Abstract: A moldable composition which comprises a novel random N-(brominated or chlorinated phenyl) maleimide-containing copolymer, a thermoplastic resin, preferably, polycarbonate and a flame retardant synergist is disclosed. The molded composition exhibits at least a 94 V-1 classification when tested in accordance with Underwriters Laboratories Inc. Test Method UL94.
Abstract: A process for generating random dialkyl or alkyl aryl peroxide functionality on elastomers is disclosed. Generally, the process involves dissolving an elastomer in a solvent followed by treating the resulting solution with an oxidizing agent in the presence of a catalyst. In a preferred embodiment, the oxidizing agent is a an alkyl or aryl hydroperoxide and the catalyst is a Group VIIa, VIII, Ib or IIb metal.
Abstract: The impact resistance of molded polyamide resin molding compositions is improved by incorporating thereinto an elastomer grafted with a polymer comprised of recurring units of, in weight percent, (A) from about 60 to about 95 vinyl aromatic monomer, (B) from about 5 to about 40 of at least one acid selected from the group consisting of acrylic acid, methacrylic acid, partially neutralized acrylic acid, partially neutralized methacrylic acid, totally neutralized acrylic acid and totally neutralized methacrylic acid and (C) 0 to about 15 acrylate monomer.
Abstract: A thermodynamically miscible polymer composition comprised of a terpolymer having recurring units of methylmethacrylate, N-aryl substituted maleimide, and vinyl aromatic monomer and an acrylonitrile copolymer is disclosed.
Abstract: The char residue formation of molded compositions, upon combustion, is improved by incorporating into the moldable composition a char-forming polymer containing recurring units of at least one monomer capable of undergoing tautomerization, at least one monomer capable of undergoing a nucleophilic substitution reaction by said monomer capable of undergoing tautomerization and, optionally, at least one additional copolymerizable monomer.
Abstract: Polymer compositions comprising from about 1 to about 99 mole % of a copolymer of a styrenic monomer selected from the group consisting of styrene, p-methylstyrene, t-butylstyrene and .alpha.-methylstyrene with a maleimide monomer selected from the group consisting of maleimide, N-phenylmaleimide, N-methylmaleimide and N-ethylmaleimide and from about 99 to about 1 mole % of a copolymer of styrene monomer with at least one isomeric cyanostyrene monomer selected from the group consisting of ortho-cyanostyrene, meta-cyanostyrene and para-cyanostyrene, are disclosed.
Abstract: A moldable composition comprising a .gamma.-sultone derivative of an ethylene/propylene/substituted methylene norbornene terpolymer and a polymer which comprises recurring units of a vinyl aromatic monomer, a monomer having an active hydrogen with an acidity constant (pKa) within the range of from about 7.5 to about 10.5 and a vinyl pyridine monomer selected from the group consisting of 2-vinyl pyridine and 4-vinyl pyridine is disclosed. Optionally, the polymer comprises recurring units of an ethylenically unsaturated monomer.
Abstract: Moldable polymer compositions comprising a polyether sulfone resin and a copolymer containing recurring units of a vinyl aromatic monomer and recurring units of a maleimide monomer are disclosed.
Abstract: [2, 5, 8, 11]-tetraalkyl-[2, 5, 8, 11]-tetracyano-cis-6a' carboxy, 12a' oxoacide-3,4:9,10 bisdiazobicyclooctane compounds are disclosed. In one embodiment, the compounds are capable of initiating free radical polymerization and are well suited for the preparation of polymers having block type structures.
Abstract: Moldable polymer compositions comprising a polyarylate resin and a copolymer containing recurring units of a vinyl aromatic monomer and recurring units of a maleimide monomer are disclosed.
Abstract: Radial block polymers having at least four arms. In one embodiment, the radial block polymers are prepared using a bisdiazobicyclooctane polymerization initiator. In another embodiment, five arm radial block polymers of this invention are well suited for use as impact modifiers for thermoformable plastic resins.
Abstract: A polymeric molding composition containing a polycarbonate resin, a styrenic copolymer and a methylmethacrylate-butadiene-styrene polymer is disclosed. The molding compositions of this invention exhibit excellent impact strength and can be molded over a wide range of processing conditions.
Abstract: Polyblends of impact modified styrene/.alpha.,.beta.-unsaturated dicarboxylic anhydride or imide copolymers and polyamides are disclosed. The resulting molded articles exhibit excellent mechanical strength, resistance to chemicals, toughness and resistance to heat.
Abstract: Polymeric composition having good impact resistance which comprises styrene, methylstyrene, a conjugated diene monomer, and optionally an unsaturated dicarboxylic acid anhydride, are described.
Abstract: The synthesis of aryl alkyl ethers from methylbenzyl alcohol and, optionally, phenol using a bis-(dithiobenzyl)nickel(II) catalyst is disclosed.
Abstract: Polymer alloys containing copolymers of methylmethacrylate/N-phenylmaleimide are disclosed. In one embodiment the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride. In another embodiment, the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride/N-phenylmaleimide.
Abstract: A flame retarding additive comprising an alternating copolymer of a brominated styrene and N-brominated phenylmaleimide, is blended with a matrix resin to produce molding compositions which when molded exhibit improved flame retarding characteristics. The flame retarding additives of this invention also exhibit non-blooming characteristics.
Abstract: Polymer alloys containing copolymers of methylmethacrylate/N-phenylmaleimide are disclosed. In one embodiment the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/acrylonitrile. In another embodiment, the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and stryene/acrylonitrile/N-phenylmaleimide.
Abstract: The incorporation of a high melt flow rate propylene-based polymer additive into a CPVC molding compound serves to retard the fusion rate of the CPVC compound during processing.