Inorganic Additive For Dye Composition, Dye Composition Containing Inorganic Additive, Process Or Product; Other Than Emulsifier, Ph Adjuster, Water, Nitrous Acid For Azo Coupling Or Sulfur Reducing Agent For Vat Or Sulfur Dye Patents (Class 8/618)
  • Patent number: 9023116
    Abstract: As associative thickener obtainable by free radical polymerization, the preparation thereof and the use thereof in paper coating slips are described. The associative thickener is formed from (a) acid monomers selected from ethylenically unsaturated C3- to C8-carboxylic acids, (b) associative monomers of the general formula H2C?CR1—COO-(EO)n—(PO)m—R2, in which R1 is hydrogen or methyl, n is a number of at least two, m is a number from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R2 is a C8-C30-alkyl group or a C8-C30-alkaryl group, and (c) nonionic, copolymerizable monomers differing from a) and b), the reaction product having been reacted, after the polymerization, with initiators forming nonionic radicals.
    Type: Grant
    Filed: February 1, 2011
    Date of Patent: May 5, 2015
    Assignee: BASF SE
    Inventors: Philipp Zacharias, Hermann Seyffer, Ilshat Gubaydullin, Harutyun Hanciogullari, Marc Bothe
  • Patent number: 8900330
    Abstract: An agent that is capable of improving dye fastness is provided. The agent includes a compound that includes at least one functional group capable of forming at least one interaction or at least one bond with a fiber or a dye molecule. Also, a method for using the agents to improve dye fastness and a dyed article including the agent are provided.
    Type: Grant
    Filed: February 26, 2010
    Date of Patent: December 2, 2014
    Assignee: Korea University Research and Business Foundation
    Inventor: Dong Hoon Choi
  • Patent number: 8828101
    Abstract: An agent that is capable of improving dye fastness is provided. The agent includes a compound that includes at least one functional group capable of forming at least one interaction or at least one bond with a fiber or a dye molecule. Also, a method for using the agents to improve dye fastness and a dyed article including the agent are provided.
    Type: Grant
    Filed: February 26, 2010
    Date of Patent: September 9, 2014
    Assignee: Korea University Research and Business Foundation
    Inventor: Dong Hoon Choi
  • Patent number: 8460399
    Abstract: The present invention provides compositions and methods which are adapted to impart color to concrete or mineral substrate surfaces. Specifically, the present invention relates to a composition and methods adapted to treat concrete surfaces which have the advantage of using a non-corrosive acid-based solution.
    Type: Grant
    Filed: May 10, 2007
    Date of Patent: June 11, 2013
    Assignee: Valspar Corporation
    Inventors: Sanford Lee Hertz, Ed Daraskevich, William W. Tao, Jason J. Netherton, Matthew S. Gebhard
  • Publication number: 20130139328
    Abstract: The present invention relates to the reaction product of (A) a polymeric backbone with (B) A chromophore; and with (C) at least one sulfide containing compound. Very good dyeing results are obtained with this new technology.
    Type: Application
    Filed: August 15, 2011
    Publication date: June 6, 2013
    Applicant: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
  • Patent number: 8262742
    Abstract: The present invention relates to a method of applying dye and stainblocker to a substrate comprising cationically dyeable fibers which reduces or eliminates the need for subsequent reapplication of dye. The present invention solves the problem of cationic dye removal resulting from stainblocker application by providing a method wherein application of stainblocker precedes the application of dye to a substrate comprising cationically dyeable fibers. Surprisingly, the invention provides a method wherein the effectiveness of cationic dye application is improved when preceded by stainblocker application compared to stainblocker application preceded by cationic dye application. The substrate comprising cationically dyeable fibers preferably further comprises acid dyeable fibers wherein even more preferably, said cationically dyeable fibers and acid dyeable fibers are attached to a backing to form a carpet.
    Type: Grant
    Filed: November 6, 2007
    Date of Patent: September 11, 2012
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Aaron Frank Self
  • Publication number: 20120030884
    Abstract: A coloring system can include a noble gas, colorant, and one or more vessels configured to convert the noble gas into a supercritical fluid, and/or receive and color an article of manufacture with the noble gas in the supercritical fluid state. A coloring process can include converting a noble gas into a supercritical fluid state; dissolving, suspending, or absorbing a colorant into the supercritical noble gas, and coloring an article of manufacture with the noble gas in the supercritical fluid state. A coloring composition can include a noble gas in a supercritical fluid state, and a colorant located in the supercritical noble gas.
    Type: Application
    Filed: August 6, 2010
    Publication date: February 9, 2012
    Applicant: EMPIRE TECHNOLOGY DEVELOPMENT LLC
    Inventors: William B. Carlson, Gregory D. Phelan, Philip A. Sullivan
  • Publication number: 20110110817
    Abstract: The present disclosure is directed to a method and system for contacting a colorant-contaminated aqueous solution with a rare earth-containing composition to form a treated solution substantially depleted of the colorant.
    Type: Application
    Filed: November 9, 2010
    Publication date: May 12, 2011
    Applicant: MOLYCORP MINERALS, LLC
    Inventors: Joseph A. Lupo, Joseph R. Pascoe
  • Patent number: 7553339
    Abstract: A method of dyeing or printing textile fiber materials, which comprises bringing the fiber material into contact with (a) at least one reactive dye containing at least one anionic group, (b) at least one compound which reduces the ionic character of the anionic group, and (c) at least one nucleophilic compound, yields dyeings or prints having deep hues and very good fastness properties.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: June 30, 2009
    Assignee: Huntsman International LLC
    Inventors: Jürgen Schmiedl, Wolfgang Mundle
  • Patent number: 7425235
    Abstract: The present invention includes a paint or coating composition comprising an organic pigment or dye complexed to the surface of a layered or fibrous inorganic clay. A wide variety of paint colors can be obtained by varying the pH during the preparation as well as by varying the synthesis conditions and changing particle size of the clay.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: September 16, 2008
    Assignee: The Board of Regents of the University of Texas System
    Inventors: Russell Chianelli, Lori A. Polette
  • Publication number: 20080120791
    Abstract: The present invention is related to an aqueous colouring composition for keratin fibres especially human hair. Accordingly the subject of the present invention is an aqueous hair colouring composition comprising at least one hair dye and at least one colour effect pigment consisting of synthetic mica coated with metal oxide or oxides and having a volume particle size distribution in the range of 1 to 750 ?m at a concentration of 0.01 to 10% by weight, calculated to total composition.
    Type: Application
    Filed: October 29, 2007
    Publication date: May 29, 2008
    Applicant: KPSS-KAO PROFESSIONAL SALON SERVICE GMBH
    Inventors: Martin Hoffmann, Mustafa Grit
  • Patent number: 7320766
    Abstract: Dyed yarns typically have inferior color fastness compared with pigmented yarns. However, dyeing offers a virtually infinite selection of colors, flexibility and more uniformity than constructions of pigmented yarns in residential carpet and other yarn applications, such as apparel. It has been found that relatively small amounts of pigment (10 to 1000 ppm) incorporated into polymeric fibers, and particularly nylon fibers used in carpets, creates lightly pigmented yarns which, when overdyed, are highly uniform and have a higher degree of apparent dye light fastness compared to normal dyed yarns. This effect is observable for both anionic and cationic polyamide polymers, and dyeing of these slightly pigmented yarns can be conducted to produce yarns of almost any color of greater depth than the base yarn.
    Type: Grant
    Filed: February 25, 2004
    Date of Patent: January 22, 2008
    Assignee: INVISTA North America S.ar.l.
    Inventor: Sundar Mohan Rao
  • Patent number: 7101407
    Abstract: The present invention relates to sulfur dye protection systems and compositions and methods employing same, as well as processes for making sulfur dyes, especially bleach stable sulfur dyes, processes for dying textiles with sulfur dyes and textiles dyed by such processes. More particularly, the present invention relates to modifying existing dyes and/or making newly formed sulfur dyes. Even more particularly, the present invention relates to materials that can chemically or physically interact with sulfur dyes to protect the sulfur dyes from oxidation by oxidizing agents, such as bleaching agents.
    Type: Grant
    Filed: February 13, 2003
    Date of Patent: September 5, 2006
    Assignee: The Board of Regents of the University of Nebraska
    Inventor: Jiping Wang
  • Patent number: 7094263
    Abstract: A composition of matter (e.g., a molded article) is described. More particularly, the composition of matter includes: (a) a resinous component selected from at least one member of the group consisting of (co)polyester, (co)polycarbonates, acrylonitrile-butadiene-styrene, polyamide, polyurethane, polyalkyl(meth)acrylate and styrene copolymers; (b) at least one water-insoluble dye; (c) a carrier represented by the following formula, R1[—O—(CH2)n]mOR2 wherein R2is butyl, R1 is H, n is 2 or 3, and m is 2–35; (d) an emulsifier that is poly(oxy-1,2-ethanediyl), alpha-phenyl-omega-hydroxy, styrenated; and (e) a particulate or plate-like material, such as metal flakes.
    Type: Grant
    Filed: March 14, 2005
    Date of Patent: August 22, 2006
    Assignee: Bayer Materialscience LLC
    Inventors: Robert A. Pyles, Rick L. Archey
  • Patent number: 7060108
    Abstract: Hair can be dyed by applying an oxidizing-agent-free, air-oxidative, one-pack hair dye composition to the hair without mixing the hair dye composition with an oxidizing agent and, after the hair is left over for 5 minutes to 1 hour, rinsing off the hair dye composition with water. The hair dye composition comprises: (a) a water soluble salt of a transition metal: 0.001 to 10 wt. % in terms of an anhydride based on the whole composition, (b) a chelating agent capable of coordinating on said transition metal: 0.001 to 10 wt. % based the whole composition, and (c) a color-developing substance: 0.001 to 10 wt. % based on the whole composition. According to the present invention, hair can be dyed by a convenient procedure without damage. The present invention is also excellent in dyeing properties and color variations.
    Type: Grant
    Filed: December 18, 2002
    Date of Patent: June 13, 2006
    Assignee: Kao Corporation
    Inventors: Kenichi Morita, Akihiro Sato
  • Patent number: 7048771
    Abstract: The present invention employs the use of nanotechnology to textile coloration. The textiles so produced have good fastness and greatly reduce environmental concerns. The present invention provides nanoparticle processed textiles, formulations and methods for producing them.
    Type: Grant
    Filed: October 22, 2001
    Date of Patent: May 23, 2006
    Assignee: University of California
    Inventors: Gang Sun, Dapeng Li
  • Patent number: 7018424
    Abstract: The present invention relates to sulfur dye protection systems and compositions and methods employing same, as well as processes for making sulfur dyes, especially bleach stable sulfur dyes, processes for dying textiles with sulfur dyes and textiles dyed by such processes. More particularly, the present invention relates to modifying existing dyes and/or making newly formed sulfur dyes. Even more particularly, the present invention relates to materials that can chemically or physically interact with sulfur dyes to protect the sulfur dyes from oxidation by oxidizing agents, such as bleaching agents.
    Type: Grant
    Filed: February 13, 2003
    Date of Patent: March 28, 2006
    Assignee: The Board of Regents of The University of Nebraska
    Inventor: Jiping Wang
  • Patent number: 6846334
    Abstract: The present invention relates to sulfur dye protection systems and compositions and methods employing same, as well as processes for making sulfur dyes, especially bleach stable sulfur dyes, processes for dying textiles with sulfur dyes and textiles dyed by such processes. More particularly, the present invention relates to modifying existing dyes and/or making newly formed sulfur dyes. Even more particularly, the present invention relates to materials that can chemically or physically interact with sulfur dyes to protect the sulfur dyes from oxidation by oxidizing agents, such as bleaching agents.
    Type: Grant
    Filed: February 13, 2003
    Date of Patent: January 25, 2005
    Assignee: The Board of Regents of the University of Nebraska
    Inventor: Jiping Wang
  • Patent number: 6830593
    Abstract: There is provided a method for preventing or reducing the fading of color on fabric by means of a divalent salt. Compositions which provide care to the color of fabrics and comprising a dye fixing agent and the divalent salt are also herein provided.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: December 14, 2004
    Assignee: The Procter & Gamble Company
    Inventor: Christian Leo Marie Vermote
  • Patent number: 6821302
    Abstract: Compositions and methods for achieving permanent hair color change which composition includes a mixture of: a) a composition A which comprises: i) at least one oxidation hair dye precursor; ii) a metal cyanate selected from the group consisting of KOCN, NaOCN, LiOCN, Ca(OCN)2, Mg(OCN)2, Zn(OCN)2 and mixtures thereof which comprises a cyanate ion at about 0.1 to about 2.5%; and iii) an alkalizing agent; b) and a composition B which comprises: i) an oxidizing compound; wherein the mixture of composition A and composition B has a pH of about 7 to about 11; are described.
    Type: Grant
    Filed: November 1, 2002
    Date of Patent: November 23, 2004
    Assignee: Unilever Home & Personal Care USA, Division of Conopco, Inc.
    Inventors: Van Au, Stephen Alan Madison, John Brian Bartolone
  • Patent number: 6790241
    Abstract: Mediator systems obtainable by mixing a salt of an electrochemically active complexing metal (M1) capable of forming a plurality of valence states with a hydroxyl-containing complexing agent, which may likewise be present as salt, and with a salt of an electrochemically inactive complexing metal (M2) in an alkaline aqueous medium, wherefor the molar ratio of metal ion M2 to metal ion M1 is from 0.8:1 to 2:1 are useful for reducing dyes and dyeing cellulosic textile material.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: September 14, 2004
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Thomas Bechtold, Eduard Burtscher, Wolfgang Schrott, Norbert Grund, Peter Maier, Georg Schnitzer, Franz Sütsch
  • Patent number: 6773462
    Abstract: A method of coloring hair comprises: treating hair with an oxidizing agent; and applying to the hair either during or after treatment with the oxidizing agent a composition comprising a compound which is capable of acting as a substrate for endogenous transglutaminase in and/or on the hair and which comprises a chromophore that is capable of absorbing and/or emitting light in the visible part of the electromagnetic spectrum. Products for use in the method comprise the oxidizing agent packaged separately from the compound.
    Type: Grant
    Filed: April 5, 2002
    Date of Patent: August 10, 2004
    Assignee: Unilever Home & Personal Care USA Division of Conopco, Inc.
    Inventor: Pawel Slusarewicz
  • Patent number: 6773464
    Abstract: A hair coloring composition or kit of parts comprises: a compound which is capable of acting as a substrate for endogenous transglutaminase in and/or on hair and which comprises a chromophore that is capable of absorbing and/or emitting light in the visible part of the electromagnetic spectrum; and a reducing agent. The composition may be used to coloring hair.
    Type: Grant
    Filed: April 5, 2002
    Date of Patent: August 10, 2004
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventor: Pawel Slusarewicz
  • Patent number: 6733542
    Abstract: A method for darkening black clothing for darkening faded black clothing and for preventing the fading of black clothing. The method for darkening black clothing includes a quantity of black dye, a quantity of sodium chloride salt, and a quantity of water. The black dye, the salt and the water are mixed together to define a mixture. The mixture in a container for later use in darkening clothing.
    Type: Grant
    Filed: September 21, 2001
    Date of Patent: May 11, 2004
    Inventor: Terri J. Fort
  • Patent number: 6712862
    Abstract: Granular compacts (G) of a mixture of (A) at least one water-soluble dye or optical brightener, and (B) extender and, optionally, (C) at least one hydrophilic surfactant and/or (D) further additives, additionally containing (E) a dust-binding oil, are low-dust dry formulations of high bulk density which feature good dissolution, transportation and storage properties and are outstandingly suitable for the dyeing of the respective substrates.
    Type: Grant
    Filed: May 1, 2000
    Date of Patent: March 30, 2004
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Roland Grimm, Claude Haldimann, Werner Schumann
  • Patent number: 6689175
    Abstract: In a preferred embodiment, the present process involves subjecting a fabric comprised of conjugate yarns to an acidic treatment, which degrades a portion of one component of the conjugate yarns and to dyeing. The acid treatment, given certain reaction kinetics, removes a portion of the polyamide element of the conjugate filament. The at least partial removal of the polyamide component results in a fabric has enhanced dyed appearance, especially when dyed a dark shade. In an alternate embodiment, the fabric may also be treated with a basic solution to improve its moisture transport properties.
    Type: Grant
    Filed: February 12, 2002
    Date of Patent: February 10, 2004
    Assignee: Milliken & Company
    Inventors: Heather J. Hayes, Crystal A. Garner, Kirkland W. Vogt, Kaushal Gandhi
  • Patent number: 6530961
    Abstract: Described are aqueous solutions comprising sodium hydroxide and potassium carbonate in a molar ratio of 1:1.7 to 1:0.5, which are useful for preparing alkaline dyeing liquors, especially padding liquors, of fiber-reactive dyes for producing dyeings on cellulosic textile material.
    Type: Grant
    Filed: July 31, 2000
    Date of Patent: March 11, 2003
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Andreas Schrell, Daniele Negri
  • Patent number: 6503317
    Abstract: Aqueous based pigment dispersions wherein the pigment is dispersed in a dispersant dye in the absence of any other dispersant or additive and aqueous based printing ink compositions containing these a pigment dispersions. Methods for preparing aqueous based pigment dispersions, wherein the pigment is dispersed in a dispersant dye, and method for preparing printing ink compositions incorporating these dispersions.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: January 7, 2003
    Assignee: Sun Chemical Corporation
    Inventors: Darren Mark Ortalano, Christopher Joseph Vissing
  • Patent number: 6432147
    Abstract: A hair coloring composition comprising: (a) from about 0.0003 moles (per 100 g of composition) to less than about 0.09 moles (per 100 g of composition) of an inorganic peroxygen oxidizing agent; and (b) an oxidative hair coloring agent; wherein the pH of each of (a) and (b) is in the range of from about 1 to about 6 and wherein the combined mixture of (a) and (b) has a pH in the range of from about 1 to about 6. The products can provide excellent hair coloring and in-use efficacy benefits including excellent initial color and good wash fastness in combination with reduced hair damage at low pH.
    Type: Grant
    Filed: June 23, 1999
    Date of Patent: August 13, 2002
    Assignee: The Procter & Gamble Company
    Inventors: Louis Carlos Dias, James Charles Dunbar, Dominic Pratt
  • Patent number: 6398821
    Abstract: A hair coloring composition comprising: (a) an inorganic peroxygen oxidizing agent; and (b) an oxidative hair coloring agent; wherein the pH of each of components (a) and (b) is in the range of from about pH 1 to about pH 4.5 and wherein the pH of the composition is in the range of from about pH 1 to about pH 4.5. The products can provide excellent hair coloring and in-use efficacy benefits including excellent initial color and good wash fastness in combination with reduced hair damage at low pH.
    Type: Grant
    Filed: June 23, 1999
    Date of Patent: June 4, 2002
    Assignee: The Procter & Gamble Company
    Inventors: Louis Carlos Dias, James Charles Dunbar, Dominic Pratt
  • Patent number: 6221113
    Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25° C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: April 24, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Jürgen Geiwiz
  • Patent number: 6214059
    Abstract: A liquid alkali composition for use in fiber reactive dyeing of cotton and cotton blended fabrics or the like. The liquid alkali is a solution of sodium hydroxide, potassium hydroxide, and potassium carbonate formed by reaction of CO2 with the potassium hydroxide solution, and adding sodium hydroxide to the resultant mixture. The resulting supersaturated solution has a high enough Total Alkalinity to achieve reaction between the dye, including vinyl sulfone dyes, and fiber but is sufficiently buffered to achieve this reaction slowly so that the fiber reactive dyes fix in a level, uniform fashion. Preferably the composition includes potassium carbonate, potassium citrate, and potassium polyacrylate. The citrate and polyacrylate act as dispersants in the dyeing process and also act as crystallization inhibitors in solution. The use of the carbonate compounds of the present invention in place of conventional silicates or phosphorus prevents the discharge of untreatable toxic wastewater into natural waterways.
    Type: Grant
    Filed: February 14, 1997
    Date of Patent: April 10, 2001
    Assignee: Burlington Chemical Co., Inc.
    Inventor: Samuel B. Moore
  • Patent number: 6179883
    Abstract: Novel 2-imino-2,3-dihydro-1H-indole derivatives of formula (I) or (II) below: in which: R1, R2 and R3 denote hydrogen, alkyl, carboxyl, alkoxycarbonyl, monohydroxyalkyl, polyhydroxyalkyl, alkoxyalkyl, monoalkylaminoalkyl or dialkylaminoalkyl; R′3 and R4 denote alkyl, carboxyl, alkoxycarbonyl, monohydroxyalkyl, polyhydroxyalkyl, alkoxyalkyl, monoalkylaminoalkyl or dialkylaminoalkyl; R5 denotes hydrogen, alkyl, monohydroxyalkyl, polyhydroxyalkyl, alkoxyalkyl, monoalkylaminoalkyl or dialkylaminoalkyl; and the addition salts thereof with an acid, as well as their uses for dyeing keratin fibres.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: January 30, 2001
    Assignee: L'Oreal
    Inventors: Eric Terranova, Aziz Fadli, Alain Lagrange
  • Patent number: 6045591
    Abstract: The invention relates to a process for the two-step direct dyeing of keratin fibres, comprising bleaching the keratin fibres; and applying to the keratin fibres a dye composition comprising at least one partially dissolved basic direct dye and an aqueous medium, wherein the dye composition is ready to use or results from mixing, at the time of use, at least one pulverulent composition (P) comprising at least one basic direct dye and an aqueous composition (A).
    Type: Grant
    Filed: December 7, 1998
    Date of Patent: April 4, 2000
    Assignee: L'Oreal
    Inventor: Christelle Deneulenaere
  • Patent number: 6004358
    Abstract: The disclosure is a process for batchwise dyeing of cellulosic textile material with indigo by the exhaust method, which comprises applying the reduced indigo to the textile material from an aqueous dyeing liquor which includes a reductant, an alkali and additionally a further dissolved alkali metal salt in a concentration of from 200 to 350 g/l as electrolyte and whose pH has been set to 10.2-11.3, oxidizing the reduced indigo on the fiber back to the pigment while maintaining the high electrolyte concentration, and finishing the dyeing in a conventional manner.
    Type: Grant
    Filed: July 9, 1997
    Date of Patent: December 21, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kruger, Gert Rainer Kuhnel, Georg Schnitzer
  • Patent number: 5972042
    Abstract: Methods of dyeing a material, comprising treating the material with a dyeing system which comprises (a) one or more mono-, di- or polycyclic aromatic or heteroaromatic compounds, and (b) (i) a hydrogen peroxide source and an enzyme exhibiting peroxidase activity or (ii) an enzyme exhibiting oxidase activity on the one or more aromatic or heteroaromatic compounds; wherein the material is a fabric, yarn, fiber, garment or film made of cotton, diacetate, flax, linen, lyocel, polyacrylic, synthetic polyamide, polyester, ramie, rayon, tencel, or triacetate.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: October 26, 1999
    Assignees: Novo Nordisk A/S, Novo Nordisk Bio-Chem North America
    Inventors: Martin Barfoed, Ole Kirk
  • Patent number: 5961668
    Abstract: Compounds of the formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another may represent a hydrogen atom, a (C.sub.1-4) alkyl group, a hydroxy (C.sub.2-3) alkyl group, an alkoxy (C.sub.2-3) alkyl group, an amino (C.sub.2-3) alkyl group or a 2,3-dihydroxypropyl group and R.sub.5 and R.sub.6 independently of one another may represent hydrogen or a (C.sub.1-4) alkyl group, are made by reacting 2,4-dinitrohalobenzenes with 4-hydroxymethyl-1,3-dioxolanes under alkaline conditions to form 4-(2,4-dinitrophenoxymethyl)-1,3-dioxolanes, which are further reduced to the compounds of formula (I). In an alternate process, the 4-hydroxymethyl-1,3-dioxolanes are reacted with 4-halo-3-nitranilines or 2-halo-5-nitranilines, the product further reacted first under basic conditions with chloroformic acid ester followed by treatment with strong base, alkylation or alkoxylation, reduction, and optionally further alkylation of alkoxylation to arrive at the compounds (I).
    Type: Grant
    Filed: May 13, 1998
    Date of Patent: October 5, 1999
    Assignee: Hans Schwarzkopf GmbH & Co. KG
    Inventors: Mustafa Akram, Wolfgang Bauer, Andreas Bittner, Astrid Kleen
  • Patent number: 5944856
    Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25.degree. C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: August 31, 1999
    Assignee: Clariant Finanace (BVI) Limited
    Inventor: Jurgen Geiwiz
  • Patent number: 5942009
    Abstract: A method for the same-day permanent waving and coloring of hair ("same-day" meaning during a twenty-four hour period and preferably during a single session of only a few hours), which can provide to the hair improved shape retention, color receptivity, color stability, color retention, color evenness, color depth, shine, strength, softness, luster, and/or elasticity. After initial preparation (shampooing, treating with a pre-wrap, and placing on rods if the hair is to be curled), the hair is processed using a waving agent (e.g., thioglycolate), the excess is preferably removed, contacted with a first composition, the excess preferably removed, optionally but preferably contacted with a second composition, heated to dry the hair, and then contacted with a coloring composition containing an oxidative colorant and an oxidizing agent, the oxidizing agent helping develop the color and rebond the hair. The first and second compositions each contain a biologically acceptable metal (preferably a polyvalent metal, e.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: August 24, 1999
    Assignee: BRG, Ltd.
    Inventor: Michael S. Burns
  • Patent number: 5900029
    Abstract: Processes for coloring a fiber or textile by adding a carbon black product having an organic group attached to the carbon black. In one process at least one diazonium salt reacts with a carbon black in the absence of an externally applied electric current sufficient to reduce the diazonium salt. In another process at least one diazonium salt reacts with a carbon black in a protic reaction medium. Carbon black products which may be prepared according to process of the invention are described as well as uses of such carbon black products in plastic compositions, rubber compositions, paper compositions, and textile compositions.
    Type: Grant
    Filed: July 7, 1998
    Date of Patent: May 4, 1999
    Assignee: Cabot Corporation
    Inventors: James A. Belmont, Robert M. Amici, Collin P. Galloway
  • Patent number: 5897673
    Abstract: Fine metallic particles-containing fibers with various fine metallic particles therein, which have fiber properties to such degree that they can be processed and worked, and which can exhibit various functions of the fine metallic particles, such as antibacterial deodorizing and electroconductive properties are provided, as well as a method for producing the same.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: April 27, 1999
    Assignee: Japan Exlan Company Limited
    Inventors: Ryosuke Nishida, Yoko Yamamoto
  • Patent number: 5885307
    Abstract: Melamine fibers and cellulose fiber combinations are dyed with certain dyes such that the cellulose fiber is dyed by the dyes but the melamine fiber is substantially undyed. When in fabric form, a chambray appearance is given.
    Type: Grant
    Filed: December 17, 1997
    Date of Patent: March 23, 1999
    Assignee: BASF Corporation
    Inventor: Dean R. Gadoury
  • Patent number: 5882936
    Abstract: The present invention provides an optical fluorescence based sensor for measuring the concentration of a gas (e.g., CO.sub.2 or ammonia) in a medium such as blood which has improved drift stability. In a preferred embodiment, the sensors of the present invention comprise microcompartments of an aqueous phase having a pH sensitive sensing component within a hydrophobic barrier phase. The sensors of the present invention are substantially free of partitioning species other than the analyte of interest which can migrate from one phase to the other in response to a change in pH in the aqueous phase and which substantially affect the concentration dependent signal. In an alternative embodiment, the sensors of the present invention are constructed so as to retard the migration of partitioning species, thus reducing the initial rate of drift.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: March 16, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: James G. Bentsen, Kenneth B. Wood
  • Patent number: 5873911
    Abstract: Polymeric, water soluble, quaternary ammonium compounds (F) obtainable by quaternization of(a) at least one amino-group-containing urea compound that contains one or more groups of the formula--NH--CO--NH--G--L-- (.alpha.)in which G signifies a bridging groupand L signifies a tertiary, quaternizable amino groupwith(b) (b.sub.1) an epihalohydrin and optionally(b.sub.2) at least one further quaternizing agentto a quaternized product (q)and reaction of the quaternized product (q) with(c) a dialdehyde of formula (I) ##STR1## in which Z signifies methylene or the direct bond, or a urea derivative thereof, are suitable as fixing adjuvants in particular in continuous processes under nearly neutral to acidic conditions especially for the improvement of wet fastnesses of dyeings on hydrophilic fibrous material.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: February 23, 1999
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bernard Danner, Francis Palacin
  • Patent number: 5858024
    Abstract: The invention relates to a composition, in particular a cosmetic composition, and more particularly one for dyeing keratin fibers, this composition containing at least one substance P antagonist in order to reduce or even eliminate the irritant effects of the dyes and/or pigments and/or dye precursors used during this dyeing. The substance P antagonist may form part of the dye composition itself or may be contained in a composition which is applied prior to the application of the dye composition.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: January 12, 1999
    Assignee: Societe L'Oreal S.A.
    Inventors: Olivier De Lacharriere, Lionel Breton, Genevieve Loussouarn
  • Patent number: 5846266
    Abstract: By using printing pastes containing thiourea dioxide together with finely dispersed calcium, magnesium or zinc hydroxide, present in the paste as such or generated from components in the printing paste during a treatment process, fabric discharge printing processes may be developed which have the advantage of decorating fabric webs, garments or garment panels effectively, even in dry heat conditions, whilst avoiding contamination of such fabrics with undesirable residues, particularly formaldehyde.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: December 8, 1998
    Inventor: Ian Durham Rattee
  • Patent number: 5772696
    Abstract: An invention is disclosed which pertains to a method for purifying water soluble dyes, such as quinoline, fluoran, and xanthene dyes. The method comprises the steps of A) adding a metal salt to the water soluble dye to form a water insoluble dye salt of the metal; B) isolating the water insoluble dye salt of step A; C) converting the water insoluble dye salt of step B into a water soluble dye solution; and D) isolating the water soluble dye from the solution of step C. The present invention teaches a straight forward, economical, and environmentally sound method for purifying water soluble dyes of FDA certifiable purity and with an aesthetically improved shade.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: June 30, 1998
    Assignee: Warner-Jenkinson Company, Inc.
    Inventor: Puthalath Koroth Sujeeth
  • Patent number: 5772697
    Abstract: Liquid caustic compositions for use in reactive dyeing, having total and alkaline activities approximating the total and alkaline activities of a predetermined liquid caustic composition are prepared by providing a source of water; providing a container of concentrated sodium hydroxide solution; providing a container of liquid buffered alkali solution; providing a mixer communicating with the containers; providing at least one liquid caustic solution storage tank in communication with the mixer; providing flow meters communicating with the mixer to monitor the quantities of sodium hydroxide and buffered alkali flowing to the mixer; determining the total and active alkalinities of the target liquid caustic composition; determining the quantities of sodium hydroxide and buffered alkali solutions required to provide a liquid caustic solution having total and active alkalinities approximating the total and active alkalinities of the target solution; diluting the concentrated sodium hydroxide with the water to for
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: June 30, 1998
    Assignee: Burlington Chemical Co., Inc.
    Inventors: Samuel B. Moore, Edwin T. Turner, James F. Leuck
  • Patent number: 5746778
    Abstract: A wood stain which is water-based, which is suitable for staining wood, and which is comprised of water; at least one dye selected from the group consisting of azo, diazo and triarylmethane dyes; and a stabilizing agent which is effective to reduce free iron ion concentration in the stain when in contact with an autoclave composed of non-rust resistant steel during the staining process. The stabilizing agent includes at least one buffer effective to maintain the pH of the wood stain at greater than 7.0. Alternatively or additionally, the stabilizing agent includes at least one complexing agent which forms a complex with iron ions.
    Type: Grant
    Filed: May 23, 1996
    Date of Patent: May 5, 1998
    Assignee: A.W. Faber-Castell Unternehmensverwaltung GmbH & Co.
    Inventors: Axel Jankewitz, Gerhard Lugert
  • Patent number: 5725604
    Abstract: The present invention relates to a process for dyeing or printing organic material, which comprises applying at last one dye selected from those containing a chromophore radical from the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, nitroaryl, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, naphthoquinone, pyrenequinone or perylenetetracarbamide series which contains an acrylamide, methacrylamide, bromoacrylamide or chloroacrylamide reactive group, at least one colourless cationic compound containing at least one polymerizable double bond, and at least one polymerization initiator and then subjecting it to thermofixation. Further auxiliaries to the organic material may optionally may optionally be included.
    Type: Grant
    Filed: March 14, 1996
    Date of Patent: March 10, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Katharina Fritzsche, Alex Kanzig