Diffusion Transfer Dyeing Process, Transfer Sheet And Product Patents (Class 8/467)
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Patent number: 4795477Abstract: The printability of oxymethylene polymers such as by the heat transfer of sublimable dyes is improved by the addition of an amorphous or partially crystalline polymer to the oxymethylene polymer molding composition.Type: GrantFiled: July 16, 1986Date of Patent: January 3, 1989Assignee: Celanese CorporationInventors: Rajal Kusumgar, K. M. Natarajan, Carl A. Amond
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Patent number: 4767420Abstract: The transfer sheet or web is intended for the use in a heat transfer printing process of cotton, of cotton-polyester blend or of nitrogen containing textile fibers such as wool, silk or nylon.It comprises on its surface at least one organic impregnating agent which has a melting point between 60.degree. and 230.degree. C. and is no polymer, at least one water insoluble, non-subliming dyestuff, and the minimum amount of a binder. The dyestuff forms a pattern or image which is heat contact printed on said textile substrate without the use of carrier vapors or vacuum. The pattern to be heat transferred may also be prepared in an electrophotographic process using a new toner comprising particles of impregnating agent, binder and dyestuff.The pattern on the transfer support is transferred at a temperature between 160.degree. and 230.degree. C. during 30 to 60 seconds to said textile substrate. The printings obtained have very good light, rubbing and washing fastnesses; the handling is not impaired.Type: GrantFiled: January 23, 1987Date of Patent: August 30, 1988Assignee: Sicpa Holding S.A.Inventors: Wolfgang Mehl, Albert Amon
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Patent number: 4682983Abstract: The transfer sheet is used for dry thermal printing of water swellable celluluse fibers with dyestuffs which are insoluble in water of 60.degree. C. The dyestuffs are difficult to evaporate and cannot be used in a conventional heat transfer printing process. They are transferred at 230.degree. C. and a contact pressure of 10.sup.4 -10.sup.6 Pa from a base paper provided with a release coating, to cellulose fibers which have been swollen with water and the swollen state of which has been preserved after drying with a polyglycol. I order to increase the penetration of dyestuffs into the textile structure, it is recommended to lower the air pressure in the transfer area down to a pressure ranging from 1 to 5.times.10.sup.4 Pa.Type: GrantFiled: March 12, 1986Date of Patent: July 28, 1987Assignee: Sicpa Holding S.A.Inventor: Wolfgang Mehl
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Patent number: 4587155Abstract: A method of applying a dye image to a plastic member and the image bearing member thereby formed. A disperse dye having a melting point which is below the thermal deflection temperature of the plastic of the member and a vaporization point which is above said deflection temperature is applied to a surface of the member in a desired image. The dye bearing plastic is then heated to a temperature which is above the melting point of the dye and below the thermal deflection temperature of the plastic, but which is nevertheless high enough to cause some softening of said plastic. The dye is then permitted to diffuse into the plastic to provide a sharp, clear and durable image thereon.Type: GrantFiled: March 15, 1985Date of Patent: May 6, 1986Assignee: Raymond IannettaInventor: David Durand
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Patent number: 4576610Abstract: This invention provides an improved method for sublimation dye transfer printing of a sublimable dye onto fabric by applied heat, comprising applying a composition comprising a polyester resin to the fabric, in which the polyester resin chemically bonds the dye to the fabric, to yield a fabric having a soft hand and deep color which is fast through repeated laundering. In preferred embodiments, the polyester resin has free carboxyl groups. In another embodiment, a conventional dye binder is also applied to the fabric. In a further modification, metallic glitter is added to the dye. The present invention also provides dye bonding compositions for bonding sublimable dyes to fabrics, and sublimation dye transfer printing elements incorporating the compositions of the invention.Type: GrantFiled: April 8, 1983Date of Patent: March 18, 1986Assignee: Doncroft Colors & Chemicals, Inc.Inventor: Henry Donenfeld
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Patent number: 4455147Abstract: Color yield of the coloration processes for textile and like materials, more especially of sublimable dyes applied by transfer printing, is enhanced by pretreatment of the material by deposition of 1 to 10% surfactant or other amphipathic substance. Preferred substances are cationic, anionic or non-ionic surfactants, which may be applied from aqueous solution at levels of 1 to 10% on the weight of the material. The material is dried before printing. The surfactants can be accompanied by swelling agents, catalysts or cross-linking agents. Preferred dyes for the printing stage are sublimable dyes containing chelatable groups, fibre-reactive groups or cross-linkable groups.Type: GrantFiled: March 26, 1981Date of Patent: June 19, 1984Assignees: I.W.S. Nominee Company, Limited, Commonwealth Scientific and Industrial Research OrganizationInventors: David M. Lewis, Peter R. Brady, Peter G. Cookson, Keith W. Fincher
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Patent number: 4383018Abstract: A color imaging device which comprises an adhesive layer between (a) means for sensing radiation comprising a planar array of charge-handling semiconductive photosensors, and (b) superimposed filter means for controlling access of radiation to the sensing means comprising a transparent polymer layer capable of receiving dyes such as heat transferable dyes; the adhesive layer comprising a polyester selected from the group consisting of (1) polyesters having recurring carboxylate units of which at least 80 mole percent are terephthalate units, and recurring alkylene units derived from glycols of which at least 40 mole percent are ether alkylene units, with the proviso that either (a) the recurring alkylene units comprise at least 60 mole percent ether alkylene units or (b) either the recurring carboxylate units comprise at least 2 mole percent pyromellitic tetracarboxylate units or at least 10 mole percent of linear aliphatic dicarboxylate units having at least 8 carbon atoms, and that when at least 10 mole perType: GrantFiled: December 12, 1980Date of Patent: May 10, 1983Assignee: Eastman Kodak CompanyInventors: Thomas W. Martin, M. Akram Sandhu
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Patent number: 4310327Abstract: In an improved method for the wet transfer printing of wool or wool-rich fabric the untreated fabric has introduced into it, as part of the wet transfer printing process, chlorine or a chlorine donor. The chlorine or chlorine donor is introduced before dye is transferred to the fabric, and when a chlorine donor is used as impregnating liquor for wet-transfer printing can be used to release chlorine from the donor.Type: GrantFiled: October 22, 1979Date of Patent: January 12, 1982Assignee: Transprints (U.K.) LimitedInventors: Malcolm L. Winterbottom, Donald W. H. Burtonshaw
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Patent number: 4304565Abstract: A process is disclosed for the heat transfer printing of cellulose-containing fabrics in garment form with disperse dyestuffs, wherein the fabric is treated only on one side by a printing or spraying technique with a formulation containing highly methylated melamine-formaldehyde crosslinking agent, acid catalyst, and other necessary additives. Fabrics with prints that are durable to washing are produced by simultaneously heat transfer printing and curing at about 190.degree. C. to 220.degree. C. for 20-30 seconds.Type: GrantFiled: December 3, 1980Date of Patent: December 8, 1981Assignee: The United States of America as represented by the Secretary of AgricultureInventors: Eugene J. Blanchard, Gloria A. Gautreaux, Robert J. Harper, Jr.
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Patent number: 4302201Abstract: A method for developing electrical latent images is disclosed in which electrically formed latent images are developed by using a mixture of at least two different toners having the same polarity. The two or more different kinds of toners in the mixture have a difference in triboelectric charge between them less that 10 .mu.c/g. Furthermore, developing is carried out by using a liquid developer containing a mixture of at least two different toners having the same polarity. Each of the toners in the mixture should have a Zeta-potential more than 50 mV in absolute value and the difference in Zeta-potential between the different kinds of toners should be less than 50 mV.Type: GrantFiled: May 14, 1979Date of Patent: November 24, 1981Assignee: Canon Kabushiki KaishaInventors: Tetsuo Hasegawa, Katsumi Nagamatsu, Yoshihiro Nishikawa
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Patent number: 4294637Abstract: A wide composite band of a patterned transfer-carrying sheet is formed of several webs or web sections secured together parallel or perpendicular to the band with the patterns of adjacent webs or web sections in registration. Webs may for example be fed side-by-side parallel to one another and any staggering of the pattern corrected by suitable adjustment of web tensioning rollers by detecting reference marks corresponding to the pattern. The webs are then joined by sticking, or could be directly used for transfer printing without being secured together. Alternatively, a web is fed perpendicular to the band being formed, and cut into sections which are adjusted relative to the band by detecting reference marks, and joined to the band.Type: GrantFiled: December 21, 1977Date of Patent: October 13, 1981Assignee: Bjorn Sigurd RumpInventor: Bjorn S. Rump
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Patent number: 4287017Abstract: An endless pressing-on and guiding belt including a belt piece having its end faces joined together, for textile treating devices, especially transfer printing machines and steaming calenders, with a rotary drum having a longitudinal section of the endless belt partially looped therearound while textile material to be treated is interposed between the drum and the belt, the latter being heated on the drum. The endless belt includes a fabric with a bronze-solid wire warp and a weft of a metallic nickel-alloy solid wire with the bronze solid wire warp extending in the longitudinal direction of the belt.Type: GrantFiled: November 5, 1979Date of Patent: September 1, 1981Assignee: Kleinewefers GmbHInventors: Karl-Peter Lopata, Wolfgang Tschirner
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Patent number: 4271224Abstract: A transfer sheet comprising, in laminated combination, a substrate sheet and, provided thereabove, a coloring layer of desired pattern containing a coloring agent possessing heat transferability and a resist layer of a desired pattern containing a metal compound for resist printing and a binder, the metal compound having the capability of causing the coloring layer to lose its heat transferability, either of the coloring layer and the resist layer being nearer than the other to the substrate sheet. Because of the capability of the metal compound, the resist power is very great, whereby ample resist printing effect can be obtained with only an extremely thin resist layer.Type: GrantFiled: February 1, 1980Date of Patent: June 2, 1981Assignee: Dai Nippon Insatsu Kabushiki KaishaInventors: Shogo Mizuno, Takao Suzuki, Sadanobu Kawasaki, Hideichiro Takeda
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Patent number: 4239842Abstract: An improved color filter array comprises a transparent heat-transfer dye-receiving layer containing an array of filter elements wherein the dye-receiving layer is a certain polyester wherein at least 30 mole percent of the recurring units contain a saturated gem-bivalent radical having a saturated polycyclic three-dimensional structure that includes a saturated bicyclic atomic bridge hydrocarbon ring member. The improved dye-receiving layers provide filter elements with excellent edge sharpness. The improved color filter arrays are useful in color imaging devices, such as solid-state video cameras.Type: GrantFiled: September 13, 1979Date of Patent: December 16, 1980Assignee: Eastman Kodak CompanyInventor: Mohammad A. Sandhu
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Patent number: 4234481Abstract: The application is concerned with new pyrazolone compounds having the structure: ##STR1## wherein R is hydrogen or halogen (especially fluorine, bromine and chlorine) and R.sub.1 and R.sub.2 independently of one another are hydrogen or halogen (especially bromine and chlorine) and R.sub.3 is lower alkyl (especially methyl, ethyl, propyl and butyl). The compounds are useful in heat transfer printing of polyester fabrics and impart yellow shades thereto. The application discloses a method of making the new compounds and discusses the utilization of the compounds in the heat transfer printing of polyester fabrics, in the preparation of ink formulations, and in making transfer sheets for heat transfer printing.Type: GrantFiled: November 30, 1977Date of Patent: November 18, 1980Assignee: Crompton & Knowles CorporationInventor: Russell I. Steiner
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Patent number: 4231742Abstract: Heat Transfer prints are made by offset printing using a UV curable ink containing subliminal dyes printed onto a heat transfer backing, followed by rapid curing using UV light. The heat transfer prints are then used for dying fabric by applying the heat transfer print to the fabric, heating the print and thereby causing the dyes to sublimate and thereby transfer from the heat transfer print to the fabric where dying of the fabric occurs.Type: GrantFiled: February 28, 1979Date of Patent: November 4, 1980Assignee: Michael Huber Munchen, GmbHInventors: Dieter Clausen, Albert Uhlemayr
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Patent number: 4220700Abstract: There is disclosed a composition and element, comprising a diazo resin and a mordant for anionic dyes that is compatible with the resin. The element of the invention is suitable for dye immersion and dye transfer to a mordanted receiver.Type: GrantFiled: February 3, 1978Date of Patent: September 2, 1980Assignee: Eastman Kodak CompanyInventors: Hugh G. McGuckin, Hyman L. Cohen
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Patent number: 4218689Abstract: An ablative recording medium comprises a substrate coated with a light reflecting layer which in turn is coated with a light absorptive layer of 6,6'-diethoxythioindigo. During recording, portions of the light absorptive layer are ablated by a modulated focussed light beam, thereby exposing portions of the reflecting layer. Video information is recorded as a reflective-antireflective pattern.Type: GrantFiled: January 30, 1978Date of Patent: August 19, 1980Assignee: RCA CorporationInventors: Allen Bloom, Robert A. Bartolini
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Patent number: 4209297Abstract: Fabrics of preferrably polyester fibres can be printed in deep yellow colors with good fastness properties if dyestuffs of the formula ##STR1## wherein X denotes hydrogen, chlorine, methyl, nitro, CF.sub.3 or cyano,Y denotes methyl, methoxy, nitro or chlorine or cyano andZ denotes hydrogen, methyl, chlorine or cyano,R.sub.1 /R.sub.2 representing hydrogen, chlorine, methyl or methoxy, with the proviso that R.sub.1 and/or R.sub.2 denote chlorine, methyl or methoxy if X represents a nitro group,are used according to the transfer printing principle.Type: GrantFiled: January 27, 1978Date of Patent: June 24, 1980Assignee: Bayer AktiengesellschaftInventors: Gunter Stephan, Hartmut Birmes, Artur Haus, Erwin Plaza
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Patent number: 4203722Abstract: Acid-modified fibre materials may be dyed in brilliant color shades in accordance with the transfer printing principle if dyestuffs of the formula ##STR1## are used in which A is a residue of the formula ##STR2## wherein R.sub.1, R.sub.3, R.sub.4, R.sub.6 -R.sub.9 are H or lower alkyl, R and R.sub.2 are lower alkyl and R.sub.5 is phenyl.The resulting transfer prints are distinguished by good fastness to light, wet processing and rubbing.Type: GrantFiled: October 18, 1978Date of Patent: May 20, 1980Assignee: Bayer AktiengesellschaftInventors: Alfred Brack, Hans-Peter Kuhlthau