Gas And Liquid Contact Apparatus For Gas Separation Including Means To Regenerate, Purify, Or Separate Contact Liquid Patents (Class 96/234)
  • Patent number: 8728210
    Abstract: An exhaust gas treatment apparatus comprises an ammonia absorption system and an ammonia conversion system. The ammonia absorption receives ammonia-containing tail gas generated by a semiconductor process, and removes dust from the tail gas, absorbs and decomposes ammonia gas from the tail gas, converts the ammonia gas into aqueous ammonia, and emits the tail gas without the dust and the ammonia to an external environment. The ammonia conversion system receives the ammonia solution from the ammonia absorption system, and converts it into gaseous ammonia, and then converts the gaseous ammonia to produce liquid ammonia by vaporization and cooling-pressurized liquefaction. After that, the liquid ammonia is purified by a purification system to formed hi-purity liquid ammonia.
    Type: Grant
    Filed: July 6, 2012
    Date of Patent: May 20, 2014
    Inventor: Hsueh Yuan Lee
  • Patent number: 8728209
    Abstract: A method for reducing energy requirements of a CO2 capture system comprises: contacting a flue gas stream with a CO2 lean absorbent stream in an absorber, thereby removing CO2 from the flue gas and providing a CO2 rich absorbent stream; heating a first portion of the CO2 rich absorbent stream using heat from the CO2 lean absorbent stream, and providing the heated first portion of the CO2 rich absorbent stream to a regenerator; providing a second portion of the CO2 rich absorbent stream to the regenerator, wherein the heated first portion is hotter than the second portion and the heated first portion is provided to the regenerator at a lower elevation in the regenerator relative to that of the second portion.
    Type: Grant
    Filed: August 2, 2011
    Date of Patent: May 20, 2014
    Assignee: ALSTOM Technology Ltd
    Inventors: Joseph P. Naumovitz, Michael Koch
  • Patent number: 8728220
    Abstract: A CO2 recovery system according to the present invention includes: a cooling tower that uses cooling water to cool a CO2-containing exhaust gas discharged from industrial equipment such as a boiler or a gas turbine; a CO2 absorber that brings the cooled CO2-containing exhaust gas into contact with a CO2-absorbent that absorbs CO2, thereby removing the CO2 from the exhaust gas; and a first absorbent regenerator and a second absorbent regenerator that release CO2 from a CO2-absorbent that has absorbed CO2 (rich solution), thereby regenerating the CO2-absorbent. A second lean solution at the outlet of the second absorbent regenerator is subjected to vacuum flash vaporization, and the resulting vapor is inputted to the first absorbent regenerator.
    Type: Grant
    Filed: July 27, 2011
    Date of Patent: May 20, 2014
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Masaki Iijima, Masahiko Tatsumi, Yasuyuki Yagi
  • Publication number: 20140134710
    Abstract: Systems and methods are presented for the purification of a biogas. The systems comprise: a gas processor for reducing CO2, volatile organic compounds, and H2S in the biogas, the gas processor comprising a scrubber tank and a scrubber liquid; and a scrubber liquid processor in fluid connection with the gas processor for reducing the amount of absorbed gas in the scrubber liquid. The scrubber liquid processor comprises a stripper tank, and is configured to reduce or eliminate airflow through the stripper tank.
    Type: Application
    Filed: November 9, 2012
    Publication date: May 15, 2014
    Inventor: Jeffrey J. Grill
  • Patent number: 8715402
    Abstract: To include a boiler 11 that burns fuel F, an air heater 13 that recovers heat of flue gas 18 from the boiler 11, a first precipitator 14 that reduces dust in the flue gas 18 after heat recovery, a desulfurizer 15 that reduces sulfur oxides in the flue gas 18 after dust reduction by an absorbent, a dewaterer 32 that reduces gypsum 31 from desulfurization discharged water 30 discharged from the desulfurizer 15, a spray drying device 34 including an atomizer that atomizes a dewatering filtration fluid 33 discharged from the dewaterer 32, and a flue-gas introducing line L11 that introduces a part of the flue gas 18 into the spray drying device 34.
    Type: Grant
    Filed: May 31, 2011
    Date of Patent: May 6, 2014
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Nobuyuki Ukai, Seiji Kagawa, Tatsuto Nagayasu, Naoyuki Kamiyama, Toshihiro Fukuda
  • Publication number: 20140116252
    Abstract: The proposed invention relates to a gas/liquid contacting vessel (100) for treatment of a gas stream at varying mass flow rates, said vessel comprising at least two distinct gas/liquid contacting compartments (101a, 101b) separated from each other by a substantially vertical partition (102), each compartment having a gas inlet (104a, 104b) and a liquid outlet (110a, 110b) near a bottom end thereof and a gas outlet (106a, 106b) and a liquid inlet (108a, 108b) near a top end thereof, and a mass transfer device (111a, 111b) arranged between said bottom end and top end, wherein one of said compartments is operable for gas/liquid contacting independently of another of said compartments. The proposed invention further relates to a flue gas treatment system for removal of carbon dioxide (CO2) from a flue gas using a liquid absorbent and to a power plant comprising such a gas/liquid contacting vessel or flue gas treatment system.
    Type: Application
    Filed: May 1, 2012
    Publication date: May 1, 2014
    Applicant: ALSTOM TECHNOLOGY LTD
    Inventors: Richard Carroni, Gian-Luigi Agostinelli, Ulrich Koss
  • Patent number: 8702852
    Abstract: The present invention relates to a condensation and washing device with which in particular the process vapors which occur during the production of polylactide can be processed and cleaned. Furthermore, the present invention relates to a polymerization device for the production of polylactide and also to a method for processing process vapors which occur during the production of polylactide; possibilities for use of both the condensation and washing devices and of the method are likewise mentioned.
    Type: Grant
    Filed: April 29, 2013
    Date of Patent: April 22, 2014
    Assignee: Uhde Inventa-Fischer GmbH
    Inventors: Rainer Hagen, Udo Muhlbauer
  • Patent number: 8696798
    Abstract: Acid gas is removed from a feed gas using a physical solvent that is regenerated using successive flashing stages after heating of the rich solvent using low-level waste heat that is preferably produced or available within the acid gas removal plant. Especially preferred waste heat sources include compressor discharges of the refrigeration system and/or recompression system for CO2, and/or (low level) heat content from the feed gas.
    Type: Grant
    Filed: September 30, 2009
    Date of Patent: April 15, 2014
    Assignee: Fluor Technologies Corporation
    Inventor: John Mak
  • Patent number: 8696804
    Abstract: A carbon dioxide storage means stores the carbon dioxide released in a heat exchanger. The heat exchanger cools the exhaust gas emitted by the internal combustion engine, and includes a thermal electric generator (TEG) configured to couple thermally the exhaust gas chamber to the absorber fluid chamber in a manner effective to heat the CO2 absorbent fluid by heat from the engine exhaust to release CO2 gas from the CO2 absorbent fluid and generate electricity in response to a temperature difference therebetween. The CO2 absorbent fluid is one of: a) an aliphatic di-functional nitrile (e.g. pimelonitrile); and b) an oligomeric poly-acrylonitrile (PAN).
    Type: Grant
    Filed: April 12, 2013
    Date of Patent: April 15, 2014
    Assignee: Delphi Technologies, Inc.
    Inventors: David W. Ihms, Bruce A. Myers
  • Publication number: 20140076166
    Abstract: A carbon dioxide recovery unit is provided with: an absorption tower for bringing an exhaust gas into contact with a CO2 absorbing liquid to thereby absorb and recover CO2 from the exhaust gas; a regeneration tower for taking out the CO2 from the CO2 absorbing liquid; a CO2 delivery line L3 for delivering the taken-out CO2 to a storage process; and a CO2 return line L5 for returning the taken-out CO2 to the absorption tower. When a CO2 recovery unit and a CO2 compressing device are activated, if a storage process side has some kind of trouble and cannot receive the CO2, a destination part to which the CO2 is delivered from the regeneration tower is switched from the CO2 delivery line L3 to the CO2 return line L5, whereby the CO2 gas is mixed with the exhaust gas in the absorption tower.
    Type: Application
    Filed: September 20, 2012
    Publication date: March 20, 2014
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Koji Nakayama, Takahito Yonekawa, Masayuki Inui, Tatsuya Tsujiuchi, Yoshiki Sorimachi
  • Publication number: 20140053731
    Abstract: Horizontal duct scrubbing systems for removing particulate matter from a gas are disclosed. The horizontal scrubbing systems may receive a particulate-containing gas stream (e.g., containing PM10 and/or PM2.5 particulate matter), and remove at least some of such particulates by spraying liquid droplets co-current to the flow of the gas stream, where the liquid droplets have a volume median droplet diameter (DV0.5) of from 240 microns to 600 microns. The scrubbing system may be substantially free of flow deflection members between a liquid inlet manifold and a demister. The system may be remove at least 50 wt. % PM10 and/or PM2.5 particulate matter from the gas stream.
    Type: Application
    Filed: March 14, 2013
    Publication date: February 27, 2014
    Applicant: ALCOA INC.
    Inventors: Rajat S. Ghosh, Neal Richard Dando, Jay N. Bruggeman
  • Patent number: 8657929
    Abstract: Presented is a method and apparatus for treating an exhaust gas. A series of filters and conditioning units are used to separate and extract various substances from the exhaust gas, typically originating from an industrial process. In an exemplary embodiment, a cyclone filter, a ceramic filter, a baghouse filter, and a pair of gas conditioners are used to initially separate and extract iron-rich dust from an exhaust gas and then extract zinc from the gas.
    Type: Grant
    Filed: February 19, 2013
    Date of Patent: February 25, 2014
    Assignee: Arcelormittal Investigacion y Desarrollo
    Inventor: Naiyang Ma
  • Patent number: 8628603
    Abstract: A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: January 14, 2014
    Assignee: Energy & Enviromental Research Center Foundation
    Inventors: Christopher L. Martin, Ye Zhuang
  • Patent number: 8623123
    Abstract: CO2 is absorbed from a gas mixture by bringing the gas mixture into contact with an absorbent that comprises water and at least one amine of the formula (I), wherein R1 and R2, independently of each other, are hydrogen or an alkyl group. According to the invention, absorption media comprise sulfolane or an ionic liquid in addition to water and an amine of the formula (I). A device according to the invention for removing CO2 from a gas mixture comprises an absorption unit, a desorption unit, and an absorption medium according to the invention that is conducted in the circuit.
    Type: Grant
    Filed: June 4, 2013
    Date of Patent: January 7, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Matthias Seiler, Jöm Rolker, Rolf Schneider, Bernd Glöckler, Axel Kobus, Wolfgang Benesch, Thomas Riethmann, Hermann Winkler, Jens Reich, Helmut Brüggemann
  • Publication number: 20130319236
    Abstract: A scrubber system for treating exhaust gas in a marine vessel with a water based solution includes a first scrubber unit and a second scrubber unit, an exhaust gas inlet in the first scrubber unit and an exhaust gas outlet in the second scrubber unit and a second conduit section connecting the first scrubber unit to the second scrubber unit, a first scrubbing medium circuit and a second scrubbing medium circuit. The first scrubber medium circuit is provided with a source of scrubbing solution having a first connection to an outside of a hull of the vessel beneath the water line of the vessel and the second scrubber medium circuit is provided with a source of scrubbing solution having a source of fresh water in the vessel.
    Type: Application
    Filed: February 15, 2012
    Publication date: December 5, 2013
    Applicant: Wartsila Finland Oy
    Inventor: Ari Suominen
  • Patent number: 8597418
    Abstract: An absorbent according to the present invention absorbs CO2 or H2S contained in flue gas emitted from a power generating plant such as a thermal plant, and contains three or more amine compounds selected from linear or cyclic amine compounds having a primary amino group, and linear or cyclic amine compounds having a secondary amino group. By way of a synergetic effect of the mixture of these compounds, the absorption speed of CO2 or H2S absorption is improved. A small amount of CO2 contained in a large amount of boiler flue gas can be absorbed efficiently.
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: December 3, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Yukihiko Inoue, Ryuji Yoshiyama, Tsuyoshi Oishi, Masaki Iijima, Masazumi Tanoura, Tomio Mimura, Yasuyuki Yagi
  • Patent number: 8597412
    Abstract: A CO2 recovery apparatus according to the present invention includes: an absorber (1003) that brings CO2-containing flue gas (1001A) into counter-current contact with CO2 absorbent (1002) to reduce CO2, and a regenerator (1005) that regenerates rich solution (1004) that has absorbed CO2, in which lean solution (1006) having CO2 reduced in the regenerator (1005) is reused in the absorber (1003). The absorber (1003) further includes a CO2 absorbing unit (1010) that recovers CO2 contained in the flue gas (1001A), and the CO2 absorbent (1002) that has absorbed CO2 is extracted from a rich side of the CO2 absorbing unit (1010) to exterior, cooled, and then supplied to a position nearer to a lean side of the absorber (1003) with respect to the position at which the CO2 absorbent (1002) is extracted.
    Type: Grant
    Filed: February 20, 2009
    Date of Patent: December 3, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Ltd.
    Inventors: Hiroshi Tanaka, Toru Takashina, Tsuyoshi Oishi, Masaki Iijima, Tomio Mimura, Kouki Ogura, Yasuyuki Yagi
  • Publication number: 20130312614
    Abstract: A separator vessel (5) comprising; a separation chamber (10) arranged to separate liquid from an inflow production fluid (45); at least one gas scrubber (15) for removing entrained liquid from a separated gas inflow from said separation chamber (10); wherein said at least one gas scrubber (15) is positioned above and proximate to said separation chamber (10), said gas scrubber (15) and separation chamber (10) connectable through a vertically oriented at least one liquid outflow conduit (20) arranged to direct the removed entrained liquid from the gas scrubber (15) to the separation chamber (10) wherein the conduit (20) is arranged such that an outflow end (22) of said conduit (20) extends into the separation chamber (10) such that it is lower than a minimum threshold liquid depth (65) in said separation chamber (10).
    Type: Application
    Filed: January 30, 2012
    Publication date: November 28, 2013
    Applicants: PETROLIAM NASIONAL BERHAD (PETRONAS), NGL TECH SDN. BHD.
    Inventors: Shahrul Azman B Zainal Abidin, Arul Jothy
  • Patent number: 8591846
    Abstract: A method and apparatus for processing a sour gas rich in carbon dioxide in a Claus process, so sulfur compounds are removed by a selective solvent in a gas scrubbing process. Sulfur components and carbon dioxide, are separated into at least two sour gas fractions, wherein at least one sour gas fraction having a higher content of sulfur components is obtained, wherein the fraction having the highest hydrogen sulfide content is introduced in the thermal reaction stage of the Claus furnace with a gas containing oxygen by means of a burner. The sulfur is converted to sulfur dioxide in the thermal reaction stage of the Claus furnace and exhaust gases are discharged into the closed Claus reaction chamber behind the burner. The remaining sour gas fractions stripped of sulfur components are fed to the Claus reaction chamber and are mixed with the combustion gases leaving the burner.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: November 26, 2013
    Assignee: Thyssenkrupp UHDE GmbH
    Inventor: Johannes Menzel
  • Publication number: 20130291724
    Abstract: An absorption column 1 for separating CO2 and a second acid gas from a gas stream, the column comprising a first and second section (4, 5) for the absorption of CO2 and the second acid gas; a solvent inlet in the second section for the addition of liquid stream 3 including an absorbent liquid for CO2 and the second acid gas; a gas inlet (21) in the first section for the addition of a gas stream (2) containing CO2 and the second acid gas; a gas outlet (15) in the second section of the column; a first solvent outlet (22) for the removal of at least a portion of the solvent (6) from the second section of the column and a second solvent outlet (23) for solvent stream (11) from the first section of the column; and a liquid flow distributor arrangement (8) to allow a portion of the solvent to flow from the second section of the column to the first section. A method of operating the apparatus and method of solvent extraction is also disclosed.
    Type: Application
    Filed: January 18, 2012
    Publication date: November 7, 2013
    Inventors: Erik Everhardus Bernardus Meuleman, Graeme Puxty, Paul Feron
  • Patent number: 8568520
    Abstract: In an embodiment, a CO2 recovery system has an absorber, a regenerator, and a circulation device. An absorption liquid has an aqueous solution of amine having an alcohol group, and dimethyl silicone oil in which a part of methyl groups is substituted by at least one type selected from an aminoalkyl group, a carboxyl group, and a hydroxyl-containing alkyl group. The absorber contacts a combustion exhaust gas of a fossil fuel and the absorption liquid to absorb CO2, which is contained in the combustion exhaust gas, into the absorption liquid. The regenerator releases CO2 by applying thermal energy to the CO2-absorbed absorption liquid. A circulation device circulates the absorption liquid between the absorber and the regenerator.
    Type: Grant
    Filed: October 5, 2010
    Date of Patent: October 29, 2013
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Yukio Ohashi, Takashi Ogawa, Susumu Yamanaka, Katsuya Yamashita
  • Patent number: 8557205
    Abstract: A method and corresponding apparatus for separation of carbon dioxide from an exhaust gas of a fossil-fired power are provided. In an absorption process, the exhaust gas containing carbon dioxide is brought into contact with an absorption medium so that the absorption medium is laden with carbon dioxide. In a desorption process, vapor from a water/steam circuit of the fossil-fired power plant is heated, wherein a laden absorption medium is regenerated. In a subsequent expansion process, the regenerated absorption medium is expanded so that a vapor and an expanded absorption medium are formed, wherein the vapor is recirculated into the desorption process. The laden absorption medium is divided into a first part stream and a second part stream. Only the second part stream is brought into heat-exchanging contact with the expanded absorption medium. The first and second part streams are supplied to the desorption process at different process stages.
    Type: Grant
    Filed: November 5, 2009
    Date of Patent: October 15, 2013
    Assignee: Siemens Aktiengesellschaft
    Inventors: Peter Richter, Rüdiger Schneider, Henning Schramm
  • Publication number: 20130263743
    Abstract: CO2 is absorbed from a gas mixture by bringing the gas mixture into contact with an absorbent that comprises water and at least one amine of the formula(I), wherein R1 and R2, independently of each other, are hydrogen or an alkyl group. According to the invention, absorption media comprise sulfolane or an ionic liquid in addition to water and an amine of the formula (I). A device according to the invention for removing CO2 from a gas mixture comprises an absorption unit, a desorption unit, and an absorption medium according to the invention that is conducted in the circuit.
    Type: Application
    Filed: June 4, 2013
    Publication date: October 10, 2013
    Inventors: Matthias Seiler, Jöm Rolker, Rolf Schneider, Bernd Glöckler, Axel Kobus, Wolfgang Benesch, Thomas Riethmann, Hermann Winkler, Jens Reich, Helmut Brüggemann
  • Patent number: 8551215
    Abstract: A nitrogen-flush scrubber system for a controlled atmosphere room in which the amount of nitrogen required to flush the regenerated scrubber beds is significantly reduced. The present invention provides a dual-bed scrubber system in which low oxygen air salvaged from the active scrubber bed is used to flush high oxygen air from the regenerated scrubber bed prior to nitrogen flush. The scrubber system may include two scrubber beds that are used alternately to scrub air from the CA room. One scrubber bed is used as an active scrubber bed to remove carbon dioxide from the air. The inactive scrubber bed may be regenerated while it is inactive. When the active scrubber bed becomes sufficiently saturated, the control system may switch the active scrubber bed, using the regenerated bed as the active scrubber bed and allowing the saturated bed to be regenerated.
    Type: Grant
    Filed: June 24, 2011
    Date of Patent: October 8, 2013
    Inventor: James C. Schaefer
  • Patent number: 8545782
    Abstract: A CO2 recovery apparatus includes a desulfurization tower which includes a desulfurization unit and a cooling unit, an absorption tower which includes a CO2 absorption unit and an acid washing unit, a regeneration tower, and an acid water production device configured to produce acid water by causing exhaust gas yet to be introduced into the desulfurization to come into contact with water. In the CO2 recovery apparatus, the water to be come in contact with the exhaust gas is condensed water that is generated in the desulfurization tower, the absorption tower, or the regeneration tower.
    Type: Grant
    Filed: October 16, 2012
    Date of Patent: October 1, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Tatsuya Tsujiuchi, Shintaro Honjo, Takahito Yonekawa, Satoru Sugita
  • Publication number: 20130247758
    Abstract: CO2 is absorbed from a gas mixture by contacting the gas mixture with an absorption medium which comprises at least water as solvent and at least one amine of formula (I) where R1 is an aliphatic radical, having 2 to 6 carbon atoms and at least one amino group, and R2 is hydrogen, a C1-4 alkyl radical or a radical R1.
    Type: Application
    Filed: November 10, 2011
    Publication date: September 26, 2013
    Applicant: Evonik Degussa GmbH
    Inventors: Matthias Seiler, Rolf Schreider, Jörn Rolker, Daniel Dembkowski, Manfred Neumann, Daniel Witthaut, Michael Keup, Volker Brehme, Muhammad Irfan
  • Publication number: 20130247766
    Abstract: In one embodiment, a gas purification system is provided. The system includes a first section having a first solvent path and a first gas path. The first gas path is configured to flow a stripping gas to remove hydrogen sulfide (H2S) and carbon dioxide (CO2) from the first solvent path in a first vessel to produce a first gas mixture. The system also includes a second section having a second solvent path. The second solvent path is configured to flow a second solvent mixture to remove H2S from the first gas mixture and CO2 from the second solvent mixture within a second vessel. The second solvent mixture has a solvent saturated in CO2 at a first pressure, the second vessel is operated at a second pressure, and the first and second pressures are within approximately 20% of one another.
    Type: Application
    Filed: March 23, 2012
    Publication date: September 26, 2013
    Applicant: General Electric Company
    Inventors: Judith Pauline Oppenheim, Anindra Mazumdar
  • Patent number: 8540803
    Abstract: A method and apparatus for drying a natural gas or an industrial gas that contains acidic gas components, wherein gas drying is followed by the removal of the acidic gas components from the dried gas. The same physical solvent is used for both of the process steps of gas drying and of acidic gas removal. The gas to be dried is brought into contact with the physical solvent, which absorbs most of the water contained in the gas. The physical solvent, loaded with water, is transferred into a solvent regenerating device to be heated where the water contained in the solvent is stripped from the solvent in the countercurrent by acidic gas that is removed from the dried useful gas during the acidic gas absorption. The acidic gas being released again in the acidic gas solvent regenerating device, stripped from the solvent, and discharged from the solvent regenerating device.
    Type: Grant
    Filed: September 22, 2010
    Date of Patent: September 24, 2013
    Assignee: ThyssenKrupp Uhde GmbH
    Inventor: Johannes Menzel
  • Patent number: 8535613
    Abstract: A method and an apparatus for separating acidic gases from syngas are capable of reducing the necessary power and are capable of obtaining high-purity CO2 at a high recovery ratio. A purification method and a purification system of coal gasification gas using the method and the apparatus are also provided. An apparatus for separating acidic gases from syngas containing acidic gases of C02 and H2S, in order, converts CO in the syngas into C02, removes H2S contained in the syngas by using a solvent for physical absorption, removes physical solvent from the syngas followed by heating in a heat exchanger using the converted syngas heat, and removes C02 from the heated syngas by using a solvent for chemical absorption.
    Type: Grant
    Filed: October 22, 2009
    Date of Patent: September 17, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Shinji Ogino, Fumiaki Sato, Yudai Kato, Motonari Aihara, Kazuo Ishida, Seiji Kakesako
  • Patent number: 8535427
    Abstract: A CO2 recovery system includes an absorption tower and a regeneration tower. CO2 rich solution is produced in the absorption tower by absorbing CO2 from CO2-containing gas. The CO2 rich solution is conveyed to the regeneration tower where lean solution is produced from the rich solution by removing CO2. A regeneration heater heats lean solution that accumulates near a bottom portion of the regeneration tower with saturated steam thereby producing steam condensate from the saturated steam. A steam-condensate heat exchanger heats the rich solution conveyed from the absorption tower to the regeneration tower with the steam condensate.
    Type: Grant
    Filed: January 25, 2011
    Date of Patent: September 17, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Masaki Iijima, Takashi Kamijo, Takahito Yonekawa, Tomio Mimura, Yasuyuki Yagi
  • Patent number: 8529678
    Abstract: A CO2 recovery system includes an absorption tower and a regeneration tower. CO2 rich solution is produced in the absorption tower by absorbing CO2 from CO2-containing gas. The CO2 rich solution is conveyed to the regeneration tower where lean solution is produced from the rich solution by removing CO2. A regeneration heater heats lean solution that accumulates near a bottom portion of the regeneration tower with saturated steam thereby producing steam condensate from the saturated steam. A steam-condensate heat exchanger heats the rich solution conveyed from the absorption tower to the regeneration tower with the steam condensate.
    Type: Grant
    Filed: January 25, 2011
    Date of Patent: September 10, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Masaki Iijima, Takashi Kamijo, Takahito Yonekawa, Tomio Mimura, Yasuyuki Yagi
  • Patent number: 8518155
    Abstract: A method and apparatus for removing carbon dioxide from a synthesis gas stream containing hydrogen is disclosed. The method includes absorbing the carbon dioxide using a physical solvent under high pressure and then liberating the carbon dioxide in a series of expansion stages where the pressure on the solvent is reduced. The expansion ratio increases with each expansion stage. The apparatus includes expansion stages having throttling devices and expansion tanks operated at increasing expansion ratios. Carbon dioxide is liberated in this manner so as to minimize the energy required compress for transport via a pipe line for sequestration of the gas. Sequestration of the carbon dioxide is preferred to atmospheric venting to curb the release of greenhouse gases.
    Type: Grant
    Filed: March 16, 2007
    Date of Patent: August 27, 2013
    Assignee: Air Products and Chemicals, Inc.
    Inventors: John Eugene Palamara, Kevin Boyle Fogash
  • Publication number: 20130205998
    Abstract: Carbon dioxide is removed from a source gas stream by admission to a vessel containing a quantity of a material preferentially absorbing carbon dioxide. The carbon dioxide content of an escaping gas stream is monitored. When the carbon dioxide content of the escaping gas stream indicates that absorbent is saturated with carbon dioxide, an inlet valve is closed, and a vacuum applied, causing the carbon dioxide to be desorbed for collection.
    Type: Application
    Filed: November 26, 2012
    Publication date: August 15, 2013
    Inventor: Lawrence V. Dressler
  • Patent number: 8506683
    Abstract: An absorbent liquid according to the present invention is an absorbent liquid for absorbing CO2 or H2S or both from gas, in which the absorbent liquid includes an alkanolamine as a first compound component, and a second component including a nitrogen-containing compound having in a molecule thereof two members or more selected from a primary nitrogen, a secondary nitrogen, and a tertiary nitrogen or a nitrogen-containing compound having in a molecule thereof all of primary, secondary, and tertiary nitrogens. The absorbent liquid has an excellent absorption capacity performance and an excellent absorption reaction heat performance, as compared to an aqueous solution containing solely an alkanolamine and a nitrogen-containing compound in the same concentration in terms of wt %, and can recover CO2 or H2S or both from gas with smaller energy.
    Type: Grant
    Filed: June 11, 2010
    Date of Patent: August 13, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Ryuji Yoshiyama, Masazumi Tanoura, Noriko Watari, Shuuji Fujii, Yukihiko Inoue, Mitsuru Sakano, Tarou Ichihara, Masaki Iijima, Tomio Mimura, Yasuyuki Yagi, Kouki Ogura
  • Patent number: 8500867
    Abstract: CO2 is absorbed from a gas mixture by bringing the gas mixture into contact with an absorbent that comprises water and at least one amine of the formula (I), wherein R1 and R2, independently of each other, are hydrogen or an alkyl group. According to the invention, absorption media comprise sulfolane or an ionic liquid in addition to water and an amine of the formula (1). A device according to the invention for removing CO2 from a gas mixture comprises an absorption unit, a desorption unit, and an absorption medium according to the invention that is conducted in the circuit.
    Type: Grant
    Filed: August 19, 2012
    Date of Patent: August 6, 2013
    Assignee: Evonik Degussa GmbH
    Inventors: Matthias Seiler, Jörn Rolker, Rolf Schneider, Bernd Glöckler, Axel Kobus, Wolfgang Benesch, Thomas Riethmann, Hermann Winkler, Jens Reich, Helmut Brüggemann
  • Patent number: 8501130
    Abstract: A method for recovering CO2 from gas to be processed containing CO2, includes bringing the gas to be processed containing CO2 and CO2 absorbent into contact with each other to absorb and remove CO2 from the gas to be processed; cleaning the treated gas from which CO2 has been removed with washing fluid at least once; heating the absorbent which has absorbed CO2, separating and removing CO2 gas from the absorbent and regenerating the absorbent; cooling the separated CO2 gas to condense moisture contained in the gas to obtain condensed water; and monitoring changes in concentration of the CO2 absorbent contained in the condensed water and depending on the value of the measured concentration, controlling supply of the condensed water so that the condensed water is reused as a part of the washing fluid or a part of the CO2 absorbent.
    Type: Grant
    Filed: September 24, 2012
    Date of Patent: August 6, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Tatsuya Tsujiuchi, Shintaro Honjo, Takahito Yonekawa, Satoru Sugita
  • Patent number: 8500892
    Abstract: CO2 is absorbed from a gas mixture by bringing the gas mixture into contact with an absorbent that comprises water and at least one amine of the formula (I), wherein R1 and R2, independently of each other, are hydrogen or an alkyl group. According to the invention, absorption media comprise sulfolane or an ionic liquid in addition to water and an amine of the formula (I). A device according to the invention for removing CO2 from a gas mixture comprises an absorption unit, a desorption unit, and an absorption medium according to the invention that is conducted in the circuit.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: August 6, 2013
    Assignee: Evonik Degussa GmbH
    Inventors: Matthias Seiler, Jörn Rolker, Rolf Schneider, Bernd Glöckler, Axel Kobus, Wolfgang Benesch, Thomas Riethmann, Hermann Winkler, Jens Reich, Helmut Brüggemann
  • Patent number: 8500891
    Abstract: A system and process for capturing CO2 100 is disclosed. The process 100 includes reusing heat from a CO2 compression process 120 by providing the heat to a fuel treatment process 130. The heat may used to dry a fossil fuel to improve the efficiency of the fossil fuel combustion.
    Type: Grant
    Filed: May 7, 2010
    Date of Patent: August 6, 2013
    Assignee: ALSTOM Technology Ltd
    Inventors: John Oliver Butler, Rasesh R. Kotdawala
  • Patent number: 8491712
    Abstract: A dehydration system is provided. The dehydration system includes an absorber configured to produce a dry gas and a rich solvent from a wet gas and from a pure solvent and a flash drum coupled in flow communication with the absorber for receiving the rich solvent discharged from the absorber. The flash drum is configured to produce flash gas from the rich solvent. The dehydration further includes a reboiler configured to produce a semi-lean solvent from the rich solvent and an inert gas system configured to strip the semi-lean solvent using at least the flash gas to produce the pure solvent.
    Type: Grant
    Filed: September 13, 2010
    Date of Patent: July 23, 2013
    Assignee: General Electric Company
    Inventors: Ganesh Prasadh Kidambi, Sachin Naphad, Rajesh Vaddi
  • Patent number: 8475563
    Abstract: In a method of treating a gas stream, an aqueous scrubbing liquor is circulated through an essentially closed loop (20) comprising an electrochemical unit (48) for reducing the acidity of the liquor. A portion of the circulating liquor is diverted away from the closed loop (20) to a gas scrubbing unit (10). The gas stream enters the scrubbing unit (10), wherein an acid, for example HF and solid particulates, for example SiO2 particulates, within the gas stream dissolve in the diverted liquor. The diverted liquor is subsequently returned to the closed loop (20), and is replenished in the scrubbing unit (10) by fresh liquor diverted from the closed loop (20). A device (46) is provided for monitoring the acidity of the liquor at a location within the closed loop (20). The reduction in the acidity of the liquor by the electrochemical cell (48) is controlled depending on the monitored concentration.
    Type: Grant
    Filed: November 28, 2007
    Date of Patent: July 2, 2013
    Assignee: Edwards Limited
    Inventors: Philip Chandler, Christopher Peter Jones, Patrick Fletcher, Christopher Germain
  • Patent number: 8475566
    Abstract: The present invention relates to a method for recovery of carbon dioxide from a gas stream. The method is a two-step method in which carbon dioxide is compressed in the first step, while the residual carbon dioxide is recovered by an absorption process in a subsequent step. The present invention also relates to the use of the method for the recovery of carbon dioxide and a plant for recovery of carbon dioxide.
    Type: Grant
    Filed: June 6, 2005
    Date of Patent: July 2, 2013
    Assignee: Union Engineering A/S
    Inventor: Rasmus Find
  • Patent number: 8475571
    Abstract: In one embodiment, a gas purification system is provided. The system includes a first solvent section having a first carbon dioxide (CO2) absorber, a hydrogen sulfide (H2S) absorber, and a first solvent path that routes a first solvent through the first CO2 absorber and the H2S absorber. The gas purification system also includes a second solvent section having a second carbon dioxide (CO2) absorber and a second solvent path that flows a second solvent through the second CO2 absorber. The gas purification system has a gas path though the first and second solvent sections, wherein the first and second solvent paths are separate from one another, and the first and second solvents are different from one another.
    Type: Grant
    Filed: April 23, 2010
    Date of Patent: July 2, 2013
    Assignee: General Electric Company
    Inventors: Judith Pauline Oppenheim, Anindra Mazumdar
  • Publication number: 20130145935
    Abstract: An object of the present invention is to provide a carbon dioxide adsorption and release device, which has high adsorptivity, and also consumes low energy upon adsorption and desorption.
    Type: Application
    Filed: April 16, 2012
    Publication date: June 13, 2013
    Applicant: PANASONIC CORPORATION
    Inventors: Michio Suzuka, Takeyuki Yamaki, Takashi Sekiguchi, Ryo kamai
  • Publication number: 20130125751
    Abstract: The invention relates to a column comprising a jacket that bounds at least a first jacket space (M) and a second jacket space arranged thereabove along the longitudinal axis (L). The e first jacket space is separated from the second jacket space by a gas-permeable first chimney tray. A gaseous phase flows upward into the first jacket space, through the first chimney tray into the second jacket space, and then flows upward into the second jacket space. In the first jacket space the gaseous phase (M), in counter-current flow, contacts a first liquid washing agent, and in the second jacket space the gaseous phase, in counter-current flow, contacts a second liquid washing agent. The first chimney tray has a separator for separating the second washing agent, which separates the second washing agent (W?) and directs it into the second jacket space. The invention further relates to an apparatus comprising the column and a method for separating CO2 from a gaseous phase.
    Type: Application
    Filed: November 19, 2012
    Publication date: May 23, 2013
    Applicant: LINDE AKTIENGESELLSCHAFT
    Inventor: LINDE AKTIENGESELLSCHAFT
  • Publication number: 20130118350
    Abstract: The invention is directed to a method for separating acid gases from a gas mixture in which the gas mixture is contacted with an absorption medium which comprises water and at least one amine and has a phase-separation temperature in the range from 0 to 130° C. In addition, the invention is directed to a device which can be used for carrying out this method.
    Type: Application
    Filed: November 13, 2012
    Publication date: May 16, 2013
    Applicant: Evonik Degussa GmbH
    Inventor: Evonik Degussa GmbH
  • Publication number: 20130109074
    Abstract: A system for carbon dioxide capture from flue gas and other industrial gas sources utilizes microcapsules with very thin polymer shells. The contents of the microcapsules can be liquids or mixtures of liquids and solids. The microcapsules are exposed to the flue gas and other industrial gas and take up carbon dioxide from the flue gas and other industrial gas and eventual precipitate solids in the capsule.
    Type: Application
    Filed: October 26, 2012
    Publication date: May 2, 2013
    Applicant: Lawrence Livermore National Security, LLC
    Inventor: Lawrence Livermore National Security, LLC
  • Publication number: 20130098248
    Abstract: A gas-liquid contactor includes a plurality of spray nozzles provided in a CO2 absorber, for spraying a CO2 absorbent downward into the CO2 absorber in which flue gas drifts upward and passes so as to bring flue gas drifting upward and the CO2 absorbent into contact with each other. The spray nozzle includes a wall-surface dedicated nozzle provided along a wall surface in the CO2 absorber and a liquid dispersion nozzle provided inside of the wall-surface dedicated nozzle in the CO2 absorber.
    Type: Application
    Filed: April 25, 2011
    Publication date: April 25, 2013
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Naoyuki Yoshizumi, Tatsuya Tsujiuchi, Hiromitsu Nagayasu, Toyoshi Nakagawa, Yuichiro Sato, Takashi Kamijo, Shinya Kishimoto, Yoshinori Kajiya, Akihiko Tanigaki, Tetsuya Maruoka, Daijirou Ogino
  • Patent number: 8425655
    Abstract: The present invention provides a gas pressurized separation system to strip a product gas from a liquid stream and yield a high pressure gaseous effluent containing the product gas. The system comprises a gas pressurized stripping apparatus, such as a column, with at least one first inlet allowing flow of one or more liquid streams in a first direction and at least one second inlet allowing flow of one or more high pressure gas streams in a second direction, to strip the product gas into the high pressure gas stream and yield through at least one outlet a high pressure gaseous effluent containing the product gas; and two or more heat supplying apparatuses provided at different locations along the column. Processes for separating a product gas from a gaseous mixture to yield a high pressure gaseous effluent containing the product gas, utilize the gas pressurized separation system described above.
    Type: Grant
    Filed: July 9, 2010
    Date of Patent: April 23, 2013
    Assignee: Carbon Capture Scientific, LLC
    Inventors: Shiaoguo Chen, Zijiang Pan
  • Publication number: 20130092026
    Abstract: Systems and processes for reducing the energy requirements of an ammonia recovery stripper in a chilled ammonia-based CO2 removal system. The systems and processes include a nanofiltration or reverse osmosis unit for physically separating the washed liquid from a wash vessel configured to receive an ammonia slip feed stream from the main absorber of the chilled ammonia-based CO2 removal system and provide first and second feed streams. Relative to the washed liquid from the wash vessel, the first feed stream has a decreased ammonia molarity whereas the second feed stream has an increased ammonia molarity. The second feed stream is then fed to the ammonia recovery stripper, which reduces steam consumption. The reduced steam consumption translates to significant energy savings, among numerous other advantages. Additionally, the systems and process provide a reduction of equipment sizes related to the stripper unit as may be desired in some applications.
    Type: Application
    Filed: October 18, 2011
    Publication date: April 18, 2013
    Applicant: ALSTOM Technology Ltd.
    Inventor: Sanjay Kumar Dube
  • Patent number: 8419843
    Abstract: In one embodiment, a system includes a hydrogen sulfide (H2S) absorber, a first flash tank, a flash gas treatment column, and a CO2 absorber. The system also includes a first fluid path extending sequentially through the H2S absorber, the first flash tank, the flash gas treatment column, the H2S absorber, and the CO2 absorber.
    Type: Grant
    Filed: May 18, 2010
    Date of Patent: April 16, 2013
    Assignee: General Electric Company
    Inventors: Arnaldo Frydman, Pradeep Stanley Thacker, Sachin Suhas Naphad