Abstract: A catalyst composition useful in the hydroprocessing of a sulfur- and metal-containing hydrocarbon feedstock comprises 1.0-5.0 weight percent of an oxide of nickel or cobalt and 10.0-25.0 weight percent of an oxide of molybdenum, all supported on a porous alumina support in such a manner that the molybdenum gradient of the catalyst has a value of less than 6.0 and 15-30% of the nickel or cobalt contained in the catalyst is in an acid extractable form. The catalyst is further characterized by having a total surface area of 150-210 m.sup.2 /g, a total more volume of 0.50-0.75 cc/g, and a pore size distribution such that pores having diameters of less than 100A constitute less than 25.0%, pores having diameters of 100-160A constitute 70.0-85.0% and pores having diameters of greater than 250A constitutes 1.0-15.0% of the total pore volume of the catalyst.
Type:
Grant
Filed:
May 13, 1988
Date of Patent:
September 10, 1991
Assignee:
Texaco Inc.
Inventors:
David E. Sherwood, Jr., Burton H. Bartley, Laurence D. Neff, Pei-Shing E. Dai
Abstract: Desalination of water is effected by use of a polyimine membrane which has been cross-linked with a combination of aliphatic and aromatic polyisocyanate or with a polycarbonyl chloride cross-linking agent.
Type:
Grant
Filed:
July 9, 1990
Date of Patent:
August 6, 1991
Assignee:
Texaco Inc.
Inventors:
Mordechai Pasternak, Abraham Morduchowitz
Abstract: An N-methyl pyrrolidone-containing middle distillate stream is separated by use of a polyethyleneimine membrane which has been cross-linked with a polyisocyanate or a poly(carbonyl chloride) cross-linking agent.
Abstract: Middle distillate fuels may be treated to improve storage stability by addition of, as additive, an acrylate polymer containing moieties derived from an N-heterocyclic amine such as 4-vinyl pyridine or the enamine ester of morpholine and propionaldehyde.
Abstract: A polyethylenimine membrane which has been cross-linked by heat treating at 100.degree. C.-200.degree. C. for 3-20 minutes may be used to dewater isopropanol or methyl ethyl ketone/toluene mixtures.
Abstract: Water-soluble organic electrolytes, such as anions of lower carboxylic acids in aqueous solution at low pH, are removed by raising the pH and subjecting the resultant charge liquid to nanofiltration.
Abstract: SO.sub.x in regenerator off gas in a fluid cracking unit is decreased by providing in the regenerator bed, a metal grid bearing a layer of rare earth oxide.
Type:
Grant
Filed:
November 8, 1989
Date of Patent:
July 2, 1991
Assignee:
Texaco Inc.
Inventors:
Roy E. Pratt, David E. Self, Joseph C. Demeter
Abstract: Water is separated from aqueous mixtures of organic oxygenates such as isopropanol by pervaporation through a non-porous separating membrane of a blend of polyvinyl alcohol and a polyacrylic acid mounted on a polysulfone porous support layer.
Abstract: A dilute solution of methyl ethyl ketone is concentrated by pervaporation through a fluorinated ion exchange membrane which has been exchanged with a quaternary ammonium cation.
Type:
Grant
Filed:
February 16, 1989
Date of Patent:
April 9, 1991
Assignee:
Texaco Inc.
Inventors:
Mordechai Pasternak, Tansukhlal G. Dorawala
Abstract: Water is separated from an MEK toluene dewaxing solvent by pervaporation through a polyvinyl alcohol membrane (optionally containing polyacrylic acid) mounted on a polyacrylonitrile support layer.
Type:
Grant
Filed:
July 5, 1988
Date of Patent:
April 2, 1991
Assignee:
Texaco Inc.
Inventors:
Mordechai Pasternak, Craig R. Bartels, John Reale, Jr.
Abstract: Concentration of aqueous solutions of isopropanol may be effected by a composite membrane including a dibromobutane cross-linked poly(4-vinyl pyridine) bonded to a porous layer of polyacrylonitrile on a polyester backing.
Abstract: Dewaxed oil containing dewaxing solvent from solvent dewaxing is treated by contact with a separating membrane to yield a retentate containing increased content of dewaxed oil and decreased content of dewaxing solvent and a permeate which contains increased content of dewaxing solvent and decreased content of dewaxing oil--the membrane including a polyimine layer which has been cross-linked with polyisocyanate or poly(carbonyl chloride).
Abstract: A furfural-containing middle distillate stream is separated by use of a polyethyleneimine membrane which has been cross-linked with a polyisocyanate or a poly(carbonyl chloride) cross-linking agent.
Abstract: Polymers, such as polysiobutylene or ethylene-propylene copolymers, are functionalized by reaction with an activated imine to yield novel polymers.
Abstract: Polymers, such as polyisobutylene or ethylene-propylene copolymers, are functionalized by reaction with an activated imine to yield novel polymers.
Abstract: Water is separated from aqueous mixtures of organic oxygenates such as isopropanol by pervaporation through a non-porous separating membrane of a blend of polyvinyl alcohol and a polyacrylic acid mounted on a polysulfone porous support layer.
Abstract: Concentration of aqueous solutions of isopropanol may be effected by a composite membrane including a glutaraldehyde cross-linked polyvinyl alcohol bonded to a porous layer of polysulfone on a polyester backing.