Abstract: Disclosed is a cermet exhibiting superconducting properties with improved mechanical properties comprising a mixture of a superconducting ceramic and one or more metals, the cermet resulting from liquid phase sintering at a temperature at which one of the metals is molten and below the melting temperature of the superconducting ceramic.
Abstract: Disclosed is a method of separating organic or organometallic materials under supercritical fluid conditions, the method comprising the steps of providing a bed of packing material selected from a metal oxide/hydroxide support material having phsophorous-containing organic molecules bonded to reactive sites on said support material, alumina and alumina-containing mixtures. The materials are introduced to the bed and a fluid is added to the bed under supercritical fluid conditions. The fluid removes one of the materials from the bed.
Type:
Grant
Filed:
July 1, 1988
Date of Patent:
November 14, 1989
Assignee:
Aluminum Company of America
Inventors:
Robinson P. Khosah, John W. Novak, Douglas G. Weaver, Karen R. Fraser-Milla, Richard R. Burr
Abstract: An active material is disclosed comprising metal oxide/hydroxide particles having chemically bonded to reactive sites on a surface thereof, a monolayer of a phosphorous-containing organic material comprised of a phosphorous-containing group and a carbon-containing group. The bond to the metal oxide/hydroxide particle surface is formed by reaction of the phosphorous-containing group with the metal oxide/hydroxide particle surface, so that the carbon-containing group of the material is oriented away from the metal oxide/hydroxide surface.
Abstract: An aluminum base alloy suitable for forming into a wrought product having improved combinations of strength and fracture toughness is provided. The alloy is comprised of 0.2 to 5.0 wt. % Li, 0.05 to 6.0 wt. % Mg, 0.2 to 5.0 wt. % Cu, 0 to 2.0 wt. % Mn, 0 to 1.0 wt. % Zr, 0.05 to 12.0 wt. % Zn, 0.05 to 1.0 wt. % Hf, 0.5 wt. % max. Fe, 0.5 wt. % max. Si, the balance aluminum and incidental impurities.
Type:
Grant
Filed:
March 24, 1988
Date of Patent:
September 26, 1989
Assignee:
Aluminum Company of America
Inventors:
Roberto J. Rioja, Philip E. Bretz, John Jacoby
Abstract: A welding alloy is disclosed for welding together an aluminum-lithium alloy to provide a weld characterized by insensitivity to weld cracking, good resistance to weld corrosion, and the ability to develop high weld strength during subsequent aging. The welding alloy consists essentially of an aluminum base alloy containing from about 4.5 to about 6.5 wt. % Cu, from about 0.2 to about 1.5 wt. % Mg, from about 0.8 to about 2.5 wt. % Li, and from about 0.07 to about 0.20 wt. % Ti; with the following maximum amounts of specific impurities: about 0.15 wt. % Si, about 0.30 wt. % Fe, about 0.3 wt. % Zn, and about 0.3 wt. % Mn; the balance consisting essentially of aluminum and not more than about 0.15 wt. % max. total of other impurities.
Type:
Grant
Filed:
March 24, 1988
Date of Patent:
July 18, 1989
Assignee:
Aluminum Company of America
Inventors:
Rebecca A. Gentry, Richard P. Martukanitz
Abstract: Disclosed is a method of making lithium containing aluminum base alloy products having improved properties in the short transverse direction. The method comprises the steps of providing a body of a lithium containing aluminum base alloy and heating the body to a temperature for initial hot working but at a temperature sufficiently low that a substantial amount of grain boundary precipitate is not dissolved. The method further includes hot working the heated body to provide an intermediate product, recrystallizing the intermediate product and then hot working the recrystallized product to a final shaped product. The final shaped product is solution heat treated, quenched and aged to provide a non-recrystallized final product having improved levels of short transverse properties.
Abstract: Aluminum alloy products particularly for automotive applications, e.g. panel members, may be produced from a body of aluminum base alloy consisting essentially of, by weight, 0.5 to 0.85% Si, 0.25 to 0.55% Mg, 0.05 to 0.4% Fe, 0.75 to 1.1% Cu, the balance essentially aluminum and incidental elements and impurities. The alloy body may be homogenized at a temperature in the range of 900.degree. to 1100.degree. F. and thereafter worked into a wrought product such as sheet which may be continuously solution heat treated and quenched and aged to a T4 condition prior to forming into vehicular panel members, for example.
Abstract: An adsorption process is disclosed for removal of carbonyl sulfide (COS) from a liquid hydrocarbon which comprises providing an activated alumina adsorbent which has preferably impregnated with a compound selected from the class consisting of one or more alkali metal compounds, one or more alkaline earth metal compounds, or a mixture of such compounds; passing a liquid hydrocarbon containing COS through the activated alumina adsorbent at a flow rate sufficient to adsorb enough COS in the liquid hydrocarbon to lower the COS content of the liquid hydrocarbon to less than 1 ppm; monitoring the effluent liquid hydrocarbon to determine when the capacity of the adsorbent to adsorb the COS has been reached; and then regenerating the activated alumina adsorbent by passing a gas, heated to a temperature of from about 150.degree. to about 300.degree. C., through the adsorbent for a period of time sufficient to remove a substantial amount of the sulfur adsorbed thereon.
Abstract: Disclosed in a process for forming a ceramic body from colloidal boehmite and alpha alumina. Alpha alumina is added to the colloidal boehmite to produce a seeded gal, the seeded gel capable of being sintered at a low temperature to produce a ceramic product having at least a 90% theoretical density.
Abstract: A method is provided for producing a high strength aluminum alloy characterized by improved resistance to exfoliation. The method comprises providing an aluminum-base alloy comprising 5.9 to 8.2 wt. % zinc, 1.5 to 4.0 wt. % magnesium, 1.5 to 3.0 wt. % copper, less than 0.01 wt. % boron not more than 0.04 wt. % chromium, and 0.5 wt. % maximum other alloying elements such as zirconium, manganese, iron, silicon and titanium, with the balance consisting of aluminum, working the alloy into a product of predetermined shape, solution heat treating the shaped product, quenching, and aging the heat treated and quenched product to a temperature of from above 270.degree. F. for a period of from 6 to 30 hours.
Abstract: An improved electrode for an electrolytic reduction cell is disclosed which comprises a nonmetallic electrode having a top surface, a central bore in the top surface, a central metal current source comprising a metal shaft or rod in the central bore, and side bores extending from the central bore toward the sides of the electrode having metallic portions therein to provide lateral current distribution from the central current source. In a preferred embodiment, the side bores are filled with metal in situ by pouring molten metal such as cast iron into the central bore to lock the central shaft in place wherein the molten metal will flow, during such filling, into the side bores to provide intimate contact with the sidewalls of side bores to provide improved lateral current distribution from the central current source across said electrode.
Type:
Grant
Filed:
December 2, 1987
Date of Patent:
April 25, 1989
Assignee:
Aluminum Company of America
Inventors:
Richard W. Peterson, Donald C. Fisher, John W. Luffy
Abstract: An improved process is disclosed for the purification of an impure aqueous solution containing heavy metal ions which comprises passing the impure solution through a bed of activated alumina adsorbent. The heavy metal ions are removed from the impure aqueous solution by adsorption onto the activated alumina adsorbent. The adsorbent may be regenerated for reuse and the adsorbed metals recovered by subsequently stripping the metal ions from the adsorbent and recycling the metal ions back to the process of origin. The pH of the effluent may be monitored to determine when the capacity of the adsorbent has been reached and regeneration of the adsorbent should be commenced. In a preferred embodiment, a portion of the activated alumina is pretreated with acid before passing the impure solution through the adsorbent to enhance the chromium ion adsorption of the acid-treated activated alumina and a portion of the regenerated activated alumina is again treated with acid after each regeneration cycle.
Type:
Grant
Filed:
July 14, 1986
Date of Patent:
April 25, 1989
Assignee:
Aluminum Company of America
Inventors:
Ajay Sood, Hubert L. Fleming, John W. Novak, Jr.
Abstract: Disclosed is generally spherical aluminum hydroxide particles comprised of solid crystals of aluminum hydroxide, the crystals extending radially outwardly from a central core region and having a shape selected from lamellar and acicular, the particle density ranging from 0.3 to 2.5 gms/cc.
Abstract: A method for purifying silicon comprises the steps of providing a body of molten silicon-rich material in a solvent metal comprising copper or copper-aluminum combination and extracting heat therefrom to provide a solid phase containing silicon in crystal form and to concentrate impurities in a molten phase. After a desired amount of heat has been extracted, a substantial part of the molten phase is separated from the solid phase. A fraction or portion of the solid phase is remelted for purposes of removing solvent metal comprising copper or copper-aluminum solvent metal, including impurities, from the crystals, and at least one fraction of the remelted material is separated from the crystals.
Abstract: Disclosed is a method of separating organic or organometallic materials under supercritical fluid conditions, the method comprising the steps of providing a bed of packing material selected from a metal oxide/hydroxide support material having phosphorous-containing organic molecules bonded to reactive sites on said support material, alumina and alumina-containing mixtures. The materials are introduced to the bed and a fluid is added to the bed under supercritical fluid conditions. The fluid removes one of the materials from the bed.
Type:
Grant
Filed:
August 31, 1987
Date of Patent:
March 28, 1989
Assignee:
Aluminum Company of America
Inventors:
Robinson P. Khosah, John W. Novak, Douglas G. Weaver, Karen R. Fraser-Milla, Richard R. Burr
Abstract: A method of producing a recrystallized aluminum-lithium product having improved levels of strength and fracture toughness is disclosed. The method comprises the steps of: providing a lithium-containing aluminum base alloy comprised of 0.5 to 4.0 wt. % Li, 0 to 5.0 wt. % Cu, 0 to 5.0 wt. % Mg, 0.10 to 1.0 wt. % of a grain structure control element selected from the class consisting of Zr, Cr, Hf, Ti, V, Sc, and Mn, 0.5 wt. % max. Fe, and 5 wt. % max. Si, with the balance consisting essentially of aluminum and incidental elements and impurities; heating the body to a high presoak temperature to homogenize the alloy; cooling the alloy to a first hot working temperature; reheating the alloy, after hot working, back to a high annealing temperature; cooling the alloy to a second hot working temperature to produce a first product; reheating the alloy to a lower annealing temperature; and then cold working the alloy.
Abstract: Disclosed is a method of making an improved aluminum alloy coated sheet stock useful for fabricating into easy-open ends for beverage containers. The method comprises the steps of providing a body of an aluminum base alloy consisting essentially of, by weight, 4.0 to 5.5% Mg, 0.2 to 0.7% Mn, 0.05 to 0.40% Cu, the balance being aluminum, incidental elements and impurities and rolling the body to produce an aluminum sheet stock. The sheet stock is subjected to a structure refining operation to precipitate finally divided magnesium containing constituent and thereafter the sheet stock is coated with an organic coating material and cured at a temperature sufficiently low and for a period of time to avoid dissolving the precipitated constituent to provide coated sheet stock having improved levels of tensile strength and high levels of formability.
Type:
Grant
Filed:
December 30, 1985
Date of Patent:
March 14, 1989
Assignee:
Aluminum Company of America
Inventors:
Robert E. Sanders, Jr., Henry W. Kaanta, John K. McBride, Milton W. Milner, Terry A. Perigo, Samuel L. Shelby
Abstract: An improved process is disclosed for carbothermically producing an alkaline earth metal aluminide from an aluminum-bearing material which, in one aspect comprises forming a mixture of a carbonaceous reducing agent and a slag comprising the aluminum-bearing material, the alkaline earth metal compound; forming, at a first temperature, an alloy containing impurities in the slag; removing the alloy containing the impurities from the slag; and then heating the slag to a higher temperature to form the alkaline earth metal aluminide. The alkaline earth metal compound used in the process may comprise calcium carbide. Alternatively, both the alkaline earth metal compound and the aluminum-bearing material may be obtained using a calcium aluminate slag such as a byproduct from the steel industry. The calcium aluminate slag is purified in a preliminary step to remove silicon by alloying it with iron and them removing a ferrosilicon alloy formed in this step.
Abstract: An aluminum base alloy wrought product having an isotropic texture and a process for preparing the same is disclosed. The product has the ability to develop improved properties in the 45.degree. direction in response to an aging treatment and is comprised of 0.5 to 4.0 wt.% Li, 0 to 5.0 wt.% Mg, up to 5.0 wt.% Cu, 0 to 1.0 wt.% Zr, 0 to 2.0 wt.% Mn, 0 to 7.0 wt.% Zn, 0.5 wt.% max. Fe, 0.5 wt.% max. Si, the balance aluminum and incidental impurities. The product has imparted thereto, prior to a hot rolling step, a recrystallization effect to provide therein after hot rolling a metallurgical structure generally lacking intense work texture characteristics. After an aging step, the product has improved levels of properties in the 45.degree. direction.
Abstract: A weldable aluminum base alloy product is disclosed which is characterized by high strength, including high resistance to ballistic penetration and resistance to stress-corrosion cracking. The alloy consists essentially of from above 5 wt. % to 7 wt. % copper, 0 to 0.8 wt. % manganese, 0.1 wt. % titanium, 0 to 0.25 wt. % vanadium, 0 to 0.25 wt. % zirconium and 0.10 to 0.30 wt. % magnesium with the balance consisting essentially of aluminum. The alloy is cold worked a minimum amount equivalent to 6% stretching at room temperature after solution heat treatment and quenching, preferably by stretching. The alloy is then aged, after cold working, for at least 2 hours at a temperature of at least 121.degree. C. (250.degree. F.).
Type:
Grant
Filed:
June 8, 1987
Date of Patent:
October 17, 1989
Assignee:
Aluminum Company of America
Inventors:
Robert E. Sanders, Jr., Jocelyn I. Petit