Dye Concentrate Composition Wherein An Additional Amount Of A Constituent Of The Composition Must Be Added Before Use Patents (Class 8/527)
  • Patent number: 5961665
    Abstract: A composition for a powdered hair dye includes an oxidative dye component, an oxidizing component and a thickening component. Other additives including protein derivatives and sucrose may also be utilized. The powdered dye composition may be placed into an applicator container so that the container is partially filled with the dye composition. Then when the user desires to use the dye, water is added to the container, the container shaken to mix the water and the powdered dye composition, and the mixture is then applied to the hair using an application mechanism which allows for easy and efficient application of the dye to the hair.
    Type: Grant
    Filed: January 7, 1998
    Date of Patent: October 5, 1999
    Inventor: Yoram Fishman
  • Patent number: 5958087
    Abstract: A cyanine dye for using in high density optical disc recording medium, having the following structure: ##STR1## wherein R represents 4-methoxycarbonyl benzyl group, X.sup.- represents an acid anion, and n represents an integer of 1 or 2. This cyanine dye is suitable for use as a .lambda.=450 nm.about.650 nm visible light-absorbing organic dye useful as a high density optical disc recording medium.
    Type: Grant
    Filed: February 8, 1999
    Date of Patent: September 28, 1999
    Assignees: Industrial Technology Research Institute, National Tsing Hua University
    Inventors: Wen-Yih Liao, Chien-Liang Huang, Der-Ray Huang, Don-Yau Chiang, Andrew Teh Hu, Hong-Ji Lee, Shi-Jae Ye, Ying-Jen Kao
  • Patent number: 5944856
    Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25.degree. C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: August 31, 1999
    Assignee: Clariant Finanace (BVI) Limited
    Inventor: Jurgen Geiwiz
  • Patent number: 5922087
    Abstract: Stable, pourable aqueous suspensions of solid particulate materials are provided, especially suspensions of sulfur dyes which are characterized a very low content of inorganic sulfides and inorganic polysulfides. The suspensions are produced using certain suspension stabilizing agents, particularly polysaccharides, such as xanthan gum, whose solutions in water are pseudoplastic. The suspensions may further comprise a non-sulfide reducing agent. An improved method is also provided for determining the the potential for such suspensions to release hydrogen sulfide upon being acidified at a given temperature, which method comprises acidifying a sample of the suspension to pH 2.9-3.7, capturing all of the hydrogen sulfide released during acidification in aqueous alkali and measuring the sulfide ion content of the aqueous alkali.
    Type: Grant
    Filed: September 9, 1996
    Date of Patent: July 13, 1999
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Masato Nishioka, Michel M. Trawalter, Catherine S. Ho, Livius T. Percy, May N. Szeto, Yi Lai Wang, Guido J. Danhieux, Jon W. Merkert, Dwayne R. Myers
  • Patent number: 5910623
    Abstract: Liquid or solid mixtures of low-salt sulfo-containing 1:2 metal complex dyes and poly-N-vinylpyrrolidone or copolymers of N-vinylpyrrolidone and vinyl acetate are especially useful for dyeing paper and wood and also for dyeing and finishing leather and fur.
    Type: Grant
    Filed: August 13, 1997
    Date of Patent: June 8, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Knut Kessel, Manfred Patsch, Manfred Herrmann, Kurt Reiner, Jorg Jessen, Matthias Wiesenfeldt
  • Patent number: 5882358
    Abstract: Automatic transmission fluid containing a red dye stable even in long-lived transmission fluids.
    Type: Grant
    Filed: June 12, 1996
    Date of Patent: March 16, 1999
    Assignee: United Color Manufacturing, Inc.
    Inventors: Michael J. Smith, Bharat Desai
  • Patent number: 5883234
    Abstract: The novel process for dyeing cellulosic materials with disazo dyestuffs of the formula ##STR1## in which the substituents NHR.sup.1 and NHR.sup.2 are in each case in the 6- and/or 7-position and R.sup.1, R.sup.2, m, n, p and q have the meaning given in the description, produces blue dyeings with very good fastness properties.
    Type: Grant
    Filed: September 18, 1997
    Date of Patent: March 16, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Winfried Mennicke, Klaus Kunde
  • Patent number: 5869627
    Abstract: A composition of a water-soluble bis-azo dye of the Formula (1) and an oxidising agent. ##STR1## wherein A is optionally substituted phenyl or optionally substituted naphthyl;B is optionally substituted phenylene or optionally substituted naphthylene;R.sup.1 is H or sulpho;R.sup.2 is H, optionally substituted alkyl, optionally substituted aryl or optionally substituted acyl;R.sup.3 is H, optionally substituted aryl, optionally substituted alkyl or a group, -D-E,D is optionally substituted C.sub.2-6 -alkylene; andE is a group of the Formula (1a): ##STR2## R.sup.4 & R.sup.5 each independently is H or optionally substituted alkyl; andR.sup.6 is H, optionally substituted alkyl, optionally substituted aryl or optionally substituted acyl.
    Type: Grant
    Filed: January 8, 1998
    Date of Patent: February 9, 1999
    Assignee: Zeneca Limited
    Inventors: Peter Gregory, Ronald Wynford Kenyon, Paul Wight
  • Patent number: 5865853
    Abstract: The composition for dyeing keratin fibers is mixed with water prior to use and contains from 35 to 75 percent by weight of at least one powdery vegetable dye material; from 25 to 65 percent by weight of at least one oil; and from 0.001 to 15 percent by weight of a physiologically unobjectionable nitro dye compound, azo dye compound, quinone dye compound and/or a triphenylmethane dye compound. A method of dyeing hair using this composition is also described.
    Type: Grant
    Filed: May 1, 1997
    Date of Patent: February 2, 1999
    Assignee: Wella Aktiengesellschaft
    Inventors: Manfred Schmitt, Uwe Lenz, Wolfgang Balzer, Henk Niessink
  • Patent number: 5853431
    Abstract: Compounds of formula (I) ##STR1## wherein R.sub.1 is H or SO.sub.3 M, ##STR2## M is hydrogen or a non-chromophoric cation and X.sup.+ is hydrogen or a non-chromophoric cation, are useful as dyes for oxidized aluminium substrates.
    Type: Grant
    Filed: November 6, 1997
    Date of Patent: December 29, 1998
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Klaus Korte
  • Patent number: 5769901
    Abstract: A composition for a powdered hair dye includes an oxidative dye component, an oxidizing component and a thickening component. Other additives including protein derivatives and sucrose may also be utilized. The powdered dye composition may be placed into an applicator container so that the container is partially filled with the dye composition. Then when the user desires to use the dye, water is added to the container, the container shaken to mix the water and the powdered dye composition, and the mixture is then applied to the hair using an application mechanism which allows for easy and efficient application of the dye to the hair.
    Type: Grant
    Filed: April 1, 1996
    Date of Patent: June 23, 1998
    Inventor: Yoram Fishman
  • Patent number: 5770708
    Abstract: A process for preparing aqueous preparations of azo dyes of the formula ##STR1## where R is hydrogen or C.sub.1 -C.sub.4 -alkyl andKat.sym. is the equivalent of a cation which derives from a tertiary amine of the ethanolamine or propanolamine series,by diazotization of an aniline of the formula ##STR2## with neopentylglycol dinitrite in an aqueous medium and coupling of the resulting reaction mixture with .beta.-naphthol in the presence of a water-miscible diluent and of an amine comprises using an amine comprising a tertiary amine of the ethanolamine or propanolamine series.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: June 23, 1998
    Assignee: BASF Aktiengesellschaft
    Inventor: Rudolf Bermes
  • Patent number: 5707405
    Abstract: A water-reducible composition comprises A) between about 20 and about 50 wt % of a water-insoluble nigrosine, B) between about 25 and about 40 wt % of a solvent having a flashpoint of at least about 141.degree. F. (61.degree. C.) and a boiling point of at least about 280.degree. F. (138.degree. C.), and C) between about 20 and about 40 wt % of a non-ionic surfactant, the weight percentages being based on total weight of A), B), and C).The composition is prepared by dissolving the nigrosine A) in a C.sub.1 -C.sub.3 alkanol to form an alcohol solution, mixing the alcohol solution with the solvent B) and non-ionic surfactant C, and subsequently stripping the C.sub.1 -C.sub.3 alkanol.
    Type: Grant
    Filed: April 8, 1996
    Date of Patent: January 13, 1998
    Assignee: Morton International, Inc.
    Inventors: Peter A. Caputo, Alejandro Zimin, Sr.
  • Patent number: 5697984
    Abstract: Dye preparations comprising one or more dyes with no water-solubilizing groups in the molecule from the class of the metal complex azo dyes or the metal phthalocyanines and reaction products between from 1 to 50 mol of ethylene oxide and 1 mol of castor oil are useful for coloring granular or pulverulent substrates and for preparing aqueous dye preparations useful in printing inks.
    Type: Grant
    Filed: June 10, 1996
    Date of Patent: December 16, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Dieter Swatzina, Karin Heidrun Beck, Christos Vamvakaris, Juliane Krusemann
  • Patent number: 5676708
    Abstract: A dye composition that presents lower mutagenic characteristics useful in coloring petroleum products comprising a substantial amount of the dye of the formula ##STR1##
    Type: Grant
    Filed: February 20, 1996
    Date of Patent: October 14, 1997
    Assignee: United Color, Inc.
    Inventor: Michael J. Smith
  • Patent number: 5665124
    Abstract: Dyeings having improved properties are obtained with a dyestuff of the following formula ##STR1## wherein the substituents have the meaning given in the description.
    Type: Grant
    Filed: October 20, 1995
    Date of Patent: September 9, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Jager, Joachim Wolff
  • Patent number: 5634949
    Abstract: Cellulosic textiles are printed or dyed with multiple hook reactive dyes without fabric hand harshening on using a reactive dye preparation containing 0.5 to 10% by weight of a surfactant and 0 to 10% by weight of an antifoaming agent.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: June 3, 1997
    Assignee: Hoechst AG
    Inventors: Kurt Hohmann, Peter Mischke, Gerd Pelster, Horst-Roland Mach
  • Patent number: 5626634
    Abstract: A liquid dyestuff composition comprising a solvent-soluble dyestuff and a water miscible organic solvent, the composition comprising over 25% by weight of dissolved dyestuff.
    Type: Grant
    Filed: December 2, 1994
    Date of Patent: May 6, 1997
    Assignee: Sandoz Ltd.
    Inventors: J urgen Goldmann, Bansi L. Kaul
  • Patent number: 5545724
    Abstract: The invention relates to cationically bridged tetrakisazo compounds, corresponding to formula I, ##STR1## wherein the individual symbols are defined as in claim 1, as well as residues and liquid preparations thereof. The compounds and their preparations are used for dyeing and printing hydroxy-group-containing or nitrogen-containing organic substrates by a known method. Preferred substrates are textile materials which consist of or contain cellulose, especially cotton, or also bast fibres, leather and preferably paper or paper pulp products, especially wood-containing paper.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: August 13, 1996
    Assignee: Sandoz Ltd.
    Inventor: Helmut A. Moser
  • Patent number: 5519121
    Abstract: Novel dyestuffs of the formula (I) ##STR1## in which DK denotes a radical of the formula ##STR2## where m is 1 or 2 and DK' denotes a radical of the formula ##STR3## where n is 1 or 2 R.sub.1 represents hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkyl,R.sub.2 represents hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sub.3 represents substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -acylamino andR.sub.4 represents substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl.have now been found.The invention also relates to a process for their preparation and to their use for dyeing/coloring and printing textiles and paper, in particular in printing inks containing these dyestuffs.
    Type: Grant
    Filed: February 24, 1995
    Date of Patent: May 21, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerd-Friedrich Renner, Peter Wild, Karin Hassenruck
  • Patent number: 5508389
    Abstract: If highly concentrated aqueous solutions of azo dyes are prepared directly by diazotization and coupling reactions, appreciable difficulties generally result as a consequence of the fact that the diazotization and coupling reactions give rise to viscous phases which lead to stirring problems in the reaction apparatus used, which in turn results in an incomplete synthesis. The novel process for preparing concentrated aqueous dye solutions of an anionic dye in an aqueous medium overcomes this disadvantage by carrying out the diazotization of the aromatic amine diazo component and/or the coupling reaction between the diazonium salt and the coupling component in the presence of an auxiliary which exerts a viscosity-reducing effect on pasty phases. Examples of such auxiliaries are optionally alkyl-substituted naphthalenesulfonic acid-formaldehyde condensation products, ligninsulfonates, polyacrylates and copolymers of maleic anhydride and methacrylic acid or acrylic acid.
    Type: Grant
    Filed: March 26, 1993
    Date of Patent: April 16, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Peter Mischke, Kurt Hohmann, Eckhard Schwab, Manfred Sittig
  • Patent number: 5498701
    Abstract: Basic sulpho group-containing disazo compounds which are metal-free, correspond to the formula ##STR1## in which the symbols are as defined in claim 1. These compounds, in form of their water-soluble salts, and preparations thereof are used for dyeing or printing cationically dyeable materials such as hydroxy group- or nitrogen-containing organic substrates of which textile material comprising natural or synthetic polyamide or natural or regenerated cellulose and especially cotton, leather and paper are preferred. Furthermore, they can be used for the preparation of inks in a conventional manner.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: March 12, 1996
    Assignee: Sandoz Ltd.
    Inventor: Reinhard Pedrazzi
  • Patent number: 5487761
    Abstract: The dyestuffs of the formula ##STR1## in which A, R.sub.1, M and n are as defined in claim 1, are suitable for dyeing paper with good light-fastness.
    Type: Grant
    Filed: April 20, 1994
    Date of Patent: January 30, 1996
    Assignee: Ciba-Geigy Corporation
    Inventor: Adolf Kaser
  • Patent number: 5484900
    Abstract: 1:2 chromium complex dyestuffs of the formula (I) ##STR1## in which A, B, R.sup.1, R.sup.2, R.sup.3, R.sup.4, p, m, n, n' and Cat.sup.(+) have the meaning given in the description, are suitable for dyeing and printing amido-containing materials.
    Type: Grant
    Filed: February 25, 1994
    Date of Patent: January 16, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventor: Winfried Mennicke
  • Patent number: 5476519
    Abstract: Water insoluble or sparingly soluble dyestuffs such as disperse dyes as concentrates for making up dyebaths or for use as printing pastes, and optical brightening agents for laundry detergents are formulated as stable suspensions in aqueous structured surfactants.
    Type: Grant
    Filed: March 8, 1995
    Date of Patent: December 19, 1995
    Assignee: Albright & Wilson, Limited
    Inventors: William P. Haslop, Jill E. Newton, Richard M. Clapperton
  • Patent number: 5401834
    Abstract: Complexes of the formula ##STR1## which are in free acid or salt form, and mixtures thereof, wherein each ofR.sub.1 and R.sub.3 is independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by hydroxy, amino, sulfo or carboxy,each ofR.sub.2 and R.sub.4 is independently hydrogen; C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by hydroxy, amino, sulfo or carboxy; --COR.sub.5 ; --COOR.sub.6 or --CONHR.sub.7,M is chromium or cobalt, andM.sub.K.sup..sym. is hydrogen or a non-chromophoric cation, useful for dyeing or printing, materials such as natural and synthetic polyamides and particularly artificially produced oxide layers on aluminum and aluminum alloys.
    Type: Grant
    Filed: June 22, 1993
    Date of Patent: March 28, 1995
    Assignee: Sandoz Ltd.
    Inventor: Klaus Koerte
  • Patent number: 5391207
    Abstract: Improved dyestuff solutions for the dyeing of leather contain 5 to 30 parts by weight of a dyestuff, 20 to 80 parts by weight of an alkoxy alcohol of the formula (I)R--O--(--A--O--).sub.n --H (I),10 to 40 parts by weight of a lactone, lactam or cyclic urea and 5 to 50 parts by weight of water.
    Type: Grant
    Filed: March 30, 1994
    Date of Patent: February 21, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rainer Gerlach, Winfried Mennicke, Wolfgang Mullers
  • Patent number: 5358537
    Abstract: There is disclosed a process and a composition for dyeing polymeric fibers which have limited dye sites and/or difficult to penetrate chemical structures. Briefly stated, the process comprises the steps of contacting polymeric fibers with a dye composition comprising a disperse dye and a swelling agent. The fibers in contact with said dye composition are then preferably heated to a temperature and for a time sufficient to effect dispersion of a portion of said dye into said polymeric fibers. Subsequently, the fibers are treated to remove residual dye composition.
    Type: Grant
    Filed: September 17, 1991
    Date of Patent: October 25, 1994
    Assignee: Shaw Industries, Inc.
    Inventors: David R. Kelly, Richard Castle, Christopher Bryant
  • Patent number: 5320647
    Abstract: Fluent dye preparations useful for dyeing leather or wool containa) at least 15% of the weight of the dye preparation of one or more polyazo dyes in salt form which have one or more hydroxysulfonyl and/or carboxyl groups and may be present in the form of a 1:1 or 1:2 metal complex,b) from 2 to 15% of the weight of the dye preparation of a surfactant, andc) water.
    Type: Grant
    Filed: August 14, 1992
    Date of Patent: June 14, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Georg Henning, Georg Zeidler, Ortwin Schaffer
  • Patent number: 5298034
    Abstract: Pulverulent dye preparations useful for preparing printing inks or finishes comprise one or more solvent dyes and an auxiliary selected from the group consisting of alkyl vinyl ethers, primary, secondary or tertiary alkylamines, polybutylene glycols and addition products of ethylene oxide with polybutylene glycols.
    Type: Grant
    Filed: November 30, 1992
    Date of Patent: March 29, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Bast, Ronald Sawa, Wolfgang Keil
  • Patent number: 5284939
    Abstract: There is described a process for the preparation of highly concentrated aqueous solutions of specific cationic azo dyes. The solutions are prepared by diazotising a diazo component in a solution which contains sulfuric acid, coupling the diazotised component to a coupling component, treating the resultant azo dye with a bicarbonate, and converting the dye bicarbonate with an organic acid into the dye salt of said acid.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: February 8, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Alex Nicopoulos, Hanspeter Birri, Gerhard Hanika
  • Patent number: 5264560
    Abstract: Quaternized azo dyes whose diazo components are derived from a five-membered nitrogen-containing aromatic aminoheterocycle and whose coupling components are derived from the aniline series are prepared by reacting to corresponding neutral dye-bases with an alkylating agent in .gamma.-butyrolactone as inert diluent.
    Type: Grant
    Filed: July 17, 1992
    Date of Patent: November 23, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Guenter Hansen, Johannes P. Dix, Helmut Reichelt, Clemens Grund
  • Patent number: 5256161
    Abstract: An improved aqueous dyestuff preparation which is suitable for the dyeing or printing of substrates contains a water-soluble lithium compound and an alkali, in particular sodium hydroxide.
    Type: Grant
    Filed: April 28, 1992
    Date of Patent: October 26, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Joachim Grutze, Friedhelm Buse, Johannes Haas, Manfred Hobohm
  • Patent number: 5250671
    Abstract: The novel unsymmetrical 1:2 chromium complex dyestuffs of the formula ##STR1## in which the substituents R.sup.1, R.sup.2, R.sup.3, n and Cat.sup.(+) have the meaning given in the description, are highly suitable for the dyeing and printing of natural and synthetic amido-containing materials in predominantly red hues having good light, wet and diffusion fastness properties.
    Type: Grant
    Filed: September 8, 1992
    Date of Patent: October 5, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventor: Winfried Mennicke
  • Patent number: 5244476
    Abstract: The present invention relates to compounds of the general formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, x and y are defined as in the description, processes for their preparation, their use for improving the light stability of polyester dyeings and a dyeing process and dye preparations.
    Type: Grant
    Filed: March 13, 1992
    Date of Patent: September 14, 1993
    Assignee: Cassella AG
    Inventors: Joachim Schulz, Gunter Bartels
  • Patent number: 5242467
    Abstract: A reactive dye mixture which comprises, as dye components, from 10 to 57% by weight of C.I. Reactive Orange 16 and from 90 to 43% by weight of C.I. Reactive Orange 7.
    Type: Grant
    Filed: August 28, 1992
    Date of Patent: September 7, 1993
    Assignee: Hoechst Mitsubishi Kasei Co., Ltd.
    Inventors: Yuji Yamada, Mitsuhiro Suzuki, Kensuke Suzuki
  • Patent number: 5240465
    Abstract: A process for applying a reactive dye to a cellulosic substrate comprising:(a) adding one or more dyeing assistants selected from the condensation product of sulphonated diphenyl ethers, condensation product of sulphonated ditolyl ethers, condensation products of polydiphenylsulphones with formaldehyde and condensation products of polyditolyl sulphones with formaldehyde (and salts thereof) into an aqueous liquor, optionally together with a salt (hereinafter defined as Process Step a);(b) introducing the substrate into the dyebath and adding one or more reactive dyes, (hereinafter defined as Process Step b) ; and(c) fixing the dyestuff onto the substrate (hereinafter defined as Process Step c).
    Type: Grant
    Filed: December 3, 1992
    Date of Patent: August 31, 1993
    Assignee: Sandoz Ltd.
    Inventor: Francis Palacin
  • Patent number: 5233027
    Abstract: The new disazo dyestuffs of the formula (I) ##STR1## in which the substituents and indices have the meaning given in the description, and salts thereof are outstandingly suitable for dyeing cellulose-containing materials and leather in blue shades having good wet- and light-fastnesses.
    Type: Grant
    Filed: May 23, 1991
    Date of Patent: August 3, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rolf Hinrichs, Klaus Kunde
  • Patent number: 5216138
    Abstract: There are described water soluble azo compounds conforming to the formula (1)D--N.dbd.N--K (1)where D is a radical of the formula (2), (2a) or (2b) ##STR1##where Y is a substituent which is eliminable by alkali to form a vinyl group, Y.sup.2 has one of the meanings of Y or is hydroxyl, X is chlorine or bromine, and R is hydrogen, lower alkyl, phenyl or halogen, and K is a radical of a singly couplable coupling component which may additionally contain an azo group, or the radical of a doubly couplable coupling component.The compounds of the formula (1) have fiber-reactive properties and are very highly suitable for use as dyes for dyeing hydroxy- and/or carboxamido-containing material, in particular fiber material, for example cellulose-fiber materials, wool and synthetic polyamide fibers, in strong, fast shades.There are also described novel starting compounds of the formulae (7), (7a) and (7b) ##STR2##where Y.sup.2, X and R are each as defined above, x is zero or 2 and W is nitro or amino.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: June 1, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Jorg Dannheim
  • Patent number: 5211719
    Abstract: Concentrated aqueous solutions are described comprising specific anionic disazo dyes and polyglycol amines, which are highly suitable as commercial forms.
    Type: Grant
    Filed: September 27, 1991
    Date of Patent: May 18, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Adolf Kaser
  • Patent number: 5209758
    Abstract: The invention relates to novel pasty or solid dye melts which contain, per 1 part of a sparingly water-soluble or water-insoluble dye whose melting point is higher than 150.degree. C., 2 to less than 5 parts of a nonionic surfactant with a melting point of 25.degree.-100.degree. C. and having an HLB value of 13 to 19 or of a cationic surfactant with a melting point of 25.degree.-100.degree. C., or a mixture of said surfactants, to a process for their preparation and to the use of said melts, preferably for dyeing and printing polyester materials, to give level dyeings having a high degree of exhaustion.
    Type: Grant
    Filed: December 4, 1991
    Date of Patent: May 11, 1993
    Assignee: Giba-Geigy Corporation
    Inventors: Rainer H. Traber, Ulrich Strahm
  • Patent number: 5207802
    Abstract: Compounds and mixtures of compounds obtainable by condensation of sulphonation products of defined alkyl-substituted naphthalenes and sulphonation products of optionally alkyl-substituted diphenylethers with formaldehye and optionally treated with further components, are valuable interface-active compounds suitable as assistants in various application fields, in particular as dispersing or levelling agents in the dyeing with disperse dyes or as tanning-assistants or dyeing-assistants for leather.
    Type: Grant
    Filed: August 23, 1990
    Date of Patent: May 4, 1993
    Assignee: Sandoz Ltd.
    Inventor: Hans-Peter Baumann
  • Patent number: 5205838
    Abstract: Liquid dye preparations useful for making color ribbons or ballpoint pen pastes contain at least one dye of the formula ##STR1## where X is hydroxyl, amino or C.sub.1 -C.sub.15 -monoalkylamino, R.sup.1 and R.sup.4 are each a carboxylate group or substituted or unsubstituted C.sub.1 -C.sub.15 -alkoxy, R.sup.2 and R.sup.5 are each hydrogen, nitro or chlorine, and R.sup.3 is hydrogen or C.sub.1 -C.sub.13 -alkyl, plus as solvent at least one product selected from the group consisting of benzyl alcohol, tridecanol, isotridecanol, glycol ethers, olein, dialkyl phthalates, chloroalkanes, alkanes disubstituted by phenyl, dialkylnaphthalenes and partly hydrogenated terphenyl.
    Type: Grant
    Filed: January 24, 1992
    Date of Patent: April 27, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Dyllick-Brenzinger, Heinz Hartmann, Helmut Bellaire, Georg Zeidler
  • Patent number: 5203876
    Abstract: The dyes of formula ##STR1## wherein R, M and n are as defined in claim 1, are preeminently suitable for dyeing paper in blue shades.
    Type: Grant
    Filed: February 22, 1991
    Date of Patent: April 20, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Adolf Kaser
  • Patent number: 5176718
    Abstract: Preparations of water-soluble reactive dyestuffs containing pyridine derivatives of the formula ##STR1## or salts of, in which the substituents have the meanings given in the description, are highly suitable for the dyeing of cellulose materials.
    Type: Grant
    Filed: June 12, 1991
    Date of Patent: January 5, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Michna, Manfred Hoppe, Karl-Josef Herd, Hermann Henk, Frank-Michael Stohr
  • Patent number: 5174791
    Abstract: Process for dyeing and printing blended fabrics made from polyester and natural fibre materials, characterized in that the dye baths, padding liquors or printing pastes contain compounds of general formula (I). Dye preparations containing one or more compounds of general formula (I).
    Type: Grant
    Filed: August 5, 1991
    Date of Patent: December 29, 1992
    Assignee: Cassella Aktiengesellschaft
    Inventors: Ulrich Buhler, Klaus Hofmann, Hubert Kruse, Jurgen Kuhlwein, Willi Steckelberg
  • Patent number: 5174792
    Abstract: The invention relates to mixtures of monoazo dyes, which are characterized in that they consist of one or more dyes of the general formula I ##STR1## and one or more dyes of the general formula II ##STR2## where R.sup.1 is methyl, ethyl, n-propyl or i-propyl,R.sup.2 is ethyl or n-propyl,m is 2 or 3 andn is 1 or 2, with the proviso that m+n is 4,processes for preparing same and the use thereof for dyeing and printing hydrophobic fibre materials and blends thereof with natural fibre materials.
    Type: Grant
    Filed: August 12, 1991
    Date of Patent: December 29, 1992
    Assignee: Cassella Aktiengesellschaft
    Inventors: Hirotsugu Tsumura, Ulrich Buhler, Reinhard Kuhn, Margareta Boos
  • Patent number: 5173086
    Abstract: Aqueous solutions containing, each percentage being based on the weight of the aqueous solution,a) from 5 to 20% by weight of the dye of the formula ##STR1## (calculated as free acid) where cat.sup..sym. is a mixture of cations comprising from 5 to 50 mol % of lithium ions, from 5 to 40 mol % of diethanolammonium ions and from 20 to 90 mol % of triethanolammonium ions, andb) from 0 to 15% of urea, are useful for dyeing paper stock.
    Type: Grant
    Filed: September 12, 1991
    Date of Patent: December 22, 1992
    Assignee: BASF Aktiengesellschaft
    Inventor: Rudolf Bermes
  • Patent number: 5163972
    Abstract: Process to dye polyacrylonitrile in blue shades with cationic dye compounds: substituted benzothiazolium azo N-alkyl-N-hydroxyalkyl alkyl-aniline salts.
    Type: Grant
    Filed: December 3, 1990
    Date of Patent: November 17, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Wilfried Herter, Josef Koller
  • Patent number: 5149791
    Abstract: Novel reactive dyes of the formula ##STR1## in which Z is a radical of the formula ##STR2## in which R.sub.1 and R.sub.2 independently of one another are hydrogen or C.sub.1 -C.sub.6 alkyl, which can be substituted by C.sub.1 -C.sub.4 alkoxy, hydroxy-C.sub.1 -C.sub.4 alkoxy, HO--(CH.sub.2 CH.sub.2 --O).sub.2-4 --, C.sub.1 -C.sub.4 alkoxy-carbonyl, C.sub.2 -C.sub.4 alkanoyloxy, carboxyl, cyano, chlorine, sulfo or sulfato, n is the number 0, 1 or 2 and m is the number 1 or 2, (Q.sub.1).sub.m is 1 or 2 substituents Q.sub.1 independent of one another from the group comprising C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, acetylamino and carboxyl, (Q.sub.2).sub.n is 0 to 2 substituents Q.sub.2 and (Q.sub.2).sub.m is 1 or 2 substituents Q.sub.2 independent of one another from the group comprising C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.
    Type: Grant
    Filed: October 26, 1990
    Date of Patent: September 22, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Athanassios Tzikas, Urs Lauk