Abstract: A polyester resin has an oxyalkylene content of from about 40 percent to about 75 percent. The polyester resin is especially useful as a pigment dispersant in coating compositions. Such compositions can be formulated without the need for conventional low molecular weight dispersants and surfactants which oftentimes adversely affect the film properties of the applied compositions.
Type:
Grant
Filed:
November 29, 1982
Date of Patent:
October 18, 1983
Assignee:
PPG Industries, Inc.
Inventors:
Karl F. Schimmel, Michael A. Traficante, Rostyslaw Dowbenko
Abstract: Water repellent treating compositions are based upon olefin and paraffin materials containing a substantial proportion of compounds containing from 20 to 24 carbon atoms. The treating compositions are especially useful for application to wood. Additives such as wood preservatives, alkyd resins and, in especially preferred compositions, organic ionizable compounds are included. The preferred compositions are useful for application to wood substrates which are subsequently electrostatically sprayed with a topcoating.
Abstract: Coating compositions especially useful as primers for metal substrates consist essentially of polyepoxide resin, acrylic resin and fluorocarbon resin.
Type:
Grant
Filed:
December 29, 1980
Date of Patent:
April 12, 1983
Assignee:
PPG Industries, Inc.
Inventors:
John D. Miller, Valentine J. Grunewalder
Abstract: Rheology modifiers useful in water and organic solvent-based compositions are derived from the reaction of polyalkylene oxide, polyfunctional material, diisocyanate, water and end-capping compounds in an organic solvent. The organic solvent is compatible with latex coating compositions.
Abstract: Water repellent treating compositions are based upon olefin and paraffin materials containing a substantial proportion of compounds containing from 20 to 24 carbon atoms. The treating compositions are especially useful for application to wood. Additives such as wood preservatives, alkyd resins and, in especially preferred compositions, organic ionizable compounds are included. The preferred compositions are useful for application to wood substrates which are subsequently electrostatically sprayed with a topcoating.
Abstract: Coating compositions capable of liquid application to substrates consist essentially of a curable film forming polyol-containing component and an organic reactive diluent. The reactive diluent is an organic compound containing a primary or secondary hydroxyl group and further characterized by having a retained solids value of greater than about 80 percent, a hydroxyl equivalent weight of from about 180 to about 800, and a liquid viscosity of less than about 10 poise at 60.degree. C. The coating compositions can be formulated to contain little or no volatile organic solvent and/or water.
Type:
Grant
Filed:
December 7, 1979
Date of Patent:
August 10, 1982
Assignee:
PPG Industries, Inc.
Inventors:
Wen-Hsuan Chang, James B. O'Dwyer, John R. Peffer
Abstract: Coating compositions contain pigment dispersants wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety.
Type:
Grant
Filed:
December 12, 1980
Date of Patent:
July 13, 1982
Assignee:
PPG Industries, Inc.
Inventors:
David Z. Becher, Roger M. Christenson, Richard L. Coalson, Percy E. Pierce, Karl F. Schimmel
Abstract: Rheology modifiers useful in water-based and organic solvent-based compositions are derived from the reaction of polyalkylene oxide, polyfunctional material, diisocyanate and little or no water. The modifiers are characterized by having a branched structure and containing substantially no terminal hydrophobic groups.
Type:
Grant
Filed:
December 29, 1980
Date of Patent:
June 29, 1982
Assignee:
PPG Industries, Inc.
Inventors:
Karl F. Schimmel, Jerome A. Seiner, Rostyslaw Dowbenko, Roger M. Christenson
Abstract: Rheology modifiers useful in water-based and organic solvent-based compositions are derived from the reaction of polyalkylene oxide, polyfunctional material, diisocyanate, water and a monofunctional active hydrogen-containing compound or monoisocyanate. The modifiers are characterized by having a branched structure, urea linkages and terminal hydrophobic groups.
Type:
Grant
Filed:
December 29, 1980
Date of Patent:
April 27, 1982
Assignee:
PPG Industries, Inc.
Inventors:
Karl F. Schimmel, Jerome A. Seiner, Roger M. Christenson, Rostyslaw Dowbenko
Abstract: This invention relates to pigmented curable silicate compositions having better pigment dispersions as evidenced by improved color uniformity, hiding power, lower viscosity and consistency. The aqueous compositions contain water-soluble or -dispersible silicate glass, pigment and a base having a basicity greater than that of the silicate glass. Preferred compositions also contain a water-soluble latent insolubilizing agent.
Type:
Grant
Filed:
November 26, 1980
Date of Patent:
March 9, 1982
Assignee:
PPG Industries, Inc.
Inventors:
John E. Blasko, William G. Boberski, Jerome A. Seiner
Abstract: Coating compositions consist essentially of (a) ethylenically unsaturated monomers, (b) polyol-containing curable resins, (c) resins having ethylenic unsaturation and (d) solvent. The compositions are especially useful for the coating of products made from sheet molding compounds.
Abstract: Reactive diluents are derived from the reaction of a glycidyl ester and a hydroxyl and/or carboxyl functional compound. The diluents are useful in coating compositions together with crosslinking agents and, optionally, polyols.
Type:
Grant
Filed:
June 26, 1980
Date of Patent:
February 9, 1982
Assignee:
PPG Industries, Inc.
Inventors:
William J. Birkmeyer, Ronald J. Lewarchik, Joseph A. Klanica, Carl C. Anderson
Abstract: Coating compositions are formulated using a polyol with a hydroxyl functionality of at least three modified by reaction with a glycidyl ether in proportion of about 0.1 to about 4, preferably from about 0.2 to about 2 moles of glycidyl ether per mole of polyol, with which is combined, as curing agent, a compatible aminoplast resin. When the polyol is trimethylol ethane, for example, and is so modified with allyl or butyl glycidyl ether, for example, and is so modified with allyl or butyl glycidyl ether, for example, and the compositions contain a methylated melamine formaldehyde condensate as curing agent, they are especially suitable for clear top coating surfaces of wood or flat woodstock containing printing inks to simulate woodgrain, to provide a durable coating highly adherent to the inks as well as the cellulosic materials. The compositions may contain high solids content yet they are stable on storage without development of crystallization and are reducible or thinnable with water.
Type:
Grant
Filed:
June 4, 1980
Date of Patent:
February 9, 1982
Assignee:
PPG Industries, Inc.
Inventors:
Wen-Hsuan Chang, Robert Piccirilli, David A. Diehl
Abstract: Methods of providing substrates with a durable coating comprises applying a pigmented composition of fluorocarbon resin and acrylic resin to the substrate followed by application of a clear composition of flurocarbon resin and acrylic resin. Articles produced by the methods are especially useful wherever outdoor exposure is encountered.
Abstract: Coating compositions based on stable aqueous dispersions of particles of vinylidene fluoride polymer are prepared by bringing into admixture unstabilized particles of vinylidene fluoride polymer, liquid organic active solvent for the vinylidene fluoride polymer, liquid nonsolvent, which may be liquid organic nonsolvent, water or a combination of liquid organic nonsolvent and water, and, if not present in the liquid nonsolvent, water. The mixing is conducted such that the particles of vinylidene fluoride polymer are wetted by the dispersion vehicle, yet the particles are not substantially solubilized by the active solvent.
Type:
Grant
Filed:
November 28, 1979
Date of Patent:
January 5, 1982
Assignee:
PPG Industries, Inc.
Inventors:
Dennis W. Carson, Ralph C. Gray, Glenn W. Luckock
Abstract: Water based primer-surfacer compositions for application in the automotive industry over bare or treated metal and under a top coat of acrylic lacquer or enamel are formulated in aqueous medium using a latex of an addition copolymer prepared by emulsion polymerization of a mixture of styrenic and acrylic monomers, with hydroxyl and carboxyl functionality, preferably a mixture of styrene, ethyl acrylate, 2-hydroxy-ethyl methacrylate and acrylic acid. The latex is the predominant film forming ingredient in the composition and is combined with minor amounts of other film forming ingredients including a water soluble epoxy ester, preferably derived from bisphenol A, diglycidyl ether, drying oil fatty acids and maleic anhydride and water soluble or dispersible aminoplast resins, preferably methoxylated melamine formaldehyde resin and butoxylated urea formaldehyde resin. Pigments are also normally present in the composition.
Type:
Grant
Filed:
July 16, 1980
Date of Patent:
December 1, 1981
Assignee:
PPG Industries, Inc.
Inventors:
Morris Levine, Michael Yurcheshen, Roland W. Hight
Abstract: Pigment dispersants for use in coating compositions wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety.
Type:
Grant
Filed:
July 7, 1980
Date of Patent:
December 1, 1981
Assignee:
PPG Industries, Inc.
Inventors:
David Z. Becher, Roger M. Christenson, Richard L. Coalson, Percy E. Pierce, Karl F. Schimmel
Abstract: Pigment dispersants for use in coating compositions wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acids, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety.
Type:
Grant
Filed:
August 14, 1980
Date of Patent:
November 24, 1981
Assignee:
PPG Industries, Inc.
Inventors:
David Z. Becher, Roger M. Christenson, Richard L. Coalson, Percy E. Pierce, Karl F. Schimmel
Abstract: Pigment dispersants for use in coating compositions wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety.
Type:
Grant
Filed:
August 14, 1980
Date of Patent:
November 24, 1981
Assignee:
PPG Industries, Inc.
Inventors:
David Z. Becher, Roger M. Christenson, Richard L. Coalson, Percy E. Pierce, Karl F. Schimmel
Abstract: Pigment dispersants for use in coating compositions wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety.
Type:
Grant
Filed:
August 14, 1980
Date of Patent:
November 24, 1981
Assignee:
PPG Industries, Inc.
Inventors:
David Z. Becher, Roger M. Christenson, Richard L. Coalson, Percy E. Pierce, Karl F. Schimmel