Heating And Cooling Patents (Class 95/115)
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Patent number: 7326821Abstract: This invention is to a process for removing dimethyl ether from an olefin stream. The process includes contacting the olefin stream with a molecular sieve that has improved capacity to adsorb the dimethyl ether from the olefin stream. The molecular sieve used to remove the dimethyl ether has low or no activity in converting the olefin in the olefin stream to other products.Type: GrantFiled: June 16, 2003Date of Patent: February 5, 2008Assignee: ExxonMobil Chemical Patents Inc.Inventors: Michael A. Risch, John Di-Yi Ou
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Publication number: 20080006152Abstract: A method of processing a volatile organic compound is provided, wherein a volatile organic compound contained in gas to be treated is adsorbed in an adsorbent; the thus-adsorbed volatile organic compound is desorbed with the aid of steam and mixed in the steam; and the steam containing the volatile organic compound is combusted. This method further includes: separating a vessel for the adsorption and desorption into an inner side room and an outer side room by means of a separation member part of which is formed of the adsorbent; thermally retaining the vessel for the adsorption and desorption; at the time of adsorption, supplying the gas to be treated to the inner side room and therefrom to the outer side room; and at the time of desorption, supplying the steam to the outer side room and therefrom to the inner side room.Type: ApplicationFiled: June 29, 2007Publication date: January 10, 2008Inventors: Shigekazu UJI, Masahito YAMAGUCHI
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Patent number: 7314506Abstract: A system and method for processing a matrix fluid to remove one or more impurities (such as moisture from a process gas). The purifier includes a pre-cooler that receives the matrix fluid and cools the matrix fluid to a second, lower temperature. A container is provided to contain a purifier element made up of a high surface area material. The container includes an inlet for receiving the matrix fluid from the pre-cooler and an outlet for outputting the matrix fluid after it is forced to flow through the purifier element. The purifier includes a cooler in thermal contact with an outer surface of the container to cool the outer surface of the container to a purifying temperature, which is selected to be below the ambient temperature and above a phase change point of the matrix fluid and is typically in the range of about 0 to ?200° C.Type: GrantFiled: October 17, 2005Date of Patent: January 1, 2008Assignee: Matheson Tri-Gas, Inc.Inventors: Joseph V. Vininski, Robert Torres, Jr., Virginia H. Houlding, Harold Spicer
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Patent number: 7300498Abstract: A system and method for removal of solvents, or other materials, from an exhaust stream, uses an active adsorption bed and a bed that is periodically regenerated. Electrically heated nitrogen may be used to regenerate the beds. A portion of the exhaust stream to be cleaned is diverted to a heat exchanger, so as to pre-heat the nitrogen used for regeneration. Liquid nitrogen, preferably from the same source as that used to provide gas for regeneration, is directed to the active bed, lowering its temperature and increasing its efficiency. The invention avoids the need for the use of steam to heat the nitrogen, and provides a system that is more efficient than those known in the prior art.Type: GrantFiled: December 27, 2004Date of Patent: November 27, 2007Assignee: American Air Liquide, Inc.Inventor: Sudhir R. Brahmbhatt
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Patent number: 7147695Abstract: Devices for enhancing the sensitivity of a microsensor or any other micro device by providing on-line preconcentration. Microconcentrators that can be integrated with a sensor or a micromachined GC to enhance the signal to noise ratio can include a miniaturized sorbent trap fabricated on a microchip. The microconcentrator can be made on a silicon substrate so that a sensor can be integrated on the same chip. The microconcentrator is composed of at least one microchannel lined with a microheater for in-situ heating. Preconcentration may be achieved on a thin-film polymeric layer deposited above the heater in the microchannel. Rapid heating by the channel heater generates a “desorption pulse” to be injected into a detector or a sensor.Type: GrantFiled: December 15, 2003Date of Patent: December 12, 2006Assignee: New Jersey Institute of TechnologyInventor: Somenath Mitra
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Patent number: 7128776Abstract: An improved thermal swing adsorption process is set forth which addresses the problem of water ingress into the adsorbent by periodically heating the adsorbent to a temperature greater than the temperature used in the normal regeneration cycle.Type: GrantFiled: March 10, 2004Date of Patent: October 31, 2006Assignee: Air Products and Chemicals, Inc.Inventors: William Paul Schmidt, Steven Ray Auvil, Mohammad Ali Kalbassi, Timothy Christopher Golden
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Patent number: 7115152Abstract: A regenerable filter system includes a flow path along which a stream of fluid flows between an inlet and an outlet. A first filtering unit is located in the flow path. The first filter unit includes first and second regenerable filter beds, wherein each bed has a first adsorbent for removing a first contaminant from the fluid stream. A first valve is located between the inlet and the first and second filter beds for selectively directing the fluid stream through one of the first and the second filter beds. The other of the first and second filter beds is removed from the flow path. A second filtering unit is located in the flow path between the first filtering unit and the outlet. The second filtering unit includes third and fourth regenerable filter beds for removing a second contaminant from the stream of fluid.Type: GrantFiled: January 12, 2004Date of Patent: October 3, 2006Inventors: David K. Friday, John L. Creed
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Patent number: 7101415Abstract: A continuous method of producing a process fluid gas from a feed stream that includes the process fluid and impurities. The method includes: (a) providing a first and second vessel, each vessel containing one or more regenerable purifier materials for removing at least one of the impurities from the feed stream; (b) removing at least one of the impurities by passing the feed stream through one or the other of the vessels to provide a purified process fluid gas, with the vessel being maintained at a first temperature during the removal of impurities; and (c) regenerating the purifier materials in the vessels at a second temperature and during the time when it is not purifying the feed stream by flowing a portion of the purified process fluid or the feed stream or a separate source of the process fluid gas therethrough.Type: GrantFiled: August 28, 2003Date of Patent: September 5, 2006Assignee: Matheson Tri-Gas, Inc.Inventors: Robert Torres, Jr., Joseph Vivinski, David Lawrence
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Patent number: 7101414Abstract: A method of reducing the sorbate concentration of a process fluid stream using a sorption bed system includes the following steps. A mass of a sorbent material is rotated so that, in a cycle of operation, a given volume of the sorbent mass sequentially passes through first, second, third, fourth, fifth, and sixth zones, before returning to the first zone. A process fluid stream is passed through the sorbent mass in the first zone, and a regeneration fluid stream is passed through the sorbent mass in the fourth zone. A first isolation fluid stream is recycled in a closed loop, independent of the process fluid stream and the regeneration fluid stream, between the sorbent mass in the second zone and in the sixth zone. A second isolation fluid stream, meanwhile, is recycled in a closed loop, independent of the process fluid stream, the regeneration fluid stream, and the first isolation fluid stream, between the sorbent mass in the third zone and in the fifth zone.Type: GrantFiled: April 27, 2004Date of Patent: September 5, 2006Assignee: Munters CorporationInventors: Paul A. Dinnage, Stephen C. Brickley
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Patent number: 7066986Abstract: An adsorber vessel for use in the adsorption of a component from a gas and subsequent regeneration by thermally induced desorption of the component comprises an inlet for regeneration gas having an inlet nozzle containing at least one heater element, and an outlet for regeneration gas, the inlet and outlet for regeneration being separated by a flow path including a flow chamber containing a body of adsorbent, and wherein the body of adsorbent has a first end which is adjacent the inlet for regeneration gas and a second end which is remote from the inlet for regeneration gas, and the or each heater element is located so as not to penetrate through the first end of the body of adsorbent.Type: GrantFiled: November 21, 2003Date of Patent: June 27, 2006Assignee: Air Products and Chemicals, Inc.Inventors: Christopher Richard Haben, Mohammad Ali Kalbassi, Declan Patrick O'Connor
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Patent number: 7033419Abstract: A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.Type: GrantFiled: September 16, 2003Date of Patent: April 25, 2006Assignee: The United States of America as represented by the United States Department of EnergyInventors: Evan J. Granite, Henry W. Pennline
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Patent number: 7014683Abstract: A method for the regeneration of humidity-laden drying cartridges includes heating to 220 to 300° C. and introducing it into a drying cartridge for regeneration. Subsequent cooling of the drying cartridge is achieved by a partial stream of air diverted from the dried process air. An arrangement suitable for carrying out the method is also disclosed.Type: GrantFiled: April 5, 2002Date of Patent: March 21, 2006Assignee: Wittmann Robot Systeme GmbHInventor: Andreas Vierling
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Patent number: 6984258Abstract: Method and apparatus for treating a gas by adsorption. A gas is compressed and then treated by being circulated in an adsorber. A regenerating fluid is indirectly heated by the gas coming from the compressor. In a second regeneration phase, the regenerating fluid is sent directly to the adsorber, while the treated gas is refrigerated by an auxiliary refrigerator.Type: GrantFiled: October 9, 2002Date of Patent: January 10, 2006Assignee: L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Norbert Niclout, Marc Wagner
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Patent number: 6984765Abstract: The present invention is a separation process for producing a methanol, ethanol and/or dimethyl ether stream from a first stream containing C3+ hydrocarbons. The first stream comprises C3+ hydrocarbons, methanol, ethanol and/or dimethyl ether. The process comprises the step of passing the first stream through an adsorbent bed having a crystalline microporous material that preferentially adsorbs methanol, ethanol and/or dimethyl ether over the C3+ hydrocarbons.Type: GrantFiled: September 8, 2003Date of Patent: January 10, 2006Assignee: ExxonMobil Chemical Patents Inc.Inventors: Sebastian C. Reyes, Venkatesan V. Krishnan, Gregory J. DeMartin, John Henry Sinfelt, Karl G. Strohmaier, Jose Guadalupe Santiesteban
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Patent number: 6942719Abstract: Methods and systems for pressure swing absorption for hydrogen generation are presented. In one embodiment, a method includes absorbing at least one oxide of carbon with a pressure swing absorber from a steam reformation of methane. The steam reformation may occur at an ambient pressure in excess of 300 psia and at an ambient temperature in excess of 600° centigrade. The steam reformation of methane produces a stream of product gas. The steam reformation of methane is interrupted allowing the regenerating of the pressure swing absorber at an ambient pressure of less than 10 psia and at an ambient temperature sufficient to calcine the pressure swing absorber to exude carbon dioxide.Type: GrantFiled: June 30, 2003Date of Patent: September 13, 2005Assignee: The Boeing CompanyInventor: Albert E. Stewart
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Patent number: 6939518Abstract: A purifier to purify exhaust gas includes a case, a plurality of metal sheets disposed in the case, a catalyst held to each of the metal sheets, partition plates disposed between the respective metal sheets, a metallic pipe disposed piercing through the metal sheets, and a catalyst heater disposed in the metallic pipe. The plurality of metal sheets are arranged at predetermined intervals, and each of the metal sheets has at least one through-hole. The partition plates serve to partition the spaces between the respective metal sheets. The exhaust gas is circulated through the spaces between the respective metal sheets and then passes through the through-holes and is exhausted from the outlet of the case. In this way, it is possible to increase the number of metal sheets without increase of the pressure loss and to enlarge the outer diameter of same. As a result, the exhaust gas purifying capacity will be improved.Type: GrantFiled: August 20, 2001Date of Patent: September 6, 2005Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Motomichi Mishima, Mitsuyasu Ogawa, Yoshiyuki Higashiyama, Shigehiko Shimomura, Tadashi Matsuyo, Seiichi Ueno, Hiromi Maeda, Masahiro Kimura
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Patent number: 6911065Abstract: A fluid purifying apparatus that includes a manifold that includes a first branch and a second branch, a first check valve coupled to the first branch of the manifold, and a purifier unit that includes a first end and a second end, wherein the first end is coupled to the second branch of the manifold. Also, a fluid purifying apparatus that includes a vessel that includes a first interior compartment for containing a purifier material and a second interior compartment for containment of a fluid containing impurities, wherein the first interior compartment is separated from the second interior compartment by a fluid permeable support, and a rupturable seal.Type: GrantFiled: December 26, 2002Date of Patent: June 28, 2005Assignee: Matheson Tri-Gas, Inc.Inventors: Tadaharu Watanabe, Robert Torres, Jr., Joseph Vininski
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Patent number: 6828499Abstract: A condensation panel to be used for harvesting water from atmospheric moisture during those times of the diurnal cycle when relative humidity is at or near 100% utilizes very localized cooling to optimize condensation on a surface whose materials promote the condensation and collection of the water. The panel is passive in the sense that it can be deployed and left in an unmaintained condition for considerable periods of time. At least one time each day, almost certainly in the morning, water harvested by the process of assisted condensation can be collected for use.Type: GrantFiled: December 20, 2002Date of Patent: December 7, 2004Assignee: Marine Desalination Systems, L.L.C.Inventor: Michael David Max
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Patent number: 6761753Abstract: A filter includes at least two different adsorptive media. First, chemisorptive media, which is porous and includes an acidic functional group, is used to remove molecular bases, including ammonia, organic amines, imides and aminoalcohols, from the atmosphere used in semiconductor fabrication and other processes that require uncontaminated gaseous environments of high quality. Second, physisorptive media is able to adsorb condensable contaminants, particularly those having a boiling point greater than 150 degrees C. The physisorptive media can include untreated, activated carbon.Type: GrantFiled: July 26, 2002Date of Patent: July 13, 2004Assignee: Extraction Systems, Inc.Inventors: Oleg P. Kishkovich, Devon Kinkead, Anatoly Grayfer, William M. Goodwin, David Ruede
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Patent number: 6746515Abstract: The present invention provides compact adsorption systems that are capable of rapid temperature swings and rapid cycling. Novel methods of thermal swing adsorption and thermally-enhanced pressure swing adsorption are also described. In some aspects of the invention, a gas is passed through the adsorbent thus allowing heat exchangers to be very close to all portions of the adsorbent and utilize less space. In another aspect, the adsorption media is selectively heated, thus reducing energy costs. Methods and systems for gas adsorption/desorption having improved energy efficiency with capability of short cycle times are also described. In another aspect, the apparatus or methods utilize heat exchange channels of varying lengths that have volumes controlled to provide equal heat fluxes. Methods of fuel cell startup are also described. Advantages of the invention include the ability to use (typically) 30-100 times less adsorbent compared to conventional systems.Type: GrantFiled: April 29, 2002Date of Patent: June 8, 2004Assignee: Battelle Memorial InstituteInventors: Robert S. Wegeng, Scot D. Rassat, Ward E. TeGrotenhuis, Kevin Drost, Vilayanur V. Vishwanathan
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Patent number: 6733571Abstract: The present invention provides a gas purification system with improved efficiency, simpler construction, cost reduction, form factor improvements, and increased durability. The present invention provides cost and form factor improvements through fewer components overall and through utilizing multiple integrated components. Prior art gas purification system are more bulky and complicated. The present invention achieves increased thermal efficiency through utilization of a regenerative heat exchanger to recapture a portion of the heat energy transferred to the gas during the purification process. Prior art purifiers lacked a regenerative heat exchanger. The present invention integrates the two components into one integrated heater and purification vessel assembly. The present invention integrates the two discrete components into one integrated hydrogen sorption and particle filter assembly. The integrated hydrogen sorption and particle filter assembly is also capable of operating at higher temperatures.Type: GrantFiled: July 12, 2000Date of Patent: May 11, 2004Assignee: SAES Pure Gas, Inc.Inventors: Pierre J. Arquin, Nels W. Lindahl, Mark A. Canaan
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Patent number: 6733572Abstract: The present invention is a process for separating propylene and dimethylether from a mixture comprising propylene, dimethylether, and propane. The mixture is passed through a bed of an adsorbent comprising a porous crystalline material having (i) diffusion time constants for dimethylether and propylene of at least 0.1 sec−1, and (ii) a diffusion time constant for propane of than 0.02 of the diffusion time constants for dimethylether and propylene. The bed preferentially adsorbs propylene and dimethylether from the mixture. The adsorbed propylene and dimethylether are then desorbed from the bed.Type: GrantFiled: July 30, 2002Date of Patent: May 11, 2004Assignee: ExxonMobil Chemical Patents Inc.Inventors: Sebastian C. Reyes, Krishnan V. Venkatesan, Gregory J. DeMartin, John H. Sinfelt, Karl G. Strohmaier, Jose Guadalupe Santiesteban
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Patent number: 6730142Abstract: In a process for separating propylene from a mixture comprising propylene and propane, the mixture is passed through a bed of an adsorbent comprising a porous crystalline material having (i) a diffusion time constant for propylene of at least 0.1 sec−1, when measured at a temperature of 373° K and a propylene partial pressure of 8 kPa, and (ii) a diffusion time constant for propane, when measured at a temperature of 373° K and a propane partial pressure of 8 kPa, less than 0.02 of said diffusion time constant for propylene. The bed preferentially adsorbs propylene from the mixture. The adsorbed propylene is then desorbed from the bed either by lowering the pressure or raising the temperature of the bed.Type: GrantFiled: March 19, 2002Date of Patent: May 4, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Sebastian C. Reyes, Venkatesan V. Krishnan, Gregory J. DeMartin, John H. Sinfelt, Karl G. Strohmaier, Jose G. Santiesteban
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Patent number: 6726746Abstract: A method for removing a first sorbate having a first desorption activation energy and a second sorbate having a second desorption activation energy from a sorbent, involves a two-stage desorber. In a first stage, the first sorbate, second sorbate and the sorbent are contacted with a stripping fluid having a first temperature sufficient to separate the first sorbate in a vapor phase from the sorbent. In a second stage, the second sorbate and the sorbent is heated to a second temperature higher than the first temperature to separate the second sorbate in a vapor phase from the sorbent. The second sorbate can then be condensed to a liquid phase and sold to offset the costs of the process. Heating in the second phase can be facilitated by the introduction of microwave or infrared energy for stripping the second sorbate from the sorbent. Use of the microwave or infrared energy can be facilitated with a purging gas which can also be heated to function as a stripping gas.Type: GrantFiled: October 19, 2001Date of Patent: April 27, 2004Assignee: American Purification, Inc.Inventors: Xiangfeng Dai, Kevin Simpson
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Patent number: 6699562Abstract: The invention provides an improved ceramic packing element having the basic shape of a cylinder with an aspect ratio, defined by the diameter to length dimensions that is from 2.7 to 4.5.Type: GrantFiled: February 28, 2002Date of Patent: March 2, 2004Assignee: Saint-Gobain CorporationInventors: Hassan S. Niknafs, Robert L. Miller
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Patent number: 6669759Abstract: Methods for regenerating activated carbon mainly used in air-treating devices in transportation, in particular for passenger compartments in transportation conveyances. The invention can be also used for regenerating activated carbon for air-treating devices in other areas. The method for regeneration of activated carbon comprises a regeneration, which is performed with the help of water vapor obtained from condensate of humidity in the atmosphere. The condensate is pre-adsorbed on silica gel during air cleaning. The regeneration is carried out at the atmospheric pressure, at a temperature of up to 160° C. followed by cooling with the help of the fan with an air flow of no less than 25 min−1.Type: GrantFiled: November 4, 2002Date of Patent: December 30, 2003Assignee: Kutyev Anatoly AnatolyevichInventors: Anatoly A Kutyev, Vladimir Matveevich Zlotopolsky, Arkady Samuilovich Guzenberg, Dmitry Anatolyevich Krychenkov, Sergei Ivanovich Eremeev
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Patent number: 6652627Abstract: This invention relates to a process for separating a fluid component from a fluid mixture comprising the fluid component, the process comprising: (A) flowing the fluid mixture into a microchannel separator; the microchannel separator comprising a plurality of process microchannels containing a sorption medium, a header and a footer, the combined internal volume of the header and the footer being up to about 40% of the internal volume of the process microchannels; the fluid mixture being maintained in the microchannel separator until at least part of the fluid component is sorbed by the sorption medium; purging the microchannel separator to displace non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the fluid component from the sorption medium and flowing a flush fluid through the microchannel separator to displace the desorbed fluid component from the microchannel separator. The process is suitable for purifying oxygen as well as effecting other fluid separations.Type: GrantFiled: October 30, 2002Date of Patent: November 25, 2003Assignee: Velocys, Inc.Inventors: Anna Lee Tonkovich, Bruce F. Monzyk, Dongming Qiu, Matthew B. Schmidt, G. Bradley Chadwell, Wesley Bruno, Eric Burckle
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Patent number: 6652628Abstract: Desiccants employed in dehumidifying moisturized air present within a water-damaged building are themselves dehumidified to liberate collected moisture through the use of ambient air drawn over and about a heat exchanger fired by diesel fuel.Type: GrantFiled: July 8, 2002Date of Patent: November 25, 2003Inventor: Spencer W. Hess
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Patent number: 6630012Abstract: The present invention provides compact adsorption systems that are capable of rapid temperature swings and rapid cycling. Novel methods of thermal swing adsorption and thermally-enhanced pressure swing adsorption are also described. In some aspects of the invention, a gas is passed through the adsorbent thus allowing heat exchangers to be very close to all portions of the adsorbent and utilize less space. In another aspect, the adsorption media is selectively heated, thus reducing energy costs. Methods and systems for gas adsorption/desorption having improved energy efficiency with capability of short cycle times are also described. Advantages of the invention include the ability to use (typically) 30-100 times less adsorbent compared to conventional systems.Type: GrantFiled: April 30, 2001Date of Patent: October 7, 2003Assignee: Battelle Memorial InstituteInventors: Robert S. Wegeng, Scot D. Rassat, Victoria S. Stenkamp, Ward E. TeGrotenhuis, Dean W. Matson, M. Kevin Drost, Vilayanur V. Viswanathan
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Patent number: 6613126Abstract: A method for storing natural gas by adsorption which comprises separating an available natural gas in an infrastructure side (10) into a low carbon number component mainly containing methane and ethane and a high carbon number component mainly containing propane, butane and the like, and storing the low carbon number component by adsorption in a first adsorption tank (16) and storing the high carbon number component by adsorption in a second adsorption tank (18). The method can solve the problem that the high carbon number component condenses within a pore of an adsorbing agent and hence the adsorption of the carbon number component, the main component of natural gas, is inhibited, and thus improves the storage density. Accordingly, the method can be used for ensuring a high storage density also for an available natural gas. An adsorbing agent for use in the method is also disclosed.Type: GrantFiled: September 5, 2001Date of Patent: September 2, 2003Assignee: Toyota Jidosha Kabushiki KaishaInventors: Kyoichi Tange, Tamio Shinozawa, Hiroshi Hasegawa, Kouetsu Hibino
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Patent number: 6572682Abstract: A Diesel particulate filter cartridge system for filtering particulate matter and nitrogen oxide from a flow of air containing particular matter includes a filter support plate with a plurality of cylindrical electrically regenerable filter media members connected thereto. A NOx trap is also provided that is either incorporated directly into the filter media members or provided as a separate structure in close proximity to the filter media members. A valve assembly includes a number of independently actuatable damper valves that correspond to a number of through holes in the filter support plate. When actuated, the damper valves limiting flow of air through a corresponding through hole and filter media member connected thereto. An outer housing is disposed about the valve assembly and filter media members to contain them in a compact package. A programmable computer control module shuts off the flow of air through a filter media member and selectively electrically regenerates it.Type: GrantFiled: June 26, 2001Date of Patent: June 3, 2003Assignee: Rypos, Inc.Inventors: Klaus J. Peter, Osama M. Ibrahim
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Patent number: 6514317Abstract: Purification of a hydrogen-based gas mixture containing impurities such as carbon monoxide, nitrogen and methane is effected by contacting the gaseous mixture with a zeolite adsorbent which is a shaped product comprised of at least 95%, as determined on the basis of the moisture equilibrium adsorption value, of a low-silica type X zeolite having a SiO2/Al2O3 molar ratio of 1.9 to 2.1. The zeolite adsorbent is preferably ion-exchanged with lithium and/or calcium. The zeolite adsorbent is preferably prepared by a process including a step of contacting with a caustic solution a calcined product of a mixture of a low-silica type X zeolite and kaolin clay whereby the kaolin clay is converted to a low-silica type X zeolite.Type: GrantFiled: April 20, 2001Date of Patent: February 4, 2003Assignee: Tosoh CorporationInventors: Shigeru Hirano, Atsushi Harada
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Patent number: 6508858Abstract: An apparatus for treating exhaust gases. The apparatus includes an adsorbing tower containing an adsorbent to adsorb an impurity gas included in the exhaust gases. A desorbing tower heats the adsorbent to desorb the impurity gas from the adsorbent so that the adsorbent can be re-used. A transfer unit circulates the adsorbent between the adsorbing tower and the desorbing tower. A controller controls the temperature of the adsorbent. A helical heater is arranged in the desorbing tower to heat the adsorbent.Type: GrantFiled: April 25, 2000Date of Patent: January 21, 2003Assignee: Fujitsu LimitedInventors: Hideki Hirose, Mikio Hachikawa, Kouji Teramoto
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Patent number: 6508862Abstract: The present invention provides apparatus and methods for separating fluid components. In preferred embodiments, the apparatus and methods utilize microchannel devices with small distances for heat and mass transfer to achieve rapid cycle times and surprisingly large volumes of fluid components separated in short times using relatively compact hardware.Type: GrantFiled: April 30, 2001Date of Patent: January 21, 2003Assignee: Battelle Memorial InstituteInventors: Anna Lee Y. Tonkovich, Bruce F. Monzyk, Yong Wang, David P. VanderWiel, Steven T. Perry, Sean P. Fitzgerald, Wayne W. Simmons, Jeffrey S. McDaniel, Albert E. Weller, Jr.
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Patent number: 6460401Abstract: The invention relates to a method of trace analysis of organic compounds which calls for the steps of setting a test piece in a flow cell, and thereafter removing organic compounds from the test piece by heating it at high temperature in an oven. The compounds are concentrated in a trap tube and then removed from the trap tube and carried into a concentrating/inlet unit, such as a thermal desorption cold trap injector. In this unit, cryofocusing of the compounds is performed, and then the organic compounds are introduced into a gas chromatograph to be analyzed therein, wherein a part of the purified inert gas is caused, except during the process of trapping the organic compounds, to flow into the flow cell from the direction opposite the direction from which the gas flows along the trapping line.Type: GrantFiled: December 15, 1999Date of Patent: October 8, 2002Assignee: GL Science Inc.Inventors: Kunihiro Hoshino, Yoshihiko Takano, Takeshi Miyabayashi
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Patent number: 6458186Abstract: In a method for regenerating an electrically conducting adsorbent laden with organic substances the adsorbent is heated by passing electric current through the adsorbent while not passing a flushing gas through the adsorbent. Subsequently, the flushing gas is passed through the adsorbent while not heating the adsorbent by passing electric current through the adsorbent so that the adsorbed organic substances are flushed from the adsorbent and the adsorbent is simultaneously cooled by the flushing gas.Type: GrantFiled: July 5, 2001Date of Patent: October 1, 2002Assignee: M+W Zander Facility Engineering GmbHInventors: Horst Chmiel, Egbert Schippert, Cornelia Möhner
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Patent number: 6458185Abstract: A process for the recovery of a volatile organic compound (VOC) from a process stream by use of a bed of activated carbon is disclosed. In the first step, VOC laden gas passes through to the bed, in a first direction. In the second step, steam passes through the bed in a second direction. The first direction is opposite to the second direction. In the final step, cooling gas, ambient atmospheric air, passes through the bed in the second direction. This process yields greater VOC recovery efficiency and longer cycle life for the bed of activated carbon.Type: GrantFiled: March 29, 2001Date of Patent: October 1, 2002Assignee: Celanese Acetate LLCInventors: Timothy D. Reiter, Stephen C. Jones
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Patent number: 6444012Abstract: A pressure swing adsorption process for the separation of nitrogen from natural gas utilizes two separate pressure swing adsorption stages, the first containing a hydrocarbon-selective adsorbent and the second containing a nitrogen-selective adsorbent. In the process, the product stream from the first pressure swing adsorption unit contains a natural gas stream having a reduced hydrocarbon content and the product stream from the second pressure swing adsorption unit is a natural gas stream having a reduced nitrogen concentration. The product from the second pressure swing adsorption unit is used to desorb the hydrocarbons from the first pressure swing adsorption unit so as to add the hydrocarbons, which have heat value to the product natural gas stream. Periodically, heating the nitrogen-selective adsorbent with heated product stream from the second pressure swing adsorption unit has been found to improve the capacity of the nitrogen-selective adsorbent to adsorb nitrogen.Type: GrantFiled: October 30, 2000Date of Patent: September 3, 2002Assignee: Engelhard CorporationInventors: William B. Dolan, Kenneth F. Butwell
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Patent number: 6402814Abstract: The regeneration phase of the adsorption cycle includes a depressurization step, a heating/elution step, during which the bed is purged with a hot heating/elution gas, and a cooling/elution step, during which the bed is purged with a cold cooling/elution gas. The cooling/elution step is terminated while the cooling/elution gas leaving the bed is at a temperature markedly higher than the temperature of the gas to be treated and the adsorption phase comprises an initial adsorption step during which the bed is cooled down to the low adsorption temperature due to the effect of the gas to be treated.Type: GrantFiled: October 5, 2000Date of Patent: June 11, 2002Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Georges Kraus, Patrick Le Bot, Lian-Ming Sun
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Patent number: 6383259Abstract: The invention relates to an improved apparatus for thermal management in a gas purification process. As known in the prior art, a gas purification apparatus includes a two-section unitary vessel, wherein the primary section includes an impure gas inlet and a heating assembly and the secondary section includes a cooling device and an outlet for purified gas. Within the primary and secondary sections of the vessels are gas sorbing materials such as getters for removing impurities from the gas to be purified. A feature of the present invention is the continuous, serpentine shape of the gas purification vessel which allows for a longer residence time of the gas and a more efficient purification process. Another feature of the invention is a Joule-Thomson cooling device which divides the primary section of the vessel from the secondary section. The Joule-Thomson cooling device cools the secondary section of the vessel and the gas contained within it.Type: GrantFiled: August 30, 2000Date of Patent: May 7, 2002Assignee: C&M IncorporatedInventors: Kye-Jin Lim, Dan Weber, Gwon Sagong
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Patent number: 6379430Abstract: A process, especially a PSA or TSA process, for purifying a gas containing at least carbon dioxide (CO2) as impurity, in which the carbon dioxide is adsorbed on an adsorbent comprising particles of activated alumina. According to this process, the activated alumina has a specific surface area of between 200 m2/g and 299 m2/g and contains at least 80% aluminum oxide (Al2O3), silicon oxide (SiO2), iron oxide (Fe2O3) and from 0.001% to 7.25% of at least one oxide of at least one alkali or alkaline-earth metal, such as sodium and potassium oxides. According to the invention, the gas stream to be purified is air or a synthesis gas.Type: GrantFiled: July 31, 2000Date of Patent: April 30, 2002Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'exploitation des procedes Georges ClaudeInventor: Christian Monereau
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Patent number: 6364936Abstract: An adsorption/desorption unit includes a hollow enclosure containing one or more elongate hollow elements of activated carbon fiber cloth (ACFC) of appropriate length to cross sectional area to provide suitable electrical resistance for heating. The elements conduct electrical current to heat to a temperature that permits selective adsorption of a gas stream constituent and subsequent desorption to recover sorbate. An enclosure houses the ACFC elements and is arranged to direct gas stream flow through the elements and into and out of the enclosure via gas ports. The ability to heat the elements to a desired temperature by electrical current flow allows for straightforward implementation of selective adsorption. After an adsorption step, altering the temperature of the element or elements enables desorption.Type: GrantFiled: May 15, 2000Date of Patent: April 2, 2002Assignee: The Board of Trustees of the University of IllinoisInventors: Mark J. Rood, Patrick Sullivan, K. James Hay
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Patent number: 6336957Abstract: The present invention relates to method and apparatus for extracting water from atmospheric air. The method according to an embodiment of the invention does not depend on day and night temperature differentials and can operate at lower temperatures than were possible before. The present invention makes it possible to extract water vapors from the atmospheric air in relatively simple, inexpensive industrial plants or in smaller portable devices.Type: GrantFiled: February 19, 2001Date of Patent: January 8, 2002Assignee: Watertech M.A.S. Ltd.Inventor: Alexander Tsymerman
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Patent number: 6294000Abstract: A rotary concentrator heats media in a desorption zone to a desorption temperature, then removes the pollutants using a second cold desorbent gas stream in a desorbent zone. First, the adsorbent media is rotated and an inlet gas stream is passed over the media in the adsorbent zone, thereby removing the adsorbable pollutants. A first gas stream having a temperature equal to or greater than the desorption temperature of the adsorbable pollutants is passed over the media in the desorbent zone to heat the media to generally the desorption temperature of the adsorbable pollutants. A second gas having a temperature less than the desorption temperature of the adsorbent media is passed over the media in the desorbent zone to remove the adsorbable pollutants from the desorbent zone. Subsequently, the gas containing the adsorbable pollutants received from the desorbent zone is processed by destroying or removing the adsorbable pollutants.Type: GrantFiled: September 24, 1999Date of Patent: September 25, 2001Assignee: Durr Environmental, Inc.Inventor: Joseph M. Klobucar
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Patent number: 6293998Abstract: An apparatus for pressure and temperature swing adsorption processes is described. Such processes include pressure swing adsorption, temperature swing adsorption, and sorption cooling. The apparatus, a spirally wound module, provides high efficiency gas separations by reducing the differential pressure required between the adsorption pressure and the desorption pressure. The apparatus comprises an adsorption zone containing at least one adsorbent paper layer containing a selective adsorbent and an adsorbent spacer spirally wound about a hollow mandrel and in intimate thermal contact with a heat transfer zone. For pressure and temperature swing processes, the adsorption zone is disposed on the outside of the heat transfer zone, and for sorption cooling processes, the heat transfer zone is disposed on the outside of the adsorption zone and the adsorption zone is contained in an envelope-like leaf.Type: GrantFiled: December 11, 1998Date of Patent: September 25, 2001Assignee: UOP LLCInventors: William B. Dolan, Mark M. Davis, Man-Wing Tang
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Patent number: 6261345Abstract: There are disclosed a process for recovering ammonia which comprises installing a shell and multi-tube adsorber which is equipped with plural adsorption tubes each packed inside with an ammonia adsorbent (e.g. synthetic zeolite) and equipped with a flow mechanism for a heat transfer medium for performing heat exchange through the adsorption tubes, passing an ammonia-containing gas through the adsorption tubes, while cooling the adsorbent with a heat transfer medium (e.g. water) to adsorb the ammonia, and thereafter collecting the adsorbed ammonia through desorption, while heating the adsorbent with a heat transfer medium (e.g. hot water) under reduced pressure; and an apparatus for the above process.Type: GrantFiled: October 7, 1999Date of Patent: July 17, 2001Assignee: Japan Pionics Co., Ltd.Inventors: Yasusada Miyano, Kenji Otsuka, Satoshi Arakawa
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Patent number: 6251164Abstract: Separation of one or more fluidic components from a feed fluid containing a plurality of components is accomplished by adsorbent powder entrained in a stream of fluid, such as gas, and preferably is operated as a temperature swing adsorption process using waste thermal energy from a plant.Type: GrantFiled: August 27, 1999Date of Patent: June 26, 2001Assignee: Praxair Technology, Inc.Inventors: Frank Notaro, Jeffert John Nowobilski, Dariush Habibollih Zadeh
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Patent number: 6251165Abstract: Process for recovering a solvent from a gas coming from a treating process using the solvent, the gas having a low temperature Ta and a high temperature Td, the difference Td-Ta being sufficient to carry out an adsorption step and a desorption step. The process is characterized in that/ a) a first solvent-containing gas stream is sent to an adsorption step, this gas being at a temperature Ta, at the end of this step the gas is practically solvent-free and the solvent is collected in a first adsorber, b) a second gas stream at a temperature Td, this gas being solvent-free, is sent to carry out desorption of a second adsorption means loaded with solvent during a previous step a), and c) the solvent is sent at least partly to a step of the treating process using the solvent.Type: GrantFiled: June 2, 1999Date of Patent: June 26, 2001Assignee: Institut Francais du PetroleInventors: Sophie Jullian, Etienne Lebas, Michel Thomas
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Patent number: 6196050Abstract: The present invention enables siloxanes which have a detrimental effect on the quality of products during semiconductor production to be efficiently removed from silicon compound gases, and enables minute amounts of siloxanes in these gases to be accurately measured to a few ppb, thus allowing for improvements in quality control by offering silicon compound gases of high purity. Diatomaceous earth M filled into a removal column 2 is heated by heating means provided on the removal column 2, while an inert gas such as nitrogen or helium is fed from an inert gas delivery pipe 13 via a pressure regulator 5 and an entry valve 6 into the removal-column 2, and is allowed to flow out through an outlet valve 8 in order to thermally activate the diatomaceous earth M. After activation, the removal column is cooled to a temperature of 60-0° C.Type: GrantFiled: December 22, 1998Date of Patent: March 6, 2001Assignee: Nippon Sanso CorporationInventors: Takuya Ikeda, Toyohiko Abe
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Patent number: 6197092Abstract: A pressure swing adsorption process for the separation of hydrogen from a mixture of the same with methane, utilizing two separate PSA stages, one containing a nitrogen selective crystalline zeolite, and the second containing a methane selective adsorbent.Type: GrantFiled: March 22, 1999Date of Patent: March 6, 2001Assignee: Engelhard CorporationInventors: Kenneth F. Butwell, William B. Dolan, Steven M. Kuznicki