Patents Represented by Attorney Carl G. Seutter
  • Patent number: 5397456
    Abstract: Heavy oils may be hydrotreated in the presence of a porous alumina support bearing metals of Group VIII and VI-B and optionally phosphorus, the catalyst having a Total Surface Area of 240-310 m.sup.2 /g, a Total Pore Volume of 0.5-0.75 cc/g, and a Pore Diameter Distribution whereby 63-78% of the Total Pore Volume is present as micropores of diameter 55-115A and 11-18% of the Total Pore Volume is present as macropores of diameter greater than 250A. The heavy oils and hydrogen are contacted with the catalyst such that the catalyst is maintained at isothermal conditions and is exposed to a uniform quality of feed. The process is particularly effective in achieving desired levels of hydroconversion of feedstock components having a boiling point greater than 1000.degree. F. to products having a boiling point less than 1000.degree. F.
    Type: Grant
    Filed: February 19, 1993
    Date of Patent: March 14, 1995
    Assignee: Texaco Inc.
    Inventors: Pei-Shing E. Dai, David E. Sherwood, Jr.
  • Patent number: 5370788
    Abstract: Charge waxy hydrocarbon is converted to lube oil base stock by hydrotreating in the presence of catalyst characterized by its ability to convert a waxy hydrocarbon distillate of high pour point to a hydrocarbon product of reduced pour point and high viscosity index, suitable for use as a lube oil base stock, which comprises a support containing about 2-50 w % silica and 50-98 w % alumina, bearing 2-10 w % of a non-noble Group VIII metal, as metal, metal oxide, or metal sulfide, about 8-20 w % of a Group VI-B metal, as metal, metal oxide, or metal sulfide, less than 0.5% halogen; and 0-2 w % of phosphorus, the atom ratio of Group VIII metal to Group VI-B metal being about 0.3-2:1, said catalyst being characterized by a micropore mode of about 60-130 .ANG. diameter, a Total Surface Area of about 150-300 m.sup.2 /g, a Total Pore Volume of about 0.45-0.9 cc/g and a Pore Volume of pores with pore diameter >500 .ANG. of about 0.02-0.25 cc/g.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: December 6, 1994
    Assignee: Texaco Inc.
    Inventors: Pei-Shing E. Dai, Joseph A. Durkin, Bobby R. Martin
  • Patent number: 5358633
    Abstract: Hydrodesulfurization of a cracked naphtha is effected in the presence of a transition alumina support bearing a Group VIII non-noble metal oxide and a Group VI-B metal oxide, the atom ratio of Group VIII metal to Group VI-B metal being 1-8. The process of the instant invention gives high levels of hydrodesulfurization compared to prior art magnesia-containing catalysts and lower levels of olefin saturation, and less octane reduction in the desulfurized gasoline.
    Type: Grant
    Filed: May 28, 1993
    Date of Patent: October 25, 1994
    Assignee: Texaco Inc.
    Inventors: Eugene Pei-Shing Dai, David E. Sherwood, Jr.
  • Patent number: 5358629
    Abstract: A waste molybdenum-containing stream recovered from the work-up of a reaction mixture wherein propylene has reacted with t-butyl hydroperoxide to form propylene oxide (in the presence of a complex of ethylene glycol and a molybdenum compound) is passed as an oil-miscible/soluble molybdenum-containing catalyst to a reaction wherein heavy hydrocarbon is hydroconverted to lower boiling products in the presence of heterogeneous catalyst.
    Type: Grant
    Filed: January 21, 1993
    Date of Patent: October 25, 1994
    Assignee: Texaco Inc.
    Inventors: George R. Tamalis, David D. Chess, Mahendra S. Patel, Ajit K. Bhattacharya, Robert M. Gipson
  • Patent number: 5354452
    Abstract: A novel zeolite characterized by a large number of secondary pores, a substantially decreased lattice constant, and a substantially decreased acid site density is attained by hydrothermal and acid-treating of an ultrastable Y-zeolite or a superultrastable Y-zeolite.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: October 11, 1994
    Assignee: Texaco Inc.
    Inventors: Eugene P. Dai, David E. Sherwood, Jr., Burton H. Bartley
  • Patent number: 5340466
    Abstract: Hydrodesulfurization of a cracked naphtha is effected in the presence of, as catalyst, an alkali metal, a metal of Group VIII, and a metal of Group VI-B on an alumina support containing a hydrotalcite-like composition.
    Type: Grant
    Filed: April 19, 1993
    Date of Patent: August 23, 1994
    Assignee: Texaco Inc.
    Inventors: Pei-Shing E. Dai, David E. Sherwood, Jr., Randall Hughes Petty
  • Patent number: 5292426
    Abstract: Hydrocarbon lube boiling range stock of high Pour Point may be catalytically hydrotreated to yield a product of high viscosity index and reduced Pour Point which is suitable as a lube base oil.
    Type: Grant
    Filed: October 18, 1991
    Date of Patent: March 8, 1994
    Assignee: Texaco Inc.
    Inventors: John B. Holland, Gerald F. Prescott, Dann G. Roy, Avilino Sequeira, Jr., James R. Whiteman
  • Patent number: 5281337
    Abstract: Membrane separation process is improved by use, as a support membrane, of (i) a polyacrylonitrile membrane on which at least a portion of the surface --CN groups have been hydrolyzed to --COOH groups or (ii) a membrane formed of polyacrylonitrile and polyacrylic acid.
    Type: Grant
    Filed: July 13, 1992
    Date of Patent: January 25, 1994
    Assignee: Texaco Inc.
    Inventors: Kechia J. Chou, Kathleen M. Hellmuth
  • Patent number: 5266300
    Abstract: Hydrodesulfurization and demetallalization of hydrocarbon charge is effected by hydrogenation in the presence of, as catalyst, a Group VI A metal and a non-noble Group VIII metal on a trimodal alumina support. The alumina support is formed by mixing at least two different finely divided charge aluminas each of which has a different pore mode.
    Type: Grant
    Filed: August 2, 1989
    Date of Patent: November 30, 1993
    Assignee: Texaco Inc.
    Inventor: Jeffrey B. Harrison
  • Patent number: 5240591
    Abstract: A charge containing dewaxed oil/dewaxing solvent may be treated to effect separation of components by a thermally cross-linked hydrocarbon-derived elastomer membrane, typified by polybutadiene.
    Type: Grant
    Filed: September 3, 1991
    Date of Patent: August 31, 1993
    Assignee: Texaco Inc.
    Inventor: Mordechai Pasternak
  • Patent number: 5238573
    Abstract: Mixtures containing methanol and dimethyl carbonate or methanol and methyl t-butyl ether may be treated by pervaporation to recover product containing decreased quantity of methanol.
    Type: Grant
    Filed: April 9, 1992
    Date of Patent: August 24, 1993
    Assignee: Texaco Inc.
    Inventor: Mordechai Pasternak
  • Patent number: 5238567
    Abstract: A charge containing dewaxed oil/dewaxing solvent may be treated to effect separation of components by a thermally cross-linked hydrocarbon-derived elastomer membrane, typified by polybutadiene.
    Type: Grant
    Filed: January 29, 1993
    Date of Patent: August 24, 1993
    Assignee: Texaco Inc.
    Inventor: Mordechai Pasternak
  • Patent number: 5234579
    Abstract: Dewaxed oil containing dewaxing solvent from solvent dewaxing is treated by contact with a separating elastomer membrane to yield a retentate containing increased content of dewaxed oil and decreased content of dewaxing solvent and a permeate which contains increased content of dewaxing solvent and decreased content of dewaxed oil--the membrane including a barrier layer of an adduct of maleic acid anhydride and a poly(aliphatic terpene) which has been thermally cross-linked.
    Type: Grant
    Filed: March 19, 1991
    Date of Patent: August 10, 1993
    Assignee: Texaco Inc.
    Inventor: Mordechai Pasternak
  • Patent number: 5206157
    Abstract: N-substituted dialkanolamine may be converted to N-substituted-2-morpholone by the action of Gluconobacter oxydan ATCC #621 or Gluconobacter roseus IAM 1841.
    Type: Grant
    Filed: September 28, 1988
    Date of Patent: April 27, 1993
    Assignee: Texaco Inc.
    Inventor: Kechia J. Chou
  • Patent number: 5183482
    Abstract: Mixture of gases such as hydrogen/carbon dioxide may be separated by use of membrane formed by reaction of an aluminum alkoxide with steam at high temperatures and pressures.
    Type: Grant
    Filed: June 19, 1991
    Date of Patent: February 2, 1993
    Assignee: Texaco Inc.
    Inventors: Mitri S. Najjar, Martin D. Hilmar
  • Patent number: 5181941
    Abstract: A novel membrane system, including a layer of platinum or palladium on graphite, is used to separate hydrogen from a hydrocarbon stream.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: January 26, 1993
    Assignee: Texaco Inc.
    Inventors: Mitri S. Najjar, Carl A. Hultman
  • Patent number: 5182022
    Abstract: Charge aqueous solution containing 85 w % ethylene glycol is concentrated by pervaporation across a sulfonated polyethylene membrane to yield retentate containing 95 w % ethylene glycol.
    Type: Grant
    Filed: June 19, 1991
    Date of Patent: January 26, 1993
    Assignee: Texaco Inc.
    Inventors: Mordechai Pasternak, John Reale, Jr.
  • Patent number: 5171449
    Abstract: Charge compositions containing aqueous mixtures of organic nitrogen compounds may be separated by pervaporation through a membrane assembly containing a porous ceramic support bearing as separating layer, polyvinyl alcohol which has been cross-linked as with glutaraldehyde.
    Type: Grant
    Filed: January 6, 1992
    Date of Patent: December 15, 1992
    Assignee: Texaco Inc.
    Inventors: Mordechai Pasternak, Uygur Kokturk
  • Patent number: 5160046
    Abstract: Aqueous solutions of organic oxygenates, typified by concentrated aqueous solutions of ethanol or isopropanol, are dewatered by pervaporation through a polyimine membrane which has been interfacially cross-linked with a polyisocyanate or a poly(carbonyl chloride).
    Type: Grant
    Filed: November 18, 1991
    Date of Patent: November 3, 1992
    Assignee: Texaco Inc.
    Inventor: Mordechai Pasternak
  • Patent number: 5160352
    Abstract: A porous support layer is loaded with blocking liquid, such as an alcohol, prior to contact with an aluminum alkoxide to form thereon a layer of alumina which is dried and calcined to yield a membrane suitable for separation of gases.
    Type: Grant
    Filed: September 6, 1991
    Date of Patent: November 3, 1992
    Assignee: Texaco Inc.
    Inventors: Mitri S. Najjar, Martin D. Hilmar