Abstract: Provided are dialkyloxy-substituted terephthalic acids of the formula ##STR1## wherein R is an alkyl group having about 8 to 12 carbon atoms. Also provided is a method for preparing these dialkyloxy-substituted terephthalic acids.

Abstract: Described herein is an improved cure catalyst, ferric-bis(acetylacetonato)oxinate, for urethane polymers derived form polyetherdiols and thiols, polybutadienediols and triols, polyesters and the like.

Abstract: A method of analysis by high performance liquid chromatography is provided for obtaining an analysis of three components, namely acyclic paraffins, cycloparaffins and unsaturates, present in a liquid hydrocarbon mixture. The method comprises introducing a sample of the mixture to be analyzed into an unsaturates-selective column, passing the eluents from the unsaturates-selective column to a second column, eluting the separated components from the second column, detecting the presence of paraffins and naphthenes in the effluent from the second column, eluting the separated components from the unsaturates-selective column, and detecting the presence of unsaturates in the effluent from the unsaturates-selective column. The unsaturates-selective column is a silver-modified ion exchange column. The second column is a slurry packed column packed with a microparticulate material. The detector is a dielectric constant detector.

Abstract: A method to produce titanium alloy articles having high creep resistance which comprises the steps of:(a) providing a titanium alloy material containing at least one dispersoid forming alloy addition:(b) hydrogenating the alloy material to a level of about 0.1 to 4.0 weight percent hydrogen;(c) introducing the resulting hydrogenated material into a mold;(d) hot compacting the alloy material in the mold to produce a substantially fully dense article;(e) beta heat treating the compacted article; and,(f) dehydrogenating the article.Following heat treatment, the microstructure in the article will be lenticular transformed beta which is highly creep resistant, while size of the dispersoid will be approximately the same as before the heat treatment, due to the relatively low beta treatment temperature.

Abstract: A method for producing an integral titanium alloy article having at least two regions, each region having a distinct microstructure is provided. The method comprises heat treating one or more selected region(s) of the article at a temperature greater than the beta-transus temperature of the region(s), while simultaneously heat treating the remaining region(s) of the article at a temperature below the beta-transus temperature of the remaining region(s).

Abstract: An improved alloy consisting essentially of about 6 to 10 weight percent Fe, about 2 to 10 weight percent Gd, balance Al. The alloy may also contain minor amounts of one or more refractory metals.

Abstract: Provided is an acetylene-terminated aromatic amide compound of the formula ##STR1## wherein X is --O-- or --S--, Z is --O--, --S--, --SO.sub.2 --, or --CO--, and R is --H or --C.tbd.CH in the ortho, meta or para position, wherein at least one R is --.tbd.CH.

Abstract: Provided are novel para-ordered aromatic heterocyclic polymers having repeating groups of the following formula ##STR1## wherein Y is --O--, --S--, or --NH--, n is 1 or 2, and Q is ##STR2## wherein Z is --O-- or --S--. There are also provided methods for preparing the above polymers.

Abstract: A method for improving the microstructure of prealloyed titanium alloy compacted articles which comprises the steps of hydrogenating the article at a temperature of about 780.degree. to 1020.degree. C. to a hydrogen level of about 0.50 to 1.50 weight percent, cooling the thus-hydrogenated article to room temperature at a controlled rate, heating the thus-cooled, hydrogenated article to a temperature of about 650.degree. to 750.degree. C. and applying a vacuum to dehydrogenate the article.

Abstract: A method for producing an integral titanium alloy article having at least o regions, each region having a distinct microstructure, which comprises the steps of(a) providing a suitable mold for the article;(b) introducing a first titanium alloy into a first portion of the mold;(c) introducing a second titanium alloy in powder form into a second portion of the mold; and(d) hot compacting the first and second alloys in the mold to produce a substantially fully dense article.The second alloy may be the hydrided version of the first alloy, or may have a different overall composition from the first alloy, or may be hydrided and have a different overall composition from the first alloy.

Abstract: A porous body consisting of a felted fibrous skeleton covered with and bonded together by a ceramic material is provided. Also provided are methods for making such a porous body which comprise the use of ceramic polymer solutions.

Abstract: This invention concerns analysis by high performance liquid chromatography HPLC) of crude oils and petroleum products.In one embodiment of the invention a sample is quantitatively separated into saturates, alkyl benzenes and polynuclear aromatics using a system comprising a column packed with a porous silica packing material having a polar amino-cyano bonded phase in tandem with a column packed with a tetranitrofluorenimino packing material, and a dielectric constant detector.In another embodiment of the invention a sample is qualitatively separated into saturates, olefins, and total aromatics using a system employing an olefin-selective column and a dielectric constant detector.

Abstract: A method for improving the microstructure of consolidated titanium alloy metal matrix composites which comprises the steps of(a) heating the composite to a temperature in the range of 800.degree. to 2000.degree. F., the temperature being below the temperature at which interfacial reactions occur between the metal matrix and the fiber, and diffusing hydrogen into the composite to achieve a hydrogen level of about 0.50 to 1.50 weight percent;(b) altering the temperature of the composite to a transformation temperature at or near the temperature of transformation of (HCP) alpha in the hydrogenated composite to (BCC) beta;(c) cooling the composite to room temperature;(d) heating the thus-cooled composite to a temperature below the transformation temperature, and diffusing hydrogen out from the composite; and(e) cooling the composite to room temperature.

Abstract: A method for improving the microstructure of cast titanium alloy articles which comprises the steps of hydrogenating the cast article at a temperature near or above the titanium-hydrogen eutectoid of 815.degree. C. (of about 780.degree. to 1020.degree. C.) to a hydrogen level of about 0.50 to 1.50 weight percent, cooling the thus-hydrogenated article to room temperature at a controlled rate, heating the thus-cooled, hydrogenated article to a temperature of about 650.degree. to 750.degree. C., applying a vacuum to dehydrogenate the article, and cooling the thus-dehydrogenated article at a controlled rate.

Abstract: A method for fabricating an improved titanium alloy composite consisting of at least one high strength/high stiffness filament or fiber embedded in an alpha-beta titanium alloy matrix which comprises the steps of providing a rapidly-solidified foil made of a rich metastable beta titanium alloy, fabricating a preform consisting of alternating layers of the rapidly-solidified foil and the filamentary material, and applying heat and pressure to consolidate the preform, wherein consolidation is carried out at a temperature below the beta-transus temperature of the alloy.

Abstract: A method for fabricating an improved titanium alloy composite consisting of at least one high strength/high stiffness filament or fiber embedded in an alpha-beta titanium alloy matrix which comprises the steps of providing a rapidly-solidified foil made of a lean metastable beta titanium alloy, fabricating a preform consisting of alternating layers of the rapidly-solidified foil and the filamentary material, and applying heat and pressure to consolidate the preform, wherein consolidation is carried out at a temperature below the beta-transus temperature of the alloy.

Abstract: A method for producing an integral titanium alloy article having at least two regions, each region having a distinct microstructure is provided. The method comprises heat treating one or more selected region(s) of the article at a temperature greater than the beta-transus temperature of the region(s), while simultaneously heat treating the remaining region(s) of the article at a temperature below the beta-transus temperature of the remaining region(s).

Abstract: A method for improving the microstructure of blended elemental titanium alloy compacted articles which comprises the steps of hydrogenating the article at a temperature of about 780.degree. to 1020.degree. C. to a hydrogen level of about 0.50 to 1.50 weight percent, cooling the thus-hydrogenated article to room temperature at a controlled rate, heating the thus-cooled, hydrogenated article to a temperature of about 650.degree. to 750.degree. C. and applying a vacuum to dehydrogenate the article, and cooling the thus-dehydrogenated article to room temperature at a controlled rate.

Abstract: This invention concerns analysis by high performance liquid chromatography (HPLC) of crude oils and petroleum products.In one embodiment of the invention a sample is quantitatively separated into saturates, alkyl benzenes and polynuclear aromatics using a system comprising a column packed with a porous silica packing material having a polar amino-cyano bonded phase in tandem with a column packed with a tetranitrofluorenimino packing material, and a dielectric constant detector.In another embodiment of the invention a sample is qualitatively separated into saturates, olefins, and total aromatics using a system employing an olefin-selective column and a dielectric constant detector.

Abstract: There is provided the compound 4-azido-4,4-dinitro-1-butanol (ADNBOH) and a method for making same which comprises reacting trinitromethane and acrolein at a reduced temperature to provide 4,4,4-trinitro-butyraldehyde (TNBAl), reducing the TNBSl to provide 4,4-trinitro-1-butanol (TNBOH) which is further reduced to provide 4,4-dinitro-1-butanol (DNBOH), reacting the DNBOH with acetyl chloride to provide 4,4-dinitro-1-butyl acetate (DNBAc), reacting the DNBAc with an alkali metal azide in an electrolysis cell to provide 4-azido-4,4-dinitro-1-butyl acetate (ADNBAc) and reacting the ADNBAc with a lower alcohol and recovering the 4-azido-4,4-dinitro-1-butanol (ADNBOH).Also provided are several azidodinitro derivatives of 4-azido-4,4-dinitro-1-butanol and methods for making same.