Abstract: The present invention provides methods for reducing the level of free aldehydes in coatings for flexible substrates, such as tanned leather, and substantially aldehyde free substrates. The methods comprise applying to the substrate a composition of one or more aqueous emulsion or suspension composition of an acrylic polymer or silicon containing polymer that is made from, or contains one or more lower alkyl alcohol or degrades on storage or in use to form such an alcohol, and one or more water-insoluble to slightly water soluble aldehyde scavenger compound, followed by drying or curing the applied composition to form a coating. In addition, the methods provide enhanced aldehyde scrubbing, especially for acetaldehyde, by applying to a substrate an aqueous acrylic polymer or silicon containing polymer emulsion or suspension comprising a aldehyde scavenger compound that is substantially deprotonated, i.e. by raising the pH composition to 5.5 or higher.

Abstract: A curable composition, useful as a thermosetting binder, having a polycarboxy polymer or co-polymer and a multifunctional polyol.

Abstract: A binder composition comprising an emulsion copolymer, and a polyol crosslinker.

Abstract: The present invention provides methods of making composite materials comprising combining particles of crosslinked rubber with coagulated aqueous polymer dispersions to form a mixture in aqueous dispersion, and subjecting the aqueous dispersion mixture to solid state shear pulverization to form materials that can be processed as thermoplastics at crosslinked rubber concentrations of from 10 to as high as 95 wt. %, based on the total solids of the material. The method may further comprise kneading the pulverized product to form useful articles, such as roofing membranes and shoe soles.

Abstract: The present invention provides methods of making shapeable composites in the form of finely divided materials or articles and the materials and articles produced by the methods, the methods comprising forming mixtures by (i) treating an aqueous thermoplastic acrylic or vinyl polymer to increase the particle size thereof to a weight average particle size of 1 ?m or more, and, optionally, dewatering to form a crumb mixture; and (ii) combining a thermoplastic acrylic or vinyl polymer with one or more waste rubber vulcanizate having a sieve particle size ranging from 10 to 600 ?m in the amount of from 15 to 95 wt. %, based on the total weight of polymer and rubber to form a crumb slurry, such that (ii) can take place before, during, after (i) but before any dewatering, or after any dewatering; and (iii) thermoplastic processing the mixture. Thermoplastic processing can directly form articles, like sheets or films. The shapeable composites have excellent adhesion to other materials.

Abstract: The present invention provides methods of making composite materials comprising combining particles of crosslinked rubber with one or more aqueous polymer dispersion of a suspension polymer to form a mixture in aqueous dispersion, and, optionally, subjecting the aqueous dispersion mixture to solid state shear pulverization to form materials that can be processed as thermoplastics at crosslinked rubber concentrations of from 10 to as high as 95 wt. %, based on the total solids of the material. The method may further comprise kneading and/or compression molding the pulverized product to form useful articles, such as roofing membranes and shoe soles.

Abstract: A curable composition useful as a thermosetting binder, comprising a polycarboxy polymer or copolymer, a polyol, and, optionally, a phosphorous containing compound.

Abstract: A curable binder composition consisting essentially of one or more ammonium salt of an inorganic acid and at least one carbohydrate, and the use thereof as a thermosetting binder. Also described are composite materials comprising the curable binder composition, and methods of application.

Abstract: A water redispersible polymer powder is produced by drying an aqueous mixture of a high Tg carboxylated styrene butadiene polymer and a low Tg carboxylated styrene butadiene polymer, where the ratio of the mean or average particle size of the high Tg polymer to the particle size of the low Tg polymer is from 1:1 to 5:1, preferably from 1:1 to 3:1, and the amount of the high Tg polymer is from 20 wt. % to 35 wt. %, preferably from 25 wt. % to 30 wt. %, based upon the total weight of the high Tg polymer and the low Tg polymer. Cement compositions such as mortars, which contain the redispersible polymer powder exhibit unexpectedly superior high bond strength and high impact resistance.

Abstract: A coating for paperboard comprises an aqueous dispersion of a hollow core binder comprising a first polymer that, when dry, has at least one void, the first polymer being substantially encapsulated by at least one second polymer having a glass transition temperature (Tg) ranging from more than ?15° C. and up to and including 30° C., wherein the weight ratio of the said second polymer to the said first polymer ranges from 1:1 to 4:1. One or both of the first polymer and the second polymer may be formed from, as polymerized units, at least one ethylenically unsaturated monomer. The hollow core binder allows for glossy, bright and smooth paperboard coatings while reducing the amount of binder and opacifying pigment necessary to achieve such coating properties. The present invention also provides coated paperboard articles, as well as paper and paperboard that is made from a mixture of pulp with the inventive hollow core binder.

Abstract: A curable aqueous binder composition comprising one or more amine reactant selected from the group consisting of: a protein, a peptide, an amino acid, an ammonium salt of a polycarboxylic acid, an ammonium salt of a (poly)hydroxy-(poly)carboxylic acid; one or more carbohydrate; and one or more emulsion polymer; and the use thereof as thermosetting binders. Also described are composite materials comprising the curable binder composition, and methods of application.

Abstract: A curable binder composition comprising an emulsion polymer and a natural binder.

Abstract: A stable aqueous soy flour slurry comprising defatted soy flour, water, and a water soluble polymer dispersing agent having a molecular weight in the range of from 1,000 to 20,000, wherein the viscosity of the slurry is in the range from 200 to 2,000 cps as measured by a DV-III Ultra LV Viscometer viscometer at 6 rpm using spindle #31 at 25° C.; and a method for providing such a slurry.

Abstract: We form a weather-resistive barrier on a building by applying a compressible latex foam on the joints between adjacent sheets of construction sheathing, with the sheets having been coated with an aqueous coating composition.

Abstract: The present invention provides water repellant curable compositions comprising (i) one or more polyacid comprising at least two carboxylic acid groups, anhydride groups, or salts thereof, (ii) one or more polyol comprising at least two hydroxyl groups, (iii) one or more reactive waterproofing agent chosen from a C5 to C30 alk(en)yl 2-hydroxyethyl (alk(en))amide, C5 to C30 alk(en)yl bis(2-hydroxyethyl)amide, C11 to C30 alk(en)yl 2-hydroxyethyl (alk(en))amine, C11 to C30 alk(en)yl bis(2-hydroxy-ethyl)amine, C11 to C30 alk(en)yl tris(2-hydroxyethyl)amine, C5 to C30 alk(en)yl monoglyceride, C5 to C30 alk(en)yl monocarboxylate of a trihydric polyol, and mixtures thereof, and, (iv), optionally, one or more phosphorous-containing accelerator, wherein the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof to the total number of equivalents of said hydroxyl groups is from 1/0.01 to 1/3.

Abstract: The present invention provides coating powder compositions for making filiform corrosion resistant coatings, the compositions comprising particles or agglomerates which include, intimately mixed, each of one or more thermosetting acrylic copolymer, one or more crosslinker for the acrylic copolymer and one or more hydrophobic submicron particle additive, wherein the hydrophobic submicron particle additive comprises from 0.01 to 1.5 wt. %, based on the total weight of the coating powder. The hydrophobic submicron particle additive comprises a submicron inorganic oxide, e.g. fume silica or a metal oxide, and one or more organosilicon compound, e.g. polydimethylsiloxane. In addition, the invention provides filiform corrosion resistant clear coat or tinted clear coat powder coatings on metal, e.g. aluminum wheels or forged alloy substrates.

Abstract: The present invention provides fast-drying aqueous compositions that lower the cost of making roadway markings without impairing the quality or appearance of the markings made therewith. The aqueous compositions comprise one or more hollow core binder having an average particle size of from 200 to 500 nanometers (nm), preferably from 300 to 470 nm, and made of a first polymer having a glass transition temperature (Tg) of 50° C. or more and containing one or more void, the first polymer being substantially encapsulated by one or more second polymer having a Tg of ?30° C. or more, preferably, ?20° C. or more. Fast-drying aqueous compositions may be one component or two component compositions.

Abstract: The present invention provides storage stable powder compositions comprising one or more carboxylic acid or anhydride functional, phosphorus-containing polyester chosen from aromatic polyesters having an acid number of 15 or higher mg KOH/g polyester, aliphatic polyesters having an acid number of 20 or higher mg KOH/g polyester. The acid functional, phosphorus-containing polyester comprises the reaction product of one or more polyacid, one or more phosphorus-containing acid or salt thereof and one or more polyol. Preferably, the one or more polyol reactant contains no ?-hydrogen such as, for example, neopentyl glycol (NPG). The acid functional, phosphorus-containing polyester may comprise all or part of a binder powder composition, such as a coating powder, or it may comprise an additive thereto that imparts improved pigment wetting and corrosion resistance to a binder composition.

Abstract: According to the present invention, aqueous multi-stage polymer dispersions comprising an acid-functional first polymer and an epoxy-functional second polymer, wherein 90 mole % or more of the said epoxy groups, based on the moles of epoxy groups in the monomer mixture used to form the second polymer, are retained in the aqueous dispersion after said dispersion is stored in a sealed container for 10 days at 60° C. Further, methods of making the aqueous multistage polymer dispersion comprise polymerizing the monomers used to make the second polymer in the presence of an aqueous dispersion of the first polymer. Preferably, the second polymer is formed in the presence of 0.3 wt. % or less, based on the total weight of the first polymer and the ingredients to form the second polymer, of one or more strong acid surfactant, and 3) 0.1 wt.

Abstract: A paint manufacturing method includes receiving each of a group of fluid prepaints at different inputs of a fluid component mixing system, determining at a computer system a first fluid prepaint ratio, and mixing the fluid prepaints in accordance with the first ratio to form a base paint at an output of the mixing system. A paint manufacturing system includes a computer-controlled prepaint mixing system. The prepaint mixing system includes multiple fluid inputs providing for computer-controllable flow of prepaints into the mixing system. The computer system includes a memory storing software instructions that configured the computer system to receive user input selecting a base paint to be produced, determine a ratio of fluid prepaints needed to produce the base paint, and regulate each fluid flow control to establish, in the determined ratio, a flow of fluid prepaints entering the fluid mixing system.