Abstract: A process is provided for recovering oxygen-rich gas by enriching gaseous oxygen contained in crude gas by a single-tank PSA process which utilizes a single adsorption tower loaded with an adsorbent. A cycle is repeated including introducing crude gas into the adsorption tower, desorbing unnecessary components from the adsorbent, introducing washing gas into the adsorption tower for discharging the remaining gas from the adsorption tower, and raising the internal pressure of the adsorption tower. The desorbing includes recovering semi-enriched oxygen gas existing in the adsorption tower after finishing of the adsorption for retention in a recovery tank. The introduction of washing gas includes introducing part of the semi-enriched oxygen gas existing in the recovery tank into the adsorption tower as the washing gas. Raising the internal pressure includes introducing the rest of the semi-enriched oxygen gas retained in the recovery tank into the adsorption tower.

Abstract: The invention relates to ammonia synthesis loops containing gases, which do not react and would accumulate if they were not purged out. By the present invention ammonia in a purge gas is recovered by an absorption agent operating at the full synthesis loop pressure. The absorption agent is chosen in such a way that the ammonia can be removed again by passing a gas comprising hydrogen and nitrogen through it at the same elevated pressure as the loop pressure. This enables the adsorption agent to be regenerated by fresh synthesis gas coming from the synthesis gas compressor just before this gas enters the synthesis loop. Thereby, the regeneration requires an absolute minimum of energy consumption and equipment.

Abstract: A gas transfer segment of a vacuum swing adsorption process cycle utilizing multiple parallel adsorbent beds which undergo cyclic process steps to separate the components of a feed gas mixture, each bed having a feed end and a product end, wherein the gas transfer segment comprises a step of withdrawing a waste gas stream from the feed end of a first bed, withdrawing a transfer gas from the product end of the first bed and introducing the transfer gas into the product end of a second bed, and withdrawing a waste gas stream from the feed end of the second bed.

Abstract: A pressure swing adsorption process for the separation of impurities such as nitrogen and carbon dioxide and recovery of hydrocarbons from a natural gas stream utilizes two separate adsorption systems, the first containing an adsorbent selective for nitrogen, carbon dioxide or both and the second containing a hydrocarbon-selective adsorbent. In the process, the natural gas stream is passed through a first adsorbent to form a product stream enriched with methane and to adsorb nitrogen and/or carbon dioxide and which further co-adsorbs at least a portion of the hydrocarbons contained in the feed stream. The hydrocarbons are recovered by passing a low pressure waste stream from the first pressure swing adsorption stage which contains co-adsorbed nitrogen and/or carbon dioxide and hydrocarbons and directing the waste stream to the second pressure swing adsorption stage to adsorb the hydrocarbons and produce a product stream enriched in nitrogen and/or carbon dioxide.

Abstract: A pressure swing adsorption process which comprises introducing a feed gas mixture into an inlet of an adsorber vessel during a feed period, wherein the feed gas mixture contains a more strongly adsorbable component and a less strongly adsorbable component and the adsorber vessel contains a bed of adsorbent material which selectively adsorbs the more strongly adsorbable component, and withdrawing a product gas enriched in the less strongly adsorbable component from an outlet of the adsorber vessel during at least a portion of the feed period, wherein a dimensionless cycle-compensated mass transfer coefficient defined as K tfeedVads/Vfeed is maintained in the range of about 23 to about 250.

Abstract: A method for operating a pressure swing adsorption process at turndown conditions by adding selected steps to the normal design operation of the process. The selected steps include the extension of a make product/no feed step and the addition of idle steps at specific points in the process cycle during depressurization and repressurization. The average volumetric flow ratio of the pressurized feed gas to the final product gas during design operation and during turndown operation may be essentially equal. The average oxygen concentration in the final product gas during design operation and during turndown operation also may be essentially equal.

Abstract: A pressure swing adsorption process wherein a constant flow of feed gas and product gas is maintained to and from a pressure swing adsorption installation. A part of repressurization is carried out by a product gas split-off, in three stages, with an additional pressure equilibration step between two adsorbers during the second of the three stages, thereby cyclically fluctuating one of the number of adsorbers receiving feed gas during some period. In addition, either combined herewith or not, in case of the use of a higher purge gas pressure, is the return to a regenerated adsorber of a least impure part of the offgas, driven by its initially higher pressure. The result is an increased product recovery efficiency and an improved flexibility of functioning of the installation.

Abstract: A method for the separation of a gas mixture comprises (a) obtaining a feed gas mixture comprising nitrogen and at least one hydrocarbon having two to six carbon atoms; (b) introducing the feed gas mixture at a temperature of about 60° F. to about 105° F. into an adsorbent bed containing adsorbent material which selectively adsorbs the hydrocarbon, and withdrawing from the adsorbent bed an effluent gas enriched in nitrogen; (c) discontinuing the flow of the feed gas mixture into the adsorbent bed and depressurizing the adsorbent bed by withdrawing depressurization gas therefrom; (d) purging the adsorbent bed by introducing a purge gas into the bed and withdrawing therefrom an effluent gas comprising the hydrocarbon, wherein the purge gas contains nitrogen at a concentration higher than that of the nitrogen in the feed gas mixture; (e) pressurizing the adsorbent bed by introducing pressurization gas into the bed; and (f) repeating (b) through (e) in a cyclic manner.

Abstract: A gas mixture comprised of nitric oxide and one or more impurities selected from nitrous oxide, nitrogen dioxide, nitrous acid, sulfur dioxide, carbonyl sulfide, water vapor and carbon dioxide is purified by pressure swing adsorption or temperature swing adsorption using a porous, metal-free polymer adsorbent that does not promote the disproportionation of nitric oxide to nitrogen dioxide and nitrogen or nitrous oxide. The adsorption step is preferably carried out at tempereatures in the range of about −120 to about 0° C.

Abstract: A method to reduce the cycle time in a pressure swing adsorption process by reducing the required pressure equalization time in a cycle, thereby reducing the overall cycle time and increasing product recovery per unit of adsorbent used. This reduces the amount of adsorbent required in the beds for a given feed rate while continuing to provide product at an acceptable product purity, and has the desirable effect of reducing the capital cost of the process equipment required for a given volumetric production rate.

Abstract: A pressure swing process and system for purifying a first gas, preferably argon, from a crude feed gas stream containing the first gas and second gas(es) utilizes two adsorption beds and continuously promotes the crude feed gas to the bed during the process and simultaneous equalization of pressure in the two beds in top-to-top end and bottom-to-bottom end equalizations in each bed following purging of each bed.

Abstract: A pressure swing adsorption process for recovery of a more readily adsorbable component, such as nitrogen, and a larger amount of a less readily adsorbable component, such as oxygen, from a feed gas mixture, such as air, wherein the ratio of nitrogen to oxygen is less than about 3:1 and the ratio of the co-purge:feed gas of the process is maintained at less than about 1.15:1.

Abstract: A two bed vacuum swing adsorption process for the production of oxygen is disclosed. Efficient use of air blowers and vacuum pumps maximizes the machine utilization and product gas purges in low flow and high flow modes to increase productivity while lessening power consumption.

Abstract: Gas separation by pressure swing adsorption (PSA) and vacuum pressure swing adsorption (VPSA), to obtain a purified product gas of the less strongly adsorbed fraction of the feed gas mixture, is performed with an apparatus having a plurality of adsorbers. The adsorbers cooperate with first and second valves in a rotary PSA module, with the PSA cycle characterized by multiple intermediate pressure levels between the higher and lower pressures of the PSA cycle. Gas flows enter or exit the PSA module at the immediate pressure levels as well as the higher and lower pressure levels, under substantially steady conditions of flow and pressure. The PSA module comprises a rotor containing laminated sheet adsorbers and rotating within a stator, with ported valve faces between the rotor and stator to control the timing of the flows entering or exiting the adsorbers in the rotor.

Abstract: A seal for an opening defined by a sidewall portion of the pressurizable tank. The tank contains desiccant for drying gases which pass through the desiccant. An elongate antenna extends from an interior portion to an exterior portion of the tank and is used for carrying microwave energy to the desiccant for regeneration of the desiccant. The seal has an insulator with an interior surface for receiving engagement with the antenna at the opening of the tank. In one embodiment, the interior surface of the insulator is tapered such that a distance between opposing portions of the insulator reduces as the insulator extends in a direction through the opening toward the exterior of the tank. The antenna has a cross sectional dimension which reduces in size as the antenna extends in the direction through the opening toward the exterior of the tank.

Abstract: An improved pressure swing adsorption process and system for producing a high recovery of a highly purified product gas, such as argon, from a feed gas stream containing the product gas and impurity gases employs first and second adsorption stages with beds for adsorbing impurity gases. The system and process provides for sequential steps of: feed pressurization; simultaneous feed pressurization and product pressurization; adsorption; adsorption and purge; adsorption in the absence of purge; pressure equalization between beds; evacuation and depressurization of adsorbent bed; evacuation with product purge; evacuation without purge; and pressure equalization between beds.

Abstract: The present invention is a two stage PSA process for producing high purity oxygen from a feed air stream. Water, carbon dioxide and nitrogen are removed in a first stage. An oxygen selective adsorbent is used to adsorb oxygen in the second stage. High purity oxygen product is recovered during regeneration of the second stage. Importantly, the high purity of the oxygen product is achieved without inclusion of an oxygen rinse step in the process cycle. The high purity oxygen product is obtained by collecting the middle cut of the second stage effluent stream during regeneration.

Abstract: The present invention involves a vacuum-pressure swing adsorption process for the separation of components of a fluid mixture. The process includes (a) transferring a fluid mixture through an adsorbent bed at an elevated pressure Ph so as to produce a purified product fluid; (b) venting the adsorbent bed down to an ambient fluid pressure Pa; (c) applying a vacuum force to the adsorbent bed to bring the adsorbent bed to a reduced pressure Pl; and (d) venting the adsorbent bed up to an ambient fluid pressure Pa.

Abstract: A pressure swing adsorption process includes providing a pressure swing adsorption apparatus having six beds, and equalizing a pressure of each of the six beds in four steps, wherein at all times during the process, at least one of the six beds is providing offgas. The process is particularly suitable for purifying hydrogen from a feed gas mixture containing hydrogen and at least one of methane, carbon dioxide, carbon monoxide, nitrogen and water vapor.

Abstract: A pressure swing adsorption process for the separation of nitrogen from natural gas utilizes two separate pressure swing adsorption stages, the first containing a hydrocarbon-selective adsorbent and the second containing a nitrogen-selective adsorbent. In the process, the product stream from the first pressure swing adsorption unit contains a natural gas stream having a reduced hydrocarbon content and the product stream from the second pressure swing adsorption unit is a natural gas stream having a reduced nitrogen concentration. The product from the second pressure swing adsorption unit is used to desorb the hydrocarbons from the first pressure swing adsorption unit so as to add the hydrocarbons, which have heat value to the product natural gas stream. Periodically, heating the nitrogen-selective adsorbent with heated product stream from the second pressure swing adsorption unit has been found to improve the capacity of the nitrogen-selective adsorbent to adsorb nitrogen.

Abstract: A pressure swing adsorption process for the separation of a pressurized feed gas containing at least one more strongly adsorbable component and at least one less strongly adsorbable component.

Abstract: A single bed pressure swing adsorption process with at least one transfer tank is utilized to separate less adsorbable components from more adsorbable components such as the separation of oxygen from air. Depressurization gas is collected in the transfer tank and is used later exclusively for purging the bed during the regeneration period.

Abstract: A gas supply system including a gas cabinet defining an enclosure including therein a gas dispensing manifold and one or more adsorbent-based gas storage and dispensing vessels mounted in the enclosure and joined in gas flow communication with the gas dispensing manifold. The enclosure may be maintained under low or negative pressure conditions for enhanced safety in the event of leakage of gas from the gas storage and dispensing vessel(s) in the enclosure. The gas supply system may be coupled to a gas-consuming unit in a semiconductor manufacturing facility, e.g., an ion implanter, an etch chamber, or a chemical vapor deposition reactor.

Abstract: A process is provided for the concentration and recovery of propylene from propane by a pressure swing adsorption (PSA) process using an adsorbent comprising AlPO-14. A PSA process is used to remove propylene from a C3 hydrocarbon stream comprising propylene and propane. The PSA process of the present invention can be employed in petroleum refining and petrochemical processes to purify and separate propylene from mixtures of propylene and propane without fractionation.

Abstract: A process and a system for purifying gas, such as air, before cryogenic distillation, in which at least one energy parameter, chosen from the flow rate of the regeneration gas entering and/or leaving at least one adsorber, the duration of the regeneration step and the regeneration temperature of the regeneration gas entering at least one adsorber, is controlled, modified and/or regulated depending on at least one operating condition chosen from the pressure of the gas to be purified entering and/or leaving at least one adsorber, the flow rate of the gas to be purified entering and/or leaving at least one adsorber, the temperature (Ta) of the gas to be purified entering at least one adsorber and the content of impurities contained in the gas to be purified entering at least one adsorber and depending on the thermal profile of the heat front output by at least one adsorber at the end of regeneration.

Abstract: A gas separation system for separating a feed gas mixture into a first gas component and a second gas component comprises a stator, and a rotor rotatably coupled to the stator. The stator includes a first stator valve face, a second stator valve surface, and a plurality of function compartments opening into the stator valve surfaces. The rotor includes a first rotor valve surface in communication with the first stator valve surface, and a second rotor valve surface in communication with the second stator valve surface. The rotor also includes a plurality of rotor flow paths for receiving gas adsorbent material therein for preferentially adsorbing the first gas component in response to increasing pressure in the rotor flow paths in comparison to the second gas component. Each rotor flow path includes a pair of opposite ends opening into the rotor valve faces for communication with the function compartments.

Abstract: A molecular sieve type gas separation apparatus (10) for separating product gas from a gas supply (14) includes at least one sieve bed (11-13) which during an adsorption charge phase of a cycle, adsorbs non product gas in the gas supply (14), and in a desorption regeneration phase of the cycle desorbs the previously adsorbed non product gas. The apparatus further includes an outlet (18) to which product gas is delivered during the adsorption charge phase, and an outlet (31) for non product gas during the desorption regeneration phase. A sensor (36) responsive to the concentration of a constituent in the product gas, and a control (20) to switch the apparatus (10) between the adsorption charge and desorption regeneration phases are further provided. The control (20) is adapted to adjust the duration of adsorption charge phase relative to the duration of the desorption regeneration phase in each cycle.

Abstract: A method of removing individual gas components of a mixture of gases within a controlled environment container uses apparatus which comprises first and second chambers which are arranged in parallel for the gas mixture to flow through them from their inlet ends to their outlet ends. The chambers contain adsorbent material with different affinities for the gas components of the mixture. The method comprises supplying the gas mixture to the first chamber so as to pressurize it while allowing a purge stream to flow from the outlet end of the first chamber to the second chamber to purge adsorbed gas from the adsorbent material in the second chamber. A purge pulse of gas is then supplied from the outlet end of the first chamber to the second chamber to purge adsorbed gas from the adsorbent material in the second chamber, the rate of flow of the purge stream being less than that of the purge pulse.

Abstract: A pressure swing adsorption cycle in which a regeneration phase is terminated by at least one final step in which a residual gas is withdrawn counter-current to the adsorber (1 to 3). A variable portion of the residual gas is recycled, representing from 0 to 30% of the flow of the purified gas product, into the impure gas to be treated, the rest of this residual gas constituting a purge. The duration of the cycle is reduced when this recycling is carried out, the more so as the recycle flow rate is the greater. The cycle has particular application in the production of hydrogen, helium or neon.

Abstract: A vacuum swing adsorption process is provided for the separation of propylene from a feedstream comprising propylene and propane using an adsorbent comprising AlPO-14 to produce a high purity propylene product stream at high recovery. The vacuum swing adsorption process of the present invention can be employed in a variety of petroleum refining and petrochemical processes to purify and separate propylene from mixtures of propylene and propane alone or in combination with fractionation.

Abstract: A method and plant to process a fluid comprising one or more compounds G2 having a kinetic diameter less than or equal to that of nitrogen and one or more compounds G1 having a kinetic diameter greater than or equal to that of methane. The method and plant use in combination, several adsorption and desorption stages during which a first stream F1 mainly comprising compounds G1, a second stream F2 enriched in compounds G2, a third stream F3 mainly comprising compounds G2 and a fourth stream F4 mainly comprising compounds G1 are produced. At least a fraction of stream F3 is used to flush adsorption section A1.

Abstract: A repressurization phase of an adsorber comprises a step of first countercurrent repressurization with at least gas from a first co-current decompression of another adsorber, this phase ending in a step of co-current production. Immediately following the first countercurrent repressurization step, air is introduced co-current into the adsorber.

Abstract: A low pressure swing adsorption process and apparatus for the recovery of carbon dioxide from multi-component gas mixtures, utilizing the simultaneous purge and evacuation of opposite ends of the adsorber(s) to effect controlled depressurization in the adsorber bed(s) to maintain the constant purity of a carbon dioxide-enriched product stream recovered from the adsorber inlet(s).

Abstract: Upon a reduction of the production flow rate, there is added to the cycle, at an extreme pressure PM and/or Pm of the cycle substantially different from atmospheric pressure, an idle time in the course of which the adsorber (1A, 1B) is isolated. The process is used in trans-atmospheric cycles for the production of oxygen from atmospheric air.

Abstract: A method and apparatus for operating a pressure swing adsorption process is disclosed that may utilize only a single adsorption stage yet still produce a continuous stream of a concentrated fluid. A portion of the enriched fluid produced during the adsorption cycle in an adsorption chamber is used to purge the adsorption chamber.

Abstract: According to the present invention, a process is provided which overcomes historical limitations to the capacity of PSA units for a wide variety of gas separations. Capacities in excess of about 110 thousand normal cubic meters per hour (100 million standard cubic feet per day) can now be achieved in a single integrated process train. The corresponding significant equipment reduction results from a departure from the accepted principle in the PSA arts that the length of the purge step must be equal to or less than the length of the adsorption step.

Abstract: Ethene is separated from a gas mixture containing ethane by a pressure swing adsorption process carried out at a temperature in the range of about 50 to about 200° C., wherein the adsorption step of the process is conducted by passing the gas mixture through an adsorption zone containing type A zeolite whose exchangeable cations are preferably made up of at least about 60 but not more than 75% sodium ions and more than 25 and up to about 40 percent potassium ions.

Abstract: The flow of gas between two vessels, each of which undergoes cyclic changes in gas pressure, is controlled by two check valves installed in parallel between the vessels. The first check valve allows gas to flow from the first vessel to the second vessel when the differential pressure between the vessels exceeds a first value, and the second check valve allows gas to flow from the second vessel to the first vessel when the differential pressure between the vessels exceeds a second value. The gas flow control method is particularly useful in pressure swing adsorption processes.

Abstract: Pressure swing adsorption separation of a feed gas mixture, to obtain a purified product gas of the less strongly adsorbed fraction of the feed gas mixture, is performed in a plurality of preferably an even number of adsorbent beds, with each adsorbent bed communicating at its product end directly to a variable volume expansion chamber, and at its feed end by directional valves to a feed compressor and an exhaust vacuum pump. For high frequency operation of the pressure swing adsorption cycle, a high surface area layered support is used for the adsorbent. The compressor and vacuum pump pistons may be integrated with the cycle, reciprocating at twice the cycle frequency. Alternative configurations of the layered adsorbent beds are disclosed.

Abstract: A method and apparatus for operating a pressure swing adsorption process having an adsorption zone is disclosed that may utilize only a single adsorption stage. The purge cycle is automatically commenced by a pressure build up in the enriched fluid vented from an adsorption zone.

Abstract: A PSA process and system utilizes a combination of cyclic feed, evacuation, purge, and repressurization steps to provide a final gas product enriched in one of the feed components. The process is carried out in a simple system which utilizes a single two-way four-port valve for controlling gas flow between an adsorber vessel and a blower, and the blower is used for the introduction of feed gas into the adsorber and the evacuation of gas from the adsorber. The control of gas flow in either direction between the adsorber vessel and a product gas storage tank is accomplished by two check valves installed in parallel between the vessel and the tank.

Abstract: A method and apparatus for operating a pressure swing adsorption process is disclosed that may utilize only a single adsorption stage yet still produce a continuous stream of a concentrated fluid.

Abstract: In a gas refining method using a PSA method, a cleaning step is divided into a preparatory cleaning step and a substantial cleaning step, and an exhaust gas (particularly a high concentration gas obtained in the latter half is effective) obtained in the substantial cleaning step is used as a gas to be admitted into an adsorption column in the preparatory cleaning step. This method is employed, for example, to refine carbon monoxide from a material gas containing carbon monoxide. Accordingly, the gas refining method using the PSA method can ensure a specified amount of collected gas product without resulting in an increase in the amount of adsorbent even if a low concentration material gas is used.

Abstract: A process for controlling the atmosphere in a container including the steps of passing a pressurized portion of the atmosphere serially through a plurality of separate but inter-communicating adsorbent beds which selectively adsorb water vapor, ethylene, carbon dioxide and nitrogen from the compressed atmosphere, then isolating the ethylene-selective adsorbent and desorbing ethylene therefrom, then desorbing nitrogen from the nitrogen-selective adsorbent and purging the carbon dioxide-selective bed, the ethylene-selective bed and the water vapor-selective bed with the desorbed nitrogen, and returning the purge and purged gas mixture to the container.

Abstract: The strongly adsorbed component of a gas mixture is produced in enhanced purity and yield by novel PSA cycles. The basic steps of the cycles include an adsorption vessel prepressurization step, a cocurrent nonadsorbed gas production step, a cocurrent purge step with strongly adsorbed gas product and a countercurrent depressurization step which produces the strongly adsorbed gas product that is used in the cocurrent purge step. In addition to the basic steps, a first depressurization equalization step precedes or follows the cocurrent purge step and a corresponding first pressurization equalization step follows the countercurrent depressurization step. The cycle optionally includes one or two depressurization equalization steps before the cocurrent purge step and one or two corresponding pressurization equalization steps after the first pressurization equalization step.

Abstract: Pressure swing adsorption process and system for separating gas mixtures comprising at least one more strongly adsorbable component and at least one less strongly adsorbable component. The process includes storing gas enriched in one of the components in a first storage tank and a second storage tank. Final product gas is provided from the second storage tank while gas for purge, rinse, and/or repressurization is provided from the first storage tank.

Abstract: A method is described for providing clean air at desired temperature to an environment. Incoming air possibly contaminated with nuclear biological and chemical contaminants is compressed. The compressed air is cooled in a first heat exchanger. The cooled air from the first heat exchanger is compressed in a secondary compressor. Compressed air from the secondary compressor is cooled in a second heat exchanger. Cooled air from the secondary heat exchanger is directed through a regenerative pressure swing absorption system to provide clean output air with the contaminants removed therefrom. This cleaned air is expanded in a turbine coupled to the secondary compressor, whereby to recover energy from the cleaned air to drive the secondary compressor. The expanded cleaned air from the turbine is utilized to condition air in the environment. The regenerative pressure swing absorption system is purged with air derived from the expanded clean air.

Abstract: This process uses a pressure variation cycle, in which, at at least one instant in the cycle, a terminal of a compression machine (1, 3) is switched from a first space (A1) which is at a first pressure P1 to a second space (A2) which is at a pressure P2 significantly different from P1. The switching comprises an intermediate operation in which the terminal is brought simultaneously into communication with the first space and with the second space. The process is useful in the production of oxygen from atmospheric air by adsorption.

Abstract: Pressure swing adsorption process and system for separating gas mixtures comprising at least one more strongly adsorbable component and at least one less strongly adsorbable component. The process includes storing gas enriched in one of the components in a first storage tank and a second storage tank which are arranged in series. Final product gas is provided from the second storage tank while gas for purge, rinse, and/or repressurization is provided from the first storage tank.

Abstract: According to this process, in the case of a reduction in the production rate, the maximum pressure PM of the cycle is lowered and the ratio of this maximum pressure to the minimum pressure Pm of the cycle is reduced, in particular by altering the durations of compression and decompression stages. The process is applicable to the production of oxygen at variable rate.