Abstract: A method, apparatus, and system for loading organic chemical liquids in a transporting vessel are described. The invention provides for selective transfer of vapor released during loading to a vapor control system or to vent. A vapor control logic system which controls flow direction of vapor captured from a transporting vessel being loaded, either to a vapor control system, or to vent in the environment, is described.
Abstract: In a principal embodiment, the invention relates to a method in which a water sample containing dissolved hydrocarbon fuel to be identified is contacted with a fiber optic element adapted to adsorb a hydrocarbon fuel on at least a portion of the element, for a time sufficient to adsorb a characterizing amount of the fuel from the water sample. The fiber optic element containing adsorbed hydrocarbon fuel is then removed from the water sample, and then at least the portion of the fiber optic element containing adsorbed fuel is immersed in or surrounded with water. The adsorbed hydrocarbon fuel is allowed to desorb from the fiber optic element while the rate of desorption of the fuel from the fiber optic element is measured by a fiber optic chemical sensor system of which the fiber optic element is a part.
Abstract: A method is disclosed for borehole compensation of measurements of earth formations penetrated by a borehole including differential time (.DELTA.t) measurements obtained from a borehole tool in the formation. The borehole tool includes at least one transmitter and a plurality of receivers spaced apart from each transmitter. Each transmitter generates a waveform, and the receivers are responsive to the waveform. A receiver array .DELTA.t measurement is generated for a depth interval spanned by the receivers by cross-correlating receiver array waveforms relevant to the spanned depth interval. A synthesized transmitter array .DELTA.t measurement corresponding to the spanned depth interval is generated by cross-correlating selected transmitter array waveforms.
Abstract: In drilling a well, a condition at the surface which contributes to a downhole condition is identified. A set of observed measurements is collected for the surface and downhole conditions. From this set of observations a predictor equation is derived which expresses the downhole condition as a function of the measured surface condition. After the predictor equation has been developed, it is applied to a measured surface condition to estimate the resulting downhole condition.
Abstract: Minor amounts of C.sub.3 -C.sub.4 hydrocarbons from amine absorbents used in removing H.sub.2 S liquid C.sub.3 -C.sub.4 hydrocarbon are recovered. The process features recovery of the C.sub.3 -C.sub.4 hydrocarbon in a hydrocarbon gas from a second absorption zone where H.sub.2 S is removed from the hydrocarbon gas, the hydrocarbon gas functioning as a stripping gas.
Type:
Grant
Filed:
August 18, 1995
Date of Patent:
April 29, 1997
Assignee:
Ashland Inc.
Inventors:
Gerald O. Henderson, William M. Rice, Ric T. Zima
Abstract: Novel compositions comprising asphalt, having improved durability, are disclosed, the compositions comprising or containing (a) from about 0.1 percent to about 5.0 percent of a metal hydrocarbyldithiophosphate, or mixture thereof, and (b) from about 0.1 percent to about 5.0 percent of an antioxidant butylated phenol, or mixture thereof, the ratio of (a) to (b) being from about 0.75:1 to about 4.0:1. A process of making such improved compositions is also described, as well as methods of utilizing such compositions.
Abstract: A process for the gasification of coal is disclosed, the process being characterized by the removal of flyslag deposits in the quench zone of the process by temporarily reducing or stopping the flow of the quench gas to melt the deposits, and then resuming the ordinary quench gas flow.
Abstract: A process for the treatment of flyslag from the gasification of coal is described, the process being characterized, in one embodiment, by mixing of the flyslag with a residual waste stream from a coal gasification process, the wast stream containing particulate flyslag solids.
Type:
Grant
Filed:
March 9, 1990
Date of Patent:
November 13, 1990
Assignee:
Shell Oil Company
Inventors:
Edward H. Hsu, Daniel C. Baker, Charles M. Arbore
Abstract: A process for the treatment of flyslag from the gasification of coal is described, the process being characterized, in one embodiment, by mixing of the flyslag with a cementitious material and a residual waste stream from a coal gasification process, the waste stream containing particulate flyslag solids. A composition comprising flyslag and a cementitious material, in specified proportions is also disclosed.
Abstract: A process for the gasification of coal is disclosed, the process being characterized by the removal of flyslag deposits in the quench zone of the process by temporary reduction or stoppage of the flow of the quench gas to melt the deposits, and by diversion of a portion or all of the quench gas during the reduction or stoppage to a locus between the quench zone and the heat exchange zone.
Abstract: A method for determining blockage of a coal gasification process gasifier outlet or quench zone by observing changes in the sound pressure between the quench zone and the gasifier is disclosed.
Type:
Grant
Filed:
December 28, 1989
Date of Patent:
October 16, 1990
Assignee:
Shell Oil Company
Inventors:
Lloyd A. Clomburg, Jr., Otto E. Crenwelge, Jr.
Abstract: A process and reaction for the gasification of coal disclosed, the invention being characterized by the provision in each of a plurality of layers of slag coalescing materials on the inner liner of the reactor to provide a protective coating on the wall or walls of the reactor.
Abstract: A process for the gasification of coal is described which comprises partially combusting particulate coal in a gasification reactor comprising a gasification zone and a water bath and producing a hot gaseous stream containing synthesis gas and flyash, and slag, in the gasification zone. The slag produced is allowed to discharge from the gasification zone into the water bath, the redox potential of the water bath being formulated or maintained at a level sufficient to inhibit sulfide presence or inclusion in the slag.
Abstract: A process for production of a flyash-slag composite is described in which, in one embodiment, slag particles are tumbled with an aqueous suspension of finely divided clay, flyash and a cementitious material are added, and the mixture is tumbled to produce the desired composite.
Abstract: Fouling or plugging of surfaces in the heat exchange zone following a coal gasification reaction zone caused by deposition of flyslag is inhibited by addition of an amount of graphite to the synthesis gas at a suitable locus or loci.
Type:
Grant
Filed:
June 27, 1989
Date of Patent:
January 30, 1990
Assignee:
Shell Oil Company
Inventors:
Chih-hsiung F. Liu, Charles V. Sternling
Abstract: Deposits of flyslag on the walls of a heat exchange zone employed to quench and cool synthesis gas and flyslag particles produced from the gasification of coal may be reduced by (a) temporarily increasing the flow rate of the synthesis gas and flyslag particles during the process to a space velocity of greater than at least 12 meters per second; or (b) after a shutdown or incident where flyslag is deposited, utilizing a space velocity of the synthesis gas and flyslag of greater than 12 meters per second for a time sufficient to remove the deposits, and then utilizing flow rates which prevent or inhibit deposition of flyslag.
Abstract: A process for removal of H.sub.2 S from gas streams is described, the process being characterized by use of a novel iron chelate treating solution containing a specified ferric to ferrous chelate ratio, aqueous ammonia, and thiosulfate ion.
Type:
Grant
Filed:
July 16, 1987
Date of Patent:
October 3, 1989
Assignee:
Shell Oil Company
Inventors:
Donald C. Olson, John J. Miller, deceased, Wayne R. Miller, executor, George C. Blytas, Zaida Diaz
Abstract: A process for removal of H.sub.2 S from gas streams is described, the process being characterized by use of a novel iron chelate treating solution containing a specified ferric to ferrous chelate ratio and aqueous ammonia.
Type:
Grant
Filed:
July 16, 1987
Date of Patent:
August 22, 1989
Assignee:
Shell Oil Company
Inventors:
Donald C. Olson, John J. Miller, deceased
Abstract: A process for the treatment of flyslag from the gasification of coal is described, the process being characterized, in one embodiment, by mixing of the flyslag with a cementitious material, a composition capable of converting sulfides in the flyslag at least to sulfur, and an aqueous waste stream from the gasification of coal, in specified proportions. A composition comprising flyslag, a cementitious material, and a composition capable of converting sulfides in the flyslag at least to sulfur, is also disclosed.
Abstract: A process for the gasification of coal to produce synthesis gas is disclosed, the process being characterized by passage of product gas stream containing sticky or molten particles upward from the gasification zone and quenching of the product gas stream and particles in a quench zone coated or lined internally with boron nitride.
Type:
Grant
Filed:
July 13, 1988
Date of Patent:
April 25, 1989
Assignee:
Shell Oil Company
Inventors:
Drucilla G. Davis, L. W. R. Dicks, J. A. Horwege