Abstract: Method for making a water insoluble hydrophilic polymeric substrate having incorporated therein a dispersion of a finely precipitated metal sulfide for sorbing by ion exchange heavy metals from aqueous solutions such as photographic solutions, seawater, mine tailings, electroplating baths and the like, the substrate being formed from such polymers as cellulose esters, cellulose ethers, starches cross-linked to render them water insoluble, natural polymers, or regenerated cellulose; and the product of the method.

Abstract: Copolyesters of terephthalic acid, phenylhydroquinone and 25 to 50 mole percent hydroquinone based on total moles of diol. These copolyesters are characterized by unexpected chemical resistance.

Abstract: It has been found that unexpectedly high yields of a high purity product can be obtained when substituted p-quinones are prepared by oxidation, using a molecular oxygen-containing gas, of the corresponding phenols in an inert solvent having a dipole moment of at least 2.7 and in the presence of a salcomine catalyst.

Abstract: Process for the preparation of polyesters and poly(ester-carbonates) comprising heating aromatic diol polycarbonates and esters of dicarboxylic acids in the presence of ester exchange and polymerization catalysts.

Abstract: This invention relates to novel low density polyethylene containing blends useful as extrusion coating compositions which provide coatings having good coatability and a broad heat seal range. These coated substrates then can be used in fabricating bags and other packaging applications. These coatings contain a blend of low density polyethylene and a degraded crystalline polypropylene or propylene containing copolymer.

Abstract: Disclosed are colored polyester compositions containing copolymerized anthraquinone dyes as colorants, which compositions may be used, for example, for food packaging and to mold colored beverage bottles. The copolymerized dyes are thermally stable at the processing temperatures, and are colorfast and nonextractable. The useful dyes have the general formula: ##STR1## wherein either or both of rings A and B may contain in any position thereon one or two groups of the formula ##STR2## R and R.sup.3 each is hydrogen, lower alkyl or lower hydroxyalkyl; R.sup.1, R.sup.2, R.sup.4 and R.sup.5 each is hydrogen or 1-3 substituents such as lower alkyl, lower alkoxy, phenyl, Cl, Br, or the like; X is --S-- or --NH--; n is 1 or 2; m is 0, 1, or 2.

Abstract: Process for manufacturing polyethylene terephthalate fibers having improved low-pilling properties by admixing ethylene glycol with polyethylene terephthalate polymer in extruder and holding the resulting processed fiber at constant length while heatsetting the fiber, and preferably relaxing the fiber up to about 5% while being heatset to a controlled length; and a polyester fiber as made by the process.

Abstract: This invention relates to a process for controlling viscosity during the preparation of modified or grafted low viscosity polyethylene and ethylene/alpha olefin waxes comprising reacting the low viscosity waxes with an unsaturated polycarboxylic component in the presence of a free radical source and at least one viscosity stabilizer.

Abstract: The hot-melt adhesives of the present invention comprise a blend of ethylene-vinyl acetate copolymer, hydrocarbon tackifier resin, aromatic low softening point tackifying resin and paraffin wax. These hot-melt adhesive compositions provide adhesives especially useful for bonding polyethylene film to a nonwoven support. The bonds provided by this adhesive have a novel combination of properties such as good static shear lap bond strength, low elongation and good elevated temperature properties.

Abstract: Thermoplastic materials are converted directly into thermally bonded, coherent fibrous products by melt blowing techniques. The fibrous product is in the form of a rod having a relatively dense, rigid skin in which the fiber portions are oriented primarily in a longitudinal direction with respect to the axis of the product, and a less dense core where the fiber portions are oriented primarily in a transverse direction with respect to the axis of the product. The products are made by melt blowing fibers and intercepting them by a fiber collecting and forming device which permits a relatively heavy build-up of fiber mass in the central portion and a relatively light build-up of fibers in a lip portion surrounding the central portion.

Abstract: Disclosed are polyester substrates or sheets laminated with an acrylic film and having exceptionally improved resistance to surface deterioration on weathering. These laminates are especially suited for use in applications such as windows, signs, solar collectors, green house covers and the like which are subject to extended periods of outdoor exposure. Typical polyesters include modified poly(ethylene terephthalate), and modified poly(1,4-cyclohexylenedimethylene terephthalate) such as those of terephthalic acid with ethylene glycol and 1,4-cyclohexanedimethanol, e.g., poly(69/31 molar-ethylene/1,4-cyclohexylenedimethylene terephthalate) and poly(65/35 molar-1,4-cyclohexylenedimethylene/ethylene terephthalate). The acrylic polymer films suitable forlamination to the polyester sheeting are homopolymers and copolymers prepared from either or both of the monomers H.sub.2 C.dbd.CHCO.sub.2 R and H.sub.2 C.dbd.C(CH.sub.3)CO.sub.2 R.sup.1 wherein R and R.sup.1 are each selected from C.sub.1 -C.sub.

Abstract: Disclosed are novel azo dyes containing an isothiazole azo moiety which may be substituted, and a heterocyclic coupler which also may be substituted. The dyes produce yellow shades on, for example, hydrophobic textile fiber including polyesters, polyamides, and cellulose esters and have excellent fastness properties including lightfastness, washfastness and resistance to sublimation, and dye at unusually low energy levels. The dyes have the general formulae: ##STR1## wherein the various substituents, R.sup.1 and R.sup.2 are each selected from hydrogen and a wide variety of groups such as lower alkyl, --CN, halogen, and the like, R.sup.3 and R.sup.4 are each selected from hydrogen, lower alkyl, benzyl and phenyl, and Z represents the atoms necessary to complete a five or six membered ring.

Abstract: Disclosed are compositions comprising a polyester derived from 100 mole % of an acid component and 100 mole % of a glycol component, the acid component comprising about 30-90 mole % of at least one .alpha.,.beta.-ethylenically unsaturated dicarboxylic acid and about 70-10 mole % of a compound containing a cinnamic acid moiety, and the glycol component comprising at least one saturated aliphatic glycol containing from 2 to 10 carbon atoms. These compositions have improved resistance to attack by organic solvents.

Abstract: An ends-down sensor device for detecting breakage or absence of a cabinet end of filamentary yarn, involving a cylindrical roller seated upon a fixed center post with the center of gravity of the roller causing it to rotate relative to the center post in one direction and activate a suitable signal device when a cabinet end breaks or becomes missing; and upon a cabinet end frictionally engaging the cylindrical roller, causing the roller to rotate relative to the center post in the opposite direction and deactivate the signal device.

Abstract: Disclosed are heat-resistant adhesive compositions comprising a copolyester derived from terephthalic acid, from about 30 to about 50 mol % diethylene glycol, and at least 50 mol % ethylene glycol, the polyester having an inherent viscosity of from about 0.4 to about 1.0. The composition is especially useful in bonding parts of ovenable food containers.

Abstract: Disclosed are crystalline polyesters having low melt viscosities and thermosetting compositions comprising these polyesters. The compositions are especially useful as powder coatings. The polyesters are derived from 1,4-butanediol and trans-1,4-cyclohexanedicarboxylic acid. The polyesters are characterized as having a molecular weight of about 700-3000, a melt viscosity of about 50-3500 cps at 160.degree. C. and a hydroxyl number of about 35-160. The thermosetting composition contains a curing agent which is reactive with the hydroxyl groups to crosslink the polyester.

Abstract: Disclosed are compositions of matter comprising the reaction products of polyesters and 2,2-dimethyl-3-hydroxypropyl-2,2-dimethyl-3-hydroxypropionate, the reaction products containing, by weight, about 40-80% of a polyester and about 60-20% of 2,2-dimethyl-3-hydroxypropyl-2,2-dimethyl- 3-hydroxypropionate and having a hydroxyl number of about 150-300. The compositions are especially useful in high-solids coatings.

Abstract: Process for preparation of poly(ester-carbonates) from aromatic diol bis(alkylcarbonates) and esters of dicarboxylic, and/or carboxylate-carbonate esters of hydroxy acids by suitably heating the reactants in the presence of a suitable polymerization catalyst.

Abstract: Disclosed are copolyesters derived from 100 mole % of a dibasic acid component, at least 2 mole % of which is the reaction product of ethylene and at least one dialkyl ester of an aliphatic or cycloaliphatic dibasic acid, said dibasic acid containing from 3 to 22 carbon atoms and the alkyl groups of wich contain from 1 to 8 carbon atoms, and 100 mole % of at least one aliphatic or alicyclic glycol having 2 to 12 carbon atoms. These polyesters are useful as adhesives.

Abstract: Disclosed are copolyesters derived from 100 mole % of a dibasic acid component, about 2-30 mole % of which is the reaction product of ethylene and at least one dialkyl ester of an aliphatic or cycloaliphatic dibasic acid, said dibasic acid containing from 3 to 22 carbon atoms and the alkyl groups of which contain from 1 to 8 carbon atoms, and 100 mole % of at least one aliphatic or alicyclic glycol having 2 to 12 carbon atoms. These polyesters have a crystalline melting point of at least 200.degree. C. and are useful in the form of fibers, films, and molded objects.