Patents Represented by Attorney Clinton S. Janes
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Patent number: 5375012Abstract: A birefringent waveplate is composed of an integral, transparent, glass body having a thermally developed dispersed phase therein composed of particles having a high aspect ratio and being oriented and aligned in one direction, whereby the glass body is rendered birefringent so that polarized components of light transmitted through the glass body have a phase shift introduced.Type: GrantFiled: October 13, 1992Date of Patent: December 20, 1994Assignee: Corning IncorporatedInventors: Nicholas F. Borrelli, Thomas P. Seward, III
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Patent number: 5372860Abstract: A method for producing a glass panel for silicon device fabrication, which method comprises forming a noncrystalline, or mixed-phase, silicon film on a glass substrate, the glass having a strain point greater than 560.degree. C., and subjecting the filmed glass to a heat treatment comprising heating at a temperature of at least 550.degree. C. for a period of time sufficient to convert the silicon film to polycrystalline silicon and to compact the glass.Type: GrantFiled: July 6, 1993Date of Patent: December 13, 1994Assignee: Corning IncorporatedInventors: Francis P. Fehlner, Paul A. Sachenik
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Patent number: 5371048Abstract: A dense barium crown glass consisting essentially of, as calculated in weight % on an oxide basis, 35-42% SiO.sub.2, 11-17% B.sub.2 O.sub.3, 5.5-7.7% Al.sub.2 O.sub.3, 35-42% BaO, 0.25-1.5% Li.sub.2 O. The glasses have a liquidus temperature bellow 900.degree. C. and a viscosity at the liquidus temperature that is greater than 1000 Pa.s (10,000 poises).Type: GrantFiled: October 18, 1993Date of Patent: December 6, 1994Assignee: Corning IncorporatedInventor: Lisa A. Tietz
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Patent number: 5367012Abstract: This invention is directed to an alloy, and a method of producing an alloy, of increased resistance to moisture, comprising a melt mixture of at least one phosphate glass, at least one organic thermoplastic or thermosetting polymer, and an amount of a water soluble stabilizer component which provides a source of metal cations having a valency of 2.sup.+ or higher The amount of the stabilizer component added is that amount effective to improve the alloy's resistance to moisture. Preferably, the alloy is comprised of: (a) 5-80% of the matrix material; (b) 15-90% of the phosphate glass; and, (c) 0.1 to 40% of the stabilizer component. Additionally, the metal cations which are found in the stabilizer component and which form part of the insoluble surface layer are preferably selected from the group consisting of Ba.sup.2+, Mg.sup.2+, Ca.sup.2+, Al.sup.3+, Zn.sup.2+, Sr.sup.+2 and Fe.sup.3+.Type: GrantFiled: August 9, 1993Date of Patent: November 22, 1994Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Dana C. Bookbinder, James E. Dickinson, Jr., Brent M. Wedding
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Patent number: 5364487Abstract: A method of applying a tough, abrasion-resistant, organic film to a back surface of a thin, glass body to form a glass-plastic composite, the method comprising preheating the film to a temperature at which residual solvent and moisture are removed from the film, preheating a presshead to a pressing temperature, pressing the film and the glass together, maintaining the glass-film assembly at a controlled temperature and pressure for a period of time to form a sealed composite body, and cooling the sealed body to solidify the glass-plastic composite.Type: GrantFiled: September 15, 1993Date of Patent: November 15, 1994Assignee: Corning IncorporatedInventors: Mark S. Friske, Ronald E. Johnson, Christine M. Reagan, Theresa A. Winer, Lung-Ming Wu
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Patent number: 5332702Abstract: A fired, porous, zircon refractory body consisting essentially of zircon and having a sodium ion content, as an impurity, of less than 30 ppm. A furnace for making fused silica constructed with a crown and cup of such zircon refractory, and a method of making fused silica using such furnace.Type: GrantFiled: April 16, 1993Date of Patent: July 26, 1994Assignee: Corning IncorporatedInventors: Daniel R. Sempolinski, Latha I. Swaroop
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Patent number: 5328874Abstract: This invention relates to the preparation of a glass exhibiting a transition temperature normally below about 300.degree., a working temperature below about 400.degree., while, at the same time, exhibiting excellent resistance to attack by water. Specifically, the present invention discloses a glass consisting essentially in terms of mole percent on the oxide basis, of 15-35% P.sub.2 O.sub.5, 1-25% SO.sub.3, 30-55% ZnO, 0-25% R.sub.2 O, wherein R.sub.2 O is selected from the group consisting of 0-25% Li.sub.2 O, 0-25% Na.sub.2 O, and 0-25% K.sub.2 O, and up to a total of 15% of optional ingredients in the indicated proportions selected from the group consisting of 0-10% Al.sub.2 O.sub.3, 0-10% MgO, 0-10% CaO, 0-10% SrO, 0-10% BaO, 0-10% MnO, 0-10% transition metal oxides and 0-15% Cl+F, as analyzed in weight percent.Type: GrantFiled: October 18, 1993Date of Patent: July 12, 1994Assignee: Corning IncorporatedInventors: George H. Beall, Joseph E. Pierson
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Patent number: 5322819Abstract: A non-photochromic R.sub.2 O-B.sub.2 O.sub.3 -SiO.sub.2 glass containing a cuprous or cuprous-cadmium halide crystal phase, having a sharp spectral cutoff at about 400 nm, the glass composition consisting essentially of, in cation percent, 35-73% SiO.sub.2, 15-45% B.sub.2 O.sub.3, 0-12% Al.sub.2 O.sub.3, the Al.sub.2 O.sub.3 being less than 10% when the SiO.sub.2 is over 55%, 0-12% Li.sub.2 O, 0-20% Na.sub.2 O, 0-12% K.sub.2 O, the Li.sub.2 O+Na.sub.2 O+K.sub.2 O being 4.75-20%, 0-5% CaO+BaO+SrO, 0.125-1.0% Cu.sub.2 O, 0-1% CdO, 0-5% ZrO.sub.2, 0-0.75% SnO.sub.2, 0-1% As.sub.2 O.sub.3 and/or Sb.sub.2 O.sub.3, the glass containing 0-1.75%. Cl, 0-1.0% Br, 0.25-2.0% Cl+Br and 0-2% F by weight, and having an R-value, calculated in mole percent of 0.15-0.45, the R-value not exceeding 0.30, except as the glass composition meets at least one condition selected from the group: up to 12 cation % Li.sub.2 O, less than 10 cation % Al.sub.2 O.sub.3, at least 0.3 cation % Cu.sub.2 O and 0.50-2.0% Cl+Br.Type: GrantFiled: October 12, 1993Date of Patent: June 21, 1994Assignee: Corning IncorporatedInventors: Roger J. Araujo, David W. Morgan
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Patent number: 5312689Abstract: An improved, laminated, ophthalmic lens structure, and method of producing the structure. The structure comprises two adjacent layers of dissimilar, organic plastic materials, either or both of which contain matter that tends to migrate. The improvement comprises a barrier layer that is intermediate the adjacent organic plastic layers; that is impermeable to migrating matter; and that is composed of a polyolefin polymeric material modified by the presence of acid or anhydride functional groups.Type: GrantFiled: February 22, 1993Date of Patent: May 17, 1994Assignee: Corning IncorporatedInventors: David Dasher, E. Robert Fretz, Jr., Mark S. Friske, Ronald E. Johnson
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Patent number: 5300464Abstract: Glass or crystal particles of nanocrystalline size having a minor dimension of 0.1 to 100 Angstrom units. They may be prepared by controlled thermal separation of phase-separable glasses. Preferred crystal forms are zinc pyrophosphate and lithium disilicate. A crystallizable glass is combined with phyllosilicate particles and sintered to form an oriented composite body. During slow sintering, the crystal grows epitaxially on the phyllosilicate.Type: GrantFiled: December 16, 1992Date of Patent: April 5, 1994Assignee: Corning IncorporatedInventor: Hermann L. Rittler
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Patent number: 5300170Abstract: Apparatus and method for transfer and application of an offset, heat release decal to an article surface. A thin, supported, silicone membrane is indexed through successive work positions where the membrane is heated, picks up a heated decal and brings the decal into contact with the article surface for printing.Type: GrantFiled: March 1, 1993Date of Patent: April 5, 1994Assignee: Corning IncorporatedInventor: John Donohoe
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Patent number: 5288669Abstract: This invention relates to glasses exhibiting refractive indices higher than 1.880, Abbe numbers of at least 29, densities lower than 4.1, good chemical durability and stability against devitrification, and an integrated transmission over the range of 380-800 nm at a thickness of 10 mm greater than 79%, the glasses consisting essentially, expressed in terms of weight percent on the oxide basis, of______________________________________ SiO.sub.2 5-8 B.sub.2 O.sub.3 15-21 ZrO.sub.2 3-10 TiO.sub.2 7-17 Nb.sub.2 O.sub.5 20.5-26 ZrO.sub.2 + TiO.sub.2 + Nb.sub.2 O.sub.5 29-45 La.sub.2 O.sub.3 19-32 Y.sub.2 O.sub.3 0-9 CaO 8-16 SrO 0-5 BaO 0-5 MgO 0-5 CaO + SrO + BaO + MgO 8-16 ZnO 0-5 Li.sub.2 O 0-2 Na.sub.2 O 0-2 K.sub.2 O 0-2 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 0-2.Type: GrantFiled: February 12, 1993Date of Patent: February 22, 1994Assignee: Corning France S.A.Inventors: Luc Grateau, Pascale Laborde, Michel Prassas
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Patent number: 5288668Abstract: This invention is directed to the production of borosilicate glasses displaying a pink coloration and a chromaticity at a thickness of 4 mm with Illuminant C within the ranges of:x=0.3115-0.4200y=0.3170-0.3600Y=15-92%The glasses consist essentially, expressed in terms of weight percent on the oxide basis, of______________________________________ SiO.sub.2 65-85 B.sub.2 O.sub.3 <20 Na.sub.2 O 0-8 K.sub.2 O 0-8 Na.sub.2 O + K.sub.2 O 2-8 Al.sub.2 O.sub.3 1-6 MnO.sub.2 0.05-1.Type: GrantFiled: August 9, 1993Date of Patent: February 22, 1994Assignee: Corning IncorporatedInventor: Paul L. Netter
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Patent number: 5286683Abstract: This invention is directed to the production of glasses exhibiting transition temperatures below 375.degree. C., preferably below 350.degree. C., and superior resistance to attack by boiling water. The glasses contain at least 10% copper, as expressed in terms of CuO, the predominant proportion of the copper being present in the Cu.sup.+2 oxidation state. The glasses consist essentially, in mole percent, of______________________________________ Li.sub.2 O 0-15 MgO 0-15 B.sub.2 O.sub.3 0-5 Na.sub.2 O 0-20 CaO 0-20 ZnO 0-37 K.sub.2 O 0-10 SrO 0-20 Sb.sub.2 O.sub.3 0-36 Tl.sub.2 O 0-15 BaO 0-20 CeO.sub.2 0-3 Li.sub.2 O + Na.sub.2 O + 12-30 MgO + 0-25 MoO.sub.3 0-7 K.sub.2 O + Tl.sub.2 O CaO + SrO + BaO CuO 10-50 Al.sub.2 O.sub.3 + B.sub.2 O.sub.3 0-5 RE.sub.2 O.sub.3 0-2 P.sub.2 O.sub.5 28-36 Al.sub.2 O.sub.3 0-5 WO.sub.3 0-7 MnO 0-20 ______________________________________wherein at least two alkali metal oxides are present and up to 12% by weight fluoride may optionally be present.Type: GrantFiled: November 5, 1992Date of Patent: February 15, 1994Assignee: Corning IncorporatedInventor: Bruce G. Aitken
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Patent number: 5283211Abstract: This invention relates to thallium germanate, tellurite, and antimonite glasses possessing high optical nonlinearity, as well as good visible and infrared transmission, making them suitable materials for the fabrication of active optical devices.Type: GrantFiled: September 21, 1992Date of Patent: February 1, 1994Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Douglas W. Hall, Mark A. Newhouse
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Patent number: 5283212Abstract: This invention relates to thallium tellurite glasses possessing a high Verdet constant and high optical nonlinearity, as well as good visible and infrared transmission, making them suitable materials for the fabrication of active optical devices. The glasses consist essentially, expressed in terms of cation percent, of 5-74.5% TeO.sub.2, 0.5-20% SiO.sub.2, 4-50% TlO.sub.0.5, and 0-71% PbO, wherein PbO+T10.sub.0.5.gtoreq.25 %, TeO.sub.2 +SiO.sub.2 .gtoreq.25%, and TeO.sub.2 +SiO.sub.2 +TlO.sub.0.5 +PbO constitutes at least 65% of the total composition.Type: GrantFiled: December 17, 1992Date of Patent: February 1, 1994Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Douglas W. Hall, Mark A. Newhouse
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Patent number: 5281560Abstract: Lead-free, tin phosphate glasses contain 25-50 mole percent P.sub.2 O.sub.5, 30-70% SnO, 0-15% ZnO, the mole ratio of SnO:ZnO being greater than 5:1, and an effective amount up to 25% total of at least one oxide in the indicated proportion selected from the group consisting of up to 25% R.sub.2 O, wherein R.sub.2 O consists of 0-25% Li.sub.2 O, 0-25% Na.sub.2 O, and 0-25% K.sub.2 O, up to 20% B.sub.2 O.sub.3, up to 5% Al.sub.2 O.sub.3, up to 5% SiO.sub.2, and up to 5% WO.sub.3. The glasses are particularly useful as sealing glass frits in sealing material to join component parts in electrical and electronic devices. The sealing glass material may contain mill additions to reduce the effective coefficient of thermal expansion in a seal, as well as a strength reinforcing additive having a coefficient of thermal expansion preferably below 120.times.10.sup.-7 /.degree.C.Type: GrantFiled: June 21, 1993Date of Patent: January 25, 1994Assignee: Corning IncorporatedInventors: Gaylord L. Francis, Robert Morena
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Patent number: 5281249Abstract: A method and apparatus for imparting a predetermined contour to an ophthalmic glass lens.The method comprises positioning a forming manifold in the base of a reshaping chamber, the upper surface of the manifold having a surface contour that is the reverse of the bottom contour surface of the reshaped lens, positioning the lens blank in the chamber, heating the lens blank to a temperature at which the blank deforms, and establishing a continuous, lateral flow of gas on the upper surface of the forming manifold whereby the glass is supported while it sags to the desired shape.The apparatus comprises a reshaping chamber, a source of heat to bring a lens blank to its deforming temperature, a forming manifold having an upper surface contour that is the reverse of the desired contour on the lower surface of the reshaped lens blank, and means to supply a continuous, lateral flow of gas on the upper surface of the manifold whereby the glass blank is supported while it deforms to the desired shape.Type: GrantFiled: June 1, 1993Date of Patent: January 25, 1994Assignee: Corning IncorporatedInventors: Leslie E. Hampton, John W. Nelson
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Patent number: 5281562Abstract: A non-photochromic R.sub.2 O--B.sub.2 O.sub.3 --SiO.sub.2 glass containing a cuprous or cuprous-cadmium halide crystal phase, having a sharp spectral cutoff at about 400 nm, the glass composition consisting essentially of, in cation percent, 35-73% SiO.sub.2, 15-45% B.sub.2 O.sub.3, 0-12% Al.sub.2 O.sub.3, the Al.sub.2 O.sub.3 being less than 10% when the SiO.sub.2 is over 55%, 0-12% Li.sub.2 O, O-20% Na.sub.2 O, 0-12% K.sub.2 O, the Li.sub.2 O+Na.sub.2 O+K.sub.2 O being 4.75-20%, 0-5% CaO+BaO+SrO, 0.125-1.0% Cu.sub.2 O, 0-1% CdO, 0-5% ZrO.sub.2, 0-0.75% SnO.sub.2, 0-1% As.sub.2 O.sub.3 and/or Sb.sub.2 O.sub.3, the glass containing 0-1.75% Cl, 0-1.0% Br, 0.25-2.0% Cl+Br and 0-2% F by weight, and having an R-value, calculated in mole percent of 0.15-0.45, the R-value not exceeding 0.30, except as the glass composition meets at least one condition selected from the group: up to 12 cation % Li.sub.2 O, less than 10 cation % Al.sub.2 O.sub.3, at least 0.3 cation % Cu.sub.2 O and 0.50-2.0% Cl+Br.Type: GrantFiled: November 25, 1992Date of Patent: January 25, 1994Assignee: Corning IncorporatedInventors: Roger J. Araujo, David W. Morgan
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Patent number: 5281399Abstract: A refractory body assembly includes a refractory container, a refractory body having multiple gas passageways and positioned within the container, and a barrier layer in the intermediate space. The barrier layer is a rigid foam which, in a basic form, may be composed essentially of a crystalline aluminum phosphate, and may be produced by heating a mixture of a source of phosphorous, an organic liquid buffer and a source of aluminum. The assembly may further include a positioning ring for positioning and maintaining the refractory body in a central position until the barrier layer becomes rigid.Type: GrantFiled: July 19, 1991Date of Patent: January 25, 1994Assignee: Corning IncorporatedInventor: Hermann Rittler