Abstract: A single-bed PSA system comprising a blower, an adsorber vessel, and a gas product storage tank separates a gas mixture using a three-step cycle comprising adsorption, evacuation, and pressurization. Pressurization is accomplished by introducing gas from the gas product storage tank into both the feed end and the product end of the adsorber vessel. Preferably a portion of the pressurization gas is introduced into the adsorber vessel by the blower, which also is used for providing feed to the adsorber and for withdrawing gas from the adsorber during the evacuation step.

Abstract: A pressure swing adsorption apparatus to vary selectively the concentration of at least one constituent of a gaseous mixture by sending a gaseous mixture into an adsorber to generate a particular product gas while delivering to another adsorber both a predetermined portion of the product gas to purge the other adsorber of its adsorbed gas and a selected amount of the product gas, independent of the flow rate and in addition to the predetermined portion, to produce a desired relative concentration of the constituents of the product gas from a range of relative concentrations.

Abstract: This invention relates to a VPSA method for the production of a product that is enriched with a more preferred gas from a mixture of the more preferred gas and a less preferred gas and, preferably to a VPSA method for the production of an oxygen-enriched product from air, using an oxygen-preferential adsorbent under equilibrium conditions. In a preferred embodiment the process uses a desorption purge at a nearly constant pressure that is selected to produce a steady stream of oxygen having a purity from 30% to 60% at a pressure in the range of 60 kPa to 20 kPa.

Abstract: Four adsorbers 1 to 4, each operating in a cycle comprising (described for adsorber 2): an adsorption step 1 wherein a feed from adsorber 2 is circulated to adsorber 2; an adsorption step 2 wherein feed is injected to the bottom of adsorber 2 and a product rich in isoparaffins is recovered from the head of adsorber 2; an adsorption step 3 wherein a portion of the fluid leaving adsorber 2 is sent to adsorber 3; an adsorption step 4 wherein the head of adsorber 2 receiving the feed is connected to the bottom of adsorber 3; a first depressurisation step 5 wherein adsorber 2 at high pressure is connected to adsorber 4 at a lower pressure; a second depressurisation step 6 wherein the head of adsorber 2 is closed; a stripping step 7 wherein the bottom of adsorber 2, which receives desorbent overhead, is connected to the top of adsorber 2; two principal stripping steps 8 and 9 wherein adsorber 2 alone is supplied with desorbent; a stripping finishing step 10 wherein adsorber 2 is continued to be supplied with desorb

Abstract: The process comprises a regeneration phase including a co-current depressurization step, in order to participate in the repressurization of another adsorber, a countercurrent depressurization down to the low pressure of the cycle without gas intake, and then a countercurrent elution step at the low pressure of the cycle with oxygen taken off from production. The cycle time does not exceed 20 seconds. The process is particularly application to the production of oxygen having a purity greater than 90% with flow rates of 2 to 6 liters/minute for oxygenotherapy.

Abstract: Segregated external gas storage tanks are used to store gases of varying purity for use in the purge and pressure equalization and product repressurization steps of pressure swing adsorption operations, thereby enabling the bed size factor and the power requirements of pressure swing adsorption-gas separation operations to be significantly reduced.

Abstract: In a "vacuum" type cycle, the depressurization of a first adsorber at the high pressure of the cycle is effected by placing it in communication with the outlet of a second adsorber at the low pressure of the cycle. This communication takes place simultaneously with countercurrent pumping in a first stage for the second adsorber and in a second stage for the first adsorber, the recompression to the high pressure of the cycle being effected by production gas. Used for the production of oxygen from air.

Abstract: A method for recovering argon and hydrogen simultaneously from a feed mixture comprising argon, hydrogen, methane, nitrogen, ammonia, and moisture by passing a two stage adsorption separation (PSA). The feed gas including 4-6% hydrogen is sent to the first stage PSA to obtain a product hydrogen during the first period of adsorption step, and to obtain an intermediate product of argon and hydrogen mixture during the next period of adsorption step. The adsorbed gases are evacuated and sent to fuel gas. The intermediate product argon and hydrogen mixture is sent to the second stage adsorption bed. The effluent of adsorption step is recovered as another product hydrogen. After the adsorption step, the second stage adsorber is undergone concurrent blowdown, pressure equalization, argon recovery, argon purge, desorption production of argon, pressure equalization, pressurization with product hydrogen. Through such cyclic operation of two-stage PSA, high purity argon and hydrogen are recovered simultaneously.

Abstract: The present invention is an apparatus and process for separating oxygen from air by adsorption of at least nitrogen on multiple layers of air separation adsorbent in an adsorption bed wherein the multiple layers are Na X-zeolite followed by at least another layer of adsorbent selected from the group consisting of Ca X-zeolite, Li X-zeolite, Ca A-zeolite followed by Ca X-zeolite, Ca A-zeolite followed by Li X-zeolite, Ca X-zeolite followed by Li X-zeolite, Li X-zeolite followed by Ca X-zeolite and Mg A-zeolite followed by Ca X-zeolite.

Abstract: Oxygen of uniform purity is produced in a two-bed air-fed oxygen pressure swing adsorption process in which the beds are operated out of phase. The steps of the adsorption cycle include a pressurization/production step and a bed regeneration step, with the bed undergoing regeneration being purged with a low pressure stream of the oxygen-enriched gas produced as the nonadsorbed product of the process. The oxygen concentration in the purged gas effluent is continuously periodically monitored, and the maximum oxygen concentration in the effluent during selected purge steps is compared with the maximum oxygen concentration in the effluent during a previous purge step, and the difference is used to adjust the timing and duration of a purge step following the selected purge step in a manner that reduces the difference between the oxygen concentration in the sequential purge steps.

Abstract: A pressure swing adsorption process employs a simultaneous equalization and evacuation step followed by simultaneous feed and product gas repressurization steps, resulting in faster processing, and a reduction in power requirements, in the recovery of oxygen and argon from feed air.

Abstract: A method of separating nitrogen-enriched gas is performed by PSA with the use of an apparatus which comprises a plurality of adsorbers (1, 2), a balance tank (3), and a product receiver (4). The method is characterized by comprising the steps of (a) passing, at a predetermined flow rate, high-purity nitrogen gas from the balance tank (3) to an outlet of an adsorber (2) undergoing regeneration; (b) establishing communication between the outlets of both adsorbers (1, 2) through a pressure equalization line while opening the inlets of both adsorbers to atmospheric pressure; (c) after the above step (b), causing a predetermined amount of high-purity nitrogen gas in the balance tank (3) to reversely pass via the outlet of the adsorber (2) which is to be switched from regeneration to adsorption while also supplying the crude gas through its inlet.

Abstract: A process for removing argon from a feed gas stream comprising oxygen and argon to yield a high purity oxygen stream and the system for carrying out the process. The process includes the steps of: (a) providing a feed gas of oxygen and argon at a temperature between -30.degree. C. and 100.degree. C. and a pressure between 5 psia and 160 psia; and (b) passing the feed gas over an adsorbent bed comprising a Ag ion exchanged type X zeolite wherein at least 80% of the available ion sites are occupied by Ag such that at least a portion of the argon in the feed gas is adsorbed by the adsorbent bed thereby leaving an oxygen-enriched gas stream.

Abstract: The present invention is a nitrogen pressure swing adsorption process for separating gas mixtures containing nitrogen and oxygen, such as air, using a unique gas transfer process step, continuous feed gas introduction and an appropriate isolation step with continued product purge/repressurization to achieve high purity nitrogen product of 99.9% or greater by volume nitrogen, preferably 99.99% or greater by volume of nitrogen.

Abstract: The process is conducted in a circuit having first and second adsorbers and a product reservoir vessel, connected serially. The feedstock is a gas mixture containing contaminant and product components (for example, air containing N.sub.2 and O.sub.2). The process steps involved are: (1) feeding a charge of feed gas into the first adsorber, temporarily retaining it therein, and pressurizing it, so that the adsorbent adsorbs most of the contaminant component and purified product gas is produced; (2) co-currently depressurizing the first adsorber by discharging purified product gas through the second adsorber and reservoir vessel; (3) counter-currently venting both adsorbers; (4) partly re-pressurizing both the adsorbers with purified gas from the reservoir vessel; and then repeating steps (1)-(4) inclusive.

Abstract: Carbon-clad zirconium oxide particles are disclosed which are useful in sorbent applications, particularly as packing materials for High Performance Liquid Chromatography (HPLC). A method for the preparation of chromatographic support material is also disclosed which utilizes low pressure.

Abstract: Separation process of gaseous impurities from hydrogen gas by the known pressure swing adsorption method uses a holding column of the feed-in/feed-out sequence retaining type and at least three adsorption columns containing adsorbents. Each adsorption column is pressurized and depressurized in cycle to repeat adsorption and desorption, during which the holding column is used as an intermediate gas reservoir so that the efficiency of the separation of the impurity can be improved. In this invention, at least one of the following structures is used as the holding column:j) at least one row of spaces divided by partition walls and arranged in series;k) at least one hollow body; andl) at least one row of divided compartments arranged in series.

Abstract: Pressure swing adsorption separation of a gas mixture is performed in an apparatus with a plurality of adsorbent beds cooperating to exchange energy from an adsorbent bed undergoing a depressurization step to an adsorbent bed undergoing a pressurization step, and with provision for thermal coupling in order to improve process efficiency. Thermal coupling is provided as heating to augment expansion energy recovery, and as a temperature gradient imposed in adsorbent beds to provide the function of a thermal regenerator in a regenerative thermodynamic cycle. The invention provides improved techniques for recovery of expansion energy in pressure swing adsorption, and for direct application of thermal energy to power pressure swing adsorption processes.

Abstract: Process for the purification of a gas containing selectively adsorbable impurities, of the type using several adsorbers with, for each adsorber, a cycle comprising the following operating phases which are offset from one adsorber to the next timewise by a fraction 1/n of the duration of the cycle in which n is the number of adsorbers, the cycle comprising substantially isobaric production at a high pressure of the cycle, this production comprising the admission of impure gas to be treated into an adsorber at a first end of the adsorber with circulation of this gas in the adsorber and simultaneous withdrawal from a second end of the adsorber of purified gas, the direction of flow in the adsorber from the first end to the second end being cocurrent and the opposite direction being countercurrent; regeneration of the adsorber comprising a decompression of the adsorber to a low pressure of the cycle, this decompression comprising at least one stage in which a residual gas is withdrawn countercurrent from the adso

Abstract: A process is provided for the concentration and recovery of ethylene and heavier components from a hydrocarbon feedstream. A pressure swing adsorption (PSA) process is used to remove from hydrocarbon feedstream light cut comprising hydrogen, carbon monoxide, and methane and subsequently concentrate a heavy cut comprising the ethylene and heavy components in the PSA tail gas. In one aspect of the invention, an FCC off gas is separated into a light cut and a heavy cut and the heavy cut is routed to an ethylene plant. In another aspect of the invention, a C.sub.2 -rich stream is withdrawn from an ethylene plant and used to enhance the recovery of the ethylene and heavier stream in the PSA process and an ethylene-rich stream is returned to the ethylene plant.