Carbon Dioxide Sorbed Patents (Class 95/236)
  • Patent number: 8652236
    Abstract: The present invention describes a method for recovery of high purity carbon dioxide, which is substantially free of nitrogen oxides. This high purity carbon dioxide is obtained by introducing into the method a step in which carbon dioxide absorbed in an absorbing agent is flashed. The present invention also discloses a plant for recovery of said high purity carbon dioxide comprising an absorption column, a flash column, a stripper column, and a down stream purification unit comprising a washing column, a dehydrator, a condenser and a distillation unit.
    Type: Grant
    Filed: January 16, 2008
    Date of Patent: February 18, 2014
    Assignee: Union Engineering A/S
    Inventors: Rasmus Find, Svend Geleff, Maj Toft Andersen
  • Patent number: 8647421
    Abstract: [Problem to be solved] A CO2 recovery apparatus which can significantly reduce the amount of steam and provide further improved energy efficiency is provided. [Solution] The apparatus includes: a flue gas cooling apparatus 14 for allowing cooling water 13 to cool a CO2 and O2 containing flue gas 12 that is emitted from an industrial combustion facility 11 such as a boiler or gas turbine; a CO2 absorber 16 having a CO2 recovery section 16A for bringing the cooled CO2 containing flue gas 12 and a CO2 absorbing CO2 absorbent 15 into contact with each other to remove CO2 from the flue gas 12; and an absorbent regenerator 18 for releasing CO2 from a CO2 absorbed CO2 absorbent 17 to regenerate the CO2 absorbent.
    Type: Grant
    Filed: April 28, 2011
    Date of Patent: February 11, 2014
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventor: Takahito Yonekawa
  • Patent number: 8647420
    Abstract: [Problem] To provide a system for recovering carbon dioxide from flue gas, in which a reboiler in a regenerator can be compactly installed, and a method therefor, in facilities where CO2 or the like contained in flue gas is recovered. [Solving Means] To include an absorber 1006 that absorbs CO2 contained in flue gas 1002, a regenerator 1008 that strips CO2 from CO2 absorbent (rich solution) 1007 to regenerate absorbent, internal shells 101 provided at a bottom of the regenerator 1008 with a predetermined interval therebetween, into which regenerated CO2 absorbent is introduced by a feeding unit 102 from a bottom side thereof so that the CO2 absorbent overflows from an upper end of the internal shell thereof toward the bottom of the regenerator, and a reboiler that is inserted into the internal shells 101 in a direction orthogonal to a vertical axis and includes a heat-transfer tube 103 that reboils absorbent.
    Type: Grant
    Filed: April 7, 2011
    Date of Patent: February 11, 2014
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Hiroshi Tsubone, Toyoshi Nakagawa, Takashi Kamijo, Tsuyoshi Oishi, Katsufumi Inoue, Osamu Miyamoto
  • Patent number: 8647413
    Abstract: A method for recovering carbon dioxide (CO2) from a gas stream is disclosed. The method includes the step of reacting CO2 in the gas stream with fine droplets of a liquid absorbent, so as to form a solid material in which the CO2 is bound. The solid material is then transported to a desorption site, where it is heated, to release substantially pure CO2 gas. The CO2 gas can then be collected and used or transported in any desired way. A related apparatus for recovering carbon dioxide (CO2) from a gas stream is also described herein.
    Type: Grant
    Filed: October 30, 2009
    Date of Patent: February 11, 2014
    Assignee: General Electric Company
    Inventors: Grigorii Lev Soloveichik, Robert James Perry, Benjamin Rue Wood, Sarah Elizabeth Genovese
  • Patent number: 8641805
    Abstract: The present invention relates to reactor vessels such as absorbing or stripping columns that are suitable for capturing carbon dioxide from flue gas streams of fossil fuel fired powered stations such as coal fired power stations generating 100 to 500 MW. The side walls of the reactors are made of concrete or structural ceramics that are preferrably steel reinforced. The reactors are on a sufficiently large scale such that a flue gas stream in the order of at least 1,000 t/hr and normally greater than 2,000 or 3,000 t/hr can be scrubbed of carbon dioxide in a single absorption column and then recovered in a stripping column. The absorbing and stripping columns may be free standing structures or, alternatively, the absorbing column may be located at least partially within the stripping column.
    Type: Grant
    Filed: May 12, 2008
    Date of Patent: February 4, 2014
    Assignee: CO2CRC Technologies PTY Ltd.
    Inventors: Geoff Stevens, Barry Hooper, Craig Dugan, Paul Anthony Webley
  • Patent number: 8641802
    Abstract: From the CO2-containing stream of process gas obtained in a process for the treatment of a CO2-containing stream of process gas, which is obtained in the production of pure synthesis gas from raw gas in the partial oxidation of heavy oils, petroleum coke or wastes, or in the gasification of coal, or when processing natural gas or accompanying natural gas, CO2 is removed physisorptively or chemisorptively, and the solvent loaded with CO2 is expanded to a lower pressure for the desorption of CO2. In order to generate CO2 as pure as possible, the contaminated CO2 is condensed to at least 60 bar[a] or below its critical temperature to at least 70 bar[a], and the impurities contained in the liquid CO2 are removed by stripping with gaseous CO2 guided in counterflow.
    Type: Grant
    Filed: September 5, 2008
    Date of Patent: February 4, 2014
    Assignee: LURGI GmbH
    Inventors: Ulrich Koss, Manfred Meyer, Alexander Schriefl
  • Patent number: 8636018
    Abstract: A microbubble cleaning system includes a tank in which a solution into which a product is immersed to clean the product is stored; supplying means for putting microbubbles into the solution and supplying the solution that includes the microbubbles into the tank; oil separating apparatus that collects bubbles that have risen to a surface of the solution stored in the tank as a result of cleaning the product, as well as a portion of the solution that is near the surface of the solution, in order to separate oil from the solution; generating means for generating a surface flow of the solution near the surface of the solution in order to remove the bubbles that have risen to the surface of the solution in the tank; and removing means for removing carbon dioxide from air that is used to generate the microbubbles by the supplying means.
    Type: Grant
    Filed: February 24, 2011
    Date of Patent: January 28, 2014
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Hiroshi Kozuka, Masahiro Inoue, Kanji Imura, Yuji Nemoto
  • Patent number: 8623123
    Abstract: CO2 is absorbed from a gas mixture by bringing the gas mixture into contact with an absorbent that comprises water and at least one amine of the formula (I), wherein R1 and R2, independently of each other, are hydrogen or an alkyl group. According to the invention, absorption media comprise sulfolane or an ionic liquid in addition to water and an amine of the formula (I). A device according to the invention for removing CO2 from a gas mixture comprises an absorption unit, a desorption unit, and an absorption medium according to the invention that is conducted in the circuit.
    Type: Grant
    Filed: June 4, 2013
    Date of Patent: January 7, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Matthias Seiler, Jöm Rolker, Rolf Schneider, Bernd Glöckler, Axel Kobus, Wolfgang Benesch, Thomas Riethmann, Hermann Winkler, Jens Reich, Helmut Brüggemann
  • Patent number: 8613865
    Abstract: The present invention relates to a carbon dioxide absorbent, an ionic liquid obtained by reacting amide and an organic acid and a method of using the same. The amidium-based ionic liquid of the present invention has excellent CO2 absorption capability, which is hardly reduced even with repeated use, is easy to synthesize and has low manufacturing cost thus being useful as a CO2 absorbent.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: December 24, 2013
    Assignees: Hyundai Motor Company, Kia Motors Corporation
    Inventors: Seok Jin Choi, Jelliarko Palgunadi, Je Eun Kang, Hoon Sik Kim, Sung Yeup Chung
  • Patent number: 8613794
    Abstract: A process for producing a pressurized CO2 stream in a power plant integrated with a CO2 capture unit, wherein the power plant comprises at least one gas turbine (1) coupled to a heat recovery steam generator unit (2) and the CO2 capture unit comprises an absorber (18) and a regenerator (21), the process comprising the steps of: (a) introducing hot exhaust gas exiting a gas turbine into a heat recovery steam generator unit to produce a first amount of steam and a flue gas stream (17) comprising CO2; (b) removing CO2 from the flue gas stream comprising CO2 by contacting the flue gas stream with absorbing liquid in an absorber (18) to obtain absorbing liquid enriched in CO2 (20) and a purified flue gas stream; (c) contacting the absorbing liquid enriched in CO2 with a stripping gas at elevated temperature in a regenerator (21) to obtain regenerated absorbing liquid and a gas stream enriched in CO2 (23); (d) pressurizing the gas stream enriched in CO2 using a CO2 compressor (24) to obtain the pressurized CO2 stre
    Type: Grant
    Filed: January 23, 2008
    Date of Patent: December 24, 2013
    Assignee: Shell Oil Company
    Inventors: Kuei-Jung Li, Georgios Protopapas
  • Patent number: 8609049
    Abstract: A process for removing CO2 from a CO2 containing gas stream in which the CO2 containing gas stream is contacted with an aqueous ammonium solution. The aqueous ammonia solution comprises 0.1-40% w/v, v/v/w/w ammonia, and a soluble salt at a concentration range of 0.01%-10% wt or v/v or w/v, the soluble salt having cations selected from the group of group IA, IIA, IIIA and IVA metals with counter anions selected from the group of anion of group VIIA elements, NO3?, SO42?, OH?, PO43? and HCO3?. The invention also extends to a CO2 capture solvent comprising an aqueous ammonia solution and the above soluble salt.
    Type: Grant
    Filed: February 21, 2011
    Date of Patent: December 17, 2013
    Assignee: Commonwealth Scientific and Industrial Research Organisation
    Inventors: Phil Jackson, Moetaz Ibrahim Attalla, Benjamin Jack Ballinger
  • Patent number: 8603226
    Abstract: An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution of A) at least one cyclic amine compound having solely tertiary amine groups and/or sterically hindered secondary amine groups and B) at least one cyclic amine compound having at least one sterically unhindered secondary amine group. The absorption medium comprises, e.g., an aqueous solution of A) 1-hydroxyethylpiperidine and/or triethylenediamine and B) piperazine. The absorption medium is particularly suitable for separating off carbon dioxide from flue gases and satisfies the following criteria: (i) sufficient capacity at low CO2 partial pressures; (ii) sufficiently rapid absorption rate at low CO2 partial pressures; (iii) stability toward oxygen; (iv) low vapor pressure for reducing solvent losses; and (v) low energy requirement for regeneration of the absorption medium.
    Type: Grant
    Filed: February 2, 2010
    Date of Patent: December 10, 2013
    Assignee: BASF SE
    Inventors: Hugo Rafael Garcia Andarcia, Ute Lichtfers, Georg Sieder, Oliver Spuhl, Steven Brughmans
  • Patent number: 8597412
    Abstract: A CO2 recovery apparatus according to the present invention includes: an absorber (1003) that brings CO2-containing flue gas (1001A) into counter-current contact with CO2 absorbent (1002) to reduce CO2, and a regenerator (1005) that regenerates rich solution (1004) that has absorbed CO2, in which lean solution (1006) having CO2 reduced in the regenerator (1005) is reused in the absorber (1003). The absorber (1003) further includes a CO2 absorbing unit (1010) that recovers CO2 contained in the flue gas (1001A), and the CO2 absorbent (1002) that has absorbed CO2 is extracted from a rich side of the CO2 absorbing unit (1010) to exterior, cooled, and then supplied to a position nearer to a lean side of the absorber (1003) with respect to the position at which the CO2 absorbent (1002) is extracted.
    Type: Grant
    Filed: February 20, 2009
    Date of Patent: December 3, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Ltd.
    Inventors: Hiroshi Tanaka, Toru Takashina, Tsuyoshi Oishi, Masaki Iijima, Tomio Mimura, Kouki Ogura, Yasuyuki Yagi
  • Patent number: 8597418
    Abstract: An absorbent according to the present invention absorbs CO2 or H2S contained in flue gas emitted from a power generating plant such as a thermal plant, and contains three or more amine compounds selected from linear or cyclic amine compounds having a primary amino group, and linear or cyclic amine compounds having a secondary amino group. By way of a synergetic effect of the mixture of these compounds, the absorption speed of CO2 or H2S absorption is improved. A small amount of CO2 contained in a large amount of boiler flue gas can be absorbed efficiently.
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: December 3, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Yukihiko Inoue, Ryuji Yoshiyama, Tsuyoshi Oishi, Masaki Iijima, Masazumi Tanoura, Tomio Mimura, Yasuyuki Yagi
  • Publication number: 20130312607
    Abstract: The present invention relates to the use of (poly)-oxymethylene dialkyl ethers as agents for capturing carbon oxides, CO and/or CO2. The invention also relates to the process for capturing carbon oxides using at least one absorption agent chosen from said (poly)oxymethylene dialkyl ethers.
    Type: Application
    Filed: October 18, 2011
    Publication date: November 28, 2013
    Applicant: Arkema France
    Inventors: Dominique Plee, Georges Fremy
  • Patent number: 8591626
    Abstract: The invention relates to a method as well as a device for separation of a carbon-dioxide-containing gas mixture (1), whereby carbon dioxide is separated from the carbon-dioxide-containing gas mixture (1) by physical gas washing (W1) and is converted into two product streams (3, 4) that consist primarily of carbon dioxide and have different pressures, and in the event of an operational breakdown, after their pressures are balanced, the product streams are subjected to an after-treatment step (W2) and then are released into the atmosphere. For balancing the pressures of the two carbon dioxide product streams (3, 4), the carbon dioxide stream (3, 7) that has the lower pressure is compressed by a gas jet ventilator (G), whereby the carbon dioxide stream (4) that has the higher pressure is used as a pumping medium (6).
    Type: Grant
    Filed: November 3, 2011
    Date of Patent: November 26, 2013
    Assignee: Linde Aktiengesellschaft
    Inventor: Alexander Brandl
  • Patent number: 8591846
    Abstract: A method and apparatus for processing a sour gas rich in carbon dioxide in a Claus process, so sulfur compounds are removed by a selective solvent in a gas scrubbing process. Sulfur components and carbon dioxide, are separated into at least two sour gas fractions, wherein at least one sour gas fraction having a higher content of sulfur components is obtained, wherein the fraction having the highest hydrogen sulfide content is introduced in the thermal reaction stage of the Claus furnace with a gas containing oxygen by means of a burner. The sulfur is converted to sulfur dioxide in the thermal reaction stage of the Claus furnace and exhaust gases are discharged into the closed Claus reaction chamber behind the burner. The remaining sour gas fractions stripped of sulfur components are fed to the Claus reaction chamber and are mixed with the combustion gases leaving the burner.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: November 26, 2013
    Assignee: Thyssenkrupp UHDE GmbH
    Inventor: Johannes Menzel
  • Patent number: 8591631
    Abstract: A method of assembling an acid gas component reduction system includes coupling at least one acid removal system in flow communication with at least one first synthetic gas (syngas) stream with at least one acid gas component having a first acid gas component concentration. The method also includes coupling at least one integral absorber in flow communication with the at least one acid removal system. The method further includes configuring the at least one integral absorber such that substantially continuous service of the at least one integral absorber facilitates producing a second syngas stream having a second acid gas component concentration that is less than the first acid gas component concentration.
    Type: Grant
    Filed: July 31, 2007
    Date of Patent: November 26, 2013
    Assignee: General Electric Company
    Inventors: Sachin Naphad, Pradeep Thacker
  • Patent number: 8585802
    Abstract: An energy-efficient method of recovering carbon dioxide (CO2) in a high-pressure liquid state from a high-pressure gas stream. The method includes cooling, condensing, and/or separating CO2 from a high-pressure gas stream in two or more separation zones and further purifying the resulting sub-critical pressure liquid CO2 streams in a third purification zone to thereby provide purified CO2. The purified liquid CO2 may be pumped to above the critical pressure for further utilization and/or sequestration for industrial or environmental purposes.
    Type: Grant
    Filed: July 7, 2011
    Date of Patent: November 19, 2013
    Inventor: Arnold Keller
  • Patent number: 8585810
    Abstract: Provided is an apparatus for regenerating a carbon dioxide absorption solution that regenerates an absorption solution for absorbing carbon dioxide contained in a combustion exhaust gas emitted during a combustion process of a vehicle, thereby reducing energy costs while simplifying its configuration.
    Type: Grant
    Filed: February 18, 2011
    Date of Patent: November 19, 2013
    Assignees: Hyundai Motor Company, Kia Motors Corporation
    Inventor: Yoon Ji Lee
  • Patent number: 8568520
    Abstract: In an embodiment, a CO2 recovery system has an absorber, a regenerator, and a circulation device. An absorption liquid has an aqueous solution of amine having an alcohol group, and dimethyl silicone oil in which a part of methyl groups is substituted by at least one type selected from an aminoalkyl group, a carboxyl group, and a hydroxyl-containing alkyl group. The absorber contacts a combustion exhaust gas of a fossil fuel and the absorption liquid to absorb CO2, which is contained in the combustion exhaust gas, into the absorption liquid. The regenerator releases CO2 by applying thermal energy to the CO2-absorbed absorption liquid. A circulation device circulates the absorption liquid between the absorber and the regenerator.
    Type: Grant
    Filed: October 5, 2010
    Date of Patent: October 29, 2013
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Yukio Ohashi, Takashi Ogawa, Susumu Yamanaka, Katsuya Yamashita
  • Patent number: 8568676
    Abstract: A process for workup of an industrial carbon dioxide-rich gas to be freed of sulfur components, in which an industrial gas to be freed of sulfur components is purified by a gas scrubbing, and the laden solvent is freed of carbon dioxide and hydrogen sulfide by a regeneration to obtain at least one acid gas fraction having a relatively high content of sulfur components, and the fraction with the highest hydrogen sulfide (H2S) content is supplied to a Claus plant with downstream Claus process gas hydrogenation, and at least one carbon dioxide-laden, low-hydrogen sulfide acid gas fraction from the regeneration device, which has a reduced sulfur content compared to the fraction with the highest hydrogen sulfide (H2S) content, is combined with the hydrogenated Claus process gas to give a combined process gas stream, which is supplied to further processing or to recycling into the process.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: October 29, 2013
    Assignee: Thyssenkrupp Uhde GmbH
    Inventor: Johannes Menzel
  • Patent number: 8562719
    Abstract: A gas purification system including a hydrogen sulfide (H2S) absorber, a carbon dioxide (CO2) absorber, a flash tank, and a H2S concentrator. The gas purification system may also include a gas path though the H2S absorber prior to the CO2 absorber, a first solvent path sequentially through the CO2 absorber, the H2S absorber, and the H2S concentrator, and a second solvent path sequentially through the CO2 absorber, the flash tank, and the H2S concentrator, wherein the first and second solvent paths flow a common solvent.
    Type: Grant
    Filed: July 6, 2010
    Date of Patent: October 22, 2013
    Assignee: General Electric Company
    Inventors: Anindra Mazumdar, Judith Pauline Oppenheim
  • Patent number: 8557205
    Abstract: A method and corresponding apparatus for separation of carbon dioxide from an exhaust gas of a fossil-fired power are provided. In an absorption process, the exhaust gas containing carbon dioxide is brought into contact with an absorption medium so that the absorption medium is laden with carbon dioxide. In a desorption process, vapor from a water/steam circuit of the fossil-fired power plant is heated, wherein a laden absorption medium is regenerated. In a subsequent expansion process, the regenerated absorption medium is expanded so that a vapor and an expanded absorption medium are formed, wherein the vapor is recirculated into the desorption process. The laden absorption medium is divided into a first part stream and a second part stream. Only the second part stream is brought into heat-exchanging contact with the expanded absorption medium. The first and second part streams are supplied to the desorption process at different process stages.
    Type: Grant
    Filed: November 5, 2009
    Date of Patent: October 15, 2013
    Assignee: Siemens Aktiengesellschaft
    Inventors: Peter Richter, Rüdiger Schneider, Henning Schramm
  • Patent number: 8551221
    Abstract: Carbon Dioxide capture processes utilizing ammonia, or ammonia in water as the capture fluid for carbon dioxide generate concentrated solutions of ammonium carbonate species in water, which are subsequently decomposed to capture the carbon dioxide and recycle the ammonia. Forward osmosis processes utilize ammonium carbonate species as draw solutions to pull water from saline solutions such as seawater in the ammonium carbonate solution. The ammonium carbonate solution is then heated to decompose the ammonium carbonate to ammonia and CO2 which are both reused, while a portion of the aqueous stream is recovered as pure water. Combination of carbon capture process with an integrated forward osmosis process provide great economies over standalone operations. Furthermore, the very high concentrations of ammonium carbonate provide a further opportunity to include osmotic power recovery cycles with the integrated forward osmosis and carbon capture process.
    Type: Grant
    Filed: November 1, 2010
    Date of Patent: October 8, 2013
    Inventor: Thomas D. Wolfe
  • Patent number: 8551435
    Abstract: This invention provides novel processes utilizing compositions comprising substituted polyamines as acid gas scrubbing solutions and methods of using the compositions in an industrial system. The invention relates to the use of such polyamine compounds in industrial processes to remove acidic contaminants from natural and industrial fluid streams, such as natural gas, combustion gas, natural gas, synthesis gas, biogas, and other industrial fluid streams. The compositions and methods of the invention are useful for removal, absorption, or sequestration of acidic contaminants and sulfide contaminants including CO2, H2S, RSH, CS2, COS, and SO2.
    Type: Grant
    Filed: February 15, 2012
    Date of Patent: October 8, 2013
    Assignee: Nalco Company
    Inventors: Alan M. Blair, Keith N. Garside, William J. Andrews, Kailas B. Sawant
  • Publication number: 20130255496
    Abstract: An ionic liquid solvent and gas purification method using the same are provided. The ionic liquid solvent consists of a main absorbent, a regulator for the main absorbent, an auxiliary absorbent, an activator, an antioxidant and water. The ionic liquid involves a low synthetic cost, low viscosity and high absorption capacity, and can be easily regenerated and recycled. The method, compared with traditional processes, has advantages such as a greater absorption capability and lower operation cost.
    Type: Application
    Filed: September 26, 2010
    Publication date: October 3, 2013
    Applicant: INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMY
    Inventors: Xiangping Zhang, Yansong Zhao, Shaojuan Zeng, Suojiang Zhang, Haifeng Dong, Yingpeng Zhen, Lei Huang
  • Patent number: 8545782
    Abstract: A CO2 recovery apparatus includes a desulfurization tower which includes a desulfurization unit and a cooling unit, an absorption tower which includes a CO2 absorption unit and an acid washing unit, a regeneration tower, and an acid water production device configured to produce acid water by causing exhaust gas yet to be introduced into the desulfurization to come into contact with water. In the CO2 recovery apparatus, the water to be come in contact with the exhaust gas is condensed water that is generated in the desulfurization tower, the absorption tower, or the regeneration tower.
    Type: Grant
    Filed: October 16, 2012
    Date of Patent: October 1, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Tatsuya Tsujiuchi, Shintaro Honjo, Takahito Yonekawa, Satoru Sugita
  • Patent number: 8540803
    Abstract: A method and apparatus for drying a natural gas or an industrial gas that contains acidic gas components, wherein gas drying is followed by the removal of the acidic gas components from the dried gas. The same physical solvent is used for both of the process steps of gas drying and of acidic gas removal. The gas to be dried is brought into contact with the physical solvent, which absorbs most of the water contained in the gas. The physical solvent, loaded with water, is transferred into a solvent regenerating device to be heated where the water contained in the solvent is stripped from the solvent in the countercurrent by acidic gas that is removed from the dried useful gas during the acidic gas absorption. The acidic gas being released again in the acidic gas solvent regenerating device, stripped from the solvent, and discharged from the solvent regenerating device.
    Type: Grant
    Filed: September 22, 2010
    Date of Patent: September 24, 2013
    Assignee: ThyssenKrupp Uhde GmbH
    Inventor: Johannes Menzel
  • Patent number: 8541622
    Abstract: This invention provides novel compositions comprising substituted polyamines as acid gas scrubbing solutions and methods of using the compositions in an industrial system. The invention relates to the use of such polyamine compounds in industrial processes to remove acidic contaminants from natural and industrial fluid streams, such as natural gas, combustion gas, natural gas, synthesis gas, biogas, and other industrial fluid streams. The compositions and methods of the invention are useful for removal, absorption, or sequestration of acidic contaminants and sulfide contaminants including CO2, H2S, RSH, CS2, COS, and SO2.
    Type: Grant
    Filed: June 30, 2009
    Date of Patent: September 24, 2013
    Assignee: Nalco Company
    Inventors: Alan M. Blair, Keith N. Garside, William J. Andrews, Kailas B. Sawant
  • Patent number: 8535419
    Abstract: A modular amine plant having a front-end module and a back-end module in fluid communication with each other. The front-end module having pre-fabricated connections for the association of various equipment including: a filter, an absorption tower, and a flash tank. The back-end module having pre-fabricated connections for the association of other various equipment including: a heat exchanger, a distillation tower, and a reboiler. The modular amine plant capable of being installed at a site in less than about 5 days. The modular amine plant further having moment forces sufficient to withstand wind speeds of about 100 miles per hour.
    Type: Grant
    Filed: April 1, 2010
    Date of Patent: September 17, 2013
    Assignee: Zephyr Gas Services LLC
    Inventors: Glen Wind, John Kenton Thompson, Lance Perryman
  • Patent number: 8535425
    Abstract: A separation and scrubbing system for exhaust gases includes a plurality of industrial discharge outlets, a separation unit, pipelines to direct exhaust gases from the industrial discharge outlets to the separation unit and pipelines to return treated exhaust gases to stacks corresponding to the industrial discharge outlets.
    Type: Grant
    Filed: May 22, 2009
    Date of Patent: September 17, 2013
    Inventors: Quinn D. Rebryna, Ron E. Cookson
  • Patent number: 8535418
    Abstract: A method of removing gaseous byproducts from a gas stream includes generating via at least one partial-combustion device a gas stream that includes gaseous byproducts. The method also includes channeling the gas stream from the at least one partial-combustion device to a fluid compression device that is configured to increase a pressure of the gas stream. The method further includes channeling the gas stream to a gaseous byproducts removal system to absorb at least a portion of the gaseous byproducts from the gas stream using a solvent. The method also includes discharging at least a portion of the gaseous byproducts from the gaseous byproducts removal system.
    Type: Grant
    Filed: November 22, 2010
    Date of Patent: September 17, 2013
    Assignee: General Electric Company
    Inventors: Asiff Apdul Supahan, Ganesh Prasadh Kidambi, Rajalakshmi Vengadasamy, Richard A. DePuy
  • Patent number: 8535428
    Abstract: To include an absorber (1006) that brings CO2 absorbent that absorbs CO2 contained in flue gas (1002) into contact with the flue gas to remove CO2 from the flue gas, a regenerator (1008) that strips CO2 from CO2 absorbent (rich solution), which is fed from the absorber through a first feed line L1 and has absorbed CO2, to regenerate CO2 absorbent, thereby acquiring regenerated CO2 absorbent (lean solution) (1009), falling film reboilers (1101-1 and 1101-2) that draw off CO2 absorbent (amine solution) (1033) from near the bottom of the regenerator and reheats regenerated CO2 absorbent via steam (1031), a first liquid-vapor separator (1103) that separates the CO2 absorbent reheated by the falling film reboilers into regenerated CO2 absorbent in which CO2 has been removed and vapor containing CO2, and a second feed line L2 for supplying the separated regenerated CO2 absorbent to the absorber.
    Type: Grant
    Filed: January 26, 2009
    Date of Patent: September 17, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Katsufumi Inoue, Takashi Kamijo, Tsuyoshi Oishi, Takahito Yonekawa, Hiroshi Tanaka
  • Patent number: 8523979
    Abstract: A process for removing acid gases from a fluid stream in which a) the fluid stream is treated with an absorption liquid which comprises at least one amine, a stripping aid, and water, wherein the stripping aid is selected from water-miscible liquids, the boiling temperature of which at atmospheric pressure is lower than that of water, b) the treated fluid stream is treated with a liquid aqueous phase in order to convert entrained stripping aid at least in part to the aqueous phase, c) the loaded aqueous phase is heated in order to expel the stripping aid at least in part, and d) the regenerated aqueous phase is cooled and at least in part recycled to step b). The stripping aid promotes the regeneration of the absorbent by stripping. Emissions of the stripping aid via the treated fluid stream are avoided by the treated fluid stream being scrubbed with a liquid aqueous phase.
    Type: Grant
    Filed: June 21, 2010
    Date of Patent: September 3, 2013
    Assignee: BASF SE
    Inventors: Hugo Rafael Garcia Andarcia, Ralf Notz, Georg Sieder, Oliver Spuhl, Hans Hasse, Inga Toennies, Sebastian Hoch, Hari Prasad Mangalapally
  • Patent number: 8523978
    Abstract: A method of deacidizing a gaseous effluent comprising acid compounds where the gaseous effluent is contacted in C1 with an adsorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. The absorbent solution laden with acid compounds is then heated in E1 and E3 so as to separate two fractions: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds. These two fractions are then separated in BS1. The second fraction is regenerated in C2 so as to release part of the acid compounds, and the first absorbent solution fraction and the regenerated absorbent solution are recycled as absorbent solution.
    Type: Grant
    Filed: March 9, 2007
    Date of Patent: September 3, 2013
    Assignee: Institut Francais du Petrole
    Inventors: Alexandre Rojey, Renaud Cadours, Pierre-Louis Carrette, Pierre Boucot
  • Patent number: 8518148
    Abstract: A method and system for dehumidifying flue gas from a flue gas-generating process that supplies the flue gas to a wet flue gas processor. A wet cooling tower supplies water to a wet flue gas processor to condense water from the flue gas and form a liquid mixture in the wet flue gas processor.
    Type: Grant
    Filed: July 8, 2011
    Date of Patent: August 27, 2013
    Assignee: Babcock & Wilcox Power Generation Group, Inc.
    Inventors: Dennis K. McDonald, Douglas J. DeVault, Paul J. Williams
  • Patent number: 8518155
    Abstract: A method and apparatus for removing carbon dioxide from a synthesis gas stream containing hydrogen is disclosed. The method includes absorbing the carbon dioxide using a physical solvent under high pressure and then liberating the carbon dioxide in a series of expansion stages where the pressure on the solvent is reduced. The expansion ratio increases with each expansion stage. The apparatus includes expansion stages having throttling devices and expansion tanks operated at increasing expansion ratios. Carbon dioxide is liberated in this manner so as to minimize the energy required compress for transport via a pipe line for sequestration of the gas. Sequestration of the carbon dioxide is preferred to atmospheric venting to curb the release of greenhouse gases.
    Type: Grant
    Filed: March 16, 2007
    Date of Patent: August 27, 2013
    Assignee: Air Products and Chemicals, Inc.
    Inventors: John Eugene Palamara, Kevin Boyle Fogash
  • Patent number: 8518156
    Abstract: A process and system (100) for removing contaminants from a solution to regenerate the solution within the system. The process includes providing a solution (165) from a wash vessel (160) to a stripping column (181), the solution (165) including contaminants removed from a flue gas stream (150) present in the wash vessel (160) and contacting the solution with steam (185) inside the stripping column (181) thereby removing the contaminants from the solution and regenerating the solution. The stripping column (181) is operated at a pressure less than about 700 kilopascal.
    Type: Grant
    Filed: August 3, 2010
    Date of Patent: August 27, 2013
    Assignee: ALSTOM Technology Ltd
    Inventors: Frederic Z. Kozak, Arlyn V. Petig, Ritesh Agarwal, Rameshwar S. Hiwale
  • Patent number: 8512448
    Abstract: A multi-stage scrubbing system comprises a pre-scrubber system structured to receive a vent stream therein and pre-scrub the vent stream with a pre-scrubber fluid. The pre-scrubber system includes a first outlet for discharging a pre-scrubbed vent stream and a second outlet for discharging a discharge stream of pre-scrubber fluid. A main scrubber system is fluidly coupled to the first outlet of the pre-scrubber system for receiving and further scrubbing the pre-scrubbed vent stream.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: August 20, 2013
    Assignee: Integroenergy Group, Inc.
    Inventors: Daniel W. Sonnek, Gregory W. Loest
  • Patent number: 8512445
    Abstract: The present invention relates to systems and processes for reducing the amount of carbon dioxide in a carbon dioxide-containing gas. In particular, the carbon dioxide-containing gas is contacted with a carbonate-containing solution. At least a portion of carbon dioxide in the carbon dioxide-containing gas is absorbed in the carbonate-containing solution to produce a carbon dioxide-, carbonate-containing solution. A heat recovery mechanism is employed to recover heat from the carbon dioxide-, bicarbonate-, carbonate-containing solution exiting the chamber to maintain the temperature of the chamber within a range of from about 50° C. to about 90° C.
    Type: Grant
    Filed: June 23, 2010
    Date of Patent: August 20, 2013
    Inventors: Shiaoguo Chen, Zijiang Pan
  • Patent number: 8512446
    Abstract: A method is provided that includes removing carbon dioxide from untreated syngas received from a gasifier to produce a gas stream comprising carbon dioxide, modifying the gas stream by adding carbon monoxide, hydrogen, hydrogen sulfide, or any combination thereof, and providing the gas stream from an acid gas remover to a feed system for use as a conveyance gas to convey a feedstock into the gasifier. Systems implementing these and other methods are also provided.
    Type: Grant
    Filed: July 22, 2010
    Date of Patent: August 20, 2013
    Assignee: General Electric Company
    Inventors: Anindra Mazumdar, John Saunders Stevenson, Sunil Ramabhilakh Mishra
  • Patent number: 8506683
    Abstract: An absorbent liquid according to the present invention is an absorbent liquid for absorbing CO2 or H2S or both from gas, in which the absorbent liquid includes an alkanolamine as a first compound component, and a second component including a nitrogen-containing compound having in a molecule thereof two members or more selected from a primary nitrogen, a secondary nitrogen, and a tertiary nitrogen or a nitrogen-containing compound having in a molecule thereof all of primary, secondary, and tertiary nitrogens. The absorbent liquid has an excellent absorption capacity performance and an excellent absorption reaction heat performance, as compared to an aqueous solution containing solely an alkanolamine and a nitrogen-containing compound in the same concentration in terms of wt %, and can recover CO2 or H2S or both from gas with smaller energy.
    Type: Grant
    Filed: June 11, 2010
    Date of Patent: August 13, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Ryuji Yoshiyama, Masazumi Tanoura, Noriko Watari, Shuuji Fujii, Yukihiko Inoue, Mitsuru Sakano, Tarou Ichihara, Masaki Iijima, Tomio Mimura, Yasuyuki Yagi, Kouki Ogura
  • Patent number: 8506680
    Abstract: Systems and techniques for the reclamation from boiler flue gas of all or substantially all gaseous substances for well injection oil recovery. A system can include one or more of a boiler for generating high pressure steam, a high pressure water pump, a tower scrubber, an induced draft fan, an absorber, a separating tank, a heat exchanger, a regenerator, a reboiler, a steam boiler, a water segregator, a carbon dioxide compressor, a purifier, a nitrogen compressor, drying beds, adsorption beds, a carbon dioxide pressurizer, a nitrogen pressurizer and a mixing tank of which: the boiler for generating high pressure steam, the tower scrubber, the absorber, the regenerator and the adsorption beds connect with each other in turn. In addition, the mixing tank connects by pipelines with a gas injection tube of an oil well. Mixed gases of carbon dioxide and nitrogen can be obtained for injection into the oil well, thus gaining favorable results of crude oil output increase as well as environment protection.
    Type: Grant
    Filed: November 14, 2007
    Date of Patent: August 13, 2013
    Assignee: Liaohe Petroleum Exploration Bureau, CNPC
    Inventors: Fengshan Zhang, Yuanwen Gao
  • Patent number: 8500892
    Abstract: CO2 is absorbed from a gas mixture by bringing the gas mixture into contact with an absorbent that comprises water and at least one amine of the formula (I), wherein R1 and R2, independently of each other, are hydrogen or an alkyl group. According to the invention, absorption media comprise sulfolane or an ionic liquid in addition to water and an amine of the formula (I). A device according to the invention for removing CO2 from a gas mixture comprises an absorption unit, a desorption unit, and an absorption medium according to the invention that is conducted in the circuit.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: August 6, 2013
    Assignee: Evonik Degussa GmbH
    Inventors: Matthias Seiler, Jörn Rolker, Rolf Schneider, Bernd Glöckler, Axel Kobus, Wolfgang Benesch, Thomas Riethmann, Hermann Winkler, Jens Reich, Helmut Brüggemann
  • Patent number: 8501130
    Abstract: A method for recovering CO2 from gas to be processed containing CO2, includes bringing the gas to be processed containing CO2 and CO2 absorbent into contact with each other to absorb and remove CO2 from the gas to be processed; cleaning the treated gas from which CO2 has been removed with washing fluid at least once; heating the absorbent which has absorbed CO2, separating and removing CO2 gas from the absorbent and regenerating the absorbent; cooling the separated CO2 gas to condense moisture contained in the gas to obtain condensed water; and monitoring changes in concentration of the CO2 absorbent contained in the condensed water and depending on the value of the measured concentration, controlling supply of the condensed water so that the condensed water is reused as a part of the washing fluid or a part of the CO2 absorbent.
    Type: Grant
    Filed: September 24, 2012
    Date of Patent: August 6, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Tatsuya Tsujiuchi, Shintaro Honjo, Takahito Yonekawa, Satoru Sugita
  • Patent number: 8500867
    Abstract: CO2 is absorbed from a gas mixture by bringing the gas mixture into contact with an absorbent that comprises water and at least one amine of the formula (I), wherein R1 and R2, independently of each other, are hydrogen or an alkyl group. According to the invention, absorption media comprise sulfolane or an ionic liquid in addition to water and an amine of the formula (1). A device according to the invention for removing CO2 from a gas mixture comprises an absorption unit, a desorption unit, and an absorption medium according to the invention that is conducted in the circuit.
    Type: Grant
    Filed: August 19, 2012
    Date of Patent: August 6, 2013
    Assignee: Evonik Degussa GmbH
    Inventors: Matthias Seiler, Jörn Rolker, Rolf Schneider, Bernd Glöckler, Axel Kobus, Wolfgang Benesch, Thomas Riethmann, Hermann Winkler, Jens Reich, Helmut Brüggemann
  • Patent number: 8500865
    Abstract: The gaseous effluent to be treated is contacted in C1 with an absorbent solution selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. According to the invention, the absorbent solution is regenerated in at least two stages in regeneration zones Z1 and Z2. At the end of the first regeneration stage in Z1, at least part of the partly regenerated absorbent solution is separated into two fractions in B1: a fraction rich in acid compounds and a fraction depleted in acid compounds. Fraction 10 rich in acid compounds is sent to the second regeneration stage in Z2. The fraction depleted in acid compounds and regenerated absorbent solution 6 from the second regeneration stage are recycled to absorption column C1. The method can be applied to combustion fumes decarbonation and to natural gas or synthesis gas deacidizing.
    Type: Grant
    Filed: November 20, 2009
    Date of Patent: August 6, 2013
    Assignee: IFP
    Inventors: Pierre-Antoine Bouillon, Marc Jacquin, Alain Methivier
  • Patent number: 8500891
    Abstract: A system and process for capturing CO2 100 is disclosed. The process 100 includes reusing heat from a CO2 compression process 120 by providing the heat to a fuel treatment process 130. The heat may used to dry a fossil fuel to improve the efficiency of the fossil fuel combustion.
    Type: Grant
    Filed: May 7, 2010
    Date of Patent: August 6, 2013
    Assignee: ALSTOM Technology Ltd
    Inventors: John Oliver Butler, Rasesh R. Kotdawala
  • Patent number: 8500866
    Abstract: Upon cooling to 15 to 45° C., a process for the treatment of raw product gas generated by pressure gasification of solid fuels comprises the removal of HCN and NH3 in a preliminary stage, of H2S and COS and possibly other sulfur-containing compounds in a first stage and of CO2 in a second stage by physisorption with cold oxygenate, and the pure product gas is supplied to the direct reduction of iron ore as reduction gas and/or as fuel gas. An improvement of the process consists in that recycle gas loaded with CO2 and steam, which is branched off from the circuit of the recycle gas of the direct reduction of iron ore, is admixed to the desulfurized product gas upon removal of the steam contained therein.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: August 6, 2013
    Assignee: Lurgi Clean Coal Technology (Proprietary) Limited
    Inventor: Gerhard Schmitt