And Liquid Contact (e.g., Scrubbing, Sorption, Etc.) Patents (Class 95/92)
-
Patent number: 8337589Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.Type: GrantFiled: October 13, 2010Date of Patent: December 25, 2012Assignee: Kilimanjaro Energy, Inc.Inventors: Allen B. Wright, Klaus S. Lackner, Ursula Ginster
-
Patent number: 8328910Abstract: A method of remediating at least a portion of a building that contains defective drywall is presented. The method comprises removal of the defective drywall and cross-contaminated drywall, actively desorbing volatile compounds from the building materials exposed after removal of the drywall and passively desorbing remaining contaminants by depositing a film of an absorbent on the accessible surfaces of the exposed building materials. Active desorbing of volatiles can be carried out with forced thermal desorption, where the interior surfaces of the building are heated while the air is removed and replaced with air free of the volatile compounds. The absorbent for passive desorption can be a nanoparticulate metal oxide.Type: GrantFiled: January 21, 2011Date of Patent: December 11, 2012Inventor: Spiderman Mulholland
-
Publication number: 20120304857Abstract: A contaminant is removed from a gas in a method in which the gas is contacted with a solvent for the contaminant, and the resultant solution is contacted with intercalated graphite onto which the contaminant is adsorbed. The solvent will normally comprise water, and may itself be a contaminated liquid. In a preferred method the solvent is in a reservoir with particulate intercalated graphite; the contaminated gas is delivered to the base of the reservoir; and the gas rises in the solvent mobilizing the intercalated graphite in the reservoir.Type: ApplicationFiled: June 7, 2012Publication date: December 6, 2012Applicant: ARVIA TECHNOLOGY LIMITEDInventors: Nigel Willis Brown, Edward P. L. Roberts
-
Publication number: 20120276616Abstract: The method and system for methane separation and purification from a biogas includes collecting a raw Biogas gas stream having methane, carbon dioxide, water, sulfur compounds and non-methane organic compound (NMOC) constituents. The Biogas stream is fed into the intake of a liquid sulfur scrubber or a sulfur adsorber unit where the Biogas is separated into a main gas stream routed downstream in the system and a sulfur compounds stream removed from the system. The main gas stream is then processed by an NMOC absorber and further downstream, by an NMOC adsorber. NMOC produced by both NMOC processes is liquefied, removed from the system and stored. Upstream from the NMOC processes, the main gas stream is processed by at least one CO2, N2, O2 gas separation unit that produces a usable product stream of enriched methane gas, and an off-gas stream, which a VPSAU processes for venting and recycling.Type: ApplicationFiled: April 29, 2011Publication date: November 1, 2012Inventors: STANLEY M. SIEGEL, DENNIS C. SIEGEL
-
Publication number: 20120263634Abstract: A process of treating a gas stream containing at least one mercury compound or species, the process comprising: applying a composition into said gas stream ahead of a particulate matter collection device, wherein said composition contains a compound having the following formula (SiO2)x(OH)yMzSaF, wherein (i) SiO2 is an optional component; (ii) M comprises at least one of the following : boron, magnesium, aluminum, calcium, titanium, vanadium, manganese, iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, palladium, silver, cadmium, tin, platinum, gold, and bismuth; (iii) S comprises a sulfur-based species selected from at least one of the following: sulfide salts, dithiocarbamates, polymer-based dithiocarbamates, and polysulfide salts; (iii) F is an optional component and comprises at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane.Type: ApplicationFiled: October 7, 2011Publication date: October 18, 2012Inventors: Nicholas S. Ergang, Bruce A. Keiser, Richard Mimna
-
Publication number: 20120247330Abstract: An apparatus for capture and sequestration of CO2 from fossil fuel-fired power plant flue gas includes a polymer matrix embedded with a sorbent suitable for removing CO2 from the flue gas and a spacer mated with the polymer matrix. The spacer is adapted to create channels between adjacent portions of the polymer matrix such that the flue gas flows through the channels and comes in contact with the sorbent. Further, an apparatus for the capture and sequestration of CO2 from fossil fuel-fired power plant flue gas includes a hollow fiber membrane embedded with an adsorbent or other suitable material for removing CO2 from the flue gas. The adsorbent particles may be embedded into a wall of the membrane.Type: ApplicationFiled: March 30, 2011Publication date: October 4, 2012Applicant: ELECTRIC POWER RESEARCH INSTITUTE, INC.Inventors: Ramsay Chang, Adam Berger, Abhoyjit Bhown
-
Patent number: 8273160Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.Type: GrantFiled: October 13, 2010Date of Patent: September 25, 2012Assignee: Kilimanjaro Energy, Inc.Inventors: Allen B. Wright, Klaus S. Lackner, Ursula Ginster
-
Patent number: 8262774Abstract: Disclosed is a process for forming a CO2 capture element comprises providing a mixture of a monomer or monomer blend or a polymer binder, a miscible liquid carrier for the binder and a CO2 sorbent or getter in particle form, forming the mixture into a wet film or membrane, evaporating the liquid carrier to form a film or membrane, and treating the wet film or membrane to form pores in the body of the film or membrane. Also disclosed is a process of forming a CO2 capture element which comprises the steps of applying a mixture including a sorbent material and a polymer to an underlying material; polymerizing the mixture in place on the material; and aminating the polymer-coated material.Type: GrantFiled: November 20, 2008Date of Patent: September 11, 2012Assignee: Kilimanjaro Energy, Inc.Inventor: Ping Liu
-
Patent number: 8241399Abstract: A method of generating heat from a gas stream includes providing a first gas stream having a first temperature and a moisture content approximately saturating the gas stream, removing the moisture content from the first gas stream to form a second gas stream having a second temperature greater than the first temperature of the first gas stream, and heat exchanging the second gas stream having the second temperature greater than the first temperature of the first gas stream.Type: GrantFiled: May 16, 2009Date of Patent: August 14, 2012Inventor: Walter Albers
-
Patent number: 8231711Abstract: Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The sorbent composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.Type: GrantFiled: August 30, 2011Date of Patent: July 31, 2012Assignee: J. I. Enterprises, Inc.Inventor: Joseph Iannicelli
-
Patent number: 8221526Abstract: The invention relates to a method for purifying or separating a supply gas flow containing at least one impurity, in which: a) said supply gas flow is contacted with a first adsorbent for the adsorption-removal of at least one said impurity; b) recovering said purified or separated gas; c) heating a regeneration gas containing at least hydrogen (H2) and carbon monoxide (CO) using a heater having a skin temperature (T1) of between 150° C. and 200° C. during the gas heating phase; and d) periodically regenerating the adsorbent of step a) with the regeneration gas heated during step c) at a regeneration temperature (T2) such that: T2=T1??T with 5° C.<?T<50° C.Type: GrantFiled: December 11, 2007Date of Patent: July 17, 2012Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Christian Monereau, Guillaume Rodrigues, Simon Jallais
-
Publication number: 20120132071Abstract: An air purification system comprises a chamber having an air inlet and an air outlet, a plurality of flexible wires hanging from a ceiling of the chamber, a spray mechanism configured to spray droplets in the chamber, and a sound wave generator configured to generate a standing sound wave in the chamber. During operation of the air purification system, the plurality of flexible wires are elastically deformed by the standing sound wave generated by the sound wave generator such that portions of the plurality of flexible wires converge at nodes of the sound wave, and also the droplets move to the nodes of the standing sound wave, while trapping particles in the air during the movement to the nodes. The droplets collide against and are adsorbed to the plurality of flexible wires at the nodes of the sound wave.Type: ApplicationFiled: November 26, 2010Publication date: May 31, 2012Applicant: Empire Technology Development LLCInventor: Takahisa Kusuura
-
Publication number: 20120107202Abstract: The present invention provides a process for minimizing the emission of particulate matter and precursors thereof from a flue gas stream of an engine comprising particulate matter and precursors thereof and at least one gaseous component, which process comprises the steps of: a. Obtaining a flue gas stream of an engine comprising particulate matter and precursors thereof; b. Increasing the moisture content of the stream by contacting the same with a first aqueous medium in an amount and at a temperature at which at least 50% of the water content of the first aqueous medium is evaporated; whereby a moisture laden gas stream, optionally containing suspension droplets, is formed; c. Cooling the moisture laden gas stream whereby suspension droplets are formed; and d.Type: ApplicationFiled: October 1, 2009Publication date: May 3, 2012Inventors: Riki Canari, Aharon Eyal, Nils Christian Hoy-Petersen, Matitiahu Fichman, Carl Christian Hauge, Carmi Raz
-
Publication number: 20110319697Abstract: Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The sorbent composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.Type: ApplicationFiled: August 30, 2011Publication date: December 29, 2011Inventor: Joseph Iannicelli
-
Publication number: 20110252967Abstract: A method and arrangement for removing solid particles and tar component from carbon monoxide gas. In the method, carbon monoxide gas is conducted from a ferroalloy smelting furnace (1) to a gas scrubber (2), the carbon monoxide gas is scrubbed in the gas scrubber (2) by a liquid medium for removing part of the solid particles, the carbon monoxide gas is conducted from the gas scrubber to a blower (3), the flow rate of the carbon monoxide gas is increased by the blower (3), and the carbon monoxide gas is conducted to a particulate filter (5) and the remaining solid particles are essentially filtered in the particulate filter (5) from the carbon monoxide gas.Type: ApplicationFiled: December 21, 2009Publication date: October 20, 2011Applicant: OUTOTEC OYJInventors: Tom Ronnberg, Stefan Hajek
-
Publication number: 20110250110Abstract: A process of treating a gas stream containing mercury is disclosed.Type: ApplicationFiled: April 8, 2010Publication date: October 13, 2011Inventors: Bruce A. Keiser, Nicholas S. Ergang, Richard Mimna
-
Publication number: 20110247494Abstract: A method for sorbing a gas using an ionic liquid to sorb a vapor having an electric multi-pole moment. The ionic liquid comprises an anion and a cation. The electric multi-pole moment may be an electric dipole moment and/or an electric quadru-pole moment. The sorption may be an adsorption or an absorption. The ionic liquid may be a liquid that substantially contains only anions and cations, while not containing other components, such as water. Alternatively, a solution containing the ionic liquid and a solvent or further compound, such as water, may be used.Type: ApplicationFiled: June 22, 2011Publication date: October 13, 2011Applicant: VTU Holding GmbH.Inventors: Paul DINNAGE, Roland KALB
-
Publication number: 20110185900Abstract: A method of remediating at least a portion of a building that contains defective drywall is presented. The method comprises removal of the defective drywall and cross-contaminated drywall, actively desorbing volatile compounds from the building materials exposed after removal of the drywall and passively desorbing remaining contaminants by depositing a film of an absorbent on the accessible surfaces of the exposed building materials. Active desorbing of volatiles can be carried out with forced thermal desorption, where the interior surfaces of the building are heated while the air is removed and replaced with air free of the volatile compounds. The absorbent for passive desorption can be a nanoparticulate metal oxide.Type: ApplicationFiled: January 21, 2011Publication date: August 4, 2011Inventor: SPIDERMAN MULHOLLAND
-
Publication number: 20110189075Abstract: The present disclosure provides a method for removing carbon dioxide from a gas stream without consuming excess energy, wherein a solid sorbent material is used to capture the carbon dioxide. The solid sorbent material may utilize a water-swing for regeneration. Various geometric configurations are disclosed for advantageous recovery of CO2 and regeneration of the sorbent material.Type: ApplicationFiled: June 4, 2009Publication date: August 4, 2011Inventors: Allen B. Wright, Klaus S. Lackner, Ryuhei Ishikawa
-
Patent number: 7964017Abstract: A gas flow system and method are provided for controlling the moisture in a gas flow. The system may include a gas source from which gas flows, a processing chamber to which the gas flows, and a gas flow line through which the gas flows from the gas source to the processing chamber. The gas flow line may include a moisture control line section. The moisture control line section includes a pass-through line through which the gas may pass, so as to be exposed to a dryer. The exposure to a dryer may be controlled by a suitable valve. A scrubber is disposed in the gas flow line, the scrubber removing contaminates from the gas in the gas flow. The system may include a moisture sensor disposed in the gas flow, the moisture sensor sensing at least one parameter of the gas and outputting a signal representing the at least parameter to a moisture sensor controller, such that the moisture sensor controller determines the moisture in the gas.Type: GrantFiled: May 5, 2006Date of Patent: June 21, 2011Assignee: General Dynamics Armament and Technical Products, Inc.Inventor: John Petinarides
-
Publication number: 20110100213Abstract: A method, system, and apparatus including a compressed air energy storage system that includes an ambient air intake configured to intake a quantity of ambient air for storage in a compressed air storage volume, a compression system having a compression path that is configured to convey air compressed by the compression system through the compression system, a first path configured to convey ambient air to the compression system, a second path proceeding from the compression system to the compressed air storage volume and configured to convey compressed air to the compressed air storage volume, and a dehumidifying system. The dehumidifying system is coupleable to at least one of the first path that proceeds from the ambient air intake to the compression system, the compression path, and the second path. The dehumidifying system includes a dehumidifying component configured to remove moisture from the ambient air and/or the compressed air.Type: ApplicationFiled: October 30, 2009Publication date: May 5, 2011Inventors: Matthias Finkenrath, Cristina Botero, Sebastian W. Freund, Clarissa S.K. Belloni, Miguel Angel Gonzalez Salazar, Stephanie Marie-Noelle Hoffmann
-
Patent number: 7931723Abstract: A panel filter for removal of contaminants from a gas, the panel filter having at least one V-pocket formed of two halves, each half composed of multiple pleats of filter media. The pleats extend generally parallel, often at an angle of less than 5 degrees or even less than 1 degree, to the overall filtration path, so that air or gas to the filtered passes through the pleats in a generally straight manner, with minimal bends. Each pleat has two legs of different length. The panel filter provides improved dust collection and retention while restricting pressure drop.Type: GrantFiled: March 7, 2007Date of Patent: April 26, 2011Assignee: Donaldson Company, Inc.Inventor: Leon Robert Cuvelier
-
Publication number: 20110083554Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.Type: ApplicationFiled: October 13, 2010Publication date: April 14, 2011Inventors: Allen B. Wright, Klaus S. Lackner, Ursula Ginster
-
Publication number: 20110079144Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.Type: ApplicationFiled: October 13, 2010Publication date: April 7, 2011Inventors: Allen B. Wright, Klaus S. Lackner, Ursula Ginster
-
Publication number: 20110081710Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.Type: ApplicationFiled: October 13, 2010Publication date: April 7, 2011Inventors: Allen B. Wright, Klaus S. Lackner, Ursula Ginster
-
Publication number: 20110079146Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.Type: ApplicationFiled: October 13, 2010Publication date: April 7, 2011Inventors: Allen B. Wright, Klaus S. Lackner, Ursula Ginster
-
Publication number: 20110079147Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.Type: ApplicationFiled: October 13, 2010Publication date: April 7, 2011Inventors: Allen B. Wright, Klaus S. Lackner, Ursula Ginster
-
Patent number: 7862644Abstract: A scrubber that employs a dry chemical medium includes a first vessel defining a first cavity. A second vessel adjoining the first vessel defines a second cavity, and the first and second cavities combine to form a common chamber. A fan draws a gaseous stream into the chamber at a first location and extracts the gaseous stream from the chamber at a second location. A plurality of partitions extend substantially from the upper end of the chamber to the floor. A dry chemical medium is disposed within the spaces between the partitions for neutralizing a pollutant in a gaseous stream. The partitions have openings of a sufficiently large size to permit gas to flow therethrough but of a sufficiently small size to prevent the dry chemical medium from passing therethrough. A method for converting a wet scrubber to a dry scrubber of the type described is also disclosed.Type: GrantFiled: June 22, 2007Date of Patent: January 4, 2011Assignee: Purafil, Inc.Inventor: Michael DelGais
-
Patent number: 7850761Abstract: There is provided an apparatus for highly purifying nitric oxide by removing impurities included in nitric oxide, which comprises: a number of dehumidifiers connected to one another in a series, to remove water and carbon dioxide from the nitric oxide; a vaporizing and liquefying unit for respectively separating impurities into a gaseous state and a liquid state by cooling the nitric oxide which passed through the dehumidifiers at sub-zero temperatures; a storage tank for storing highly purified nitric oxide separated by the vaporizing and liquefying unit; an exhaust pump for discharging gaseous impurities, separated by the vaporizing and liquefying unit, to a scrubber; an outlet for discharging liquid impurities, separated by the vaporizing and liquefying unit, to the scrubber; and the scrubber 50 for purifying the gaseous and liquid impurities.Type: GrantFiled: March 23, 2007Date of Patent: December 14, 2010Assignee: Wonikmurtrealize Co., Ltd.Inventors: Jun-Youl Lee, Bong-Soo Seo
-
Publication number: 20100300287Abstract: A slurried solid media for simultaneous water purification and carbon dioxide removal from gas mixtures includes the steps of dissolving the gas mixture and carbon dioxide in water providing a gas, carbon dioxide, water mixture; adding a porous solid media to the gas, carbon dioxide, water mixture forming a slurry of gas, carbon dioxide, water, and porous solid media; heating the slurry of gas, carbon dioxide, water, and porous solid media producing steam; and cooling the steam to produce purified water and carbon dioxide.Type: ApplicationFiled: May 21, 2010Publication date: December 2, 2010Inventors: Roger D. Aines, William L. Bourcier, Brian Viani
-
Patent number: 7819942Abstract: The invention relates to a method for producing a high-molecular polyester from a solidified polyester prepolymer by solid phase polycondensation. The polycondensation cleavage products of the solid phase polycondensation reaction are extracted from the product by means of a process gas, and the process gas is then cleaned and essentially recycled. According to the invention, the process gas is cleaned by means of an aqueous washing liquid. The invention also relates to an installation for carrying out the inventive method, said installation containing a crystallisation appliance (1) and a reaction appliance (2). A gas outlet (2d) of the reaction appliance (2) is directly or indirectly connected to a gas inlet (3c) in a gas cleaning system (3), and a gas outlet (3d) of the gas cleaning system (3) is connected to a gas inlet (2c) of the reaction appliance (2).Type: GrantFiled: August 22, 2005Date of Patent: October 26, 2010Assignee: Buhler AGInventors: Andreas Christel, Claudemiro Ferreira
-
Publication number: 20100251890Abstract: A contaminant is removed from a gas in a method in which the gas is contacted with a solvent for the contaminant, and the resultant solution is contacted with intercalated graphite onto which the contaminant is adsorbed. The solvent will normally comprise water, and may itself be a contaminated liquid. In a preferred method the solvent is in a reservoir with particulate intercalated graphite; the contaminated gas is delivered to the base of the reservoir; and the gas rises in the solvent mobilizing the intercalated graphite in the reservoir.Type: ApplicationFiled: April 15, 2010Publication date: October 7, 2010Inventors: Nigel Willis Brown, Edward P.L. Roberts
-
Patent number: 7799120Abstract: A carbon dioxide storage system includes a container and a conduit attached to the container for introducing or removing a carbon dioxide-containing composition from the container. A carbon dioxide storage material is positioned within the container. The carbon dioxide-storage material includes a metal-organic framework, which has a sufficient surface area to store at least 10 carbon dioxide molecules per formula unit of the metal-organic framework at a temperature of about 25° C.Type: GrantFiled: September 26, 2006Date of Patent: September 21, 2010Assignee: The Regents of the University of MichiganInventors: Omar M. Yaghi, Andrew Robert Millward
-
Patent number: 7794523Abstract: The present invention relates to methods and systems for processing an exhaust stream containing a recyclable component mixed with other components and impurities to produce a high purity product that contains all of the recyclable component. One or more waste streams containing none of the recyclable component are also produced. The present invention particularly relates to the recovery of valuable recyclable components used in the manufacture of semiconductor devices.Type: GrantFiled: November 14, 2006Date of Patent: September 14, 2010Assignee: Linde LLCInventor: Walter H. Whitlock
-
Publication number: 20100218676Abstract: Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The sorbent composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.Type: ApplicationFiled: May 18, 2010Publication date: September 2, 2010Applicant: J.I. Enterprises, Inc.Inventor: Joseph Iannicelli
-
Publication number: 20100212493Abstract: The present application is directed to a method and system for preparing gaseous utility streams from gaseous process streams, nitrogen process streams, and other types of streams. The methods and systems may include at least one swing adsorption process including pressure swing adsorption, temperature swing adsorption, and rapid-cycle adsorption processes to treat gaseous streams for use in dry gas seals of rotating equipment such as compressors, turbines and pumps and for other utilities. The systems and processes of the present disclosure are further applicable to high pressure gaseous streams, for example, up to about 600 bar.Type: ApplicationFiled: October 14, 2008Publication date: August 26, 2010Inventors: Peter C. Rasmussen, Paul L. Tanaka, Bruce T. Kelley, Stanley O. Uptigrove, Harry W. Deckman
-
Publication number: 20100192770Abstract: An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution of A) at least one cyclic amine compound having solely tertiary amine groups and/or sterically hindered secondary amine groups and B) at least one cyclic amine compound having at least one sterically unhindered secondary amine group. The absorption medium comprises, e.g., an aqueous solution of A) 1-hydroxyethylpiperidine and/or triethylenediamine and B) piperazine. The absorption medium is particularly suitable for separating off carbon dioxide from flue gases and satisfies the following criteria: (i) sufficient capacity at low CO2 partial pressures; (ii) sufficiently rapid absorption rate at low CO2 partial pressures; (iii) stability toward oxygen; (iv) low vapor pressure for reducing solvent losses; and (v) low energy requirement for regeneration of the absorption medium.Type: ApplicationFiled: February 2, 2010Publication date: August 5, 2010Applicant: BASF SEInventors: Hugo Rafael Garcia Andarcia, Ute Lichtfers, Georg Sieder, Oliver Spuhl, Steven Brughmans
-
Publication number: 20100197984Abstract: The invention provides a process for removing COS and H2S from a feed synthesis gas stream comprising COS and H2S, the process comprising contacting the feed synthesis gas stream with solid adsorbent at a temperature in the range of from 100 to 240° C. to remove carbonyl sulphide and hydrogen sulphide, thereby obtaining a purified synthesis gas stream, wherein the solid adsorbent comprises one or more metals or oxides of the metals or combinations thereof and the metals are selected from the group of Ag, Sn, Mo, Fe and Zn.Type: ApplicationFiled: January 17, 2007Publication date: August 5, 2010Inventors: Rudolf Henri Max Herold, Thijme Last, Bernardus Josephus Maria Manshande, Cornelis Jacobus Smit
-
Patent number: 7727307Abstract: A method of removing mercury from flue gases from combustion plants, such as for example power plants or waste incineration plants, is achieved in which mercury-containing flue gases are brought into contact with an adsorption reagent either directly or indirectly by being contained in an absorption reagent, whereby mercury is substantially adsorbed by the adsorption reagent during this contact. After adsorption has occurred the adsorption reagent is separated from the flue gases and subsequently from the absorption reagent and added to an aqueous solution containing an oxidizing agent, whereby the adsorbed mercury dissolves as Hg2+. The Hg2+-containing solution is subsequently separated from the adsorption agent and the Hg2+ then is removed from the solution. This method enables the mercury to be removed from flue gas in a simple and economical manner.Type: GrantFiled: April 14, 2008Date of Patent: June 1, 2010Assignee: Evonik Energy Services GmbHInventor: Hermann Winkler
-
Patent number: 7722704Abstract: The present invention provides a nitrogen oxide removal equipment, a nitrogen oxide removal method, a container used for the removal of nitrogen oxide, and a method for filling the container. A nitrogen oxide removal equipment 94 according to the present invention supplies gas with the unevenness of flowing amounts eased to an absorption unit 94a via a gas rectification means 108 for supplying gas to a large-area side of solid absorbent layers, the absorption unit 94a being provided with solid absorbent layers including a plurality of low-profile solid absorbents 95 constituting the nitrogen oxide absorption means. Nitrogen oxide contained in gas effectively passes through the solid absorbent layers and removed.Type: GrantFiled: January 14, 2005Date of Patent: May 25, 2010Assignee: Nishimatsu Construction Co., Ltd.Inventors: Tamotsu Nishi, Tadahiko Itoh, Tsutomu Tanaka
-
Publication number: 20100107872Abstract: A process and apparatus for treating a biogas stream. The treatment is both to increase methane content and reduce H2S content, said process comprising at least, (i) taking a biogas stream having both a methane and carbon dioxide content and including an H2S content, (ii) scrubbing the stream (with or without prior modification, e.g. any one or more of compression, partition, stripping, flashing, recycle in part, etc.), (iii) drying the wet stream from step (ii) stream, and (iv) removing H2S from step (iii) stream to a level below 0.005%.Type: ApplicationFiled: March 6, 2008Publication date: May 6, 2010Inventor: Warwick James Bethell
-
Publication number: 20100107871Abstract: A fluoride ion cleaning method includes generating hydrogen fluoride (HF) gas in-situ in a cleaning retort; contacting a part in need of cleaning with the generated HF gas; scrubbing an initial effluent stream in-situ to substantially remove residual HF gas therefrom; and passing the scrubbed effluent gas stream out of the cleaning retort. In an exemplary method, a liquid or gaseous halogenated feedstock is introduced into a cleaning retort; hydrogen gas is introduced into the cleaning retort, HF gas is generated by a reaction of the feedstock with hydrogen gas at a sufficient temperature. In an exemplary method, only HF gas generated in-situ or reconstituted in-situ is utilized in the cleaning process.Type: ApplicationFiled: October 31, 2008Publication date: May 6, 2010Inventor: Thomas E. Mantkowski
-
Patent number: 7708815Abstract: Embodiments of the invention relate to a composite hydrogen storage material comprising active material particles and a binder, wherein the binder immobilizes the active material particles sufficient to maintain relative spatial relationships between the active material particles.Type: GrantFiled: April 24, 2006Date of Patent: May 4, 2010Assignee: Angstrom Power IncorporatedInventor: Joerg Zimmermann
-
Publication number: 20100101412Abstract: An alkyl halide such as methyl bromide can be effectively removed from a gas stream by passing the gas stream through a bed of adsorbent at a relatively low temperature to adsorb the alkyl halide onto the adsorbent, desorbing the alkyl halide at a higher temperature to produce a smaller volume of gas containing the alkyl halide in more concentrated form, and then reacting the alkyl halide with a nucleophile contained in a liquid phase by contacting this smaller gas volume with such liquid phase.Type: ApplicationFiled: October 23, 2008Publication date: April 29, 2010Applicant: Value Recovery, Inc.Inventors: Peter J. Joyce, Roman Bielski
-
Publication number: 20100031819Abstract: The invention relates to a method for purifying or separating a supply gas flow containing at least one impurity, in which: a) said supply gas flow is contacted with a first adsorbent for the adsorption-removal of at least one said impurity; b) recovering said purified or separated gas; c) heating a regeneration gas containing at least hydrogen (H2) and carbon monoxide (CO) using a heater having a skin temperature (T1) of between 150° C. and 200° C. during the gas heating phase; and d) periodically regenerating the adsorbent of step a) with the regeneration gas heated during step c) at a regeneration temperature (T2) such that: T2=T1??T with 5° C.<?T<50° C.Type: ApplicationFiled: December 11, 2007Publication date: February 11, 2010Inventors: Christian Monereau, Guillaume Rodrigues, Simon Jallais
-
Publication number: 20100031818Abstract: A method and apparatus for treating a coal combustion flue gas. In one embodiment, the method includes injecting a halogen into a flue gas, and injecting partially combusted, carbon enriched alkaline coal ash solid particles into the flue gas ahead of a particulate collection device. In another embodiment, the method includes exposing partially combusted, carbon enriched alkaline coal ash solid particles to a halogen containing atmosphere, and injecting the halogen atmosphere treated alkaline carbon containing solid particles into the flue gas ahead of a particulate collection device.Type: ApplicationFiled: June 19, 2007Publication date: February 11, 2010Inventors: Brian S. Higgins, Klaus Oehr, Eric Fischer
-
Patent number: 7655069Abstract: An air/liquid exchanger comprising an open-cell foam 102 supporting a liquid sorbent. The exchanger may be used for removing trace gaseous components from the air.Type: GrantFiled: February 2, 2006Date of Patent: February 2, 2010Assignee: Global Research Technologies, LLCInventors: Allen B. Wright, Klaus S. Lackner, Eddy J. Peters
-
Publication number: 20090320678Abstract: Methods and apparatuses are described for removing a contaminant, such as a vaporous trace metal contaminant like mercury, from a gas stream. In one embodiment, a primary particulate collection device that removes particulate matter is used. In this embodiment, a sorbent filter is placed within the housing of the primary particulate collection device, such as an electrostatic precipitator or a baghouse, to adsorb the contaminant of interest. In another embodiment, a sorbent filter is placed within or after a scrubber, such as a wet scrubber, to adsorb the contaminant of interest. In some embodiments, the invention provides methods and apparatuses that can advantageously be retrofit into existing particulate collection equipment. In some embodiments, the invention provides methods and apparatuses that in addition to removal of a contaminant additionally remove particulate matter from a gas stream.Type: ApplicationFiled: March 25, 2009Publication date: December 31, 2009Applicant: Electric Power Research Institute, Inc.Inventors: Ramsay Chang, Charles E. Dene, Larry Scot Monroe, Mark Simpson Berry, M. Brandon Looney
-
Publication number: 20090293720Abstract: A method device and material for performing adsorption wherein a fluid mixture is passed through a channel in a structured adsorbent bed having a solid adsorbent comprised of adsorbent particles having a general diameter less than 100 um, loaded in a porous support matrix defining at least one straight flow channel. The adsorbent bed is configured to allow passage of a fluid through said channel and diffusion of a target material into said adsorbent under a pressure gradient driving force. The targeted molecular species in the fluid mixture diffuses across the porous support retaining layer, contacts the adsorbent, and adsorbs on the adsorbent, while the remaining species in the fluid mixture flows out of the channel.Type: ApplicationFiled: June 10, 2008Publication date: December 3, 2009Inventor: Wei Liu
-
Publication number: 20090294368Abstract: Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The sorbent composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.Type: ApplicationFiled: August 7, 2009Publication date: December 3, 2009Applicant: J.I. Enterprises, Inc.Inventor: Joseph Iannicelli