Abstract: A process for preparing a melt transesterification catalyst is disclosed. The process entails (i) obtaining a phenol adduct of phosphonium phenolatein the form of crystalline solid and (ii) storing the solid phenol adductin a closed container at relative humidity of 30 to 70 % and at temperature of −30 to 50° C. The thus prepared catalyst is suitable in the production of polycarbonate in the melt transesterification process.

Abstract: The present invention relates to thermoplastic polycarbonate molding compositions which contain phosphazenes and special graft polymers produced by means of redox initiator systems and are distinguished by substantially improved mechanical properties.

Abstract: A process for working up polymer components prepared by emulsion polymerization is disclosed. The process is characterized in that coagulation of the aqueous polymer latex present after emulsion polymerization is performed using a combination of A) an aqueous solution of at least one salt selected from the group consisting of sodium chloride, calcium chloride, magnesium chloride, aluminum chloride, sodium sulfate, magnesium sulfate and aluminum sulfate, B) an aqueous solution of at least one salt of an acid selected from the group consisting of hypophosphorous acid (H3PO2), phosphorous acid (H3PO3 or HPO2) and ascorbic acid and optionally C) an aqueous dilute acid selected from the group consisting of sulfuric acid, phosphoric acid and acetic acid.

Abstract: A flame retardant thermoplastic molding composition is disclosed. The composition contains an amorphous thermoplastic polymer, at least one flame retardant in the form of a fully or partially halogenated sulfonic acid salt and at least on alkaline earth metal sulfate and/or one oxide having an average particle size of up to 400 nm.

Abstract: The present invention relates to polycarbonate/ABS moulding compositions with incorporated phosphazenes which exhibit excellent flame resistance and very good processing characteristics, wherein the graft polymer is produced by bulk, solution or bulk/suspension polymerization processes.

Abstract: A process for the removal and recovery of quaternary salt (A) and base (D) from a reaction mixture is disclosed. The reaction mixture resulting from oxidative direct carbonylation contains in addition to (A) and (D), at least one hydroxyaromatic compound (B) and at least one reaction product (C) and optionally a solvent, and the process entails a) adding acid to the reaction mixture to cause conversion of (D) into a hydroxyaromatic compound (B2) b) separating the reaction mixture into b1.) that contains (C) and optionally (B) and/or (B2) and b2.) that contains (A) and optionally (B) and/or (B2), and c) reacting b1.) with a base (E) to re-form (D).

Abstract: A thermoplastic molding composition suitable for making articles having good combination of properties is disclosed. The composition contains (A) a copolycarbonate derived from compounds of formula (I) wherein R1 to R4 independently of one another represent H, C1-C4-alkyl, phenyl, substituted phenyl or halogen, and compounds of formula (II) wherein R5 to R8 independently of the others denote H, CH3, Cl or Br and X is C1-C5-alkylene, C2-C5-alkylidene, C5-C6-cycloalkylene, C5-C10-cycloalkylidene, and (B) a homopolycarbonate derived from bisphenol A. The composition that features resistance to stress cracking and good low-temperature properties is suitable for automotive construction and exterior applications.

Abstract: The invention relates to a novel polycarbonate and its use a material in the production of molded articles and semifinished products, especially for transparent articles such as data memories or radio compact discs, slabs, cellular sheets, films, housings, panes, especially panes for motor vehicles, diffusion glasses, but also for electrical applications or the constructions of houses.

Abstract: A Polycarbonate molding composition is disclosed. The composition that contains a compound conforming to the general formula (I) wherein A represents a C10 to C40-fatty acid radical, B represents a trivalent alcohol having 3 to 20 carbon atoms, C represents a dicarboxylic acid radical having 4 to 40 carbon atoms, and n represents an integer from 0 to 15, is suitable for making a variety of molded articles having surface of good quality.

Abstract: A solid and/or cellular polyurethane elastomers which are produced using polyester polyols are disclosed. The elastomers which exhibit improved stability to hydrolysis are characterized in that their preparation is carried out in the presence of at least one esters of monobasic carboxylic acid or polybasic carboxylic acids, the (first) dissociation constant (pK) of which is 0.5 to 4.

Abstract: A process for using low-molecular weight compounds that are water-extracted from (co)polyamides in the production of polyamide is disclosed. The process entails reacting these compounds with 10 to 15 wt. % water for a period of 3.5 to 6 hours at a temperature of 220° C. to 270° C., and polymerizing the resulting product along with caprolactam.

Abstract: A process for the production of polymers by means of pseudo-living free-radical polymerization is disclosed. The process entails (i) reacting a polymerizable vinyl monomer with nitrogen monoxide and at least one initiator to prepare a free-radical intermediate product, and (ii) polymerizing the intermediate product optionally together with one or more additional monomers and/or with a free-radical initiator.

Abstract: Impact-resistant polycarbonate and/or polyester carbonate compositions containing at least one oxalate compound selected from the group consisting of metal oxalates, metal hydroxy oxalates, oxalic acid esters and metal salts of oxalic acid esters in quantities of 0.1 to 5 parts by weight (based on 100 parts by weight of the total composition) display an advantageous combination of flow line strength and stress-cracking resistance on exposure to chemicals combined with high thermal stability and good processing properties and they are also flame-resistant.

Abstract: A thermoplastic molding composition comprising polycarbonate, an impact modifier, a phosphorus-containing flameproofing agent, and high purity talc is disclosed. The composition offers flame resistance for molded parts having small wall thickness, improved rigidity and resistance to stress cracking. The talc has MgO content of 30.5 to 32 wt. %, SiO2 content of 60 to 62.5 wt. % and Al2O3 content lower than 0.7 wt. % and d50 value less than or equal to 2.5 &mgr;m.

Abstract: The use of zwitterionic compounds as mold release agents in thermoplastics is disclosed. Molding compositions having good release properties, preferably compositions containing polycarbonate resins are thus disclosed.

Abstract: Transparent moldings comprising a polymeric base material and at least one coating formed thereon is disclosed. The coating includes a primer coat that containing an epoxy and/or acrylic resin is disposed on at least one surface of the base material, a heat-absorbing coating which contains a polythiophene compound and a scratch-resistant coating. In an additional embodiment of the invention, the coating contains no primer and the heat absorbing coating contains a polythiophene compound.

Abstract: A process of dyeing a molded article is disclosed. The process entails immersing at least a portion of the article in a dyeing bath, retaining the portion in the bath for a period of time sufficient to allow an amount of dye to diffuse into the article, and removing said article from the bath. The molded article comprises a polymeric resin such as (co)polyester, (co)polycarbonates, acrylonitrile-butadiene-styrene, polyamide, polyurethane, polyalkyl(meth)acrylate, allyldiglycol carbonate and styrene copolymers. The dyeing bath contains in addition to dye, water, a plasticizing agent and a leveling agent.

Abstract: A process for the separation and recycling of catalyst components from a chemical reaction mixture is disclosed. The process entails at least one extraction step.

Abstract: A process for the separation a substantially adduct-free diaryl carbonate from reaction solution is disclosed. The process entails obtaining a solution that contains diaryl carbonate, catalyst system components and an aromatic solvent, lowering the temperature of the solution, optionally in the presence of a nucleating agent, to produce a crystallization product, and washing the crystallization product with an anhydrous wash solution to remove catalyst residues and impurities.

Abstract: A thermoplastic molding composition that features improved low-temperature properties and is thus suitable for application in exterior automotive parts is disclosed. The composition contains (A) 80 to 60 percent of a copolycarbonate wherein 65 to 75 mole percent of its structural units are derived from compounds of formula (I) wherein R1, R2, R3 and R4 independently of one another represents H, C1-C4-alkyl, phenyl, substituted phenyl or halogen, and wherein 25 to 35 mole percent of its structural units are derived from compounds of formula (II) where R5, R6, R7 and R8 independently one of the others denote H, CH3, Cl or Br and X is C1-C5-alkylene, C2-C5-alkylidene, C5-C6-cycloalkylene, C5-C10-cycloalkylidene and (B) 20 to 40 percent of a homopolycarbonate of bisphenol A having a melt flow rate, determined in accordance with ASTM D-1238 under 1.2 kg loading at 300° C. of 3 to 12 gm/10 minutes.