Dye Concentrate Composition Wherein An Additional Amount Of A Constituent Of The Composition Must Be Added Before Use Patents (Class 8/527)
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Patent number: 5145485Abstract: By adding boric acid or salts of boric acid before or during the pressure permeation of anionic dyestuff solutions, the filtration flux is substantially increased, resulting in a low-cost process, due to the shorter plant time required.Type: GrantFiled: March 6, 1991Date of Patent: September 8, 1992Assignee: Bayer AktiengesellschaftInventors: Martin Michna, Werner Zillger, Dietrich Tegtmeyer
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Patent number: 5143519Abstract: Concentrated dye solutions of dyes of the formula (1) shown in claim are described.The dye solutions are distinguished by a good storage stability and are suitable, in particular, for dyeing paper.Type: GrantFiled: March 29, 1991Date of Patent: September 1, 1992Assignee: Ciba-Geigy CorporationInventor: Willy Stingelin
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Patent number: 5136028Abstract: Novel reactive dyes of formula ##STR1## wherein Z is a radical of formula ##STR2## and R.sub.1, R.sub.2, R.sub.3, (R.sub.4).sub.2-3, (R.sub.5).sub.1-3, R.sub.7 and (R.sub.8).sub.1-3 are as defined in claim 1, give intense red dyeings and prints of good fastness properties on cellulosic fibres.Type: GrantFiled: November 9, 1990Date of Patent: August 4, 1992Assignee: Ciba-Geigy CorporationInventor: Herbert Seiler
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Patent number: 5131916Abstract: Aqueous emulsions based on certain graft polymers are outstandingly suitable for the production of colored inks for so-called marker pens. They are distinguished, for example, by a high storage stability.Type: GrantFiled: February 22, 1991Date of Patent: July 21, 1992Assignee: Bayer AktiengesellschaftInventors: Herbert Eichenauer, Artur Haus
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Patent number: 5128456Abstract: Novel reactive dyes of the formula ##STR1## in which (R).sub.0-3 is 0-3 substituents R, independent of one another, from the group comprising halogen, nitro, cyano, trifluoromethyl, sulfamoyl, carbamoyl, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, amino, acetylamino, ureido, hydroxyl, carboxyl, sulfomethyl and sulfo, R.sub.1 is hydrogen, C.sub.1-8 alky or C.sub.5-7 cycloalkyl and R.sub.2 is C.sub.1-8 alkyl or C.sub.5-7 cycloalkyl, it being possible for the alkyl and cycloalkyl radicals R.sub.1 and R.sub.2 to be substituted independently of one another by hydroxyl, C.sub.1-4 alkoxy, hydroxy-C.sub.1-4 alkoxy, HO--(CH.sub.2 CH.sub.2 --O).sub.2-4 --, sulfato-C.sub.1-4 alkoxy, C.sub.2-4 alkanoyl, C.sub.1-4 alkoxy-carbonyl, C.sub.2-4 alkanoyloxy, carboxyl, cyano, halogen, C.sub.1-4 alkylamino, or N,N-Di-C.sub.1-4 alkylamino, or sulfato, or in which R.sub.1 is C.sub.1-8 alkyl or C.sub.5-7 cycloalkyl, and the alkyl or cycloalkyl radical can be substituted as defined, and R.sub.2 is a C.sub.1-8 alkyl or C.sub.Type: GrantFiled: October 26, 1990Date of Patent: July 7, 1992Assignee: Ciba-Geigy CorporationInventors: Athanassios Tzikas, Paul Herzig
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Patent number: 5126450Abstract: Unsymmetrical triphendioxazine (TPD) reactive dyes of Formula (1) for the colouration of e.g. wool, silk, leather and cotton are claimed as well as intermediates for their manufacture. ##STR1## wherein W.sup.1 and W.sup.2 are different and each independently of the formula: ##STR2## R.sup.1 and R.sup.2 in each group defined by W.sup.1 or W.sup.2 independently represent H or an optionally substituted hydrocarbon radical or are joined together to form, with B and the two N atoms, a piperazine ring;each x independently has a value of 0 or 1;each B independently represents an optionally substituted divalent hydrocarbon radical;each Z independently represents a fibre-reactive group;T.sup.1 and T.sup.2 each independently represents H, Cl, Br, F, SO.sub.3 H or an optionally substituted alkyl or aryl radical;A.sup.1 and A.sup.2 each independently represents an alkyl, alkoxy, Cl, Br, COOH, SO.sub.Type: GrantFiled: November 1, 1990Date of Patent: June 30, 1992Assignee: Imperial Chemical Industries PlcInventor: Peter Smith
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Patent number: 5123930Abstract: 1:2 metal complexes of the formula ##STR1## wherein each of R.sub.1 and R.sub.3 is independently hydrogen or nitro, with the proviso that when a ring has two nitro groups, they are meta to each other,each of R.sub.2 and R.sub.4 is independently hydrogen, chloro or --SO.sub.3 M,each of R.sub.5 and R.sub.6 is independently hydrogen, --COR.sub.7, --CONHR.sub.8 or --SO.sub.2 R.sub.9,whereinR.sub.7 is C.sub.1-6 alkyl, C.sub.1-6 alkoxy, phenyl(C.sub.1-4 -alkyl) or phenyl (C.sub.1-4 alkyl) the phenyl group of which is substituted by 1 or 2 substituents selected from halo, C.sub.1-4 -alkyl, C.sub.1-4 alkoxy, nitro, amino, --COOM, --SO.sub.3 M and acetamido,R.sub.8 is hydrogen; C.sub.1-6 alkyl; phenyl; phenyl substituted by 1 or 2 substituents selected from halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, nitro, amino, --COOM, --SO.sub.3 M and acetamido; naphthyl or naphthyl monosubstituted by chloro, amino, phenylamino, acetamido, benzamido or --SO.sub.3 M, andR.sub.9 is C.sub.Type: GrantFiled: August 21, 1990Date of Patent: June 23, 1992Assignee: Sandoz Ltd.Inventor: Peter Bitterli
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Patent number: 5122605Abstract: Sulpho group-containing dioxazine compounds corresponding to the formula ##STR1## in which the symbols are as defined in the specification, and salts thereof as well as dyeing preparations thereof are useful for dyeing or printing hydroxy group- or nitrogen-containing organic substrates, optionally combined with a special after-treatment of the dyed or printed textiles thus obtained to improve their wet fastness properties. Most preferred substrates are textile material containing or consisting of cellulose and paper.Type: GrantFiled: February 23, 1990Date of Patent: June 16, 1992Assignee: Sandoz Ltd.Inventor: Reinhard Pedrazzi
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Patent number: 5104415Abstract: Aqueous dye formations which comprise:a) at least one water-insoluble or sparingly water-soluble dye,b) at least one sulfated polyadduct of an alkylphenol containing 2 to 12 carbon atoms in the alkyl moiety with at least 20 mol of ethylene oxide or a sulfated polyadduct of a fatty alcohol with at least 20 mol of ethylene oxide,and, as additional optional components,c) a betain monohydrate, andd) an anionic dispersant of the general formula I ##STR1## wherein X is a direct bond or oxygen,A is hydrogen or the radical of an aromatic compound which is attached through a ring carbon atom to the methylene group,n and p are each independently of the other a value from 1 to 4, andM is a monovalent cation, and/or condensates of these compounds with formaldehyde, as well ase) further optional auxiliaries andf) water.Such formulations have very good storage stability in the temperature range from -10.degree. C. to +50.degree. C. and, in particular, have very good redispersibility after drying in the air.Type: GrantFiled: November 13, 1990Date of Patent: April 14, 1992Assignee: Ciba-Geigy CorporationInventor: Zdenek Koci
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Patent number: 5096458Abstract: Stable aqueous solutions of anionic dyestuffs, preferably reactive dyestuffs, are obtained at very low costs by pressure permeation, if the feed solution for the pressure permeation is prepared by stirring the optionally dried presscake or the suspension of the crude dyestuff in an electrolyte solution.Type: GrantFiled: December 13, 1990Date of Patent: March 17, 1992Assignee: Bayer AktiengesellschaftInventors: Martin Michna, Hans-Werner Zillger, Dietrich Tegtmeyer
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Patent number: 5084068Abstract: Compounds of the formula ##STR1## and mixtures thereof, whereineach Mt is independently copper, nickel or cobalt,each Pc is the phthalocyanine radical,each R.sub.4 is independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by hydroxy,each R.sub.5 and R.sub.6 is independently C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by halo, cyano, hydroxy or phenyl; or C.sub.5-6 cycloalkyl,each W.sub.1 is independently --A--.sup..sym. NR.sub.1 R.sub.2 R.sub.3 An.sup..crclbar. or --A--NR.sub.2 R.sub.3, wherein R.sub.1 is hydrogen; C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by halo, cyano, hydroxy or phenyl; or C.sub.5-6 cycloalkyl, andeach of R.sub.2 and R.sub.3 is independently C.sub.1-4 alkyl; C.sub.1-4 alkyl monosubstituted by halo, cyano, hydroxy or phenyl; or C.sub.Type: GrantFiled: February 23, 1990Date of Patent: January 28, 1992Assignee: Sandoz Ltd.Inventors: Helmut A. Moser, Roland Wald
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Patent number: 5074884Abstract: To improve the affinity of anionic dyestuffs in the dyeing of leather materials, polycondensation products consisting of at least one amine of the formula ##STR1## in which the radicals have the meanings mentioned in the description with one dicarboxylic acid and, if desired, .omega.-aminocarboxylic acid or its lactam are highly suitable.Type: GrantFiled: October 2, 1990Date of Patent: December 24, 1991Assignee: Bayer AktiengesellschaftInventors: Winfried Mennicke, Harro Traubel
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Patent number: 5074887Abstract: Aqueous dye preparations are described which contain 15-40% by weight of dyes, 3-18% by weight of an anionic dispersant of the formula (1), 1-10% by weight of sodium lactate, 1-10% by weight of glycerol and/or propylene glycol, 0.1-5% by weight of a compound having monomer units of the general formula (2), 3-10% by weight of betaine monohydrate, 0-4% by weight of a compound having monomer units of the general formula (3) and 0.1-15% by weight of customary auxiliaries; preparations of this type have a long shelf life, are highly redispersible and do not form sediments; they are suitable in particular for the continuous dyeing of polyester textile materials or mixtures thereof with cellulose textile materials.Type: GrantFiled: October 23, 1990Date of Patent: December 24, 1991Assignee: Ciba-Geigy CorporationInventor: Zdenek Koci
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Patent number: 5066309Abstract: Concentrated, aqueous preparations of 1:2 metal complex dyes which contain 10 to 30% by weight of a 1:2 metal complex dye, 3 to 25% by weight of an anionic dispersant, 1 to 15% by weight of a polyhydroxy compound and 0 to 25% by weight of a customary formulation assistant, in each case based on the total preparation, and water in an amount such that the sum of all the components is 100%, have an excellent stability, are readily pourable and can be diluted with water as desired, and are therefore particularly suitable for the preparation of dyebaths or printing pastes which are employed, in particular, for continuous dyeing or printing of textile fibrous materials of synthetic polyamide.Type: GrantFiled: July 10, 1990Date of Patent: November 19, 1991Assignee: Ciba-Geigy CorporationInventors: Ernst Tempel, Pia Grimbu/ hler-Can
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Patent number: 5032140Abstract: A reactive dye represented by the formula (I), ##STR1## wherein R represents --NH.sub.2 or --NHC.sub.2 H.sub.4 SO.sub.3 M, and M's independently represent Li.sup..sym., Na.sup..sym., K.sup..sym. or .sup..sym. NH(C.sub.2 H.sub.4 OH).sub.3, provided that at least one of M's represents Li.sup..sym. or .sup..sym. NH(C.sub.2 H.sub.4 OH).sub.3. This reactive dye easily gives a stable liquid composition and is useful to dye cellulosic or polyamide fibers.Type: GrantFiled: October 24, 1989Date of Patent: July 16, 1991Assignee: Nippon Kayaku Kabushiki KaishaInventors: Nobuyuki Yamanaka, Kazuo Hanawa, Eiichi Ogawa
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Patent number: 5019132Abstract: Stable, concentrated, liquid preparations of 1:2 metal complex azo or azomethine dyes containing at most one sulfonic acid group are obtained by metallizing the metal-free azo or azomethine intermediates in form of their moist, almost salt-free washed, filter cakes with aqueous slurries of complex forming, preferably cobalt or chromium salts. Without isolation of the thus obtained metal complex dyes the dye slurries are then in situ converted into the stable, concentrated dye preparations by adjusting them to a final dye concentration.The dye preparations are produced in a very economic manner by avoiding any isolation of the metal complex dyes after the metallization step and by considerably reducing the amounts of effluents.The dye preparations obtained are suitable for the preparation of dye-baths or printing pastes which may be used in particular for dyeing and printing textile materials made of natural or synthetic polyamide fibres, and further of leather and paper.Type: GrantFiled: November 28, 1989Date of Patent: May 28, 1991Assignee: Ciba-Geigy CorporationInventors: Herb Davis, Charles R. Wetzel
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Patent number: 5009669Abstract: Aqueous stable dispersion of UV-absorbing 2-(2'-hydroxyphenyl)benzotriazole compounds containing(a) 15 to 50 per cent by weight of a benzotriazole compound of the formula ##STR1## where R is halogen, C.sub.1 -C.sub.12 alkyl, lower alkoxy, lower alkoxycarbonyl, cycloalkyl, aryl, C.sub.1 -C.sub.12 alkylaryl or aralkyl, and the rings A and B can be further substituted independently of one another by halogen, hydroxyl, lower alkyl, lower alkoxy or lower alkoxycarbonyl, and(b) 2 to 20 per cent by weight of an acid ester, or salt thereof, of an alkylene oxide adduct of the formula ##STR2## where X is the acid radical of an inorganic oxygen-containing acid, or else the radical of an organic acid and Y is C.sub.1 -C.sub.12 alkyl, aryl or aralkyl, "Alkylen" is the ethylene radical or propylene radical, and m is from 1 to 4 and n from 4 to 50.These dispersions are excellent agents for improving the light fastness of dyeings of synthetic fibres, in particular polyester fibres or acid-modified polyester fibres.Type: GrantFiled: May 30, 1989Date of Patent: April 23, 1991Assignee: Ciba-Geigy CorporationInventors: Martin Jollenbeck, Hans-Ulrich Berendt, Werner Fringeli
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Patent number: 4995885Abstract: Concentrated dye solutions of the formula (1) shown in claim 1 are described.The dye solutions are notable for a long shelf life and are suitable in particular for dyeing paper.Type: GrantFiled: November 13, 1989Date of Patent: February 26, 1991Assignee: Ciba-Geigy Corp.Inventor: Hans Morawietz
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Patent number: 4976744Abstract: Concentrated solutions of cationic dyes are prepared by treating the cationic dyes, which contain as the counterions the anions customarily present during their preparation, with alkali metal salts of monocarboxylic acids and with or without complexing agents in an aqueous glycol ether medium, and separating off the organic phase, which contains the dyes in the form of their monocarboxylic acid salts.Type: GrantFiled: September 12, 1989Date of Patent: December 11, 1990Assignee: BASF AktiengesellschaftInventors: Johannes P. Dix, Guenter Hansen, Hellmut Kast
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Patent number: 4940469Abstract: A stable and low-foaming composition for finishing synthetic fibres which contains, based on (a)+(b)+(c)(a) 15 to 84% by weight of a sparingly water-soluble or water-insoluble dye, fluorescent whitening agent or UV absorber,(b) 15.5% to 75% by weight of one or more dispersing agents, and(c) 0.5 to 10% by weight of an alkylenediamide.Type: GrantFiled: January 30, 1989Date of Patent: July 10, 1990Assignee: Ciba-Geigy CorporationInventors: Reinhart Mockel, Roland Putzar
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Patent number: 4934009Abstract: An aqueous liquid dye composition comprising 5 to 50% by weight of a mixture of at least one dye represented by the following formula (I), ##STR1## wherein A is a phenylene or naphthylene group unsubstituted or substituted by at least one member selected from methyl, methoxy, sulfo and carboxy, R is methyl or carboxy, Y.sub.1, Y.sub.2 and Y.sub.3 independently of one another are each hydrogen, chloro, methyl or sulfo, and Z is a group splittable by the action of an alkali, and at least one dye represented by the following formula (II), ##STR2## where A, R, Y.sub.1 Y.sub.2 and Y.sub.3 are as defined above, which can be stored for a long period of time even at lower temperatures such as 5.degree. C. or lower without crystallization of the dye.Type: GrantFiled: March 14, 1988Date of Patent: June 19, 1990Assignee: Sumitomo Chemical Company, LimitedInventors: Noriaki Yamauchi, Yutaka Kayane
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Patent number: 4923481Abstract: Aqueous dispersion of a sulfonated metallizable dye containing(a) based on the total weight at least 10% of the sulfonated metallizable dye and(b) a sulfonated condensation product obtained by reacting an aromatic compound having at least two replaceable ring-positioned hydrogen atoms in any desired order with a compound of the formula ##STR1## in which X is a direct bond or oxygen, Hal is chlorine or bromine and n is 1 to 4, and sulfonation.Type: GrantFiled: December 16, 1988Date of Patent: May 8, 1990Assignee: Ciba-Geigy CorporationInventors: Roberto Galli, Ernst Tempel
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Patent number: 4923641Abstract: Highly concentrated stable solutions of color-forming agents of the general formula ##STR1## wherein x denotes hydroxyl, alkoxy, alkenyloxy, aralkoxy, cycloalkoxy, aryloxy, acyloxy, alkylamino, dialkylamino, acylamino, aralkylamino or arylamino andR denotes alkyl, alkenyl or aralkyl,further isocyclic or heterocyclic rings can be fused onto the rings A, B, C and D and the cyclic and acyclic radicals and the rings A, B, C and D can carry further non-ionic substituents which are customary in dyestuff chemistry, or mixtures thereof, in water-insoluble organic solvents from the group comprising optionally chlorinated hydrocarbons, vegetable oils and phthalic acid esters are used for the preparation of pressure-sensitive recording materials.Type: GrantFiled: September 20, 1988Date of Patent: May 8, 1990Assignee: Bayer AktiengesellschaftInventors: Udo Eckstein, Hubertus Psaar
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Patent number: 4917706Abstract: Liquid compositions of sulfur dyes in reduced form are obtained by reducing a sulfur dye in an alkaline medium to which no sulfide reducing agent has been added, preferably employing a reducing sugar as reducing agent and a sulfur dye which has been washed to remove inorganic salts therefrom.Type: GrantFiled: February 1, 1988Date of Patent: April 17, 1990Assignee: Sandoz Ltd.Inventor: Laszlo A. Meszaros
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Patent number: 4906248Abstract: Cellulose fibers can be effectively dyed with an assistant composition comprising (a) a polymer or copolymer of maleic acid, acrylic acid, methacylic acid or a salt thereof and (b) a sulfonate of a monocyclic or polycyclic aromatic compound or a condensate thereof with an aliphatic aldehyde.Type: GrantFiled: March 24, 1988Date of Patent: March 6, 1990Assignee: Kao CorporationInventors: Naoki Kyochika, Shigeru Nagao
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Patent number: 4877412Abstract: Compounds of the formula ##STR1## in free acid or salt form and internal, external and acid addition salts thereof, whereinK is ##STR2## wherein R.sub.3 -R.sub.5, R.sub.20, R.sub.21 and X-Z are as defined in the specification,each of Q.sub.1 and Q.sub.2 is independently hydrogen or --SO.sub.3 M.sub.1,each R.sub.1 and R.sub.2 is independently hydrogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy or --COOM, andn is 0 or 1,wherein each M and M.sub.1 is independently hydrogen or a nonchromophoric cation, with the provisos that (i) the compound contains at least one --SO.sub.3 M or --SO.sub.3 M.sub.1 group, (ii) when K is a gruop of Formula (a), at least one of R.sub.4 and R.sub.5 is hydrogen, (iii) the total number of anionic groups equals or exceeds the total number of basic and cationic groups, (iv) the positive charge of each cationic group is balanced by the negative charge of an --SO.sub.3.sup..crclbar. or --COO.sup..crclbar.Type: GrantFiled: March 31, 1988Date of Patent: October 31, 1989Assignee: Sandoz Ltd.Inventor: Reinhard Pedrazzi
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Patent number: 4865885Abstract: This invention relates to a new process and group of products that are useful in preventing nylon and wool fibers, including carpeting and upholstery, from being permanently stained. Fibers can be permanently stained by food colors contained in foods spilled on the fiber. This new group of sulfonated phenol-formaldehyde or naphthol-formaldehyde and anionic surfactant compounds not only block the stain from the fiber but also minimizes any yellowing or discoloration of the treated fibers during the application and during the subsequent exposure to sunlight or commonly used lightfastness testing equipment.Type: GrantFiled: June 19, 1987Date of Patent: September 12, 1989Assignee: Crompton & Knowles CorporationInventors: Michel A. Herlant, Alexander S. Kirjanov, Vincent W. Bannigan, Jr.
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Patent number: 4851011Abstract: Concentrated aqueous dye formulations of water-soluble organic dyes are prepared by desalination and concentration of corresponding crude dye solutions by means of membrane separation processes. The effectiveness of the membrane separation process on the one hand and the stability of the dye formulations on the other hand is improved if dye solutions are subjected to cross-flow microfiltration before and/or after the membrane separation process and insoluble constituents are thus removed.Type: GrantFiled: April 15, 1988Date of Patent: July 25, 1989Assignee: Ciba-Geigy CorporationInventors: Roger Lacroix, Roland Ch.ang.telain, Petr Kvita
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Patent number: 4842646Abstract: A dye composition comprising (a) a water insoluble nigrosine dye, induline dye or basic dye, (b) a water miscible solvent, and (c) a hydroxycarboxylic acid having at least three hydroxy groups is useful in preparing aqueous inks and dye baths. If desired, such baths may also include a mordant, a humectant and a corrosion inhibitor.Type: GrantFiled: September 23, 1986Date of Patent: June 27, 1989Assignee: Saranda Consolidated Limited PartnershipInventor: Rodger L. Gamblin
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Patent number: 4838895Abstract: Concentrated aqueous dye formulations of anionic dyes are prepared from the corresponding crude dye solutions or suspensions, in which the anionic dyes are present as potassium, sodium/potassium or ammonium/potassium mixed salts, by desalinating and concentrating the solutions or suspensions by means of a membrane separation process. Sodium salts of mineral acids or lower organic carboxylic acids are added before or during this process in order to improve the solubility of the dyes and thus the stability of the dye formulations.Type: GrantFiled: April 8, 1988Date of Patent: June 13, 1989Assignee: Ciba-Geigy CorporationInventors: Roberto Galli, Petr Kvita
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Patent number: 4834771Abstract: An aqueous liquid dye composition comprising 10 to 50% by weight of a fiber-reactive copper phthalocyanine dye represented by the following formula (I) in the form of a free acid, ##STR1## wherein Y is a group of --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z, in which Z is a splittable group by the action of an alkali, and m and n are independently a number of 1 to 3, provided that they satisfy the following formula, 2<m+n.ltoreq.4, 0.1 to 20% by weight of at least one cyclic imide selected from .epsilon.-caprolactam and N-methylpyrrolidones and the balance of water, which is chemically and physically stable, even when stored for a long period of time at ambient temperature or stored at a relatively high temperature such as 50.degree. to 80.degree. C.Type: GrantFiled: March 6, 1986Date of Patent: May 30, 1989Assignee: Sumitomo Chemical Company, LimitedInventors: Noriaki Yamauchi, Shinnei Ikeou, Kunihiko Imada
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Patent number: 4832698Abstract: An aqueous liquid dye composition comprising a dye represented by the following formula in a free acid form, ##STR1## wherein Y is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 X in which X is a group splittable by the action of an alkali, and a pH buffer, the dye being in the form of a lithium salt, and the liquid dye composition having a pH value of from 3 through 7 and a dye content of from 5 through 50% by weight based on the weight of the liquid dye composition, which can be stored stably for a long period of time even at a low temperature such as 0.degree. C. or lower, and a high temperature such as 40.degree. C. or higher.Type: GrantFiled: April 8, 1987Date of Patent: May 23, 1989Assignee: Sumitomo Chemical Company, LimitedInventors: Shinei Ikeou, Takemi Tokieda, Noriaki Yamauchi, Kunihiko Imada, Yutaka Kayane
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Patent number: 4820308Abstract: Detergent cosmetic composition stable on storage, comprising in a cosmetically acceptable aqueous medium:(a) a soap,(b) a silicone cationic polymer consisting of a polysiloxane in which one or more of the silicon atoms are substituted with an aliphatic amino group,(c) a cationic surfactant, and(d) a cationic polymer chosen from cationic polysaccharides and cationic cyclopolymers(e) a direct dye.Type: GrantFiled: October 16, 1987Date of Patent: April 11, 1989Assignee: L'OrealInventors: Annie Madrange, Patrick Canivet
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Patent number: 4812143Abstract: Liquid formulations of disperse dyestuffs for dyeing hydrophobic synthetic fiber materials or mixtures of synthetic fiber materials with cellulose fiber material or wool contain from 0.1 to 10% by weight of pulverulent highly disperse inorganic oxides or silicates or mixtures of both said oxides and silicates having a specific surface area (BET) of 20 to 800 m.sup.2 /g.Type: GrantFiled: December 7, 1987Date of Patent: March 14, 1989Assignee: Cassella AktiengesellschaftInventors: Klaus Hofmann, Ulrich Buhler, Erwin Dietz
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Patent number: 4808192Abstract: In accordance with this invention an aqueous solution of a water-soluble dye containing lithium sulfonate group or ammonium sulfonate group can be obtained by a very simple and economical process in such a way that an aqueous solution of a water-soluble dye containing sodium sulfonate group is fed to a packed column packed with acid type cation exchange resin (H-form) to form an aqueous solution of a dye containing a free sulfonic acid group, and after neutralizing the resulting solution with LiOH or NH.sub.4 OH, the aqueous solution of the dye thus obtained is concentrated according to a process for separation through reverse osmotic membrane.Type: GrantFiled: September 15, 1986Date of Patent: February 28, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Yoshihiro Narita, Hiroshi Takimoto, Hideo Sano
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Patent number: 4802887Abstract: A composition comprising:(a) 30 to 90% by weight of one or more water soluble anionic dyestuffs in metal complex form,(b) 0.5 to 20% by weight of one or more compounds of formula I ##STR1## in which R.sub.1 is C.sub.12-22 alkyl or C.sub.12-22 alkenyl; R.sub.2 is hydrogen or --SO.sub.3 M;m is 2, 3 or 4;n is 2, 3 or 4;p+p' is 10 to 30 inclusive, each of p and p' being at least 1; and M is a cation; and(c) 5 to 40% by weight of a dispersing agent.These compositions are suitable for dyeing of textile and leather substrates.Type: GrantFiled: March 10, 1987Date of Patent: February 7, 1989Assignee: Sandoz Ltd.Inventor: Kamal Ateya
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Patent number: 4783196Abstract: Highly concentrated stable solutions of color-forming agents of the general formula ##STR1## wherein x denotes hydroxyl, alkoxy, alkenyloxy, aralkoxy, cycloalkoxy, aryloxy, acyloxy, alkylamino, dialkylamino, acrylamino, aralkylamino or arylamino andR denotes alkyl, alkenyl or aralkyl,further isocyclic or heterocyclic rings can be fused onto the rings A, B, C and D and the cyclic and acyclic radicals and the rings A, B, C and D can carry further non-ionic substituents which are customary in dyestuff chemistry, or mixtures thereof, in water-insoluble organic solvents from the group comprising optionally chlorinated hydrocarbons, vegetable oils and phthalic acid esters are used for the preparation of pressure-sensitive recording materials.Type: GrantFiled: February 5, 1987Date of Patent: November 8, 1988Assignee: Bayer AktiengesellshcaftInventors: Udo Eckstein, Hubertus Psaar
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Patent number: 4783195Abstract: A process for the preparation of a concentrated storage-stable aqueous solution of the dyestuff of the formula ##STR1## is characterized in that the reaction mixture obtainable from the quinone derivative of the formula ##STR2## by sulphation and subsequent oxidation cyclization, preferably with ammonium, sodium or potassium peroxodisulphate, in oleum is diluted with water or sulphuric acid to a sulphuric acid concentration of 37-50%, preferably 41-43%, and the product which thereby precipitates is separated off and brought to a pH of about 2-6, preferably 3-4, in water with basic lithium compounds, preferably lithium carbonate or lithium hydroxide.Type: GrantFiled: January 22, 1988Date of Patent: November 8, 1988Assignee: Bayer AktiengesellschaftInventors: Werner Steinbeck, Wolfgang Harms
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Patent number: 4780104Abstract: An aqueous liquid dye composition comprising 5 to 50% by weight of a reactive dye represented by the following formula, ##STR1## wherein D denotes a sulfo group-containing organic dye residue, R.sub.1 and R.sub.2 independently of one another denote a hydrogen atom or a C.sub.1 to C.sub.4 alkyl group unsubstituted or substituted with a halogen atom or a hydroxyl, cyano, C.sub.1 to C.sub.4 alkoxy, carboxy, carbamoyl, C.sub.1 to C.sub.4 alkoxycarbonyl, C.sub.1 to C.sub.4 alkylcarbonyloxy, sulfo or sulfamoyl group, A denotes a phenylene group unsubstituted or substituted with one or two members selected from methyl, ethyl, methoxy, ethoxy, chlorine, bromine and sulfo, or a naphthylene group unsubstituted or substituted with one sulfo group, X denotes a halogen atom, and Y is a group of --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z in which Z is a splittable group by the action of an alkali, 0.1 to 10% by weight of .epsilon.Type: GrantFiled: February 20, 1987Date of Patent: October 25, 1988Assignee: Sumitomo Chemical Company, LimitedInventors: Noriaki Yamauchi, Kunihiko Imada, Shinei Ikeou
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Patent number: 4765797Abstract: Liquid formulations of mixtures of cationic dyes frequently have a very short storage life. As a consequence, these formulations give rise to customer complaints concerning incorrect dyeing strengths and hues and concerning isoluble constituents. It has now been found according to the invention that powder formulations and in particular liquid formulations of cationic dyes or of mixtures of these dyes can be stabilized by adding selected oxidizing agents.Type: GrantFiled: June 8, 1987Date of Patent: August 23, 1988Assignee: Hoechst AktiengesellschaftInventors: Manfred Hahnke, Sierling Ong, Kurt Hohmann
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Patent number: 4764175Abstract: Metal-free compounds of the formula, ##STR1## and 1:1 copper complexes of metallizable metal-free compounds of said formula and internal and external salts of metal-free compounds of said formula and of 1:1 copper complexes of metallizable metal-free compounds of said formula, whereineach Q is independently linear or branched C.sub.2-6 alkylene; linear or branched C.sub.2-6 alkylene interrupted by --O--, --S-- or --NR.sub.4 --; linear or branched C.sub.3-6 alkylene monosubstituted or disubstituted by hydroxy or --*NHCO--CH.sub.2 --, wherein the * denotes the atom attached to the --NR.sub.4 -- radical,each R.sub.1 is independently hydrogen, halo, nitro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, (C.sub.1-4 alkyl)carbonylamino, --SO.sub.2 NR.sub.3 R.sub.4, --CONR.sub.4 --C.sub.6 H.sub.5 or benzamido,R.sub.2 is hydrogen, hydroxy, halo, nitro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, (C.sub.1-4 alkyl)carbonylamino or --NHCONR.sub.3 R.sub.4,X is --NR.sub.5 R.sub.6 or --N.sup..sym. R.sub.7 R.sub.8 R.sub.9 An.sup..crclbar.Type: GrantFiled: August 15, 1986Date of Patent: August 16, 1988Assignee: Sandoz Ltd.Inventors: Jacky Dore, Reinhard Pedrazzi
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Patent number: 4762524Abstract: This invention is directed to a dyestuff composition comprising the reaction product of a water-soluble, vinyl-sulfone type, reactive dye and a N-alkyl-amino-alkyl sulfonic acid and/or carboxylic acid or the salts thereof wherein the N-alkyl-amino-alkyl acid or salt is reacted with said dye in an amount of about 0.5 to 1.0 mole per mole of dye. This dyestuff composition is used to dye synthetic polyamides according to a process where said composition is applied to a polyamide fiber from an aqueous solution having a pH from about 3 to about 4; preferably 3.5 and then fixed to said fiber by heat.Type: GrantFiled: February 5, 1987Date of Patent: August 9, 1988Assignee: Hoechst Celanese CorporationInventors: Thomas V. Chambers, Manfred Deicke, Suzanne C. Fleming
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Patent number: 4752298Abstract: The invention relates to storage-stable aqueous formulations of water-insoluble or sparingly water-soluble solids which contain an electrolyte-sensitive thickener in addition to a dispersant.During storage, even for considerable periods of time, these formulations form no sediment and can be diluted by stirring in a small amount of electrolyte (e.g. a salt) and are then ready for use.Type: GrantFiled: November 17, 1986Date of Patent: June 21, 1988Assignee: Ciba-Geigy CorporationInventors: Marc Burglin, Roland Putzar
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Patent number: 4749380Abstract: An aqueous liquid composition comprising at least one dye represented by the following formula in a free acid form,D--(SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H).sub.nwherein D is an organic dye residue having 1 to 3 sulfo groups, and n is 1 or 2, in an amount of 5 to 50% by weight, a buffer in an amount of not less than 0.1% by weight but less than 1% by weight, and a substance inert to the above dye in an amount of 0 to 10% by weight, the balance being water, and a pH value of the aqueous liquid composition ranging from 2.5 to 5.5, whcih can be stored for a long period of time even at low and high temperatures without physical and chemical changes.Type: GrantFiled: July 1, 1986Date of Patent: June 7, 1988Assignee: Sumitomo Chemical Company, LimitedInventors: Noriaki Yamauchi, Kunihiko Imada
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Patent number: 4746323Abstract: This invention is directed to mixtures of water-soluble, fiber reactive yellow dyestuffs which exhibit superior build-up and color properties over those properties obtained with the individual components of the mixtures. The dyestuffs disclosed herein have the following general formula in their free acid form: ##STR1## wherein R is lower alkyl, lower alkoxy or hydrogen and wherein X is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 --Z wherein Z is --OH, --Cl, --Br, --OSO.sub.3 H, --SSO.sub.3 H, OPO.sub.3 H.sub.2 or --N(R.sub.1).sub.2, and wherein R.sub.1 is lower alkyl or hydrogen.Type: GrantFiled: August 24, 1987Date of Patent: May 24, 1988Assignee: Hoechst Celanese CorporationInventors: Thomas S. Phillips, Anthony J. Corso
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Patent number: 4737240Abstract: Black trisazo dyes for cellulosic textiles, leather and especially paper having the structure ##STR1## where A is ##STR2## one of B.sub.1 and B.sub.2 is hydrogen and the other is --SO.sub.3 M or a mixture thereof, and M is hydrogen, sodium, potassium, lithium or --HNR.sub.1 R.sub.2 R.sub.3 wherein R.sub.1, R.sub.2 and R.sub.3 represent the same or different substituents selected from hydrogen, lower alkyl and lower hydroxyalkyl, and stable liquid concentrates of these dyes are described.Type: GrantFiled: June 27, 1986Date of Patent: April 12, 1988Assignee: Ciba-Geigy CorporationInventors: Herbert S. Davis, Roy E. Smith, Mortimer Weiser
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Patent number: 4725285Abstract: Liquid compositions having high storage-stability which contain reactive dyestuffs, alkali metal polyacrylates or alkali metal polymethacrylates with number average degree of polymerization not exceeding 1000 and water. The liquid compositions are useful for a dyeing process of cellulose fiber materials.Type: GrantFiled: June 13, 1986Date of Patent: February 16, 1988Assignee: Nippon Kayaku Kabushiki KaishaInventors: Nobuyuki Yamanaka, Tamio Sunaga
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Patent number: 4722738Abstract: A waterless dye composition for apparel and other articles, made from thermoplastic materials, comprises an aliphatic polyester of a higher alkanoic acid and a polyol, of the formula (ACOO).sub.2-6 B, wherein A is alkyl of 8-22 carbon atoms and B is the residue of a polyhydric alcohol, other than glycerol, of 2-6 hydroxyl groups and an organic colorant. The compositions can further comprise an aromatic polyester of the formula C.sub.6 H.sub.z' --COOR.sub.1).sub.z, wherein z is 3, 4, 5, or 6; z' is 6-z; and R.sub.1 is higher alkyl; and/or a cycloaliphatic diester of the formula ##STR1## wherein R is substituted or unsubstituted straight or branched chain alkyl of 4-20 carbon atoms, polyoxyalkylene of the formula HO(C.sub.x H.sub.y O).sub.n C.sub.x H.sub.y --or phosphated polyoxyalkylene of the formula (HO).sub.2 P(.dbd.O)O(C.sub.x H.sub.2x O).sub.n C.sub.x H.sub.2x or a salt thereof, wherein (C.sub.x H.sub.2x O).sub.n is (CH.sub.2 CH.sub.2 O).sub.n, (C.sub.3 H.sub.6 O).sub.n or (CH.sub.2 CH.sub.2 O).sub.p (C.Type: GrantFiled: July 25, 1986Date of Patent: February 2, 1988Assignee: Crucible Chemical CompanyInventor: Robert B. Wilson
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Patent number: 4713081Abstract: The invention provides aqueous dyestuff preparations of water-insoluble or sparingly water-soluble dyes which may be used for preparing printing pastes to be used for printing textile material as well as for printing supports for transfer printing. The preparations contain at least 10% by weight of water, 10 to 60% by weight of a finely dispersed water-insoluble or sparingly water-soluble dye, 0.1 to 5% by weight of at least one anionic dispersant, and 0.5 to 5% by weight of a non-ionic copolymer of ethylene oxide and a further olefin oxide, said copolymer having an ethylene oxide content of at least 65% by weight and a molecular weight of more than 12,000, and also, if desired, further ingredients.Type: GrantFiled: April 23, 1979Date of Patent: December 15, 1987Assignee: Ciba-Geigy CorporationInventor: Carl Becker
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Patent number: 4711641Abstract: A reactive blue dye composition, which comprises a phthalocyanine dye represented by a free acid of the following formula (I), ##STR1## wherein CuPc is a copper phthalocyanine nucleus, W is a C.sub.2 -C.sub.4 alkylene group or a 1,3- or 1,4-phenylene group having one or two sulfo groups, R.sub.1 and R.sub.2 are independently a hydrogen atom or a lower alkyl group, 1 is a number of 1 to 3, m is a number of 0 to 2, and n is a number of 1 to 3, provided that the total number of 1, m and n is 4 or less, and a phthalocyanine dye represented by a free acid of the following formula (II), ##STR2## wherein CuPc, 1, m and n are as defined above, Y.sub.1 and Y.sub.2 are independently a hydrogen atom or a methyl, methoxy or sulfo group, R.sub.3 is a hydrogen atom or a lower alkyl group, and Q is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.Type: GrantFiled: March 12, 1986Date of Patent: December 8, 1987Assignee: Sumitomo Chemical Company, LimitedInventors: Toshio Nakamatsu, Tetsuya Miyamoto, Kunihiko Imada