Abstract: An extruded polycarbonate article suitable as an energy absorber is disclosed. The article includes a plurality of honeycomb chambers that are aligned substantially in the same direction, extend in the direction of the extrusion and are disposed adjacent to one another. A method of using the article entails aligning the honeycomb chambers in a direction parallel to the direction of the impact energy.
Abstract: A device for mixing and reacting multiphase gaseous and liquid mixtures is disclosed. The device comprise in sequence a first inflow cylindrical space, at least one cylindrical chamber tapering towards said cylindrical space, a second cylindrical space positioned perpendicularly to said first cylindrical space, and an outflow space. Also disclosed is a method of using the device, in particular in the interfacial process for preparing diphenyl carbonates or polycarbonates.
Type:
Grant
Filed:
August 8, 2001
Date of Patent:
April 27, 2004
Assignee:
Bayer Aktiengesellschaft
Inventors:
Werner Breuer, Frieder Heydenreich, Günter Jeromin, Helmut Judat
Abstract: A process for the preparation of a solution of a quaternary cation and an anion from a deprotonated hydroxy aromatic in an organic solvent by means of a reactive extraction of a quaternary salt in the presence of an aqueous hydroxide solution, a hydroxy aromatic and an organic solvent is disclosed. Also disclosed is a process for the recycling of a quaternary salt phenolate solution from a reaction mixture.
Type:
Grant
Filed:
December 16, 2002
Date of Patent:
April 27, 2004
Assignee:
Bayer Aktiengesellschaft
Inventors:
Claus-Peter Reisinger, Sven Michael Hansen, Peter Fischer, Michael Traving
Abstract: A thermoplastic molding composition having an improved profile of properties is disclosed. The composition contains A) a graft rubber that is a product of free-radical emulsion polymerization of vinyl monomers in the presence of rubber a) that is present in latex form and having a glass transition temperature below 0° C., using at least one peroxydisulfate compound as an initiator, and B) a graft rubber that is a product of free-radical emulsion polymerization of vinyl monomers in the presence of at least one rubber b) that is present in latex form and having a glass transition temperature below 0° C.
Abstract: The invention provides moulded items made from thermoplastic polyurethanes (TPUs), in particular medical articles such as central venous catheters which contain a homogeneous distribution of antibiotic substances, a process for the preparation thereof and preparation of the active substance-containing TPUs.
Type:
Grant
Filed:
September 15, 2000
Date of Patent:
April 20, 2004
Assignee:
Bayer Aktiengesellschaft
Inventors:
Reinhard Albers, Ralf Dujardin, Heinz Pudleiner, Joachim Simon, Günther Eberz, Wolfgang Kreiss, Christina Krasemann-Sharma
Abstract: A process for producing polymer pellets is disclosed. The process that is particular suitable for making polycarbonate pellets entails extruding a polymer melt, cooling the extrudate by contacting it with a cooling fluid and pelletizing the solidified polymer. The process is characterized in that the cooling fluid has a solids particle content of at most 10 ppm.
Abstract: The present invention relates to a process for working up solutions of polymers in organic solvents contaminated by alkaline constituents, using homogeneously soluble acids, especially by the introduction of an acid gas, and subsequent washing, and to the polymers so obtainable, which are distinguished by the fact that, on treatment with moist heat (sterilisation), only few defects caused by decomposition are formed, to the use thereof in the production of extrudates and molded specimen, and to the extrudates and molded specimen produced from those polymers themselves.
Type:
Grant
Filed:
July 16, 2002
Date of Patent:
April 6, 2004
Assignee:
Bayer Aktiengesellschaft
Inventors:
Wolfgang Alewelt, Wolfgang Ebert, Thomas Fritz, Dirk Jahn, Stefan Westernacher, Frank Bruynseels, Johann Rechner
Abstract: A molding composition containing a graft polymer is disclosed. The graft is a product of a free-radical emulsion polymerization of resin-forming vinyl monomers in the presence of rubber present in latex form having a glass transition temperature of ≦0° C. using an initiator combination comprising a persulfate compound and a redox initiator system. The process for preparing the graft polymer entails adding the persulfate compound at the beginning of the graft polymerization reaction and a later addition of the redox initiator. The composition that features good gloss and flowability is suitable for the preparation of molded articles.
Type:
Grant
Filed:
April 15, 2002
Date of Patent:
April 6, 2004
Assignee:
Bayer Aktiengesellschaft
Inventors:
Liqing-Lee Sun, Herbert Eichenauer, Heinrich Alberts
Abstract: Compositions containing:
I. at least two components selected from the group comprising aromatic poly(ester) carbonates, graft polymers of one or more vinyl monomers on one or more graft bases having a glass transition temperature of <10° C., a thermoplastic vinyl (co)polymer, or poly(alkylene terephthalate) as well as
II. 0.5 to 25 parts by weight of a mixture of phosphorus compounds of the general formula (I)
with the proviso that the composition contains at least 2 phosphorus compounds of the formula (I) in which X or one or more radicals R1, R2, R3 and R4 is/are different and wherein the sum of the parts by weight of the components is 100.
Type:
Grant
Filed:
December 3, 2001
Date of Patent:
March 30, 2004
Assignee:
Bayer Aktiengesellschaft
Inventors:
Thomas Eckel, Andreas Seidel, Dieter Wittmann, Uwe Peucker
Abstract: A thermoplastic molding composition is disclosed. The composition that contains a polymer selected from the group consisting of a polycarbonate, a transparent polycarbonate-polyester-blend, a copolyestercarbonate and a transparent polyester and a compound of formula (I)
and one or more compounds of formula (II)
wherein a is 1 to 17, b is 0 to 16, c is 6 to 14, d is 3 to 7, e is 6 to 14, f is 3 to 7, g is 5 to 40 and a+b is 9 to 25 and n is 1 to 10, was found to be especially suitable for co-extrusion applications.
Type:
Grant
Filed:
February 3, 2003
Date of Patent:
March 30, 2004
Assignee:
Bayer Aktiengesellschaft
Inventors:
Rüdiger Gorny, Siegfried Anders, Wolfgang Nising, Wolfgang Ebert
Abstract: A thermoplastic molding composition that contains a polycarbonate resin having specific extensional Theological properties is disclosed. The composition is particularly suitable for preparing containers.
Type:
Grant
Filed:
March 24, 2003
Date of Patent:
March 30, 2004
Assignee:
Bayer Aktiengesellschaft
Inventors:
Klaus Horn, Ralf Hufen, Markus Krieter, Dirk-Jacques Dijkstra, Jens Hepperle, Helmut Münstedt
Abstract: A process for the production of phosphonium phenolates is disclosed. The process entails reacting a phosphonium halide and phenol in an aqueous alkaline solution.
Abstract: Solid particles containing 10 to 90 parts by weight of a dihydroxy compound and 10 to 90 parts by weight of a carbonic acid ester are disclosed. Also disclosed is a process for the production of these particles, an apparatus suitable for the process and a method for their use in production of polycarbonate by transesterification of carbonic acid esters with dihydroxy compounds.
Abstract: A method for producing polycarbonate based on 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethyl cyclohexanone and 4,4-(metaphenylene diisopropyl) diphenol is disclosed. The method is characterized in that the recovery and/or further processing of the polycarbonate is performed at temperatures below 290° C. The polycarbonate thus produced has high purity and high transmission and is suitable for the manufacture of optical data stores.
Type:
Grant
Filed:
July 10, 2002
Date of Patent:
March 23, 2004
Assignee:
Bayer Aktiengesellschaft
Inventors:
Tony van Osselaer, Steffen Kühling, Paul Viroux, Hugo Plompen, Richard Vansant
Abstract: Flame-resistant, thermoplastic moulding compositions containing
A) 70 to 98 parts by weight of an aromatic polycarbonate,
B) 0.5 to 20 parts by weight of a graft polymer,
C) 0.5 to 5 parts by weight of a mixture of
C.1) 10 to 90 parts by weight, based on C, of a monophosphorus compound of formula (I)
C.2) 90 to 10 wt. %, based on C, of a phosphorus compound of formula (II)
D) 0.05 to 5 parts by weight of a fluorinated polyolefin with an average particle diameter of 0.05 to 1000 &mgr;m, a density of 1.2 to 2.3 g/m3 and a fluorine content of 65 to 76 wt. %.
Type:
Grant
Filed:
November 17, 1999
Date of Patent:
March 16, 2004
Assignee:
Bayer Aktiengesellschaft
Inventors:
Thomas Eckel, Michael Bödiger, Dieter Wittmann, Heinrich Alberts, Klaus Horn
Abstract: A thermoplastic molding composition comprising polycarbonate resin having improved mold release properties is disclosed the composition contain polycarbonate resin and 0.005 to 5.0% relative to the weight of the composition of at least one hydrocarbon in the form of C15-600-methyl-branched alkane. The hydrocarbon is characterized in that the weight proportion of its branches is 5 to 30 percent relative to the weight of carbons in the alkane chain.
Type:
Grant
Filed:
January 9, 2002
Date of Patent:
March 16, 2004
Assignee:
Bayer Aktiengesellschaft
Inventors:
Wolfgang Ebert, Ralf Kaufmann, Christoph Schwemler, Wilfried Haese, Peter Fischer, Martin Döbler, Joachim Genz
Abstract: A process for producing polycarbonate is disclosed. The process entails transesterification of at least one carbonic ester with a mixture that contains dihydroxyl compound and phenol. The amount of bisphenol A in the mixture is 10 to 100 mol % relative to the amount of dihydroxyl compound and phenol is present in the mixture in an amount of 0.1 to 200% relative to the weight of bisphenol A.
Abstract: A process for removing low molecular weight constituents from polyamide 6 or from copolyamides based on caprolactam (herein (co)polyamide) is disclosed. The process comprise subjecting the (co)polyamide to liquid-extraction at a temperature which is above the boiling point of the liquid at atmospheric pressure said liquid containing water in an amount of at least 80 percent relative to its weight.
Type:
Grant
Filed:
May 15, 2002
Date of Patent:
March 2, 2004
Assignee:
Bayer Aktiengesellschaft
Inventors:
Heinrich Haupt, Dieter Göbbels, Konrad Triebeneck, Andreas Gittinger
Abstract: A melt-polymerized polycarbonate is disclosed. The polycarbonate has a shear thinning ratio (y) that is defined by the limiting values of the following equation
c+axb>y>−c+axb (Q)
wherein y≧1, c=0.3 to 0.1, b=14.831±0.05 to 0.02, a=0.1262±0.005 to 0.003 and x is the relative viscosity of the polycarbonate. The polycarbonate exhibits a flow behavior similar to that of a linear polycarbonate of comparable molecular weight obtained by the interface polymerization process.
Type:
Grant
Filed:
March 22, 2002
Date of Patent:
March 2, 2004
Assignee:
Bayer Aktiengesellschaft
Inventors:
James Mason, Silke Kratschmer, Uwe Hucks