With Polymeric Or Organic Binder Patents (Class 977/753)
  • Patent number: 9034426
    Abstract: Structured films containing multi-walled carbon nanotubes (“MWCNTs”) have enhanced mechanical performance in terms of strength, fracture resistance, and creep recovery of polyimide (“PI”) films. Preferably, the loadings of MWCNTs can be in the range of 0.1 wt % to 0.5 wt %. The strength of the new PI films dried at 60° C. increased by 55% and 72% for 0.1 wt % MWCNT and 0.5 wt % MWCNT loadings, respectively, while the fracture resistance increased by 23% for the 0.1 wt % MWCNTs and then decreases at a loading of 0.5 wt % MWCNTs. The films can be advantageously be created by managing a corresponding shift in the annealing temperature at which the maximum strength occurs as the MWCNT loadings increase.
    Type: Grant
    Filed: November 16, 2012
    Date of Patent: May 19, 2015
    Assignee: Tuskegee University
    Inventor: Heshmat Aglan
  • Patent number: 9023449
    Abstract: Composite reinforcement “Astrofleks” is used in building structures for reinforcement of insulation wall panels, solid concrete and prefabricated buildings. The composite reinforcement comprises the outer layer (1), inside of which the inner layer (2) is placed, on the outer surface of outer layer (1) there are relief elements (3) to improve adhesion of nanocomposite reinforcement with concrete. According to embodiment number 1, layer (1) is made of nanocomposite carbon in which the polymer matrix is modified by carbon nanostructures. Layer (2) is made of lightweight highly mobile concrete, containing in its composition components in the following ratio (% wt.): Cement—20-50; filler—70-30; plasticizer—0.02-2.5; water—the rest. According to embodiment number 2, layer (1) is made of nanocomposite carbon in which the polymer matrix is modified by polyhedral multi-layered carbon nanostructures of fulleroid type at a ratio of 0.01-10% by weight of the polymer matrix.
    Type: Grant
    Filed: May 31, 2010
    Date of Patent: May 5, 2015
    Assignee: Virtum i Sverige AB
    Inventors: Andrey Nikolaevich Ponomarev, Aleksandr Pavlovich Beloglazov
  • Patent number: 8999369
    Abstract: Methods and devices relating to polymer-bioceramic composite implantable medical devices, such as stents are disclosed. A suspension solution is formed including a fluid, a biodegradable polymer, and bioceramic particles. The biodegradable polymer and particles are precipitated from the suspension to form a mixture. A composite is formed by combining the mixture with another polymer and a scaffolding is formed from the composite.
    Type: Grant
    Filed: August 7, 2013
    Date of Patent: April 7, 2015
    Assignee: Abbott Cardiovascular Systems Inc.
    Inventors: David C. Gale, Yunbing Wang, Syed Faiyaz Ahmed Hossainy, Bin Huang, Garth L. Wilkes, Vincent J. Gueriguian
  • Patent number: 8992799
    Abstract: A polymer composite composed of a polymerized mixture of functionalized carbon nanotubes and monomer which chemically reacts with the functionalized nanotubes. The carbon nanotubes are functionalized by reacting with oxidizing or other chemical media through chemical reactions or physical adsorption. The reacted surface carbons of the nanotubes are further functionalized with chemical moieties that react with the surface carbons and selected monomers. The functionalized nanotubes are first dispersed in an appropriate medium such as water, alcohol or a liquefied monomer and then the mixture is polymerized. The polymerization results in polymer chains of increasing weight bound to the surface carbons of the nanotubes. The composite may consists of some polymer chains imbedded in the composite without attachment to the nanotubes.
    Type: Grant
    Filed: October 26, 2005
    Date of Patent: March 31, 2015
    Assignee: Hyperion Catalysis International, Inc.
    Inventors: Chunming Niu, Lein Ngaw
  • Patent number: 8986576
    Abstract: A material consisting essentially of a vinyl thermoplastic polymer, un-functionalized carbon nanotubes and hydroxylated carbon nanotubes dissolved in a solvent. Un-functionalized carbon nanotube concentrations up to 30 wt % and hydroxylated carbon nanotube concentrations up to 40 wt % can be used with even small concentrations of each (less than 2 wt %) useful in producing enhanced conductivity properties of formed thin films.
    Type: Grant
    Filed: September 1, 2011
    Date of Patent: March 24, 2015
    Assignee: Sandia Corporation
    Inventors: Gregory O'Bryan, Jack L. Skinner, Andrew Vance, Elaine Lai Yang, Thomas Zifer
  • Patent number: 8956556
    Abstract: The present application is directed to dielectric isolators for use in aircraft fuel systems to control lightning induced current and allow dissipation of electrostatic charge. The dielectric isolators are configured to have a high enough impedance to limit lightning currents to low levels, but low enough impedance to allow electrostatic charge to dissipate without allowing buildup. Although the dielectric isolators may develop a potential difference across the dielectric length due to the effects of lightning currents and its inherent impedance, they are configured to withstand these induced voltages without dielectric breakdown or performance degradation. In one embodiment, the dielectric isolator includes a tube constructed of a composition including a thermoplastic organic polymer (e.g., PEEK) and carbon nanotubes, and a pair of fittings attached to opposing ends of the tube.
    Type: Grant
    Filed: December 31, 2008
    Date of Patent: February 17, 2015
    Assignee: Eaton Corporation
    Inventors: Clifton P. Breay, Sara D. Pfannenstiel, Stephen C. Matthews, Edward W. S. Bryant
  • Patent number: 8925736
    Abstract: The disclosed subject matter provides a filter that is modified by a polymer-carbon based nanomaterial nanocomposite intended to significantly enhance the performance of filtration, separation, and remediation of a broad variety of chemicals, heavy metal ions, organic matters, and living organisms. Polymeric materials, such as but not limited to poly-N-vinyl carbazole (PVK), are combined with (1) graphene (G) and/or graphene-like materials based nanomaterials and (2) graphene oxide (GO) chemically modified with a chelating agent such as but not limited to EDTA. The nanocomposite is homogenously deposited on the surface of the membrane.
    Type: Grant
    Filed: September 10, 2012
    Date of Patent: January 6, 2015
    Assignee: University of Houston
    Inventors: Debora F. Rodrigues, Rigoberto C. Advincula, Fritz Claydon, Catherine M. Santos, Maria Celeste R. Tria
  • Publication number: 20140376964
    Abstract: An electrophotographic imaging device includes a charging device, a cleaning device, and a fuser member that each include hydrophobic carbon nanotubes. The use of hydrophobic carbon nanotubes can increases the charging device's, the cleaning device's, and the fuser member's durability, conductivity, and contaminants deposition.
    Type: Application
    Filed: September 8, 2014
    Publication date: December 25, 2014
    Inventors: Liang-Bih Lin, David H Pan, Daniel Levy, Jin Wu
  • Patent number: 8901620
    Abstract: The present invention relates to a horizontal biosensor, comprising a reduced graphene oxide layer formed on a substrate; a molecular linker formed on the reduced graphene oxide layer; and a metal nanoparticle layer formed on the molecular linker.
    Type: Grant
    Filed: August 13, 2012
    Date of Patent: December 2, 2014
    Assignee: Research & Business Foundation Sungkyunkwan University
    Inventors: Hyoyoung Lee, Peng Cui
  • Patent number: 8877284
    Abstract: A method for making a flexible and clear plastics material article of manufacture having a low electric surface resistance, starting from a plastics material having a higher electric surface resistance, in which the electric surface conductivity of the starting article of manufacture is modified by partially including, into at least a portion of the outer surface of the article, carbon nanotubes. With respect to conventional methods, the inventive method allows to modify the starting plastics material electric surface resistance so as to lower it to values smaller than 102 k?/sq, even starting from articles having a higher resistance of the order of 1013 k?/sq, while preserving the starting clearness and flexibility thereof.
    Type: Grant
    Filed: May 4, 2010
    Date of Patent: November 4, 2014
    Assignee: IVG Colbachini S.p.A.
    Inventors: Gabriele Marcolongo, Moreno Meneghetti
  • Publication number: 20140322517
    Abstract: A carbon nanotube aggregate according to one embodiment of the present invention includes a plurality of carbon nanotubes, in which: the carbon nanotubes each have a plurality of walls; a distribution width of a wall number distribution of the carbon nanotubes is 10 walls or more; a relative frequency of a mode of the wall number distribution is 25% or less; and a length of each of the carbon nanotubes is more than 10 ?m. A carbon nanotube aggregate according to another embodiment of the present invention includes a plurality of carbon nanotubes, in which: the carbon nanotubes each have a plurality of walls; a mode of a wall number distribution of the carbon nanotubes is present at a wall number of 10 or less; a relative frequency of the mode is 30% or more; and a length of each of the carbon nanotubes is more than 10 ?m.
    Type: Application
    Filed: October 5, 2012
    Publication date: October 30, 2014
    Applicant: NITTO DENKO CORPORATION
    Inventor: Youhei Maeno
  • Patent number: 8865108
    Abstract: A process for making multi-walled carbon nanotubes includes contacting a hydrocarbon-containing gas with an electron beam-treated fly ash catalyst. The electron beam-treated fly ash catalyst contains a total amount of iron oxide and vanadium oxide of up to 5 wt. %. The multi-walled carbon nanotubes may be formed in a low pressure chemical vapor deposition apparatus.
    Type: Grant
    Filed: June 21, 2012
    Date of Patent: October 21, 2014
    Inventor: Hashem M. A. Alhebshi
  • Patent number: 8865916
    Abstract: A diamond nanoparticle can be functionalized with a substituted dienophile under ambient conditions, and in the absence of catalysts or additional reagents. The functionalization is thought to proceed through an addition reaction.
    Type: Grant
    Filed: July 4, 2013
    Date of Patent: October 21, 2014
    Assignee: King Abdullah University of Science and Technology
    Inventors: Pierre M. Beaujuge, Omar El Tall, Inam U. Raja
  • Publication number: 20140308522
    Abstract: The present invention relates to a nano-graphite plate structure with N graphene layers stacked together, where N is 30 to 300. The nanometer nano-graphite structure has a tap density of 0.1 g/cm3 to 0.01 cm3, a thickness of 10 nm to 100 nm, and a lateral dimension of 1 ?m to 100 ?m. The ratio of the lateral dimension to the thickness is between 10 and 10,000. The oxygen content is less than 3 wt %, and the carbon content is larger than 95 wt %. The nano-graphite plate structure has both the excellent features of the graphene and the original advantages of easy processability of the natural graphite so as to be broadly used in various application fields.
    Type: Application
    Filed: April 12, 2013
    Publication date: October 16, 2014
    Applicant: Enerage Inc.
    Inventors: Mark Y. WU, Cheng-Yu HSIEH, Geng-Wei LIN, Ping-Yun YEH
  • Patent number: 8846143
    Abstract: Methods for fastening nanoscale structures within an anchoring structure to form a nanostructure composite and nanostructure composites formed therefrom. A primary fluid layer is formed on an anchoring substrate. Nanostructures are provided on an initial substrate, the nanostructures having a defined height and orientation with respect to the initial substrate. The nanostructures are introduced to a desired depth in the primary fluid layer, such that the orientation of the nanostructures relative to the growth substrate is substantially maintained. The primary fluid layer comprises one or more fluid layers. Ones of multiple fluid layers are selected such that when altered to form an anchoring structure, a portion of the anchoring structure can be removed, permitting exposure of at least a portion of the nanostructures from the anchoring structure in which they are affixed. The growth substrate is removed. Ends or other parts of nanostructures may be exposed from the anchoring structure.
    Type: Grant
    Filed: May 18, 2011
    Date of Patent: September 30, 2014
    Assignee: California Institute of Technology
    Inventors: Elijah Bodhi Sansom, Derek Rinderknecht, Morteza Gharib
  • Patent number: 8834737
    Abstract: A method for making a carbon nanotube composite film is provided. A PVDF is dissolved into a first solvent to form a PVDF solution. A number of magnetic particles is dispersed into the PVDF solution to form a suspension. A carbon nanotube film is immersed into the suspension and then transferred into a second solvent. The carbon nanotube film structure is transferred from the second solvent and dried to form the carbon nanotube composite film.
    Type: Grant
    Filed: August 7, 2012
    Date of Patent: September 16, 2014
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Wei Xiong, Jia-Ping Wang, Kai-Li Jiang, Shou-Shan Fan
  • Patent number: 8796024
    Abstract: A method for culturing neural cells using a culture medium is provided. Each neural cell includes a neural cell body and at least one neurite branched from the neural cell body. The culture medium includes a substrate and a carbon nanotube structure located on the substrate. A surface of the carbon nanotube structure is polarized to form a polar surface. The neural cells are cultured on the polar surface to grow neurites along the carbon nanotube wires. The carbon nanotube structure includes a number of carbon nanotube wires spaced apart from each other. A distance between adjacent carbon nanotube wires is greater than or equal to a diameter of the neural cell body.
    Type: Grant
    Filed: August 1, 2012
    Date of Patent: August 5, 2014
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Li Fan, Chen Feng, Wen-Mei Zhao
  • Patent number: 8791222
    Abstract: This invention concerns a polymer coating composition for use as non-focal optical power limiting dye containing polymeric materials. This composition contains: (1) one or more Modified Polymers comprising a Polymer, such as a hyperbranched polymer family, especially HB-PCS, HB-PU, HB-PUSOX or PC with one or more of: a) reverse saturable dye (RSA), b) multi-photon absorption dye (MPA), c) an azo dye, or d) absorption dye, which dye is chemically bonded to the pendant groups of the Polymer (along its chain and/or termini) or which forms a part of the backbone of the Polymer; (2) carbon nanotubes (CNT) as optical power limiters (OPL); and (3) a self-focusing component.
    Type: Grant
    Filed: September 22, 2010
    Date of Patent: July 29, 2014
    Assignee: Oxazogen, Inc.
    Inventors: Abhijit Sarkar, Petar R. Dvornic, James P. Godschalx
  • Patent number: 8790774
    Abstract: Exemplary embodiments provide materials and methods for a nanocomposite material and a fuser member containing the nanocomposite material in a fusing system, wherein the nanocomposite material can contain a plurality of carbon nanotubes (CNTs) and a plurality of inorganic nano-fillers (INFs) disposed in a polymer matrix to provide the nanocomposite material with desirable properties.
    Type: Grant
    Filed: December 27, 2010
    Date of Patent: July 29, 2014
    Assignee: Xerox Corporation
    Inventors: Qi Zhang, Yu Qi, Nan-Xing Hu, Gordon Sisler
  • Patent number: 8778487
    Abstract: A tape that can be used to detect cracks in a structure to which it is attached is disclosed herein. The tape includes a plurality of structural fibers. The tape also includes an electrically-insulating binder at least partially encapsulating the plurality of structural fibers. The tape also includes quantities of electrically conductive particles, each quantity of electrically conductive particles connected with one of the plurality of structural fibers.
    Type: Grant
    Filed: October 16, 2008
    Date of Patent: July 15, 2014
    Assignee: Rolls-Royce Corporation
    Inventor: Edward Claude Rice
  • Patent number: 8741183
    Abstract: The invention relates to compositions comprising certain propylene-olefin-copolymer waxes and carbon black (CB), the compositions being in the form of masterbatches, compounds or conductive polymers, and their use for producing conductive polymers and articles made of conductive polymers.
    Type: Grant
    Filed: October 30, 2009
    Date of Patent: June 3, 2014
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Pirko Kolditz, Gerd Hohner
  • Patent number: 8734685
    Abstract: The present invention relates to design and development of carbon nanotubes (CNT) reinforced electrically conducting synthetic foams comprising resin matrix system, carbon nanotubes, hollow glass microspheres and optionally hardener or catalyst for electrical conductivity and related applications especially electromagnetic interference (EMI) shielding.
    Type: Grant
    Filed: February 9, 2009
    Date of Patent: May 27, 2014
    Assignee: Director General, Defence Reserch & Development Organization
    Inventors: Sundaram Sankaran, Samudra Dasgupta, Ravi Sekhar Kandala, Ravishankar Bare Narayana
  • Patent number: 8652391
    Abstract: Substrate containers formed from improved compositions comprise a polymer and carbon nanotubes to provide enhanced characteristics. In some embodiments, the carbon fibers, e.g., nanotubes, can be mechanically blended or incorporated into the polymer, while in some embodiments carbon nanotubes also may be covalently bonded to the polymer to form corresponding covalent materials. In particular, the polymer can be covalently bonded to the side walls of the carbon nanotubes to form a composite with particularly desirable mechanical properties. The processing of the nanotubes can be facilitated by the dispersion of the nanotubes in an aqueous solution comprising a hydrophylic polymer, such as ethyl vinyl acetate. A dispersion of nanotubes can be combined with a polymer in an extrusion process to blend the materials under high shear, such as in an extruder.
    Type: Grant
    Filed: August 23, 2006
    Date of Patent: February 18, 2014
    Assignee: Entegris, Inc.
    Inventor: Sanjiv M. Bhatt
  • Patent number: 8648004
    Abstract: A method for preparing a metal-nanotube composite catalyst for an electro-chemical oxygen reduction reaction includes: debundling carbon nanotubes (CNTs); loading a carbon-containing polymeric material onto the surfaces of the nanotubes that have been debundled; carbonizing in situ the carbon-containing polymeric material on the carbon nanotubes to form carbon char layers surrounding the surfaces of the carbon nanotubes; and loading metal catalyst particles on the carbon nanotubes. The carbon char layers contain high amount of nitrogen and may be formed into a porous structure.
    Type: Grant
    Filed: April 7, 2011
    Date of Patent: February 11, 2014
    Assignee: National Cheng Kung University
    Inventors: Ping-Lin Kuo, Chun-Han Hsu, Wan-Ting Li, Hsiu-Mei Wu
  • Patent number: 8632879
    Abstract: A flexible sheet of aligned carbon nanotubes includes an array of aligned nanotubes held in a polymer matrix material. The carbon nanotubes have an average length of between about 50 microns and about 500 microns. The polymer matrix has an average thickness of between about 10 microns and about 500 microns. The flexible sheet has a density of about 0.2 to about 1.0 g/cc and includes between about 98 to about 60 weight percent aligned carbon nanotubes and between about 2 and about 40 weight percent polymer. A tape of aligned carbon nanotubes, a method for producing a tape of aligned carbon nanotubes, a method of producing the flexible aligned carbon nanotube sheet material and a method of increasing unidirectional heat conduction from a work piece are also disclosed.
    Type: Grant
    Filed: April 25, 2008
    Date of Patent: January 21, 2014
    Assignee: The University of Kentucky Research Foundation
    Inventor: Matthew C. Weisenberger
  • Patent number: 8614189
    Abstract: The present invention provides biocompatible composite materials that can be fabricated into a scaffold having properties suitable for bone repair and regeneration. These scaffolds have sufficient mechanical strength to be useful for the repair and regeneration of cortical bone.
    Type: Grant
    Filed: September 21, 2009
    Date of Patent: December 24, 2013
    Assignee: University of Connecticut
    Inventors: Cato T. Laurencin, Syam Prasad Nukavarapu, Sangamesh G. Kumbar
  • Patent number: 8613898
    Abstract: A composition of matter includes at least one carbon nanotube (CNT) or a graphene type structure having an outer surface, and a plurality of crystalline polymer supramolecular structures that include a conjugated polymer that are non-covalently secured to the outer surface of the CNTs or the graphene type structure. The conjugated polymer can be a conjugated homopolymer or a block copolymer including at least one conjugated block. The supramolecular structures extend outward from the outer surface of the CNTs or graphene type structures.
    Type: Grant
    Filed: January 27, 2011
    Date of Patent: December 24, 2013
    Assignee: University of Central Florida Research Foundation, Inc.
    Inventors: Lei Zhai, Jianhua Liu, Jianhua Zou, Anindarupa Chunder
  • Publication number: 20130306934
    Abstract: The present invention relates to a horizontal biosensor, comprising a reduced graphene oxide layer formed on a substrate; a molecular linker formed on the reduced graphene oxide layer; and a metal nanoparticle layer formed on the molecular linker.
    Type: Application
    Filed: August 13, 2012
    Publication date: November 21, 2013
    Applicant: RESEARCH & BUSINESS FOUNDATION SUNGKYUNKWAN UNIVERSITY
    Inventor: Hyoyoung LEE
  • Patent number: 8585934
    Abstract: A composite composition includes a plurality of carbon nanotube (CNT)-infused fibers dispersed in a matrix material. The amount of carbon nanotubes in the composition is in a range between about 0.1% percent by weight to about 60 percent by weight of the composite.
    Type: Grant
    Filed: February 17, 2010
    Date of Patent: November 19, 2013
    Assignee: Applied NanoStructured Solutions, LLC
    Inventors: Tushar K. Shah, Bradley W. Pietras, Daniel Jacob Adcock, Harry C. Malecki, Mark R. Alberding
  • Publication number: 20130295439
    Abstract: Improved high energy capacity designs for lithium ion batteries are described that take advantage of the properties of high specific capacity anode active compositions and high specific capacity cathode active compositions. In particular, specific electrode designs provide for achieving very high energy densities. Furthermore, the complex behavior of the active materials is used advantageously in a radical electrode balancing design that significantly reduced wasted electrode capacity in either electrode when cycling under realistic conditions of moderate to high discharge rates and/or over a reduced depth of discharge.
    Type: Application
    Filed: May 4, 2012
    Publication date: November 7, 2013
    Inventors: Charan Masarapu, Haixia Deng, Yongbong Han, Yogesh Kumar Anguchamy, Subramanian Venkatachalam, Sujeet Kumar, Herman A. Lopez
  • Publication number: 20130264525
    Abstract: An electrically conductive film has an electrically conductive layer on at least one side, which is a thermoplastic resin film in which the electrically conductive layer contains a carbon nanotube (A), a carbon nanotube dispersant (B) and a binder resin (C), the total of contents of (A), (B) and (C) in the electrically conductive layer is 90% by weight or more relative to the entire electrically conductive layer, and weight rates of (A), (B) and (C) satisfy the following, and a weight ratio of (B) and (A) ((B)/(A)) is 0.5 or more and 15.0 or less: (A) 1.0 to 40.0% by weight, (B) 0.5 to 90.0% by weight, and (C) 4.0 to 98.5% by weight (provided that the total of contents of (A), (B) and (C) is let to be 100% by weight).
    Type: Application
    Filed: March 5, 2013
    Publication date: October 10, 2013
    Inventors: Kazuyoshi Ota, Yasushi Takada, Shotaro Tanaka
  • Patent number: 8536324
    Abstract: Functionalized Single Wall Carbon Nanotube (SWCNT) complexed with nanochitosan for use in the delivery of bioaffecting substances and diagnostic applications. fSWCNT complexed with the chitosan NG042 were used for delivery of DNA-encoding EGFP reporter protein and peptide. The results demonstrate that shown CNT-chitosan hybrid nanoparticles exhibit significantly higher transfection efficiency in vivo than chitosan alone. Furthermore, the functionalized nanotubes were tested for peptide transfer into HEK293 cells. The results showed that the hybrid nanoparticles efficiently transferred peptides. Together, these results show that hybrid SWCNT-chitosan particles increase DNA and peptide transfer into cells.
    Type: Grant
    Filed: April 18, 2008
    Date of Patent: September 17, 2013
    Assignee: University of South Florida
    Inventors: Shyam S. Mohapatra, Arun Kumar
  • Patent number: 8499445
    Abstract: Printed conductive lines and a method of preparing them using polymer nanocomposites with low resistivity and high current carrying capacity. Plasma treatment selectively removes polymers/organics from nanocomposites. Subsequent selective metal is deposited on top of the exposed metal surface of the printed conductive lines in order to improve current carrying capacity of the conductive printed lines. The printed conductive lines use a conductive ink or printing process and are then cured thermally and/or by a lamination process. Next, the printed conductive lines are treated with the plasma for 5-15 minutes in order to remove organics. E-less copper (Cu) is selectively deposited only at the conducting particle surface of the printed conductive lines. If desired, e-less gold, silver, tin, or tin-lead can be deposited on top of the e-less Cu.
    Type: Grant
    Filed: July 18, 2011
    Date of Patent: August 6, 2013
    Assignee: Endicott Interconnect Technologies, Inc.
    Inventors: Rabindra N. Das, Frank D. Egitto, Voya R. Markovich
  • Patent number: 8501850
    Abstract: The invention provides compositions and methods for inducing and enhancing order and nanostructures in block copolymers and surfactants by certain nonpolymeric additives, such as nanoparticles having an inorganic core and organic functional groups capable of hydrogen bonding. Various compositions having lattice order and nanostructures have been made from a variety of copolymers or surfactants that are mixed with nonpolymeric additives. Particularly, a variety of nanoparticles with an inorganic core and organic functional groups have been discovered to be effective in introducing or enhancing the degree of orders and nanostructures in diverse block copolymers and surfactants.
    Type: Grant
    Filed: October 14, 2010
    Date of Patent: August 6, 2013
    Assignee: University of Massachusetts
    Inventors: James J. Watkins, Vikram K. Daga, Ying Lin
  • Patent number: 8491821
    Abstract: The invention relates to compositions comprising certain propylene-olefin-copolymer waxes, and carbon nanotubes (CNTs), the compositions being in the form of masterbatches, compounds or conductive polymers, and their use for producing conductive polymers and articles made of conductive polymers.
    Type: Grant
    Filed: October 30, 2009
    Date of Patent: July 23, 2013
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Pirko Kolditz, Gerd Hohner
  • Publication number: 20130147094
    Abstract: A laser-engravable composition comprises one or more EPDM elastomeric rubbers, at least one of which comprises at least 8 weight % polyene recurring units. This laser-engravable composition of elastomeric rubbers can be quickly crosslinked using sulfur-containing vulcanizing compositions to provide laser-engravable compositions and layers in flexographic printing plate precursors. These precursors can be laser-engraved to provide relief images for flexographic printing.
    Type: Application
    Filed: December 12, 2011
    Publication date: June 13, 2013
    Inventors: Ophira Melamed, Mazi Amiel-Levy
  • Patent number: 8455583
    Abstract: The present invention is directed to carbon nanotube (CNT)/polymer composites, i.e., nanocomposites, wherein the CNTs in such nanocomposites are highly dispersed in a polymer matrix, and wherein the nanocomposites comprise a compatibilizing surfactant that interacts with both the CNTs and the polymer matrix. The present invention is also directed to methods of making these nanocomposites. In some such methods, the compatibilizing surfactant provides initial CNT dispersion and subsequent mixing with a polymer. The present invention is also directed to methods of using these nanocomposites in a variety of applications.
    Type: Grant
    Filed: August 2, 2005
    Date of Patent: June 4, 2013
    Assignee: University of Houston
    Inventors: Ramanan Krishnamoorti, Cynthia A. Mitchell, Jeffrey L. Bahr
  • Patent number: 8445090
    Abstract: Provided is a fixing belt which has high thermal conductivity capable of achieving an excellent fixing property that can respond to the recent increase in printing speed, which has a proper degree of elasticity such that color toners are sufficiently enveloped so as to be melted and mixed, and which has excellent mechanical strength and durability. A fixing belt includes a tubular base member, an elastic layer disposed on the outer circumferential side of the base member, and a surface layer disposed on a surface on the outer circumferential side of the elastic layer, the fixing belt being characterized in that the elastic layer is composed of rubber into which a filler primarily composed of silicon carbide powder and a carbon nanotube are compounded, and the formulae 10X+3Y<750, 3X+30Y>170, X>10, and Y>0.1 are satisfied, where X is the percent by volume of the filler and Y is the percent by volume of the carbon nanotube in the elastic layer.
    Type: Grant
    Filed: January 12, 2011
    Date of Patent: May 21, 2013
    Assignees: Sumitomo Electric Industries, Ltd., Sumitomo Electric Fine Polymer, Inc.
    Inventors: Shingo Nakajima, Jun Sugawara, Hiromi Kamimura, Masatoshi Ishikawa
  • Patent number: 8431217
    Abstract: The present teachings describe a core-shell particle dispersed in a layer of a fuser member, thereby improving thermal conductivity of the fuser member. The core-shell particle includes a graphene core surrounded by a shell layer. The shell layer comprises a polymer selected from the group consisting of polypentafluorostyrene, polystyrene and polydivinylbenzene. The core-shell particles can be dispersed in an intermediate layer or release layer of a fuser member.
    Type: Grant
    Filed: September 12, 2011
    Date of Patent: April 30, 2013
    Assignee: Xerox Corporation
    Inventors: David J. Gervasi, Matthew M. Kelly
  • Publication number: 20130099170
    Abstract: A method and composition wherein carbonaceous nano-scaled filler material is subjected to atmospheric plasma treatment using carbon monoxide as the active gas. The treatment with carbon monoxide plasma has been found to significantly increase the incorporation of oxygen groups on the surface of the filler material without degrading the surface and thus serves to increase wettability and dispersion throughout the matrix. The composite that incorporates the treated filler material has enhanced mechanical and electrical properties.
    Type: Application
    Filed: October 19, 2011
    Publication date: April 25, 2013
    Applicant: THE AEROSPACE CORPORATION
    Inventors: RAFAEL J. ZALDIVAR, James P. Nokes, Hyun I. Kim
  • Patent number: 8420717
    Abstract: A method of making a water soluble carbon nanostructure includes treating a fluorinated carbon nanostructure material with a polyol in the presence of a base. A water soluble carbon nanostructure comprises a fluorinated carbon nanostructure covalently bound to a polyol. Exemplary uses of water soluble carbon nanostructures include use in polymer composites, biosensors and drug delivery vehicles.
    Type: Grant
    Filed: July 23, 2008
    Date of Patent: April 16, 2013
    Assignee: William Marsh Rice University
    Inventors: Valery N. Khabashesku, Oleksandr Kuznetsov, Rui Lobo
  • Patent number: 8399553
    Abstract: The present invention relates to a (process for preparation of a) carbon nanotubes reinforced polymer, wherein the matrix polymer has both a low molecular weight fraction as well as a high molecular weight fraction, as a result of which the level of conductivity of the resulting composite can be controlled.
    Type: Grant
    Filed: April 6, 2007
    Date of Patent: March 19, 2013
    Assignee: Stichting Dutch Polymer Institute
    Inventors: Cornelis Koning, Nadia Grossiord, Jan Meuldijk, Joachim Loos
  • Publication number: 20130065045
    Abstract: The present teachings describe a core-shell particle dispersed in a layer of a fuser member, thereby improving thermal conductivity of the fuser member. The core-shell particle includes a graphene core surrounded by a shell layer. The shell layer comprises a polymer selected from the group consisting of polypentafluorostyrene, polystyrene and polydivinylbenzene. The core-shell particles can be dispersed in an intermediate layer or release layer of a fuser member.
    Type: Application
    Filed: September 12, 2011
    Publication date: March 14, 2013
    Applicant: XEROX CORPORATION
    Inventors: David J. Gervasi, Matthew M. Kelly
  • Patent number: 8389619
    Abstract: A poly(ether-ketone) composite of the formula: wherein DND is detonation nanodiamond particle; wherein Ar represents ether-ketone repeating groups of the formula wherein Q is —O— or —O—(CH2)n—O—, wherein n has a value of 2-12; wherein R is —H, —CH3, or —C2H5, m has a value of 1 or 2; wherein R? is —H or —CH3; and wherein — denotes the presence of a direct C—C bond between Ar and DND. Also provided is a process for preparing the nanocomposites.
    Type: Grant
    Filed: February 5, 2009
    Date of Patent: March 5, 2013
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Loon-Seng Tan, David H. Wang
  • Publication number: 20130040124
    Abstract: The present invention relates to transparent antistatic films using graphene, and methods for preparing the same. The films include conductive particles comprising a single-layer or multi-layer graphene, and a binder. The films are prepared by dispersing graphene in a solvent to obtain a graphene dispersion; dissolving a curable binder to a solvent to obtain a binder solution; mixing the graphene dispersion, the binder solution and optionally an additive to obtain a coating solution; applying the coating solution onto a substrate and drying the solution to form a coated film; and curing the coated film. According to the present invention, transparent or semitransparent antistatic films having excellent permeability, abrasion resistance, scratch resistance, chemical stability and dimensional stability can be prepared. The films also have superior adhesion to substrates and applicability, and thus may be advantageously applied to rigid or flexible substrates.
    Type: Application
    Filed: April 5, 2011
    Publication date: February 14, 2013
    Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Chong Min Koo, Soon Man Hong, Seung Sang Hwang, Soon Jong Kwak, Kyung Youl Baek, Kyung Ho Min, Youn Duk Park, Hee La Kwak, Myung Hee Kim, Bo Ri Kim, Seung Sock Choi, Tae Hee Han
  • Publication number: 20130029102
    Abstract: Flexographic printing precursors are prepared using laser-engraveable compositions containing a laser-engraveable resin and chemically-crosslinked organic porous particles. The presence of these porous particles, which can include an infrared radiation absorber, improves various imaging and performance properties in the preparation of flexographic printing members such as flexographic printing plates and printing sleeves.
    Type: Application
    Filed: July 28, 2011
    Publication date: January 31, 2013
    Inventors: Christine Joanne Landry-Coltrain, Mridula Nair
  • Publication number: 20130030117
    Abstract: The present invention provides a method of manufacturing polyamide-carbon nanotube composites. The method includes mixing a polyamide composition including 0.01-1% by weight of carbon nanotubes using a shearing rate equal to or greater than 1000-4400 sec?1.
    Type: Application
    Filed: November 10, 2011
    Publication date: January 31, 2013
    Applicants: GEMANKOREA CO., LTD., HYUNDAI MOTOR COMPANY
    Inventors: Kyong Hwa Song, Do Suck Han, Chi Hoon Choi, Chan Choi, Myung-Hwan Lee, Sang-Tae Lee
  • Publication number: 20130011652
    Abstract: A paper machine clothing (PMC) fabric includes a plurality of monofilament yarns. At least some of the yarns have a composition which is a mixture of between 90% to 99.8% thermoplastic resin, and between 0.2% to 10% nano-graphene. The thermoplastic resin is preferably polyethylene terephthalate (PET).
    Type: Application
    Filed: July 6, 2011
    Publication date: January 10, 2013
    Inventors: Jürgen Abraham, Ashish Sen, Brian Good
  • Patent number: 8344060
    Abstract: Polymer nanocomposites exhibit a reversible change in stiffness and strength in response to a stimulus. The polymer nanocomposites include a matrix polymer with a comparably low modulus and strength and nanoparticles that have a comparably high modulus and strength. The particle-particle interactions are switched by the stimulus, to change the overall material's mechanical properties. In a preferred embodiment, a chemical regulator is used to facilitate changes of the mechanical properties. Methods for inducing modulus changes in polymer nanocomposites are also disclosed.
    Type: Grant
    Filed: April 8, 2009
    Date of Patent: January 1, 2013
    Assignees: Case Western Reserve University, The United States of America as Represented by the Department of Veterans Affairs
    Inventors: Christoph Weder, Stuart J. Rowan, Jeffrey R. Capadona, Dustin J. Tyler, Kadhiravan Shanmuganathan, Otto van den Berg
  • Patent number: 8337979
    Abstract: The present invention provides methods for uniform growth of nanostructures such as nanotubes (e.g., carbon nanotubes) on the surface of a substrate, wherein the long axes of the nanostructures may be substantially aligned. The nanostructures may be further processed for use in various applications, such as composite materials. For example, a set of aligned nanostructures may be formed and transferred, either in bulk or to another surface, to another material to enhance the properties of the material. In some cases, the nanostructures may enhance the mechanical properties of a material, for example, providing mechanical reinforcement at an interface between two materials or plies. In some cases, the nanostructures may enhance thermal and/or electronic properties of a material. The present invention also provides systems and methods for growth of nanostructures, including batch processes and continuous processes.
    Type: Grant
    Filed: August 24, 2007
    Date of Patent: December 25, 2012
    Assignee: Massachusetts Institute of Technology
    Inventors: Brian L. Wardle, Anastasios John Hart, Enrique J. Garcia, Alexander Henry Slocum