Synthetic Fiber Produced From Material Which Contains Pendant -coo-, -(o=)s(=o)-o-, -o-(o=)p(=o)-o-, Pyridino, Dialkylaminoalkyl-, Or Quaternary Ammonium Radical, Dyeing Process Or Product Patents (Class 8/539)
  • Patent number: 4563191
    Abstract: Fiber material composed of acid-modified homopolymers or copolymers of acrylonitrile (PAC fibers) which has been obtained by a wet spinning process, has not been dried and is still in a swollen condition (gel form), can be dyed advantageously and in fast colors by means of soluble dyes, the molecule of which contains several groups, namely more than one quaternary grouping and/or a strongly basic grouping carrying no charge, which exert a basic action towards the acid groups of the fiber substance. The chromophore of this colorant can belong to the category of monoazo or diazo dyes, methine, azamethine or diazamethine dyes or naphthalactam dyes.In accordance with the invention, after substantially removing the non-aqueous spinning solvent by washing, the spun material, as a moist gel, is dyed continuously or discontinuously from an aqueous dyebath; the fibers can be stretched before the dye is applied, during the dyeing process itself or immediately afterwards.
    Type: Grant
    Filed: September 4, 1984
    Date of Patent: January 7, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Hahnke, Reinhard Mohr, Kurt Hohmann
  • Patent number: 4536185
    Abstract: A novel liquid preparation containing a mixture of dyes according to claim 1, an aliphatic carboxylic acid, and optionally water and organic solvents. This novel preparation is storage-stable and temperature-stable and can be used in particular for dyeing polyacrylonitrile materials in black shades, the dyeings obtained having a neutral shade, negligible change of shade in artificial light and very good fastness to light.
    Type: Grant
    Filed: December 23, 1983
    Date of Patent: August 20, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Arnulf R. Lapple, Alex Nicopoulos
  • Patent number: 4509948
    Abstract: Cationic dyestuffs of the general formula ##STR1## wherein D is the radical of a diazo component free of anionic groups,X is a radical of the formula COCH.sub.3, CN, COOCH.sub.3, COOC.sub.2 H.sub.5, CONH.sub.2 or COC.sub.6 H.sub.5,R.sub.1 and R.sub.2 independently of each other are hydrogen or a nonionic substituent andR.sub.3, R.sub.4 and R.sub.5 independently of one another are alkyl, alkenyl or aralkyl, orR.sub.3 and R.sub.4, together with the nitrogen to which they are bonded, form a 5- or 6-membered heterocyclic ring,n is 1 or 2 andAn.sup.(-) is an anion, andwherein the cyclic and acyclic radicals can in turn be substituted, are used for dyeing synthetic and natural cationically dyeable materials, such as cotton, paper, leather, polyacrylnitrile or acid-modified polyester or polyamide fibres.
    Type: Grant
    Filed: August 5, 1983
    Date of Patent: April 9, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Wild, Frank-Michael Stohr
  • Patent number: 4508536
    Abstract: A preparation containing a mixture of dyes for dyeing polyacrylonitrile materials in navy blue to black shades, the dyeings obtained being distinguished in particular by a very good fastness to light.
    Type: Grant
    Filed: November 14, 1983
    Date of Patent: April 2, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul Erzinger, Arnulf R. Lapple
  • Patent number: 4502862
    Abstract: Cationic polyazo dyestuffs which can be obtained by reacting diaminobenzene derivatives of the general formula ##STR1## wherein R represents hydrogen, C.sub.1 - to C.sub.4 -alkyl, C.sub.1 - to C.sub.4 -alkoxy or halogen,if appropriate in a mixture with up to 30% of aromatic monoamines of the formula ##STR2## wherein R.sup.2 represents hydrogen, C.sub.1 - to C.sub.4 -alkyl, C.sub.1 - to C.sub.4 -alkoxy, halogen or C.sub.1 - to C.sub.4 -acylamino and n represents 1 to 3,with 0.5 to 0.75 mole of a salt or ester of nitrous acid per mole of diamine and then with 1 to 4 moles of an alkylene oxide of the formula ##STR3## wherein R.sup.3 represents hydrogen or an optionally hydroxyl-, alkoxy- or halogen-substituted C.sub.1 - to C.sub.4 -alkyl radical,are used--preferably in the form of their solutions--for dyeing paper, leather and anionically modified synthetic fibres.
    Type: Grant
    Filed: January 16, 1984
    Date of Patent: March 5, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventor: Roderich Rave
  • Patent number: 4490149
    Abstract: A process for producing modified polyester products by the graft polymerization of vinyl monomers having an acidic group and replacing the acidic group with an alkali metal salt, the replacing being carried out after dyeing. By this process, decrease in strength and color fastness of polyester fibers can be avoided while giving the polyesters characteristics similar to those of cotton.
    Type: Grant
    Filed: September 9, 1983
    Date of Patent: December 25, 1984
    Assignee: Toray Industries, Inc.
    Inventors: Kouichi Saitou, Shunroku Tohyama, Yoshikazu Kosaka
  • Patent number: 4488879
    Abstract: This invention relates to dyeing textile materials of polyacrylonitrile or copolymers containing acrylonitrile in polymerized form with basic dyestuffs in aqueous dyeing liquors using the exhaust method employing retarders. The retarders are obtained by condensing (a) piperazine and piperazine derivatives with (b) ethylene chloride, epihalohydrin, propylene chloride, 1,3-dichloro-2-hydroxypropane, bis-epoxybutane, 1,4-dichlorobutene or their mixtures in mole ratios of 1:0.9 to 1:1.1. The condensation products are then quaternized with benzyl chloride using 0.8 to 1.5 moles of benzyl chloride per mole of component (a) for the quaternization. The aqueous solutions of the retarders either do not foam or show a very low foaming tendency.
    Type: Grant
    Filed: July 5, 1983
    Date of Patent: December 18, 1984
    Assignee: BASF Aktiengesellschaft
    Inventors: Rolf Fikentscher, Herbert Fleischer, Sigismund Heimann, Heinrich Mertens
  • Patent number: 4465490
    Abstract: A process for the continuous dyeing of fabric webs, in which the fabric web is impregnated at a temperature between 20.degree. and 95.degree. C. with an aqueous liquor which contains dissolved and/or dispersed dyestuffs and squeezed, and the dyestuffs are fixed in a steam/air mixture, which comprises fixing the dyestuff without the impregnated fabric having been dried at an intermediate stage, keeping the dry temperature of the steam/air mixture between 110.degree. and 140.degree. C., adjusting the steam content of the steam air mixture in such a way that the wet temperature of the moist fabric web is between 50.degree. and 95.degree. C., and fixing the dyestuffs for at least 20 seconds.
    Type: Grant
    Filed: February 16, 1983
    Date of Patent: August 14, 1984
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Hans-Ulrich von der Eltz
  • Patent number: 4462805
    Abstract: A mixture of cationic compounds of the formulae ##STR1## is obtained by reaction of a compound of the formula ##STR2## with an aldehyde of the formula II ##STR3## in an aqueous or organic medium, in the presence of an acid, in which formulae, the symbols have the meanings defined in claim 1. The mixtures obtained are suitable in particular for the dyeing of paper, whereby neutral-yellow dyeings are obtained.
    Type: Grant
    Filed: May 10, 1983
    Date of Patent: July 31, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Willy Stingelin, Peter Loew
  • Patent number: 4445904
    Abstract: A process for the continuous dyeing of fiber material of one or more acid-modified polymers or copolymers of acrylonitrile in the gel state, said fiber material having been produced by wet spinning from a spinning solution containing one or more organic solvents, which process comprises dyeing the fiber material with a solution of a carbinol base or anhydro base of a carboxyl- or sulfo-free N-arylated triarylmethane dyestuff, a carboxyl- or sulfo-free N-arylated diarylindolylmethane dyestuff, a carboxyl- or sulfo-free N-arylated diaryloxazine dyestuff, a carboxyl- or sulfo-free N-arylated diarylxanthene dyestuff, or a carboxyl- or sulfo-free N-arylated diarylazine dyestuff in a dye bath containing water and the organic spinning solvent or solvents.
    Type: Grant
    Filed: October 14, 1982
    Date of Patent: May 1, 1984
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Hahnke, Wolfgang Teige
  • Patent number: 4384870
    Abstract: Compounds of the formula ##STR1## in which A is the radical of a sulpho group-containing diazo component of the aniline or 1- or 2-aminonaphthalene series,K is a coupling component radical of the phenol series, having a free hydroxy group or an etherified or acylated hydroxy group,R.sub.1 is hydrogen C.sub.1-4 alkoxy, C.sub.1-4 alkyl or C.sub.1-4 haloalkyl,R.sub.2 is C.sub.1-4 alkyl, C.sub.1-6 alkyl-CO-, C.sub.1-6 alkyl-O-CO-, -CONH.sub.2, C.sub.1-6 alkyl-NH-CO-, di-(C.sub.1-6 alkyl)N-CO-, 2-, 3-, 4-, 5- or 6-hydroxy(C.sub.2-6 alkyl)-NH-CO- or (2-, 3-, 4-, 5- or 6-hydroxy(C.sub.2-6 alkyl)).sub.2 N-CO-, andR.sub.10 is hydrogen or C.sub.1-4 alkyl,and mixtures thereof, which compounds are in free acid or salt form and are useful for dyeing or printing anionic dyeable substrates such as leather, natural and synthetic polyamides, polyurethanes and polyolefins modified to contain basic groups, especially nylon.
    Type: Grant
    Filed: July 27, 1981
    Date of Patent: May 24, 1983
    Assignee: Sandoz Ltd.
    Inventor: Francois Benguerel
  • Patent number: 4374641
    Abstract: A color concentrate for coloring thermoplastic polymeric materials, which is prepared from a blend of a water - or organic solvent-dispersible polymer and a heat-stable, chemically-inert coloring agent selected from water-soluble dyes, organic-soluble dyes, polymer-soluble dyes, and pigments, from which blend any solvent present during processing is subsequently removed.
    Type: Grant
    Filed: June 5, 1980
    Date of Patent: February 22, 1983
    Assignee: Badische Corporation
    Inventor: Dominick A. Burlone
  • Patent number: 4362530
    Abstract: A composition containing(A) 10 parts by weight of an anionic product obtained by addition of 5 to 20 mols of ethylene oxide to an aliphatic saturated or unsaturated alcohol of 10 to 24 carbon atoms, followed by carboxymethylation(B) 1 to 15 parts by weight of a cationic addition product of 50 to 150 mols of ethylene oxide to a fatty amino-(C.sub.2-3)alkylene-amine(C) 1 to 10 parts by weight of a non-ionic addition product of 20 to 150 mols of ethylene oxide to castor oil, or a non-ionic sequenced addition product of 20 to 150 mols of ethylene oxide and 1 to 10 mols of propylene oxide to castor oil, and(D) 1 to 20 parts by weight of a N-(.beta.-hydroxy-(C.sub.2-4)alkyl)-fatty acid amide,is a dyeing auxiliary useful for the dyeing in one bath or printing of a mixed textile substrate comprising cationic dyeable fibres and anionic or disperse dyeable fibres.
    Type: Grant
    Filed: March 19, 1981
    Date of Patent: December 7, 1982
    Assignee: Sandoz Ltd.
    Inventors: Rolf Gross, Rene Fricker
  • Patent number: 4314817
    Abstract: Compounds of the formula ##STR1## in which R is --CH.sub.3, --C.sub.2 H.sub.5, --CH.sub.2 CH.sub.2 OH, --CH.sub.2 CH(OH)CH.sub.3 or --CH.sub.2 CH.dbd.CH.sub.2 ;R.sub.1 is --H or --CH.sub.3 ;R.sub.2 is --H or --CH.sub.3 ;R.sub.3 is --OCH.sub.3 or --OC.sub.2 H.sub.5 ;R.sub.4 is --H, --CH.sub.3, --C.sub.2 H.sub.5, n- or i- C.sub.3 H.sub.7, --CH.sub.2 CH.sub.2 OH or --CH.sub.2 CH.dbd.CH.sub.2 ;R.sub.5 is --H, --CH.sub.3, --C.sub.2 H.sub.5, n- or i- C.sub.3 H.sub.7 or R.sub.3 and R.sub.5 together with the N-atom to which R.sub.5 is attached and ring B form the group ##STR2## wherein R.sub.2 and R.sub.4 are as defined above, andR.sub.6 is --H or CH.sub.3 ; andA.sup..crclbar. is an anion,which are suitable for use as dyes, particularly for dyeing textile substrates comprising or consisting of homopolymers and copolymers of acrylomotrile or asymmetric dicyanoethylene, polyamides modified to contain acid groups and polyesters modified to contain acid groups and for leather, paper and plastics.
    Type: Grant
    Filed: August 11, 1980
    Date of Patent: February 9, 1982
    Assignee: Sandoz Ltd.
    Inventor: Berthold Gertisser
  • Patent number: 4306875
    Abstract: This invention relates to novel dye salts of basic dyes or basic optical brighteners and anionic esters of boric acid. The invention also includes the preparation of the aforementioned novel dye salts.
    Type: Grant
    Filed: August 5, 1980
    Date of Patent: December 22, 1981
    Assignee: Aziende Colori Nazionali Affini ACNA S.p.A.
    Inventors: Francesco De Feo, Adelio Basilico
  • Patent number: 4264325
    Abstract: 2-Phenyl-5-benzimidazol-2'-yl-furanes of the formula ##STR1## in which R.sub.1 to R.sub.6 are as defined in the specification, n is the number 0 or 1 and A.crclbar. is a colorless anion equivalent to the cation of the fluorescent brightener, their preparation as well as their use for optically brightening organic materials are disclosed.
    Type: Grant
    Filed: July 2, 1979
    Date of Patent: April 28, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans R. Meyer, Kurt Weber
  • Patent number: 4211527
    Abstract: Described is a process for dyeing polyester materials, or mixtures thereof with other fibres, by the exhaust method from an aqueous liquor, in which process the liquor contains at least 0.2 percent by weight, relative to the material, of at least one alkaline-earth metal salt, aluminium salt or organic ammonium salt of a mono- or polyvalent aliphatic organic acid or of a mono- or polyvalent inorganic acid. Preferably calcium chloride or magnesium chloride are used.
    Type: Grant
    Filed: December 9, 1977
    Date of Patent: July 8, 1980
    Assignee: Ciba-Geigy Corporation
    Inventor: Jean P. Luttringer