Patents Represented by Attorney Charles W. Stewart
  • Patent number: 6797239
    Abstract: The present invention is related to methods and apparatus for improving distributions of both spent catalyst and transport gas into a regenerator of a fluid catalytic cracking unit. Spent catalyst and transport gases move upwardly through a spent catalyst riser and are diverted in a radially outward direction by a deflector cone. The catalyst and transport gas are re-mixed as they move radially outward between two disks before discharging from the outer edges (perimeter) of the distributor into the regenerator in a substantially uniform radial direction. The distributor is adapted to provide continuous discharge from its perimeter so as to cover the entire cross-section of the regenerator.
    Type: Grant
    Filed: November 22, 2000
    Date of Patent: September 28, 2004
    Assignee: Shell Oil Company
    Inventors: Ye-Mon Chen, Mahendra Sonabhai Patel
  • Patent number: 6734670
    Abstract: A method of determining a surface profile of an electrically conductive object, using a probe having a transmitter adapted for inducing transient eddy currents in the object, and a receiver which is adapted for providing a signal indicative of a magnetic field property wherein the surface profile is determined by measuring a characteristic value at selected inspection positions at a selected set of inspection points to obtain a set of inspection values, and correcting for any offsets using a calibration function determined from a set of calibration values taken at a set of calibration positions at a calibration point.
    Type: Grant
    Filed: February 26, 2003
    Date of Patent: May 11, 2004
    Assignee: Shell Oil Company
    Inventor: Paulus Carolus Nicolaas Crouzen
  • Patent number: 6518459
    Abstract: A filtering means containing gelatinous and solid materials is cleaned without dismantling the filtering means by contacting the gelatinous material inside the filtering means with a solvent, thereby physically degrading the gelatinous material such that the degraded gelatinous material can pass through the filtering means.
    Type: Grant
    Filed: July 26, 2001
    Date of Patent: February 11, 2003
    Assignee: Phillips Petroleum Company
    Inventor: Brooks D. Bennett
  • Patent number: 6506721
    Abstract: A novel composition having the formula: wherein R1 is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group, and R2 is selected from the group consisting of an alkyl group containing from 1 to 20 carbon atoms and an aryl group. The composition is made by combining an amine compound, a carbonyl compound, a solvent, and a sulfur-containing compound. The composition is used as a detergent additive in cleaning process.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: January 14, 2003
    Assignee: Phillips Petroleum Company
    Inventors: Mitchell D. Refvik, David W. Dockter
  • Patent number: 6497809
    Abstract: Process for prolonging the effectiveness of a pyrolytic cracking tube which has been treated with an antifoulant for inhibiting the formation of coke during the cracking of hydrocarbons. The benefits of such treatment are enhanced by the desulfurization of a sulfur-containing feedstock prior to charging it to the treated pyrolytic cracking tube.
    Type: Grant
    Filed: October 25, 1995
    Date of Patent: December 24, 2002
    Assignee: Phillips Petroleum Company
    Inventors: Ronald E. Brown, Timothy P. Harper, Larry E. Reed
  • Patent number: 6472569
    Abstract: A catalyst system comprising a silicoaluminophosphate impregnated with a compound selected from the group consisting of phosphoric acid, boric acid, tributyltin acetate, and combinations of any two or more thereof, and a method of preparing such catalyst system, are disclosed. The thus-obtained catalyst system is employed as a catalyst in the conversion of a hydrocarbon feedstock comprising oxygenated hydrocarbons to olefins and/or ethers.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: October 29, 2002
    Assignee: Phillips Petroleum Company
    Inventors: An-hsiang Wu, Jianhua Yao, Charles A. Drake
  • Patent number: 6464858
    Abstract: The incremental yield of hydrocarbons having five or more carbon atoms in a cracked product from a thermal cracking process is increased by contacting or treating the tubes of a thermal cracking furnace with a composition comprising tin and silicon.
    Type: Grant
    Filed: August 25, 1994
    Date of Patent: October 15, 2002
    Assignee: Phillips Petroleum Company
    Inventors: Ronald E. Brown, Larry E. Reed, James P. Degraffenried, Timothy P. Murtha, Gil J. Greenwood, Timothy P. Harper, Mark D. Scharre
  • Patent number: 6465391
    Abstract: A catalyst composition comprising an inorganic support material, a palladium component, a silver component, and a promoter component having the formula XYFn, wherein X is an alkaline metal, Y is an element selected from the group consisting of antimony, phosphorus, boron, aluminum, gallium, indium, thallium, and arsenic, and n is an integer which makes YFn a monovalent anion. The catalyst is employed in the selective hydrogenation of acetylene. The catalyst is made by incorporating a palladium component, a silver component, and a promoter component into an inorganic support material.
    Type: Grant
    Filed: August 22, 2000
    Date of Patent: October 15, 2002
    Assignee: Phillips Petroleum Company
    Inventors: Tin-Tack Peter Cheung, Marvin M. Johnson
  • Patent number: 6451743
    Abstract: A new stable liquid suspension containing non-soluble particles dispersed in a non-aqueous liquid medium having a concentration of a suspension aid and a method of making and use thereof.
    Type: Grant
    Filed: November 14, 2000
    Date of Patent: September 17, 2002
    Assignee: Chevron Phillips Chemical Company LP
    Inventor: Kelly B. Fox
  • Patent number: 6441229
    Abstract: Higher-alkane sulfonyl halides are prepared by contacting a sulfur-containing compound, a halogen-containing compound, and a phase transfer agent within a reaction zone under reaction conditions.
    Type: Grant
    Filed: June 23, 2000
    Date of Patent: August 27, 2002
    Assignee: Phillips Petroleum Company
    Inventor: James E. Shaw
  • Patent number: 6436863
    Abstract: A catalyst composition and process for preparing such catalyst composition which can be useful in contacting a hydrocarbon-containing fluid which contains a highly unsaturated hydrocarbon such as 1,3-butadiene, in the presence of hydrogen, with such catalyst composition in a hydrogenation zone under a hydrogenation condition effective to hydrogenate such highly unsaturated hydrocarbon to a less unsaturated hydrocarbon such as n-butene is disclosed. Such process for preparing a catalyst composition includes (1) combining a zeolite, a Group VIB metal, and an inorganic support to form a modified zeolite; (2) calcining such modified zeolite under a calcining condition to produce a calcined, modified zeolite; and (3) contacting such calcined, modified zeolite with a carburizing agent under a carburizing condition to provide such catalyst composition.
    Type: Grant
    Filed: December 5, 2000
    Date of Patent: August 20, 2002
    Assignee: Phillips Petroleum Company
    Inventors: An-hsiang Wu, Charles A. Drake
  • Patent number: 6437210
    Abstract: A catalyst, method for preparing the catalyst, and method for using the catalyst having improved conversion and/or selectivity in the dehydrogenation of hydrocarbons. The catalyst being prepared by modifying and impregnating a mazzite zeolite. Modification of the original mazzite zeolite may include steps for ion-exchanging, dealuminating, physically mixing with chromic oxide, shaping, and calcining. Once modified, the mazzite zeolite may be impregnated with at least one metal selected from the group consisting of chromium, molybdenum, tungsten and oxides of these metals.
    Type: Grant
    Filed: August 3, 2000
    Date of Patent: August 20, 2002
    Assignee: Phillips Petroleum Company
    Inventors: An-hsiang Wu, Charles A. Drake
  • Patent number: 6433241
    Abstract: A process in which a hydrocarbon feedstock containing n-butane is selectively dehydrogenated to a product containing butenes. A catalyst suitable for the selective dehydrogenation of a feedstock containing n-butane to provide a product containing butenes. A method for producing a catalyst suitable for the selective dehydrogenation of a feedstock containing n-butane to provide a product containing butenes.
    Type: Grant
    Filed: March 2, 2001
    Date of Patent: August 13, 2002
    Assignee: Phillips Petroleum Company
    Inventors: An-hsiang Wu, Charles A. Drake
  • Patent number: 6420579
    Abstract: Bridged and unbridged fluorenyl-containing metallocenes of the formula R″x(FlRn)(CpRm)MQk wherein Fl is a fluorenyl radical, Cp is a cyclopentadienyl, indenyl, tetrahydroindenyl, or fluorenyl radical, each R is an organo radical, R″ is a structural bridge linking (FlRn) and (CpRm), M is a metal selected from the group consisting of IVB, VB, and VIB metals, each Q is selected from the group consisting of hydrocarbyl or hydrocarbyloxy radicals and halogen, x is 1 or 0, k is an integer sufficient to fill out the remaining valences of M, n is in the range of 0 to 7, and m is 0 to 7, further characterized by the fact that if (CpRm) is unsubstituted fluorenyl and metallocene is an unbridged metallocene, then n is 1 to 7 and if R″ is 1,1-dimethylmethylene and (CpRm) is unsubstituted cyclopentadienyl or 3-methylcyclopentadienyl, then n is 1 to 7.
    Type: Grant
    Filed: December 9, 1994
    Date of Patent: July 16, 2002
    Assignee: Phillips Petroleum Company
    Inventors: Helmut G. Alt, Syriac J. Palackal, Konstantinos Patsidis, M. Bruce Welch, Rolf L. Geerts, Eric T. Hsieh, Max P. McDaniel, Gil R. Hawley, Paul D. Smith
  • Patent number: 6420295
    Abstract: A catalyst composition, a process for producing the catalyst composition, and a hydroconversion process for converting a fluid stream comprising at least one saturated hydrocarbon to C6 to C8 aromatic hydrocarbons such as benzene, toluene, and xylenes are disclosed. The catalyst composition comprises a zeolite and a promoter. The process for producing the composition comprises the steps of: (1) combining a zeolite with a complexing ligand and a promoter compound under a condition sufficient to produce a modified zeolite; and (2) heating the modified zeolite to produce a promoted zeolite. The hydroconversion process comprises contacting a fluid stream with the catalyst composition under a condition sufficient to effect the conversion of a saturated hydrocarbon to a C6 to C8 aromatic hydrocarbon.
    Type: Grant
    Filed: August 8, 2000
    Date of Patent: July 16, 2002
    Assignee: Phillips Petroleum Company
    Inventors: An-hsiang Wu, Charles A. Drake
  • Patent number: 6417136
    Abstract: A catalyst composition is provided which can be used for hydrogenating a highly unsaturated hydrocarbon such as an alkyne or a diolefin. The catalyst composition contains palladium, a catalyst component of either silver or an alkali metal compound, or both silver and an alkali metal compound, and a metal aluminate catalyst support. Such metal aluminate catalyst support is prepared by a process of incorporating alumina with a metal component, preferably impregnating alumina with a melted metal component, to thereby provide a metal-incorporated alumina followed by drying and high temperature calcining to thereby provide a metal aluminate catalyst support. The catalyst composition disclosed can be used for hydrogenating a highly unsaturated hydrocarbon to a less unsaturated hydrocarbon. The process involves contacting a highly unsaturated hydrocarbon with a catalyst composition in the presence of hydrogen under a hydrogenation condition sufficient to effect a hydrogenation of the highly unsaturated hydrocarbon.
    Type: Grant
    Filed: September 17, 1999
    Date of Patent: July 9, 2002
    Assignee: Phillips Petroleum Company
    Inventors: Tin-Tack Peter Cheung, Darin B. Tiedtke, Marvin M. Johnson, Gary A. Delzer
  • Patent number: 6399832
    Abstract: Selectively producing organic trisulfides by contacting a mercaptan, a sulfur compound, and a catalyst under conditions sufficient to produce a reaction product comprising organic polysulfides, and subjecting the reaction product to trisulfide enhancing conditions which are effective to inhibit the formation of organic disulfides and promote the conversion of organic tetrasulfides to organic trisulfides.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: June 4, 2002
    Assignee: Phillips Petroleum Company
    Inventor: Brooks D. Bennett
  • Patent number: 6395948
    Abstract: A process for preparing very high viscosity polyalphaolefins using an acidic ionic liquid oligomerization catalyst in the absence of an organic diluent and the products formed thereby.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: May 28, 2002
    Assignee: Chevron Chemical Company LLC
    Inventors: Kenneth D. Hope, Michael S. Driver, Thomas V. Harris
  • Patent number: 6395949
    Abstract: A method of increasing total diluent conversion in a process for the conversion of cracked gasoline and a first diluent comprising iso-pentane to aromatics and light olefins by contacting the cracked gasoline, the first diluent and a second diluent comprising either propane or 1-hexene with a zeolite catalyst containing phosphorus. The zeolite catalyst comprises a calcined, acid-leached zeolite and phosphorus. Also described is a method of making such catalyst.
    Type: Grant
    Filed: July 27, 2000
    Date of Patent: May 28, 2002
    Assignee: Phillips Petroleum Company
    Inventors: Charles A. Drake, Jianhua Yao
  • Patent number: 6372680
    Abstract: A catalyst system comprising a first solid material comprising a silicoaluminophosphate and a second solid material comprising a zeolite and a compound containing zinc and a metal selected from the group consisting of Group IIIA and Group VIB, and a method of preparing such catalyst system, are disclosed. The thus-obtained catalyst system is employed as a catalyst in the conversion of at least a portion of a hydrocarbon feedstock comprising oxygenated hydrocarbons to aromatics (BTX), and, in particular, xylenes. In an alternate embodiment, a hydrocarbon feedstock comprising oxygenated hydrocarbons are converted to aromatics by sequentially contacting the hydrocarbon feedstock with the first solid material and then the second solid material.
    Type: Grant
    Filed: July 27, 1999
    Date of Patent: April 16, 2002
    Assignee: Phillips Petroleum Company
    Inventors: An-hsiang Wu, Charles A. Drake