Abstract: Methods for the fluidized catalytic cracking of plural hydrocarbon feedstocks in a riser reactor are disclosed. The processes generally comprises contacting a relatively light hydrocarbon feedstock in a first reaction zone with a first catalyst stream comprising spent catalyst, contacting a relatively heavy hydrocarbon feedstock in a second reaction zone with a second catalyst stream comprising freshly regenerated catalyst, and introducing at least a portion of the effluent from the first reaction zone into the second reaction zone. The first reaction zone and the second reaction zone preferably comprise first and second riser reaction zones, respectively.
Abstract: There is provided a vacancy titanate intercalated with a cationic hydroxy aluminum complex, such as Keggin ion. A method for making this material and a process for using this material as a catalyst are also provided.
Abstract: In the manufacture of thermoplastic film zipper bags and the like heat sealing the film to the zipper produces a seal line that shrinks, resulting in unsightly apearance. A system and method are disclosed for restoring the shrunk seal line to its orginal length by corrugating and stretching it between mating teeth. A method is also disclosed for restretching the seal without corrugation.
Abstract: The invention comprises the discovery has been made that the reactivation of spent medium pore, shape selective metallosilicate catalyst particles can be enhanced by carrying out the removal of deactivating coke and carbonaceous deposits on the surface and within the pores of the catalyst using hydrogen in a two stage process. The first stage consists of reactivation with hydrogen at elevated temperature and relatively high pressure to crack, strip and remove the more volatile deactivating coke and carbonaceous components on the catalyst surface. The second stage of the reactivation process is carried out at low pressure and elevated temperature, leading to the stripping of the deactivating carbonaceous residue of low volatility on the catalyst surface and pores. The effect of the two stage regeneration process is to improve the removal of coke and carbonaceous materials from the catalyst surface, pores and voids providing a more effective reactivated catalyst.
Abstract: A catalyst composition comprises a molecular sieve material and a boron phosphate-containing matrix. The catalyst composition is used in a catalytic cracking process to produce higher octane gasoline.
Abstract: Barium sulfate scale is dissolved by contacting the scale with an aqueous solvent having a pH of about 10 to about 14, preferably about 12, and comprising a chelating agent comprising a polyaminopolycarboxylic acid or salt of such an acid, and a synergist anion. The solvent containing the dissolved scale is regenerated by acidifying the spent solvent with an acidic chelating agent such as EDTA or DTPA, preferably DTPA, that release alkaline earth cations which react with sulfate ions present in the solvent to form a precipitate of an insoluble salt of the alkaline earth metal. The precipitate is then removed from the solvent by settling/decanting, filtering, or centrifuging. Thereafter, caustic is added to increase the pH of the solvent to a pH of about 10 to about 14, preferably about 12, to recover a regenerated solvent for reuse, in dissolving scale.
Abstract: There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of at least one polymerized conjugated diene of at least five (5) carbon atoms, such as isoprene, and B is a block of a polymer of at least one conjugated diene, different from that used to polymerize the block I, of at least four (4) carbon atoms, such as 1,3-butadiene. The B block is selectively hydrogenated, while each of the I blocks is unhydrogenated and therefore retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from a minor proportion of at least one aryl-substituted olefin, such as styrene, and a major proportion of at least one conjugated diene used to polymerize the block I, the second middle polymer block of at least one diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block.
Type:
Grant
Filed:
January 16, 1990
Date of Patent:
September 22, 1992
Assignee:
Mobil Oil Corporation
Inventors:
Thomas S. Coolbaugh, Frederick C. Loveless, Demetreos N. Matthews, Leslie R. Rudnick
Abstract: There is provided a process for the partial oxidation of methane to produce a product including carbon monoxide and hydrogen. The process involves contacting a source of methane and a source of oxygen with a perovskite catalyst, such as LaCoO.sub.3.
Type:
Grant
Filed:
October 15, 1990
Date of Patent:
September 22, 1992
Assignee:
Mobil Oil Corp.
Inventors:
Scott Han, Lorenzo C. DeCaul, Robert E. Palermo, Dennis E. Walsh
Abstract: The aging properties of Group VIII metal modified non-acidic microporous crystalline materials which in catalysis exhibit high selectivity for dehydrogenation and dehydrocyclization are improved by the incorporation therein of titanium and/or titania.
Abstract: This invention relates to a new crystalline aluminophosphate composition, to a new and useful improvement in synthesizing said crystalline composition and to use of said crystalline composition prepared in accordance herewith as a catalyst component for organic compound, e.g. hydrocarbon compound, conversion.
Abstract: This invention relates to a new crystalline metalloaluminophosphate composition, to a new and useful improvement in synthesizing said crystalline composition and to use of said crystalline composition prepared in accordance herewith as a catalyst component for organic compound, e.g. hydrocarbon compound, conversion.
Abstract: This invention relates to a new form of crystalline porous chalcogenide, e.g. silicate or like material, to a new and useful improvement in synthesizing said crystalline material and to use of said crystalline material prepared in accordance herewith as a catalyst for organic compound, e.g. hydrocarbon compound, conversion.
Type:
Grant
Filed:
July 24, 1991
Date of Patent:
September 15, 1992
Assignee:
Mobil Oil Corporation
Inventors:
David O. Marler, John P. McWilliams, James C. Vartuli
Abstract: A method for removing calcium sulfate scale from a well comprising mixing carbon dioxide and water at a downhole location within the well to form an acidic solution containing an equilibrium mixture of carbonic acid, bicarbonate and carbonate ions that will convert the calcium sulfate scale to calcium carbonate scale and subsequent in situ dissolution of the calcium carbonate scale into the acidic solution that flows into the formation about the well.
Abstract: A process vessel has an inlet for receiving a process fluid and an outlet for exhausting process fluid into the atmosphere should the pressure within the vessel exceed a preset limit. A pneumatic safety device positioned within such inlet shuts down the flow of process fluid into the process vessel when actuated pneumatically. A pressure-relieving device positioned within such outlet exhausts process gas into the atmosphere when the pressure within the process vessel exceeds the preset limit as established by the burst pressure level of the pressure relieving device. A pneumatic control link connects the pressure-relieving device to the pneumatic safety device. Such control link actuates the pneumatic safety device to shut-down the flow of process fluid into the process vessel in response to the exhausting of process fluid from the process vessel into the atmosphere.
Abstract: A polymer blend including from about 80 to about 98 weight percent LLDPE and from about 2 to about 20 weight percent PP having an isotacticity of from about 70 to 90 percent, the blend having a viscosity ratio of LLDPE to PP greater than 3, improves the processability of LLPDE into films without loss in film properties.
Abstract: This invention relates to a new crystalline silicoaluminophosphate composition, to a new and useful improvement in synthesizing said crystalline composition and to use of said crystalline composition prepared in accordance herewith as a catalyst component for organic compound, e.g. hydrocarbon compound, conversion.
Abstract: A process and apparatus are disclosed for achieving turbulent or fast fluidized bed regeneration of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. A closed coke combustor vessel is added alongside an existing regenerator vessel, and spent catalyst is discharged into a transfer pot beneath the existing dense bed, then into the coke combustor. Catalyst is regenerated in a turbulent or fast fluidized bed, and discharged into the dilute phase region above the existing bubbling dense bed. The discharge line preferably encompasses, and is in a heat exchange relationship with, the spent catalyst standpipe. Discharged catalyst is collected in the bubbling dense bed surrounding the coke combustor, and may be given an additional stage of regeneration. Catalyst may be recycled from the dense bed to the transfer pot.
Abstract: A novel composition is disclosed that is particularly useful as a lubricant viscosity index improver. The composition comprises branched C.sub.30 -C.sub.10000 hydrocarbons that have a branch ratio of less than 0.19 and viscosity at 100.degree. C. between 725 cS and 15,000 cS. The novel compositions comprise the product of the oligomerization of C.sub.6 to C.sub.20 alpha-olefin feedstock, or mixtures thereof, under oligomerization conditions at a temperature between -20.degree. C. and +90.degree. C. in contact with a reduced valence state Group VIB metal catalyst on porous support. The compositions have viscosities at 100.degree. C. between 725 cS and 15,000 cS. Using the foregoing compositions in admixture with mineral oil and synthetic lubricants provides novel lubricant blends that show an elevated viscosity index. The mixtures also show an increased stability to shear stress at high temperture with all blends notable by exhibiting Newtonian flow.
Type:
Grant
Filed:
April 17, 1991
Date of Patent:
September 8, 1992
Assignee:
Mobil Oil Corporation
Inventors:
Andrew Jackson, Margaret M. Wu, Alice S. Chu, Bruce P. Pelrine
Abstract: An integrated process comprising the steps of pressurizing a C.sub.3.sup.+ olefin hydrocarbon stream and a methanol feed and contacting the C.sub.3.sup.+ hydrocarbon stream and methanol feed in a first reaction zone with a medium-pore shape selective oligomerization zeolite catalyst at elevated pressure and moderate temperature to convert at least a portion of the C.sub.3.sup.+ hydrocarbons and methanol feed to heavier liquid hydrocarbon product stream comprising olefinic gasoline and distillate range liquids. An ethene stream and a stream containing unreacted methanol and water are recovered from the first reaction zone effluent and the methanol is separated from the water.The ethene and the separated unreacted methanol are contacted with a medium-pore shape selective zeolite catalyst in a second reaction zone at elevated temperature and moderate pressure to convert the methanol feed to hydrocarbons comprising C.sub.3.sup.+ olefins and cooling effluent from the second reaction zone to recover a C.sub.3.sup.
Abstract: A protective cell for use in conducting dermal studies on mammals. The protective cell comprises a shell-like section terminating in a leading edge and a rim section integral to the leading edge of the shell-like section and contoured to form a surface for contacting the animal so that the area of skin to be used for the dermatological study is protected. The cavity of the shell-like section is of a shape and volume sufficient to substantially eliminate contact of the interior surface of the shell-like section with the mammal. A method for conduting dermal studies is also provided.