Diffusion Transfer Dyeing Process, Transfer Sheet And Product Patents (Class 8/467)
  • Patent number: 4795477
    Abstract: The printability of oxymethylene polymers such as by the heat transfer of sublimable dyes is improved by the addition of an amorphous or partially crystalline polymer to the oxymethylene polymer molding composition.
    Type: Grant
    Filed: July 16, 1986
    Date of Patent: January 3, 1989
    Assignee: Celanese Corporation
    Inventors: Rajal Kusumgar, K. M. Natarajan, Carl A. Amond
  • Patent number: 4767420
    Abstract: The transfer sheet or web is intended for the use in a heat transfer printing process of cotton, of cotton-polyester blend or of nitrogen containing textile fibers such as wool, silk or nylon.It comprises on its surface at least one organic impregnating agent which has a melting point between 60.degree. and 230.degree. C. and is no polymer, at least one water insoluble, non-subliming dyestuff, and the minimum amount of a binder. The dyestuff forms a pattern or image which is heat contact printed on said textile substrate without the use of carrier vapors or vacuum. The pattern to be heat transferred may also be prepared in an electrophotographic process using a new toner comprising particles of impregnating agent, binder and dyestuff.The pattern on the transfer support is transferred at a temperature between 160.degree. and 230.degree. C. during 30 to 60 seconds to said textile substrate. The printings obtained have very good light, rubbing and washing fastnesses; the handling is not impaired.
    Type: Grant
    Filed: January 23, 1987
    Date of Patent: August 30, 1988
    Assignee: Sicpa Holding S.A.
    Inventors: Wolfgang Mehl, Albert Amon
  • Patent number: 4682983
    Abstract: The transfer sheet is used for dry thermal printing of water swellable celluluse fibers with dyestuffs which are insoluble in water of 60.degree. C. The dyestuffs are difficult to evaporate and cannot be used in a conventional heat transfer printing process. They are transferred at 230.degree. C. and a contact pressure of 10.sup.4 -10.sup.6 Pa from a base paper provided with a release coating, to cellulose fibers which have been swollen with water and the swollen state of which has been preserved after drying with a polyglycol. I order to increase the penetration of dyestuffs into the textile structure, it is recommended to lower the air pressure in the transfer area down to a pressure ranging from 1 to 5.times.10.sup.4 Pa.
    Type: Grant
    Filed: March 12, 1986
    Date of Patent: July 28, 1987
    Assignee: Sicpa Holding S.A.
    Inventor: Wolfgang Mehl
  • Patent number: 4587155
    Abstract: A method of applying a dye image to a plastic member and the image bearing member thereby formed. A disperse dye having a melting point which is below the thermal deflection temperature of the plastic of the member and a vaporization point which is above said deflection temperature is applied to a surface of the member in a desired image. The dye bearing plastic is then heated to a temperature which is above the melting point of the dye and below the thermal deflection temperature of the plastic, but which is nevertheless high enough to cause some softening of said plastic. The dye is then permitted to diffuse into the plastic to provide a sharp, clear and durable image thereon.
    Type: Grant
    Filed: March 15, 1985
    Date of Patent: May 6, 1986
    Assignee: Raymond Iannetta
    Inventor: David Durand
  • Patent number: 4576610
    Abstract: This invention provides an improved method for sublimation dye transfer printing of a sublimable dye onto fabric by applied heat, comprising applying a composition comprising a polyester resin to the fabric, in which the polyester resin chemically bonds the dye to the fabric, to yield a fabric having a soft hand and deep color which is fast through repeated laundering. In preferred embodiments, the polyester resin has free carboxyl groups. In another embodiment, a conventional dye binder is also applied to the fabric. In a further modification, metallic glitter is added to the dye. The present invention also provides dye bonding compositions for bonding sublimable dyes to fabrics, and sublimation dye transfer printing elements incorporating the compositions of the invention.
    Type: Grant
    Filed: April 8, 1983
    Date of Patent: March 18, 1986
    Assignee: Doncroft Colors & Chemicals, Inc.
    Inventor: Henry Donenfeld
  • Patent number: 4455147
    Abstract: Color yield of the coloration processes for textile and like materials, more especially of sublimable dyes applied by transfer printing, is enhanced by pretreatment of the material by deposition of 1 to 10% surfactant or other amphipathic substance. Preferred substances are cationic, anionic or non-ionic surfactants, which may be applied from aqueous solution at levels of 1 to 10% on the weight of the material. The material is dried before printing. The surfactants can be accompanied by swelling agents, catalysts or cross-linking agents. Preferred dyes for the printing stage are sublimable dyes containing chelatable groups, fibre-reactive groups or cross-linkable groups.
    Type: Grant
    Filed: March 26, 1981
    Date of Patent: June 19, 1984
    Assignees: I.W.S. Nominee Company, Limited, Commonwealth Scientific and Industrial Research Organization
    Inventors: David M. Lewis, Peter R. Brady, Peter G. Cookson, Keith W. Fincher
  • Patent number: 4383018
    Abstract: A color imaging device which comprises an adhesive layer between (a) means for sensing radiation comprising a planar array of charge-handling semiconductive photosensors, and (b) superimposed filter means for controlling access of radiation to the sensing means comprising a transparent polymer layer capable of receiving dyes such as heat transferable dyes; the adhesive layer comprising a polyester selected from the group consisting of (1) polyesters having recurring carboxylate units of which at least 80 mole percent are terephthalate units, and recurring alkylene units derived from glycols of which at least 40 mole percent are ether alkylene units, with the proviso that either (a) the recurring alkylene units comprise at least 60 mole percent ether alkylene units or (b) either the recurring carboxylate units comprise at least 2 mole percent pyromellitic tetracarboxylate units or at least 10 mole percent of linear aliphatic dicarboxylate units having at least 8 carbon atoms, and that when at least 10 mole per
    Type: Grant
    Filed: December 12, 1980
    Date of Patent: May 10, 1983
    Assignee: Eastman Kodak Company
    Inventors: Thomas W. Martin, M. Akram Sandhu
  • Patent number: 4310327
    Abstract: In an improved method for the wet transfer printing of wool or wool-rich fabric the untreated fabric has introduced into it, as part of the wet transfer printing process, chlorine or a chlorine donor. The chlorine or chlorine donor is introduced before dye is transferred to the fabric, and when a chlorine donor is used as impregnating liquor for wet-transfer printing can be used to release chlorine from the donor.
    Type: Grant
    Filed: October 22, 1979
    Date of Patent: January 12, 1982
    Assignee: Transprints (U.K.) Limited
    Inventors: Malcolm L. Winterbottom, Donald W. H. Burtonshaw
  • Patent number: 4304565
    Abstract: A process is disclosed for the heat transfer printing of cellulose-containing fabrics in garment form with disperse dyestuffs, wherein the fabric is treated only on one side by a printing or spraying technique with a formulation containing highly methylated melamine-formaldehyde crosslinking agent, acid catalyst, and other necessary additives. Fabrics with prints that are durable to washing are produced by simultaneously heat transfer printing and curing at about 190.degree. C. to 220.degree. C. for 20-30 seconds.
    Type: Grant
    Filed: December 3, 1980
    Date of Patent: December 8, 1981
    Assignee: The United States of America as represented by the Secretary of Agriculture
    Inventors: Eugene J. Blanchard, Gloria A. Gautreaux, Robert J. Harper, Jr.
  • Patent number: 4302201
    Abstract: A method for developing electrical latent images is disclosed in which electrically formed latent images are developed by using a mixture of at least two different toners having the same polarity. The two or more different kinds of toners in the mixture have a difference in triboelectric charge between them less that 10 .mu.c/g. Furthermore, developing is carried out by using a liquid developer containing a mixture of at least two different toners having the same polarity. Each of the toners in the mixture should have a Zeta-potential more than 50 mV in absolute value and the difference in Zeta-potential between the different kinds of toners should be less than 50 mV.
    Type: Grant
    Filed: May 14, 1979
    Date of Patent: November 24, 1981
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuo Hasegawa, Katsumi Nagamatsu, Yoshihiro Nishikawa
  • Patent number: 4294637
    Abstract: A wide composite band of a patterned transfer-carrying sheet is formed of several webs or web sections secured together parallel or perpendicular to the band with the patterns of adjacent webs or web sections in registration. Webs may for example be fed side-by-side parallel to one another and any staggering of the pattern corrected by suitable adjustment of web tensioning rollers by detecting reference marks corresponding to the pattern. The webs are then joined by sticking, or could be directly used for transfer printing without being secured together. Alternatively, a web is fed perpendicular to the band being formed, and cut into sections which are adjusted relative to the band by detecting reference marks, and joined to the band.
    Type: Grant
    Filed: December 21, 1977
    Date of Patent: October 13, 1981
    Assignee: Bjorn Sigurd Rump
    Inventor: Bjorn S. Rump
  • Patent number: 4287017
    Abstract: An endless pressing-on and guiding belt including a belt piece having its end faces joined together, for textile treating devices, especially transfer printing machines and steaming calenders, with a rotary drum having a longitudinal section of the endless belt partially looped therearound while textile material to be treated is interposed between the drum and the belt, the latter being heated on the drum. The endless belt includes a fabric with a bronze-solid wire warp and a weft of a metallic nickel-alloy solid wire with the bronze solid wire warp extending in the longitudinal direction of the belt.
    Type: Grant
    Filed: November 5, 1979
    Date of Patent: September 1, 1981
    Assignee: Kleinewefers GmbH
    Inventors: Karl-Peter Lopata, Wolfgang Tschirner
  • Patent number: 4271224
    Abstract: A transfer sheet comprising, in laminated combination, a substrate sheet and, provided thereabove, a coloring layer of desired pattern containing a coloring agent possessing heat transferability and a resist layer of a desired pattern containing a metal compound for resist printing and a binder, the metal compound having the capability of causing the coloring layer to lose its heat transferability, either of the coloring layer and the resist layer being nearer than the other to the substrate sheet. Because of the capability of the metal compound, the resist power is very great, whereby ample resist printing effect can be obtained with only an extremely thin resist layer.
    Type: Grant
    Filed: February 1, 1980
    Date of Patent: June 2, 1981
    Assignee: Dai Nippon Insatsu Kabushiki Kaisha
    Inventors: Shogo Mizuno, Takao Suzuki, Sadanobu Kawasaki, Hideichiro Takeda
  • Patent number: 4239842
    Abstract: An improved color filter array comprises a transparent heat-transfer dye-receiving layer containing an array of filter elements wherein the dye-receiving layer is a certain polyester wherein at least 30 mole percent of the recurring units contain a saturated gem-bivalent radical having a saturated polycyclic three-dimensional structure that includes a saturated bicyclic atomic bridge hydrocarbon ring member. The improved dye-receiving layers provide filter elements with excellent edge sharpness. The improved color filter arrays are useful in color imaging devices, such as solid-state video cameras.
    Type: Grant
    Filed: September 13, 1979
    Date of Patent: December 16, 1980
    Assignee: Eastman Kodak Company
    Inventor: Mohammad A. Sandhu
  • Patent number: 4234481
    Abstract: The application is concerned with new pyrazolone compounds having the structure: ##STR1## wherein R is hydrogen or halogen (especially fluorine, bromine and chlorine) and R.sub.1 and R.sub.2 independently of one another are hydrogen or halogen (especially bromine and chlorine) and R.sub.3 is lower alkyl (especially methyl, ethyl, propyl and butyl). The compounds are useful in heat transfer printing of polyester fabrics and impart yellow shades thereto. The application discloses a method of making the new compounds and discusses the utilization of the compounds in the heat transfer printing of polyester fabrics, in the preparation of ink formulations, and in making transfer sheets for heat transfer printing.
    Type: Grant
    Filed: November 30, 1977
    Date of Patent: November 18, 1980
    Assignee: Crompton & Knowles Corporation
    Inventor: Russell I. Steiner
  • Patent number: 4231742
    Abstract: Heat Transfer prints are made by offset printing using a UV curable ink containing subliminal dyes printed onto a heat transfer backing, followed by rapid curing using UV light. The heat transfer prints are then used for dying fabric by applying the heat transfer print to the fabric, heating the print and thereby causing the dyes to sublimate and thereby transfer from the heat transfer print to the fabric where dying of the fabric occurs.
    Type: Grant
    Filed: February 28, 1979
    Date of Patent: November 4, 1980
    Assignee: Michael Huber Munchen, GmbH
    Inventors: Dieter Clausen, Albert Uhlemayr
  • Patent number: 4220700
    Abstract: There is disclosed a composition and element, comprising a diazo resin and a mordant for anionic dyes that is compatible with the resin. The element of the invention is suitable for dye immersion and dye transfer to a mordanted receiver.
    Type: Grant
    Filed: February 3, 1978
    Date of Patent: September 2, 1980
    Assignee: Eastman Kodak Company
    Inventors: Hugh G. McGuckin, Hyman L. Cohen
  • Patent number: 4218689
    Abstract: An ablative recording medium comprises a substrate coated with a light reflecting layer which in turn is coated with a light absorptive layer of 6,6'-diethoxythioindigo. During recording, portions of the light absorptive layer are ablated by a modulated focussed light beam, thereby exposing portions of the reflecting layer. Video information is recorded as a reflective-antireflective pattern.
    Type: Grant
    Filed: January 30, 1978
    Date of Patent: August 19, 1980
    Assignee: RCA Corporation
    Inventors: Allen Bloom, Robert A. Bartolini
  • Patent number: 4209297
    Abstract: Fabrics of preferrably polyester fibres can be printed in deep yellow colors with good fastness properties if dyestuffs of the formula ##STR1## wherein X denotes hydrogen, chlorine, methyl, nitro, CF.sub.3 or cyano,Y denotes methyl, methoxy, nitro or chlorine or cyano andZ denotes hydrogen, methyl, chlorine or cyano,R.sub.1 /R.sub.2 representing hydrogen, chlorine, methyl or methoxy, with the proviso that R.sub.1 and/or R.sub.2 denote chlorine, methyl or methoxy if X represents a nitro group,are used according to the transfer printing principle.
    Type: Grant
    Filed: January 27, 1978
    Date of Patent: June 24, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunter Stephan, Hartmut Birmes, Artur Haus, Erwin Plaza
  • Patent number: 4203722
    Abstract: Acid-modified fibre materials may be dyed in brilliant color shades in accordance with the transfer printing principle if dyestuffs of the formula ##STR1## are used in which A is a residue of the formula ##STR2## wherein R.sub.1, R.sub.3, R.sub.4, R.sub.6 -R.sub.9 are H or lower alkyl, R and R.sub.2 are lower alkyl and R.sub.5 is phenyl.The resulting transfer prints are distinguished by good fastness to light, wet processing and rubbing.
    Type: Grant
    Filed: October 18, 1978
    Date of Patent: May 20, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Alfred Brack, Hans-Peter Kuhlthau