Abstract: Practice of this invention provides, at least, a method of making a hydrogen storage material comprising the steps of: 1. forming a molten mixture comprising nickel and at least one other transition metal element, the combination of which will form a TiNi alloy and including in said molten mixture from about 0.1 at. % to about 10 at. % of one or more elements which will form an alloy which is immiscible in the TiNi-type alloy; and (b) cooling said molten mixture to form a solid alloy-system material by rapid solidification of said molten mixture at a cooling rate of at least 103° C. per second.

Abstract: Hydrogen propelled vehicles and fundamentally new magnesium-based hydrogen storage alloy materials which for the first time make it feasible and practical to use solid state storage and delivery of hydrogen to power internal combustion engine or fuel cell vehicles. These exceptional alloys have remarkable hydrogen storage capacity of well over 6 weight % coupled with extraordinary absorption kinetics such that the alloy powder absorbs 80% of its total capacity within 10 minutes at 300° C. and a cycle life of at least 500 cycles without loss of capacity or kinetics.

Abstract: A composite hydrogen storage material including 1) an active material having hydrogen storage capacity; and 2) a catalytic material having greater catalytic activity toward the dissociation of molecular hydrogen and/or oxidation of hydrogen than that of said active material having hydrogen storage capacity. Also, a fuel cell employing anodes formed from the composite hydrogen storage material. The fuel cell has the ability to start up instantly and can accept recaptured energy such as that of regenerative braking by operating in reverse as an electrolyzer.

Abstract: A fuel cell which has the ability to start up instantly and can accept recaptured energy such as that of regenerative braking by operating in reverse as an electrolyzer. The instant startup fuel cells have increased efficiency and power availability (higher voltage and current) and a dramatic improvement in operating temperature range of about −20 to 150° C.

Abstract: A hydrogen gas cooled hydrogen storage element which includes a hydrogen storage alloy material in which hydrogen flow channels are provided. The flow channels provide pathways through the hydrogen storage material to allow for high speed hydrogen gas flow. A portion of the high speed hydrogen flow is stored within the storage material which releases its heat of hydride formation. The remainder of the hydrogen flows through the hydrogen storage material at a sufficient mass flow rate to remove the heat of hydride formation.

Abstract: A negative electrode alloy material including an effective amount of a catalyst to substantially increase the discharge capacity of the alloy at high discharge rates. Preferably the catalyst is palladium.

Abstract: A hydrogen cooled hydrogen storage unit. The unit employs excess hydrogen flow between hydrogen storage alloy rods in the hydrogen storage unit in order to provide convective cooling thereof. The unit provides for high packing density of the storage materials. The unit also allows for efficient thermal transfer of heat energy from a central source of heat through the rods thereof during discharge of the stored hydrogen. The hydrogen storage rods of the unit are encased in an encapsulant layer which prevents entrainment of the hydrogen storage material in the high flow rate hydrogen.

Abstract: Mechanically and thermally improved rechargeable batteries and modules. The battery is prismatic in shape with an optimized thickness to width to height aspect ratio which provides the battery with balanced optimal properties when compared with prismatic batteries lacking this optimized aspect ratio. The optimized thickness, width and height allow for maximum capacity and power output, while eliminating deleterious side affects. The battery case design allows for unidirectional expansion which is readily compensated for by applying external mechanical compression counter to that direction. In the module, the batteries are bound within a module bundling/compression means under external mechanical compression which is optimized to balance outward pressure due to expansion and provide additional inward compression to reduce the distance between the positive and negative electrodes, thereby increasing overall battery power.

Abstract: A magnesium based hydrogen storage alloy powder which is useful as a hydrogen supply material for powering internal combustion engine or fuel cell vehicles. The alloy contains greater than about 85 atomic percent magnesium, about 2-8 atomic percent nickel, about 0.5-5 atomic percent aluminum and about 2-7 atomic percent rare earth metals or mixtures of rare earth metals. The rare earth elements may be Misch metal and may predominantly contain Ce and/or La. The alloy may also contain about 0.5-5 atomic percent silicon. The alloys can be modified to store more than 4 wt. % hydrogen, with a reduced hydride bond strength (i.e. about 64 kJ/mole) which allows for economic recovery of the stored hydrogen. Also, they have a plateau pressure about two times greater than pure Mg and comparable bond energies and plateau pressures to Mg2Ni alloys, while reducing the amount of incorporated nickel by 25-30 atomic %. Also, the storage capacity of the alloy is significantly greater than the 3.6 wt. % of Mg2Ni material.

Abstract: A hydrogen cooled hydrogen storage unit which employs excess hydrogen flow through flow channels between hydrogen storage alloy plates in order to provide convective cooling of the plates. The unit provides for high packing density of the storage materials and ease of expansion of storage capacity by merely adding more storage material plates. Since the hydrogen flows transversely between the plates and does not flow along the entire length of the stack, the cooling flow path of the hydrogen is short, and the temperature differential between any point of the stack and the hydrogen coolant is maximized, which maximizes the cooling efficiency of the unit.

Abstract: A memory system comprising memory cells and reference cells each including a programmable resistance element. The resistance state of a memory cell is determined by comparing a sense signal developed by the memory cell with a reference signal developed by one or more of the reference cells. The programmable resistance elements may comprise a phase-change material.

Abstract: A complete infrastructure system for the generation, storage, transportation, and delivery of hydrogen which makes a hydrogen ecosystem possible. The infrastructure system utilizes high capacity, low cost, light weight thermal hydrogen storage alloy materials having fast kinetics. Also, a novel hydrogen storage bed design which includes a support/heat-transfer component which is made from a highly porous, high thermal conductivity, solid material such as a high thermal conductivity graphitic foam. Finally a material including at least one particle having atomically engineered local chemical and electronic environments, characterized in that the local environments providing bulk nucleation.

Abstract: A hydrogen gas cooled hydrogen storage element which includes a hydrogen storage alloy material in which hydrogen flow channels are provided. The flow channels provide pathways through the hydrogen storage material to allow for high speed hydrogen gas flow. A portion of the high speed hydrogen flow is stored within the storage material which releases its heat of hydride formation. The remainder of the hydrogen flows through the hydrogen storage material at a sufficient mass flow rate to remove the heat of hydride formation.

Abstract: A modified Ti—V—Zr—Ni—Mn—Cr electrochemical hydrogen storage alloy which has at least one of the following characteristics: 1) an increased charge/discharge rate capability over that the base Ti—V—Zr—Ni—Mn—Cr electrochemical hydrogen storage alloy; 2) a formation cycling requirement which is reduced to one tenth that of the base Ti—V—Zr—Ni—Mn—Cr electrochemical hydrogen storage alloy; or 3) an oxide surface layer having a higher electrochemical hydrogen storage catalytic activity than the base Ti—V—Zr—Ni—Mn—Cr electrochemical hydrogen storage alloy.

Abstract: A multiple cell monoblock battery in which a plurality of electrochemical cells are disposed in a plastic or metal case and each of the cells includes an enclosure providing for gas to exit while preventing electrolyte to exit the enclosure. A novel integral system of flow channels allows liquid coolant to flow between adjacent cells. Other special features, such as cell interconnections are described.

Abstract: A method and apparatus for forming polycrystalline particles by gas phase condensation employing arc plasma evaporation. The disclosed method and apparatus may be employed to form polycrystalline particles from high-melting temperature, low evaporation pressure materials such as transition metals. Arc discharge is sustained by the evaporated species, therefore, there is no need for a plasma sustaining gas. Evaporation may be sustained from either the cathode or anode. A reaction gas may be provided to form products with the evaporated species.

Abstract: Reversible hydrogen storage alloys and methods and electrodes formed therefrom for nickel metal hydride batteries, in which the alloys are quenched from a melt at cooling rates selected to provide a high degree of disorder with an optimum local environment.

Abstract: Hydrogen propelled vehicles and fundamentally new magnesium-based hydrogen storage alloy materials which for the first time make it feasible and practical to use solid state storage and delivery of hydrogen to power internal combustion engine or fuel cell vehicles. These exceptional alloys have remarkable hydrogen storage capacity of well over 6 weight % coupled with extraordinary absorption kinetics such that the alloy powder absorbs 80% of its total capacity within 2 minutes at 300° C.

Abstract: Apparatus and method for the vacuum deposition of at least two different layers of thin film material onto a substrate by two different vacuum deposition processes. Also disclosed is a novel linear applicator for using microwave enhanced CVD to uniformly deposit a thin film of material over an elongated substrate.

Abstract: An active composition for an electrode of an electrochemical cell. The active composition comprises an electrode material, and a nonfibrillating polymeric binder. The polymeric binder may comprise a fluoradditive. Also disclosed in an electrode and an electrochemical cell comprising the active composition.