Abstract: A method for deposition of metals onto a workpiece by applying a sensitizing solution to a workpiece, directing a high intensity optical beam onto the sensitized workpiece surface to flash evaporate sensitizer from the workpiece in areas which are not to be plated, and thereafter contacting the workpiece with an electroless plating solution to deposit a layer of metal in those areas from which the sensitizer is not flashed off.
Abstract: Bis(benzilyloxy) compounds having the general formula ##STR1## wherein Ph is --C.sub.6 H.sub.5 and Ar is Ph, --C.sub.6 H.sub.4 Br, --C.sub.6 H.sub.4 CH.sub.3 or --C.sub.6 H.sub.4 C.sub.2 H.sub.5. These compounds can be reacted with bis(o-diamines) to form polyquinoxalines which can be converted to thermally stable compositions by non-volatile, intramolecular cyclization.
Type:
Grant
Filed:
October 8, 1986
Date of Patent:
July 28, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Inventors:
Patricia M. Lindley, Bruce A. Reinhardt, Fred E. Arnold
Abstract: Phenylquinoxaline monomers of the formula Ar--C.tbd.C--Pq--C.tbd.C--Ar are disclosed, wherein Pq is ##STR1## wherein X is a single bond, --O--, --S--, --SO.sub.2 --, --CH.sub.2 --, --CO--, --OC.sub.6 H.sub.4 O--, --OC.sub.6 H.sub.4 --C.sub.6 H.sub.4 --O--, --OC.sub.10 H.sub.6 O-- or --OC.sub.6 H.sub.4 SO.sub.2 C.sub.6 H.sub.4 O--; and wherein Ar is an aromatic ether or thioether. These monomers can be crosslinked to provide thermoset resins of the formula ##STR2## wherein Pq and Ar are as defined above and n has a value between 2 and 3.
Type:
Grant
Filed:
January 16, 1986
Date of Patent:
July 28, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Inventors:
Marilyn R. Unroe, Bruce A. Reinhardt, Fred E. Arnold
Abstract: A method for maskless deposition of metals onto a workpiece by applying a sensitizing solution to a workpiece, directing a laser beam onto the sensitized workpiece surface to flash evaporate sensitizer from the workpiece in areas which are not to be plated, moving the workpiece or beam to describe a pattern, and thereafter contacting the thus-patterned sensitized workpiece with an electroless plating solution to deposit a layer of metal in those areas from which the sensitizer is not flashed off.
Abstract: The microstructure of forged titanium alloy components is improved by beta-transus heat treating the components, hydrogenating the components at an elevated temperature, cooling the thus-hydrogenated components to room temperature, dehydrogenating the components at an elevated temperature and cooling the dehydrogenated components to room temperature.
Type:
Grant
Filed:
August 13, 1986
Date of Patent:
July 14, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Inventors:
Russell G. Vogt, Daniel Eylon, Francis H. Froes
Abstract: Pentafluorotellurium hypohalites are reacted with fluorocarbon iodides to form intermediate adducts which are thereafter decomposed to form fluorocarbons containing the TeF.sub.5 O-- group.
Type:
Grant
Filed:
January 31, 1986
Date of Patent:
June 23, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: The carbon fiber bundles in a carbon-carbon composite are protected against oxidation by coating the fiber bundles with at least one protective layer consisting of an underlayer portion of boron carbide and an overlayer portion of silicon carbide.
Type:
Grant
Filed:
February 1, 1984
Date of Patent:
May 26, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: Phenylquinoxaline monomers containing sterically hindered ethynyl groups are provided. These monomers can be crosslinked to provide thermoset resins of the general formula ##STR1## wherein Pq is a phenylquinoxaline linking unit. Ar is an aromatic ether or thioether, and n has a value between 2 and 3.
Type:
Grant
Filed:
January 16, 1986
Date of Patent:
May 19, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Inventors:
Marilyn R. Unroe, Bruce A. Reinhardt, Fred E. Arnold
Abstract: Aromatic polyamide resins having repeating units, each containing at least one m-ethynyl amido subunit: ##STR1## These resins can be thermally treated to undergo intra-molecular cyclization, without evolution of volatiles, into polyimidines containing the following subunit.
Type:
Grant
Filed:
December 10, 1985
Date of Patent:
May 5, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: A non-destructive technique for detecting and repairing surface flaws in the silicon carbide oxidation resistant coating of a carbon-carbon composite. The surface of the composite is treated with a test liquid consisting essentially of a carrier fluid, a particulate pigment and a finely divided borosilicate glass, or a mixture of silicon dioxide and boron oxide, containing 0.25 to 8 weight percent boron oxide. The treated surface is inspected for surface flaws. Any discovered flaws are repaired by heating the surface to cause the borosilicate glass to flow and heal the flaw. The composite is thereafter heated to a further elevated temperature to deplete the boron from the flaw-sealing glass.
Type:
Grant
Filed:
September 5, 1985
Date of Patent:
April 28, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: Aromatic monomers, each containing at least one o-ethynyl carboxylic acid halide subunit: ##STR1## wherein X is Cl or Br. These monomers can be reacted with amines to form aromatic polyamide resins which can be thermally treated to undergo intromolecular cyclization, without evolution of volatiles, into polyimidines.
Type:
Grant
Filed:
December 10, 1985
Date of Patent:
April 14, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: The microstructure of titanium alloy powder compacts is refined and improved by a method which comprises beta solution heat treating the compact, hydrogenating and then dehydrogenating the compact.
Type:
Grant
Filed:
July 25, 1985
Date of Patent:
April 7, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Inventors:
Lev Levin, Russell G. Vogt, Daniel Eylon, Francis H. Froes
Abstract: A fatigue testing machine for testing materials under combined static and dynamic loads. The machine comprises a right circular ring, a pair of specimen clamps adapted for slidably fitting into diametrically opposed openings in the ring, a support cradle for the ring and a shaker. The clamps comprises means for applying a static load to a specimen clamped therebetween.
Type:
Grant
Filed:
December 6, 1985
Date of Patent:
January 20, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: A low shear battery plaque and a nickel electrode fabricated therefrom, the latter consisting essentially of a centrally located layer of a conductive felt, layers of sintered nickel on each side of the felt and nickel hydroxide active material disposed throughout the pores of the sintered nickel.
Type:
Grant
Filed:
August 23, 1985
Date of Patent:
December 16, 1986
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: A low shear battery plaque and a nickel electrode fabricated therefrom, the latter consisting essentially of a centrally located layer of a conductive felt, layers of sintered nickel on each side of the felt and nickel hydroxide active material disposed throughout the pores of the sintered nickel.
Type:
Grant
Filed:
August 23, 1985
Date of Patent:
November 18, 1986
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: A process and apparatus for continuously casting a castable material to a thickness of 10 to 40 mils. A molten material is first spread onto a spreading roller to a uniform thickness and then transferred to a quenching roller whereon the material is cooled until dimensionally stable. The apparatus may be employed to continuously cast thin sheet, platelets, wire, etc. The materials castable by this process and apparatus include metals, alloys, glasses, thermoplastic materials and metalloids.
Type:
Grant
Filed:
November 16, 1984
Date of Patent:
September 30, 1986
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: Poly (p-xylylidenes) having a high degree of polymerization in the form of films, foams or highly molecularly oriented films and fibers are chemically modified from insulators to conducting materials by exposure to either p- or n-type dopants. Poly (p-xylylidene) films are cast from aqueous solutions of a poly (p-xylene-.alpha.-dimethylsulfonium salt) polyelectrolyte. Processing of the films at elevated temperatures can yield both fibers and foams. Exposure of the poly (p-xylylidene) films, fibers or foams to p-type dopants result in an up to fifteen order of magnitude increase in conductivity, while n-type coping yields a nine order of magnitude increase. Doping of molecularly oriented films and fibers yields a highly anisotropic conductor with a greatly improved conductivity in the orientation direction.
Type:
Grant
Filed:
August 19, 1985
Date of Patent:
January 6, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Inventors:
Frank E. Karasz, Robert W. Lenz, David R. Gagnon, James D. Capistran
Abstract: The heat-sensitive components of cables and cable connectors are protected from overheating during vapor phase soldering by enclosing such components in a metal foil bag.
Type:
Grant
Filed:
March 21, 1984
Date of Patent:
January 6, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: A chemically coupled color-changing matrix display device is disclosed wherein the display material is a surfactant-treated color changing metal-diphthalocyanine complex. For example, lutetium diphthalocyanine may be treated with a mixture of silicone glycol and imidazoline surfactants to provide a deposit having substantially the same color as electrolytically cycled deposits of the same material.Also disclosed is a non-electronic chemical sensing device comprising a surfactant-treated electrochromic metal diphthalocyanine complex. Upon exposure to a hazardous gas such as chlorine, the surfactant-treated material undergoes a change in color.
Type:
Grant
Filed:
July 19, 1984
Date of Patent:
May 5, 1987
Assignee:
The United States of America as represented by the Secretary of the Air Force
Inventors:
Margie M. Nicholson, Thomas P. Weismuller