Patents Represented by Attorney Charles W. Stewart
  • Patent number: 7291320
    Abstract: A process for the selective oxidation of hydrogen sulphide in a hydrogen sulphide containing feed gas to elemental sulphur, wherein the hydrogen sulphide containing feed gas (3), an inert liquid medium (5), and a molecular-oxygen containing gas (4) are supplied to a reaction zone (1) comprising at least one catalytic zone (2) comprising an oxidation catalyst to form elemental sulphur and a gaseous stream depleted in hydrogen sulphide (8), in which process the oxidation catalyst of each catalytic zone (2) is contacted with hydrogen sulphide and/or molecular-oxygen in the presence of inert liquid medium at a temperature in the range of from 120 to 160° C., under such conditions that the elemental sulphur formed is essentially in liquid form and is removed from the reaction zone with the inert liquid medium.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: November 6, 2007
    Assignee: Shell Oil Company
    Inventors: John Wilhelm Geus, Carolus Matthias Anna Maria Mesters, Ronald Jan Schoonebeek
  • Patent number: 7284598
    Abstract: A support for a bundle of parallel tubes, comprising at least two spaced apart transverse support plates, wherein each plate is provided with a plurality of openings of substantially rhombical or substantially frustro-rhombical shape, each of which openings having a maximum of two mirror symmetry axes including a characteristic mirror symmetry axis, the openings being large enough to accommodate at least two tubes, wherein openings in different support plates are arranged to form support passages for parallel tubes so that support passages extending through the same opening in one support plate extend through different openings in another support plate, and wherein the characteristic mirror symmetry axes of at least two openings belonging to the same support passage are arranged to extend in different directions.
    Type: Grant
    Filed: August 6, 2004
    Date of Patent: October 23, 2007
    Assignee: Shell Oil Company
    Inventor: Dominicus Fredericus Mulder
  • Patent number: 7261808
    Abstract: A process to further upgrade a pre-processed used lubricating oil by: (a) contacting the partially upgraded used oil in the presence of hydrogen with a hydrodemetallization catalyst; (b) contacting the effluent of step (a) in the presence of hydrogen with a hydrotreating catalyst; (c) contacting the effluent of step (b) in the presence of hydrogen with a dewaxing catalyst; and (d) contacting the effluent of step (c) in the presence of hydrogen with a hydrotreating catalyst.
    Type: Grant
    Filed: October 16, 2002
    Date of Patent: August 28, 2007
    Assignee: Shell Oil Company
    Inventors: Pierre Grandvallet, Anthony Patrick Hagan, Laurent Georges Huve
  • Patent number: 7261806
    Abstract: A process to prepare a base oil starting from a slack wax containing feedstock by (a) contacting the feedstock in the presence of hydrogen with a sulphided hydrodesulphurisation catalyst having nickel and tungsten on an acid amorphous silica-alumina carrier and (b) performing a pour point reducing step on the effluent of step (a) to obtain the base oil.
    Type: Grant
    Filed: June 7, 2002
    Date of Patent: August 28, 2007
    Assignee: Shell Oil Company
    Inventors: Gerard Benard, Eric Duprey, Johannes Anthonius Robert Van Veen
  • Patent number: 7230148
    Abstract: The present invention relates to an improved process for the hydrogenation of aromatics in hydrocarbon feedstocks containing thiopheneic compounds as impurities, the aromatics hydrogenation being conducted in a hydrogenation reactor in the presence of a nickel based catalyst. The improvement comprises operating the hydrogenation reactor at a reaction temperature sufficiently high from the start of a run, that the thiopheneic compounds are decomposed and substantially absorbed into the bulk of the nickel catalyst, thereby substantially extending the life of the catalyst.
    Type: Grant
    Filed: April 4, 2006
    Date of Patent: June 12, 2007
    Assignee: Shell Oil Company
    Inventors: Paul Benjerman Himelfarb, Charles Eugene Wilson
  • Patent number: 7198845
    Abstract: An elongate, shaped particle having three protrusions each extending from and attached to a central position aligned along the central longitudinal axis of the particle, the cross-section of the particle occupying the area encompassed by the outer edges of six outer circles around a central circle minus the area occupied by three alternating outer circles, wherein each of the six outer circles is touching two neighbouring outer circles and wherein three alternating outer circles are equidistant to the central circle, have the same diameter, and may be attached to the central circle.
    Type: Grant
    Filed: July 30, 2002
    Date of Patent: April 3, 2007
    Assignee: Shell Oil Company
    Inventors: Bastiaan Willem Van Hasselt, Carolus Matthias Anna Maria Mesters
  • Patent number: 7192900
    Abstract: Hydrocracking catalyst composition comprising an optional metal hydrogenation component supported on a carrier comprising a zeolite of the faujasite structure having a unit cell size in the range of from 24.10 to 24.40 ?, a bulk silica to alumina ratio (SAR) above about 12, and a surface area of at least about 850 m2/g as measured by the BET method and ATSM D4365-95 with nitrogen adsorption at a p/po value of 0.03.
    Type: Grant
    Filed: November 24, 2003
    Date of Patent: March 20, 2007
    Assignee: Shell Oil Company
    Inventors: Edward Julius Creyghton, Cornelis Ouwehand
  • Patent number: 7186876
    Abstract: A process to prepare a process oil with an aromatic content of more than 50 wt % (according to ASTM D 2007) and a polycyclic aromatics (PCA) less than 3 wt % (according to IP 346) by (a) contacting a feed mixture of a petroleum fraction boiling in the lubricating oil range and an aromatic rich hydrocarbon fraction with a polar solvent in a counter-current liquid-liquid extraction column, wherein the process oil is obtained by removing the polar solvent from the top product and an extract is obtained by removing the polar solvent from the top product and an extract is obtained by removing the polar solvent from the bottom product.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: March 6, 2007
    Assignee: Shell Oil Company
    Inventors: Mark Richard Stening Manton, Marco Albert Henri Marie
  • Patent number: 7153694
    Abstract: A method for quantitative determination of hydrocarbon species in a hydrocarbon sample is disclosed. The method uses Townsend Discharge Nitric Oxide Chemical Ionization Gas Chromatography/Mass Spectrometry.
    Type: Grant
    Filed: November 26, 2002
    Date of Patent: December 26, 2006
    Assignee: Shell Oil Company
    Inventors: Knox Alex Evans, Weijan Mo, Howard Peterson, Ismet Dzidic
  • Patent number: 7132043
    Abstract: Process to prepare a lubricating base oil starting from a lubricating base oil which is obtained by first removing part of the aromatic compounds from a petroleum fraction boiling in the lubricating oil range by solvent extraction and subsequently dewaxing the solvent extracted product, wherein the following steps are performed, (a) contacting the lubricating base oil with a suitable sulphided hydrotreating catalyst in a first hydrotreating step; (b) separating the effluent of step (a) into a gaseous fraction and a liquid fraction; (c) contacting the liquid fraction of step (b) with a catalyst comprising a noble metal component supported on an amorphous refractory oxide carrier in the presence of hydrogen in a second hydrotreating step; and (d) recovering the lubricating base oil.
    Type: Grant
    Filed: May 26, 2000
    Date of Patent: November 7, 2006
    Assignee: Shell Oil Company
    Inventors: Eric Duprey, Jean-Paul Fattaz, Roland Albert Charles Garin, Patrick Moureaux
  • Patent number: 7108195
    Abstract: A protective shield for protecting a feed nozzle encloses, not only the circumference of the feed nozzle, but also encloses and protects the end of the feed nozzle. The protective shield includes an open portion in its end which corresponds to, and surrounds the slit in the end of the feed nozzle. Optimal shape of the open portion is determined by spray visualization tests.
    Type: Grant
    Filed: February 5, 2004
    Date of Patent: September 19, 2006
    Assignee: Shell Oil Company
    Inventors: Bernardus Maria Geertshuis, Jason Andrew Horwege, Ye Mon Chen, Rene Samson
  • Patent number: 7101516
    Abstract: Described is a catalyst regenerator system that includes a regenerator vessel within which is a verticaliy extending partition that divides a fluidized bed zone of the regenerator vessel into a dense phase fluidized bed zone and a fast-fluidized bed zone. Apparatus is provided to introduce spent catalyst into the fast-fluidized bed zone and to remove regenerated catalyst from the dense phase fluidized bed zone. The partition is equipped with openings that provide for the flow of catalyst from the dense phase fluidized bed zone to the fast-fluidized bed zone.
    Type: Grant
    Filed: July 17, 2001
    Date of Patent: September 5, 2006
    Assignee: Shell Oil Company
    Inventor: Rene Samson
  • Patent number: 7100478
    Abstract: A socket for easily connecting and disconnecting a standard camlock fitting, such as those used in flanges on marine vessels, includes four drive lugs, or tangs, for mating with recesses on the camlock. The socket is adapted for connection to a standard ratchet wrench for providing torque to tighten or loosen the camlocks.
    Type: Grant
    Filed: March 23, 2004
    Date of Patent: September 5, 2006
    Assignee: Shell Oil Company
    Inventor: Jerry Anthony Davis
  • Patent number: 7100627
    Abstract: A method of sequentially transporting a first and a second fluid at a volumetric flow rate through a conduit having a cross-section, wherein the first and second fluids have different densities, which method comprises the steps of estimating a critical stratification condition for a fluid density profile along the conduit, which condition takes into account the densities of the first and second fluids, the cross-section of the conduit and the volumetric flow rate, and wherein violating the critical stratification condition likely results in stratification of fluids to occur; and feeding sequentially only first fluid, a buffer fluid and only second fluid into the conduit, wherein the buffer fluid has a density between the densities of the first and second fluids, such that a density profile of fluid along the conduit is provided, which does not violate the critical stratification condition.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: September 5, 2006
    Assignee: Shell Oil Company
    Inventor: Elco Dick Hollander
  • Patent number: 7081555
    Abstract: The present invention relates to an improved process for the hydrogenation of aromatics in hydrocarbon feedstocks containing thiopheneic compounds as impurities, the aromatics hydrogenation being conducted in a hydrogenation reactor in the presence of a nickel based catalyst. The improvement comprises operating the hydrogenation reactor at a reaction temperature sufficiently high from the start of a run, that the thiopheneic compounds are decomposed and substantially absorbed into the bulk of the nickel catalyst, thereby substantially extending the life of the catalyst.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: July 25, 2006
    Assignee: Shell Oil Company
    Inventors: Paul Benjerman Himelfarb, Charles Eugene Wilson
  • Patent number: 7077948
    Abstract: Process for the catalytic dewaxing of a hydrocarbon oil feed including waxy molecules and more than 500 ppmw of sulphur or sulphur containing compounds by contacting the oil feed under catalytic dewaxing conditions with a catalyst composition comprising at least a hydrogenation component, dealuminated aluminosilicate zeolite crystallites and a low acidity refractory oxide binder material which is essentially free of alumina.
    Type: Grant
    Filed: November 16, 1999
    Date of Patent: July 18, 2006
    Assignee: Shell Oil Company
    Inventors: Guy Barre, Jean-Paul Darnanville, Laurent Georges Huve
  • Patent number: 7077949
    Abstract: A fluidized catalytic cracking reactor vessel having at its upper end means to separate catalyst particles from an effluent of a dilute phase fluidized catalytic cracking reactor riser, which separation means are fluidly connected to the downstream part of the reactor riser, fluidly connected with means to discharge the cleaned reactor riser effluent from the vessel and fluidly connected to means to discharge the separated catalyst to the lower end of the vessel, the vessel further having at its lower end means to discharge catalyst from the reactor vessel, wherein (a) between the side wall of the vessel and the separation means a shield is present, resulting in an exterior space between the vessel wall and the shield and an interior space within the shield, wherein the interior space is in open communication with the lower end of the reactor vessel at its lower end and wherein the exterior space and interior space are fluidly connected by means of one or more openings; and (b) means are present to supply a g
    Type: Grant
    Filed: July 10, 2001
    Date of Patent: July 18, 2006
    Assignee: Shell Oil Company
    Inventors: Ernst Antonius Bakker, David John Bridger, Hendricus Arien Dirkse, Stephen Brian Fowler
  • Patent number: 7078002
    Abstract: The invention relates to a mixing device for mixing fluids in a multiple bed downflow reactor comprising: (i) a substantially horizontal collection tray; (ii) a swirl chamber for mixing liquid arranged below the collection tray, having an upper end part that is in direct fluid communication with the upper surface of the collection tray and an outlet opening at its lower end, wherein the swirl chamber has a length that is at least 0.35 times its inner diameter; and (iii) a substantially horizontal distribution tray located below the swirl chamber, which distribution tray is provided with a plurality of openings or downcomers for downward flow of liquid and gas. The invention further relates to a multiple bed downflow reactor comprising such a mixing device and to the use of such a reactor in hydrocarbon processing.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: July 18, 2006
    Assignee: Shell Oil Company
    Inventors: Willem Van Vliet, Maria Den Hartog-Snoeij, legal representative, Arie Pieter Den Hartog, deceased
  • Patent number: 7074323
    Abstract: A process for the recovery of gaseous products from the product mixture obtained by contacting a hydrocarbon feed with a catalyst in a fluid catalytic cracking process, wherein the liquid, obtained by separating the top product of main fractionators into gaseous and liquid fraction, when supplied to the absorber has a temperature of between about 8–25 DEG C. This liquid may be pre-saturated with gaseous top product from absorber; or also a high boiling fraction (cat cracker naphtha/light cycle oil) may be first separated from this liquid by distillation.
    Type: Grant
    Filed: March 2, 2001
    Date of Patent: July 11, 2006
    Assignee: Shell Oil Company
    Inventor: Pim Ghijsen
  • Patent number: 7070745
    Abstract: The invention relates to a multiple bed downflow reactor comprising vertically spaced apart reaction beds, preferably beds of catalyst particles, and, between adjacent beds, a mixing device for mixing fluids, the mixing device comprising: (i) a substantially horizontal collection tray, (ii) a swirl chamber for mixing liquid arranged below the collection tray, having an upper end part that is in direct fluid communication with the upper surface of the collection tray and an outlet opening at its lower end, and (iii) a substantially horizontal distribution tray located below the swirl chamber, which distribution tray is provided with a plurality of openings or downcomers for downward flow of liquid and gas, in which reactor each reaction bed rests upon a support tray provided with a central opening and which reactor further comprises open-ended pipes extending through each central opening such that a vertical chute is formed from the reaction bed above the mixing device to the reaction bed below the mixing d
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: July 4, 2006
    Assignee: Shell Oil Company
    Inventors: Jurjen Wietze Van Der Meer, Marjanne Clara Zonnevylle