Dye Reactive With Hair Patents (Class 8/428)
  • Patent number: 4931066
    Abstract: The invention relates to a dyeing composition for keratinous fibres containing, in a suitable vehicle, at least one 2-nitro-para-phenylenediamine direct dye, in free or salified form and also at least one xanthine derivative of formula (II) ##STR1## where n=0 or 1, R'.sub.3 =H, R'.sub.1, R'.sub.2, R'.sub.4 and R'.sub.5 are substituents having various significances, the said compound of formula (II) being in free or salified form. They can be used for dyeing hair.
    Type: Grant
    Filed: August 9, 1985
    Date of Patent: June 5, 1990
    Assignee: L'Oreal
    Inventors: Jean-Francois Grollier, Jean Cotteret, Georges Rosembaum
  • Patent number: 4895575
    Abstract: The invention relates to the use of 5-hydroxy-1,4-naphthoquinones of the formula: ##STR1## in which R.sub.1 and R.sub.2, which are identical or different, independently of one another denote a hydrogen atom, a methyl, methoxy or nitro group or a halogen atom; R.sub.3 and R.sub.4, which are identical or different, independently of one another denote a hydrogen atom or a hydroxyl, methyl or methoxy group; and R.sub.5 denotes a hydrogen atom or a methyl or methoxy group, with the proviso that at least one of the substituents R.sub.1 and R.sub.2 is different from hydrogen, if R.sub.3, R.sub.4 and R.sub.5 simultaneously denote a hydrogen atom, for dyeing human keratin fibres, in particular the hair.
    Type: Grant
    Filed: June 23, 1988
    Date of Patent: January 23, 1990
    Assignee: L'Oreal
    Inventors: Michel Hocquaux, Jean Cotteret, Georges Rosenbaum
  • Patent number: 4888025
    Abstract: The present invention relates to new 1-(substituted phenoxy)-3-aminopropan-2-ol compounds in which the extra-nuclear amine group may or may not be substituted, and to the process for their preparation. The invention also relates to hair-dyeing compositions containing these new compounds and to a dyeing process using the said compositions.
    Type: Grant
    Filed: June 7, 1985
    Date of Patent: December 19, 1989
    Assignee: L'Oreal
    Inventors: Andree Bugaut, Alain Genet
  • Patent number: 4888026
    Abstract: The use in dyeing human keratin fibres, especially human hair, of 2-hydroxy-1,4-naphthoquinones of the formula: ##STR1## in which R.sub.1 denotes a hydrogen or halogen atom, or a hydroxy, alkoxy, nitro, alkyl or acyl group, and R.sub.2, R.sub.3, R.sub.4 and R.sub.5 independently of one another denote hydrogen or a hydroxyl, alkoxy, alkyl or acyl group, such that at least one of the substituents R.sub.1 to R.sub.5 is other than hydrogen, and if R.sub.1, R.sub.3 and R.sub.4 denote hydrogen, R.sub.2 and R.sub.5 cannot simultaneously denote hydroxyl is described.
    Type: Grant
    Filed: December 28, 1984
    Date of Patent: December 19, 1989
    Assignee: L'Oreal
    Inventors: Gerard Lang, Serge Forestier, Michel Hocquaux, Jean-Francois Grollier, Georges Rosenbaum
  • Patent number: 4867751
    Abstract: The invention relates to the use, for dyeing keratin fibres, and in particular human hair, of benzoquinone derivatives of the formula: ##STR1## in which R.sub.1 and R.sub.3 independently of one another denote hydrogen, a hydroxyl group, an alkoxy group or an optionally hydroxylated alkyl group, and R.sub.2 and R.sub.4 independently of one another denote hydrogen, hydroxyl, alkoxy, alkyl, or phenyl optionally substituted by OH, these compounds having at most two alkyl or alkoxy groups on the quinone ring; if one of the radicals R.sub.1, R.sub.2, R.sub.3 or R.sub.4 denotes a methyl, hydroxyl or methoxy group, at least one of the other substituents is different from hydrogen, and if two of these substituents R.sub.1, R.sub.2, R.sub.3 or R.sub.4 are identical and located in the para-position relative to one another and denote hydroxyl or methoxy, at least one of the other two substituents is different from hydrogen.
    Type: Grant
    Filed: December 17, 1984
    Date of Patent: September 19, 1989
    Assignee: L'Oreal
    Inventors: Gerard Lang, Alain Malaval, Jean-Francois Grollier, Georges Rosenbaum
  • Patent number: 4863481
    Abstract: The invention relates to oxidation dyeing compositions comprising oxidation dyestuff precursors and N-substituted ortho-nitroanilines of the formula: ##STR1## in which R.sub.1 denotes an alkyl, monohydroxyalkyl or polyhydroxyalkyl group, R.sub.2 denotes hydrogen or an amino, monoalkylamino, dialkylamino, mono- or di-(monohydroxyalkyl or polyhydroxyalkyl)-amino, (N-alkyl-N-monohydroxyalkyl or N-alkyl-N-polyhydroxyalkyl)-amino, alkoxy, monohydroxyalkoxy, polyhydroxyalkoxy or aminoalkoxy group and R.sub.3 denotes hydrogen or an alkyl group, at least one of R.sub.2 and R.sub.3 being different from H, with the proviso that if R.sub.1 denotes --CH.sub.2 CH.sub.2 OH, R.sub.2 cannot be di-(monohydroxyalkyl)-amino in an alkaline medium which is non-ammoniacal and comprises an alkali metal or ammonium bisulphite and at least one alkanolamine which is N-(C.sub.1 to C.sub.4 -alkyl-ethanolamine, N,N-di(C.sub.1 to C.sub.4 -alkyl)-ethanolamine, di-(hydroxy-C.sub.2 to C.sub.
    Type: Grant
    Filed: January 3, 1983
    Date of Patent: September 5, 1989
    Assignee: L'Oreal
    Inventors: Christian Monnais, Jean Cotteret
  • Patent number: 4838893
    Abstract: This invention is directed to compositions of the developer-coupler type of the dyeing of hair, consisting essentially of substituted dihydroxypyridine compounds or salts thereof as coupling components and, as developer components, the conventional components used in oxidation dyes.
    Type: Grant
    Filed: June 24, 1987
    Date of Patent: June 13, 1989
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: David Rose, Norbert Maak, Edgar Lieske
  • Patent number: 4834768
    Abstract: A dyeing composition for the direct coloring of the hair, containing at least one direct dyestuff, and at least one xanthane gum is disclosed.
    Type: Grant
    Filed: December 11, 1987
    Date of Patent: May 30, 1989
    Assignee: L'Oreal
    Inventor: Jean F. Grollier
  • Patent number: 4799934
    Abstract: Novel sulfur containing nitroamino benzene dyes of formula: ##STR1## and salts thereof wherein (a) R.sub.1 and R.sub.2 are the same or different and are selected from the group consisting of alkyl, hydroxyalkyl, polyhydroxyalky, aminoalkyl, monoalkylamioalkyl and dialkylaminoalkyl,wherein(b) n is 0, 1 or 2, and wherein(c) the group ##STR2## occupies a position that is meta or para to the group-NHR.sub.1 ; a process for synthesizing these compounds and their use as direct dyeing hair dyes are being disclosed.
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: January 24, 1989
    Assignee: Clairol Incorporated
    Inventors: Mu-Ill Lim, James S. Anderson
  • Patent number: 4746322
    Abstract: The subject invention concerns novel dye compositions and a process for dyeing keratinous fibers, for example, hair, to give a pleasing and stable colored product. The dye composition is a novel combination of three elements to give a dye that, unexpectedly, has highly desirable dyeing properties. This unique combination comprises (1) a suitable organic compound to assist dye dispersion, (2) dye precursors including dopamine, D-dopa, L-dopa, D,L-dopa, or analogs thereof, and (3) iodate or periodate. Desired color variations can be obtained by the use of appropriate color modifiers.
    Type: Grant
    Filed: May 11, 1987
    Date of Patent: May 24, 1988
    Assignee: Repligen Corporation
    Inventor: Walter C. Herlihy
  • Patent number: 4690685
    Abstract: The invention relates to a dyeing composition for keratinous fibres containing at least one 4-bis(.beta.-hydroxyethyl)amino-2-nitro-1-(N-substituted amino)benzene compound in which the substitution is C.sub.1 -C.sub.3 alkyl or .beta.-hydroxyethyl; this composition contains as co-solubilization agent at least one dye of formula (II) ##STR1## in which formula: R.sub.2 denotes a C.sub.2 -C.sub.3 hydroxyalkyl group;R.sub.3 denotes a C.sub.2 -C.sub.3 hydroxyalkyl group; with the proviso that, if R.sub.3 =CH.sub.2 CH.sub.2 OH, R.sub.2 is necessarily an .alpha.-hydroxyethyl or hydroxypropyl radical.
    Type: Grant
    Filed: September 26, 1985
    Date of Patent: September 1, 1987
    Assignee: L'Oreal
    Inventors: Jean-Francois Grollier, Jean Cotteret, Alex Junino, Alain Genet
  • Patent number: 4668236
    Abstract: The invention relates to a dyeing composition for keratinous fibres containing, in a suitable vehicle, at least one nitrated direct dye of the 2-nitro-paraphenylenediamine series, in which the amino group in position 4 is mono- or disubstituted with lower alkyl or hydroxyalkyl radicals and in which the amino group in position 1 is optionally monosubstituted with a lower alkyl or hydroxyalkyl radial, and the aromatic ring can be substituted or unsubstituted on the remaining positions; the invention consists in introducing into such a composition an imidazolidinedione or one of its substitution derivatives, to improve the solubility of the abovementioned nitrated direct dye by a co-solubilization phenomenon. The invention also relates to a process for dyeing keratinous fibres using such compositions.
    Type: Grant
    Filed: June 14, 1985
    Date of Patent: May 26, 1987
    Assignee: L'Oreal
    Inventors: Jean-Francois Grollier, Jean Cotteret, Georges Rosenbaum
  • Patent number: 4637821
    Abstract: A process for dyeing keratin fibres is disclosed which involved applying:(a) at least one dyestuff of the formula: ##STR1## in which R.sub.1 and R.sub.2 independently designate hydrogen, amino, alkylamino, --NH--aliphatic--(X).sub.m, dialkylamino or --N--(aliphatic-(X).sub.m).sub.2, R.sub.3 designates hydrogen, OH, alkoxy or --O--aliphatic-(X).sub.m "aliphatic" designates an aliphatic radical having 2 to 4 free valencies, m designates an integer from 1 to 3 such that if m=1 X represents OH, Cl, OCH.sub.3 or OCH.sub.2 CH.sub.2 OH, or, if m designates 2 or 3, X designates OH, and R.sub.4 designates hydrogen, alkyl or halogen, with the proviso that at least one of R.sub.1, R.sub.2 and R.sub.3 is other than hydrogen, and that, if R.sub.1 and R.sub.2 are both other than hydrogen, R.sub.3 designates hydrogen,(b) at least one dyestuff of the formula: ##STR2## in which R.sub.5 designates hydrogen, amino, aminoalkyl, NH-aliphatic-(X).sub.m, N-(alkyl).sub.2, N-(aliphatic(X).sub.m).sub.2, or NHCH.sub.2 CH.sub.2 NH.sub.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: January 20, 1987
    Assignee: L'Oreal
    Inventors: Christian Monnais, Jean Cotteret
  • Patent number: 4555246
    Abstract: A process for preparing a hair dye or bleach composition which comprises mixing a gelifiable liquid vehicle with an oxidizing solution having dissolved therein an incompatible cationic polymer. The resulting gel is applied to the hair and after an appropriate contact time, the hair is rinsed.
    Type: Grant
    Filed: April 2, 1982
    Date of Patent: November 26, 1985
    Assignee: L'Oreal
    Inventors: Jean-Francois Grollier, Christian Monnais, Lyonel Peritz
  • Patent number: 4555247
    Abstract: The dyeing compositions of the invention comprise at least one violet nitro dyestuff having a shade, on the Munsell scale, ranging from 7.5 P to 10 PB, and at least one yellow nitro dyestuff having a shade, on the Munsell scale, ranging from 10 Y to 2.5 Y, these violet and yellow dyestuffs being present in proportions such that their selectivity coefficients are substantially equal, the coefficients being from 3 to 8 when determined at a concentration of 0.1 to 0.6% by weight, the ratio by weight of the violet dyestuff to the yellow dyestuff being from 1:1 to 3:1.
    Type: Grant
    Filed: October 26, 1984
    Date of Patent: November 26, 1985
    Assignee: L'Oreal
    Inventors: Roland de la Mettrie, Patrick Canivet
  • Patent number: 4511360
    Abstract: Dyeing compositions are disclosed which comprise at least one oxidation dyestuff precursor in combination with at least one direct dyestuff, in an aqueous vehicle, the direct dyestuff being a nitro derivative of the benzene series having the formula: ##STR1## in which R.sub.1 denotes the methyl group, R.sub.2 and R.sub.4 denote hydrogen and R.sub.3 denotes the .beta.-hydroxyethoxy group, or alternatively R.sub.1, R.sub.3 and R.sub.4 denote hydrogen and R.sub.2 denotes the methyl or hydroxyl group, or alternatively R.sub.1 and R.sub.2 denote hydrogen, R.sub.3 denotes the methyl group and R.sub.4 denotes the hydroxyl, (.beta.-hydroxyethyl)-amino or (.beta.-N,N-diethylaminoethyl)-amino group, or R.sub.1, R.sub.2 and R.sub.3 denote hydrogen and R.sub.4 denotes the N,N-bis-(.beta.-hydroxyethyl)-amino group.
    Type: Grant
    Filed: October 14, 1981
    Date of Patent: April 16, 1985
    Assignee: L'Oreal
    Inventors: Christian Monnais, Jean Cotteret, Andree Bugaut
  • Patent number: 4358286
    Abstract: This invention has for its object new cosmetic compositions for treating hair and skin containing a powder of plant origin obtained from extraction residues of various plants.
    Type: Grant
    Filed: December 31, 1980
    Date of Patent: November 9, 1982
    Assignee: L'Oreal
    Inventors: Jean-Francois Grollier, Josiane Allec, Chantal Fourcadier, Georges Rosenbaum, Patrick Darmenton