Abstract: Early detection of cracks in structural members subject to stress is accomplished before cracks traverse the member by(a) affixing multiple liquid impermeable enclosures to the material to be monitored such that a crack forming in the monitored material will provide passage for liquid to enter the enclosures either through the monitored materials or by destroying the integrity of said liquid impermeable enclosures;(b) sealing a resistor having a known value onto each of the enclosures, each of the resistors having one lead capable of liquid contact within the enclosure, said lead electrically isolated from the material being monitored and/or a second wire in the enclosures;(c) forming a circuit connecting the multiple enclosures wherein the opposite resistor leads in each enclosure are connected by insulated wire to means for measuring resistance and/or conductance wherein each resistor alone or together with any combination of other resistors in said enclosures within the circuit provides a unique total resi

Abstract: High moisture coal is dried in a turbulent bed by contact with heated char. The dried coal is cooled and then treated with a coal spray for storage stability against spontaneous combustion.

Abstract: Water content of coal is reduced during heavy liquid/ash separation processes by adding an alcohol containing from 1 to 3 carbon atoms to the heavy liquid. These alcohols are miscible with both the heavy liquid and with the water and provide a continuous phase for water removal.

Abstract: A dye adsorption procedure for determining clay type and amount in subterranean formation. The procedure can be carried out at a well-site, providing rapid, accurate information for treatment of the well penetrating the formation.

Abstract: A method is provided for the production of ultrahigh molecular weight drag reducing substances and the like comprising:(a) preparing under an inert atmosphere a catalyst comprising:(1) titanium halide of the general formula TiX.sub.m wherein m=2.5 to 4.0;(2) a co-catalyst such as an organo-aluminum halide of the formula AlR.sub.n X.sub.3-n where r is a hydrocarbon radical, X is a halogen and n is 2 or 3;(3) a phosphorous compound of the formula PR.sub.1 R.sub.2 R.sub.3 or P(OR.sub.1)(OR.sub.2)(OR.sub.3) where R.sub.1, R.sub.2, and R.sub.3 are, independently, aryl, alkyl, aralkyl, or alkaryl, containing from 1 to 12 carbon atoms and placing the catalyst in contact with;(b) alpha-monoolefinic hydrocarbons from C.sub.2 -C.sub.30 under suitable temperature conditions to provide a hydrocarbon soluble ultrahigh molecular weight polymer, then ceasing polymerization at a polymer content level of 20% by weight or less, based on the total reaction mixture.

Abstract: Fluorinated alcohols are alkyoxylated using catalysts which provide reaction products having low surface tensions and which are stable in severe acidic conditions.

Abstract: Catalysts producing a sharply peaked alkoxylation distribution during the alkoxylation of organic materials comprise mixtures of BF.sub.3 and metal alkyls or metal alkoxides, SiF.sub.4 and metal alkyls or metal alkoxides, or mixtures of these catalysts.

Abstract: A method for eliminating foam in hydrocarbon distillation systems where the foaming is caused by an ionic surface-active substance is involved. Foam is eliminated by the addition of an effective amount of a surfactant electrolytically opposite to the surface-active material already in the system. The surfactant added and the surface-active substance already in the system complex to form a non-foaming combination, allowing distillation to proceed without foaming.

Abstract: An adsorbent is provided for removing color precursors from detergent range alkyl benzene prior to sulfonation. The adsorbent provided is a bauxite clay having at least one material selected from the group consisting of ferric oxide, titanium dioxide, and zirconium oxide and which contain from about 0.1 to about 20 percent by weight of sulfuric acid, said bauxite clay then being calcined at a temperature and time sufficient to activate the adsorbent prior to use.

Abstract: Reaction products of organic magnesium compounds and silyl esters and/or poly (silyl esters) are contacted with transition metal compounds to yield active polymerization catalysts. In a preferred embodiment, the active polymerization catalyst is further activated by contacting with a halogenating agent soluble in a hydrocarbon solvent.

Abstract: Catalysts comprising mixtures of HF and metal alkoxides and mixed metal alkoxides produce a sharply peaked alkoxylation distribution during the alkoxylation of organic materials.

Abstract: High activity catalysts for the polymerization of ethylene and other .alpha.-olefins are made by contacting a soluble magnesium compound of the general formula Mg(OSiR.sub.3).sub.2, wherein each R is, independently, alkyl, alkoxy or aryl, with a titanium tetralkoxide (titanate) in a saturated aliphatic hydrocarbon solution, followed by chlorination and precipitation by a suitable chlorinating agent. These catalysts show high activity for the polymerization of ethylene under slurry polymerization conditions.

Abstract: An improved sulfonate suitable for waterflooding is formed by sulfonating a blend of two alkyl aromatic feedstocks, one being a high molecular weight monoalkylbenzene while the second is a mixture of normal alkyl aromatic compounds such as monoalkyl benzenes, dialkylbenzenes, and diphenyl alkanes. This feedstock is either sulfonated after blending or before blending to provide a blended non-sulfonate/sulfonate ratio in the range of 0.10 to 0.25. The sulfonate effectiveness of this system increases as the non-sulfonate/sulfonate ratio increases.

Abstract: Internal olefins are subjected to metathesis closely coupled after an isomerization reaction to obtain desired molecular weight range linear olefins. Specific process steps and separation conditions are necessary to obtain the desired linear olefins.

Abstract: A method is provided for the production of ultrahigh molecular weight drag reducing substances and the like comprising:(a) preparing under an inert atmosphere a catalyst comprising: p1 (1) titanium halide of the general formula TiX.sub.m wherein m=2.5 to 4.0;(2) a co-catalyst of the formula AlR.sub.n X.sub.3-n where R is a hydrocarbon radical, X is a halogen or hydrogen and n is 2 or 3;(3) a phosphorous compound of the formula PR.sub.1 R.sub.2 R.sub.3 or P(OR.sub.1) (OR.sub.2) (OR.sub.3) where R.sub.1, R.sub.2, and R.sub.3 are, independently, aryl, alkyl, aralkyl, or alkaryl, containing from 1 to 12 carbon atoms and placing the catalyst in contact with;(b) alpha-monoolefinic hydrocarbons from C.sub.2 -C.sub.30 under suitable temperature conditions to provide a hydrocarbon soluble ultrahigh molecular weight polymer, then ceasing polymerization at a polymer content level of 20% by weight or less, based on the total reaction mixture.

Abstract: A process for preparing aromatic-moiety-containing polymers having modified physical properties is disclosed. Briefly, the process comprises reacting in the presence of a Friedel-Crafts catalyst: (a) a suitable aromatic-moiety containing polymer resin and (b) a homopolymer of .omega.-halo-.alpha.-olefins, or co- or terpolymer of .omega.-halo-.alpha.-olefins with other .alpha.-olefins and/or ethylene.

Abstract: A method of purifying trioxane and other acetals by contacting them with an alkali metal and a phase transfer catalyst is described. Trioxane so purified is capable of being polymerized to high molecular weight.

Abstract: A titanium oxide/magnesium sulfate/magnesium oxide catalyst which is an ortho-selective methylation catalyst can be made to exhibit higher conversion and activity index for phenol methylation by the application of pressure. The pressure can be applied throughout the methylation period or can be applied for a short time at the beginning of the methylation period and then ceased, while higher activity continues. The pressure activation effects are assisted by the presence of phenol, methanol and/or water.

Abstract: A method is provided for the production of ultrahigh molecular weight drag reducing substances and the like comprising:(a) preparing under an inert atmosphere a catalyst comprising:(1) titanium halide of the general formula TiXm wherein m=2.5 to 4.0 and X is a halogen;(2) a co-catalyst such as an organo-aluminum or organo-aluminum halide of the formula AlR.sub.n X.sub.3-n where R is a hydrocarbon radical containing from 1 to 20 carbon atoms, X is a halogen and n is 2 or 3;(3) a monoether compound of the formula R.sub.1 OR.sub.2 where R.sub.1, and R.sub.2 are, independently, aryl, alkyl, cycloalkyl, aralkyl, or alkaryl, each having up to 20 carbon atoms, and placing the catalyst in contact with;(b) alpha-monoolefinic hydrocarbons having from 2 to 30 carbon atoms under suitable temperature conditions to provide an ultrahigh molecular weight hydrocarbon soluble polymer, then(c) ceasing polymerization at a polymer content of 20% by weight or less, based on the total reaction mixture.

Abstract: Highly active, improved ethylene oxychlorination catalysts are prepared by forming alumina having specific pore volume characteristics and impregnating such alumina with an oxychlorination catalyst such as CuCl.sub.2. The improved catalysts of the present invention utilize an alumina carrier having a pore volume distribution such that substantially no pores are present which have diameters of less than 150 .ANG.ngstroms and the total alumina carrier has a surface area of at least 30 square meters per gram.