z2 independently from each other are Formula (II) are each independently from each other hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); r, q and n independently from each other are 0 or 1, if n is 0, Z3 is hydrogen; and if n is 1, Z3 is —S—; with the proviso that the method does not comprise treating the fiber with an enzyme of the type of a protein disulfidisomerase (EC 5.3.4.1).

Abstract: A composition and kit for hair dyeing comprising a first liquid containing an alkaline ingredient and an oxidation dye and a second liquid containing an oxidant wherein the improvement being the addition of a chlorophyll derivative, such as sodium iron chlorophyllin, into the first liquid.

Abstract: The present disclosure provides dye compositions comprising at least one hydrophobic direct dye with a logP of greater than 2, at least one organic or mineral acid with a pKa of less than 4.5, in an aqueous-alcoholic dyeing medium comprising at least 60% by weight of water relative to the total weight of the composition, the pH of the composition being less than 7. The compositions allow shades ranging from pastel to strong colorations to be obtained on keratin fibers. Furthermore, the coloration obtained makes it possible to achieve or even exceed the fastness of oxidation dyeing.

Abstract: Disclosed herein is a rapid dyeing process for human keratin fibers, such as hair, comprising applying to the keratin fibers at least one dye composition comprising, in a medium suitable for dyeing, at least one direct dye chosen from arylmethane dyes, cationic azo dyes, methine dyes, azomethine dyes and azine dyes; maintaining the composition in contact with the keratin fibers for a leave-in time of less than 5 minutes; and rinsing the treated keratin fibers; wherein the resulting coloration has, according to the CIELAB notation, an L* value of less than 40 and/or a C* value of greater than 20, such as greater than 25, when the composition is applied to natural hair containing 90% white hairs at a temperature of 27° C.±5° C. for a period of 4 minutes, for a bath ratio of 10. Further disclosed herein is a process for stripping the keratin fibers colored with the direct dye, comprising applying an oxidizing or reducing treatment in a time period of less than 5 minutes.

Abstract: The invention relates to the use, for dyeing keratin fibres, of at least one latent pigment, which is soluble in a medium that is suitable for dyeing, and which can be chemically, thermally or photochemically converted in the fibres into water-insoluble pigments, of formula A(B)x with A representing the chromophoric radical of dyes, and B representing a hydrogen atom or a group of formula (II) with Z representing a cationic water-solubilizing group Z+ or a polyethylene glycol residue, Y representing a hetero atom, F and F? representing a linear or branched C1-C14 alkylene chain, which may contain hetero atoms and may be substituted with one or more hydroxyl, amino or halogen groups. The invention also relates to processes for dyeing keratin fibres using latent pigments, to particular compositions containing them and to multi-compartment dyeing devices or “kits”.

Abstract: The present disclosure relates to the process of dyeing human keratinous fibers, such as the hair, with at least one specific direct dye in cosmetic compositions. Also disclosed herein are the direct dyeing and lightening compositions comprising said compounds, and the corresponding dyeing kits.

Abstract: Process of coloring porous material, which comprises a) applying to the material being colored at least one capped diazonium compound, and b) then causing the capped diazonium compound present on the material to react with the material.

Abstract: The present invention relates to a method of coloring keratin-containing fibres, especially human hair, in which method a compound of formula (I), wherein R is hydroxy or NHR1, R1 being hydrogen or C1–C4alkyl, and B is an aromatic or heterocyclic ring, is diazotised, and the resulting diazonium salt is applied at a pH of from 2 to 5 to the material being colored and then, by means of increasing the pH to from 7 to 12, is fixed on the material in the form of an oligomeric or polymeric colorant

Abstract: The present disclosure relates to a composition for dyeing human keratin fibers, such as the hair, comprising, in a medium suitable for dyeing, at least one direct dye and at least on dicationic compound. Also disclosed herein is a process for dyeing and lightening human keratin fibers, such as the hair, with the compositions disclosed, as well as a the corresponding dyeing kits.

Abstract: The present invention provides a herbal black dye from natural materials comprising of Juglans regia, Indigofera tinctoria, Terminalia chebula, Acacia accocina, Lawsonia inermis, Trigonella foenum-graecum, Sapindus mukorossi, Eclipta alba, Embelica officinalis, Acacia catechu and Piper betle, the dye derived being safe, non toxic, anti-allergic, anti-dandruff and free from toxic symptoms like itching.

Abstract: The present invention relates to the use of organomodified metallic nanoparticles preferably bearing at their surface a self-assembled monolayer of organosulphur compounds. A preferred use is in suspension form for dyeing and/or treating human keratin fibers. The invention also relates to a process for dyeing and/or treating human keratin fibers, by the application to the keratin fibers of such a suspension, and also to compositions used to perform such a process. The invention includes the colouring and/or treating of human keratin fibers, in particular the hair, with the invention suspension. Compositions of the nanoparticles with cosmetic active principles, and uses thereof, also are described.

Abstract: The present invention relates to novel reactive dyes of formula I, (I), in which the variable independently denote X hydrogen, NO2, or NR3R4, Y NR5R6, OR7, SR8, or SO2R9 or a group suitable as a leaving group under the conditions of nucleophilic, aromatic substitution, R1 to R9 independently hydrogen, C1–C8 alkyl, C2–C8 alkyl, in which non-adjacent CH2 groups can be replaced by oxygen atoms, imino groups, or C1–C4 alkylimino groups, and/or CH2 groups may be replaced by carbonyl groups, C2–C8 alkenyl, or a group containing an active site or the precursor of an active site, with the proviso that at least one group R1 to R9 is present which contains an active site or the precursor of an active site. The present invention also relates to the use of the reactivedyes of formula I for dyeing substrates containing nucleophilic groups, and to compositions containing at least one reactive dye of formula I.

Abstract: The present invention relates to a composition comprising, in a cosmetically acceptable support suitable for dyeing the hair, at least one direct dye and at least one crosslinked polymer containing acrylic residue units of the structure in which R1 denotes H, CH3 or C2H5, and C10–C30 alkyl acrylate residue units, wherein the composition is a direct dyeing composition for the hair, and wherein said at least one direct dye is an anthraquinone or azo dye which is acidic or cationic.

Abstract: A method for electrochemically dyeing, highlighting or tinting hair is provided which includes first applying to the hair an oxidative dye precursor mixture containing a primary intermediate having a standard Redox potential that is less than about 1V. This precursor mixture on the hair in then contacted with an electrode system that has sufficient voltage to electrochemically oxidize the primary intermediate to produce a colored dye through a coupling reaction. A system or kit for carrying out the method is also provided.

Abstract: The present invention relates to novel reactive dyes of the formula (I) where R1 to R4 are independently hydrogen, C1–C8-alkyl, C2–C8-alkyl, wherein nonadjacent CH2 groups may be replaced by oxygen atoms or imino or C1–C4-alkylimino groups and/or CH2 groups by carbonyl groups, C2–C8-alkenyl, aryl, arylalkylene or a moiety containing a reactive group or the precursor of a reactive group, with the proviso that at least one of R1 to R4 is a moiety which contains a reactive group or the precursor of a reactive group. The present invention further relates to the use of the reactive dyes of the formula (I) for dyeing substrates containing nucleophilic groups and to preparations containing at least one reactive dye of the formula (I).

Abstract: The invention relates to cationic aminodianthraquinones containing at least one cationic group Z, Z being chosen from quaternized aliphatic chains, aliphatic chains containing at least one quaternized saturated ring and aliphatic chains containing at least one quaternized unsaturated ring, their use as direct dye in compositions for dyeing keratinous materials, in particular human keratinous fibers such as hair, the dyeing compositions containing them, as well as the dyeing methods using them.

Abstract: The cationic dyes of formula (1) specified in claim 1 are suitable especially for colouring keratin-containing fibres, more especially for colouring hair.

Abstract: The present invention relates to the use for dyeing keratin fibers, in particular human keratin fibers such as the hair, of a dye precursor bearing at least one phosphate substituent of formula —O—PO(OH)2, in the presence of at least one acid or alkaline phosphatase.

Abstract: A method for electrochemically dyeing hair is provided which includes first applying to the hair an oxidative dye precursor mixture containing a primary intermediate having a standard Redox potential that is less than about 1V. This precursor mixture on the hair is then contacted with an electrode system that has sufficient voltage to electrochemically oxidize the primary intermediate to produce a colored dye through a coupling reaction. A system or kit is described for carrying out the method.

Abstract: A reactive dye compound comprising: (a) at least one chromophore moiety; (b) at least one SO2C2H4 group which is attached to the chromophore moiety either directly via the sulphur atom of the SO2C2H4 group or via a linking group L; characterized in that at least one SO2C2H4 group is substituted on its terminal carbon atom with at least one Y group wherein Y is derived from a hydrated aldehyde, a hydrated ketone, a hydrated alpha-hydroxy ketone or the hydrated form of formic acid, and linked via one of its oxygen atoms to the terminal carbon of the SO2C2H4 group thereby forming a hemiacetal.

Abstract: A hair coloring composition or kit of parts comprises: a compound which is capable of acting as a substrate for endogenous transglutaminase in and/or on hair and which comprises a chromophore that is capable of absorbing and/or emitting light in the visible part of the electromagnetic spectrum; and a reducing agent. The composition may be used to coloring hair.

Abstract: A method of coloring hair comprises: treating hair with an oxidizing agent; and applying to the hair either during or after treatment with the oxidizing agent a composition comprising a compound which is capable of acting as a substrate for endogenous transglutaminase in and/or on the hair and which comprises a chromophore that is capable of absorbing and/or emitting light in the visible part of the electromagnetic spectrum. Products for use in the method comprise the oxidizing agent packaged separately from the compound.

Abstract: A reactive dye compound comprising: (a) at least one chromophore moiety; (b) at least one SO2C2H4 group which is attached to the chromphore moiety either directly via the sulphur atom of the SO2C2H4 group or via a linking group L; characterized in that at least one SO2C2H4 group is substituted on its terminal carbon atom with at least one Y group wherein Y is a phosphonate or borate derivative.

Abstract: A reactive dye compound comprising: (a) at least one chromophore moiety; (b) at least one nitrogen-containing heterocycle (c) a linking group to link each chromophore moiety to each nitrogen-containing heterocycle; characterized in that at least one nitrogen-containing heterocycle is substituted with at least one Y group wherein Y is derived from a hydrated aldehyde, a hydrated ketone, a hydrated alpha-hydroxy ketone, or the hydrated form of formic acid and linked via one of its oxygen atoms to the nitrogen-containing heterocycle thereby forming a hemiacetal.

Abstract: A reactive dye compound comprising: (a) at least one chromophore moiety (b) at last one SO2C2H4 group which is attached to the chromophore moiety either direcly via the sulphur atom of the SO2C2H4 group or a linking group L; characterized in that at least one SO2C2H4 group is substituted on its terminal carbon atom with at least one Y group wherein Y is —A(CO)R* wherein A is selected from O or S and wherin R′ contains at least one terminal nucleophilic group, such as OH, NH2, SH, COOH, N, NHR1 and NR1R2 wherein R1 and R2 may be the same of different and may be selected from C1-C4 alkyl; and salts therof. Also claimed is a process of manufacture of the compounds herein and products obtainable by the process.

Abstract: A reactive dye compound comprising: (a) at least one chromophore moiety (b) at least one nitrogen-containing heterocycle (c) a linking group to link each chromophore moiety to each nitrogen-containing heterocycle; characterised in that at least one nitrogen-containing heterocycle is substituted with at least one oxy- or thio-carbonyl derivative wherein the oxy- or thio-carbonyl derivative is selected from Y wherein Y is —A(CO)R* wherein A is selected from O or S and wherein R* is an organic residue which comprises at least one nucleophilic group, and salts thereof.

Abstract: A coloring system for hair and/or skin comprises at least three separately packaged components: a) a thio compound capable of breaking the S—S bond between cysteine residues, and an alkaline reagent; b) a material and/or extract obtainable from the mucuna plant; and c) an oxidizing agent.