Abstract: The present invention relates to a process for preparing acylsuccinic acid polyesters by reactingA) a polyester, which is the reaction product oi) maleic acid, maleic acid esters, maleic anhydride, fumaric acid and/or fumaric acid esters and optionally other diacids, monoacids or their derivatives withii) diols and optionally monofunctional alcohols,wherein the molar ratio of diols to diacids and their derivatives is 0.667:1 to 1.5:1, and the molar ratio of maleic acid and its derivatives+ fumaric acid and its derivatives to other diacids and their derivatives is greater than 0.15:1, and the molar ratio of monofunctional compounds to difunctional compounds is less than 0.4:1, withB) aliphatic C.sub.2 -C.sub.22 aldehydes and/or cycloaliphatic C.sub.6 -C.sub.20 aldehydes,in the presence of 0.2 to 10 % by weight (based on the weight of polyester) of free radical initiators at a temperature of 60 to 160.degree. C.
Abstract: The present invention relates to aqueous polyurethane dispersions having a resin solids content of 20 to 60 wt %, a viscosity at 23.degree. C. of 10 to 20,000 mPa.s and a pH of 5.5 to 8.5, wherein the polyurethane has a weight average molecular weight of 5,000 to 500,000 and a urethane group content (calculated as --NHCO--O--, molecular weight=59) of 2.5 to 15 wt %, and is based on a polyisocyanate component containing 50 to 100 wt % of 1-methyl-2,4- and/or -2,6-diisocyanatocyclohexane.The present invention also relates to aqueous binder compositions containing these aqueous polyurethane dispersions and known crosslinking resins and to the use of the aqueous polyurethane dispersions and aqueous binder compositions as binders for glass fiber sizings.
Type:
Grant
Filed:
March 6, 1997
Date of Patent:
July 13, 1999
Assignee:
Bayer Aktiengesellschaft
Inventors:
Harald Blum, Karin Naujoks, Helmut Reiff, Oswald Wilmes, Hans-Ulrich Meier-Westhues, Raymond Audenaert
Abstract: The present invention relates to a process for preparing an isocyanate group-containing allophanate corresponding to formula (I) ##STR1## wherein R represents the residue obtained by removing the isocyanate groups from a (cyclo)aliphatic or araliphatic diisocyanate,Y represents the represents an m-valent residue obtained by removing the hydroxyl groups from a (poly)hydroxyl compound having m OH groups andn and m are the same or different and have a value of 1 to 5, by reacting an isocyanate group-containing oxadiazinetrione with a primary alcohol in the presence of a basic catalyst having a pKa value of >6.
Type:
Grant
Filed:
August 8, 1997
Date of Patent:
June 29, 1999
Assignee:
Bayer Aktiengesellschaft
Inventors:
Klaus Konig, Helmut Reiff, Christian Wamprecht, Harro Traubel
Abstract: The present invention relates to a process for the solvent-free production of polyisocyanate addition products, which are suitable as dispersing agents for incorporating solids into aqueous coating compositions, wherein the polyisocyanate addition products have a maximum content of 1% by weight of isocyanate groups and a content of 30 to 95% by weight of ethylene oxide units (molecular weight=44) present in the polyether chains of monofunctional alcohols B), and are prepared by reactingA) a polyisocyanate component having an average NCO functionality of 1.7 to 2.5 and an NCO content of 10 to 65% by weight with one or more of the following components:B) monohydric polyether alcohols having a number average molecular weight of 150 to 5000 and an ethylene oxide content of 40 to 99.
Type:
Grant
Filed:
August 20, 1997
Date of Patent:
June 8, 1999
Assignee:
Bayer Aktiengesellschaft
Inventors:
Christian Wamprecht, Oswald Wilmes, Stephan Kirchmeyer, Jan Mazanek
Abstract: This invention relates to polyisocyanates which are partially or completely blocked with 3,5-dimethyl-1,2,4-triazole, to heat curable, one-component coating compositions containing these blocked polyisocyanates and to the resulting coatings.
Type:
Grant
Filed:
July 24, 1997
Date of Patent:
March 30, 1999
Assignee:
Bayer Aktiengesellschaft
Inventors:
Gerald Kurek, Eberhard Konig, Klaus Nachtkamp, Theodor Engbert
Abstract: The present invention relates to polycyclic iminooxadiazinediones A corresponding to formula I ##STR1## The present invention also relates to mixtures of these polycyclic iminooxadiazinediones with other isocyanate derivatives and to their use for the production of optionally foamed polyurethane plastics, for the production of paints and coatings and for the production or formulation of active ingredients, pharmaceutical products, etc.
Type:
Grant
Filed:
December 11, 1997
Date of Patent:
March 16, 1999
Assignee:
Bayer Aktiengesellschaft
Inventors:
Frank Richter, Dieter Mager, Josef Pedain
Abstract: The present invention relates to aqueous polyurethane coating compositions wherein the binder containsa) a polyol component, which is soluble or dispersible in water and is the reaction product of a polyisocyanate component containing 50 to 100 wt. % of 4,4'-diisocyanatodicyclohexylmethane, a polyol component containing one or more polyether polyols and having an OH number of 25 to 350 mg KOH/g solids and an isocyanate-reactive component containing at least one group capable of salt formation andb) a polyisocyanate component, which is soluble or dispersible in water, has blocked isocyanate groups and is the reaction product of a polyisocyanate having an isocyanurate group content of 2 to 30 wt.
Abstract: The present invention relates to hydroxy-functional polyhydantoin prepolymers corresponding to the formula ##STR1## wherein R represents the residue obtained by removing the isocyanate groups from an organic monomeric diisocyanate, a polyisocyanate adduct or an NCO prepolymer containing hydantoin groups, R.sub.2 represents an organic group which is inert towards isocyanate groups at a temperature of 100.degree. C. or less, R.sub.3 and R.sub.4 may be identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less, R.sub.5 represents the hydrocarbon radical obtained by removing the amino and hydroxyl groups from an amino alcohol, n has a value of 1 to 3 and m has a value of 2 to 6. The present invention is also directed to compositions suitable for the production of coatings, adhesives or elastomers containing these polyhydantoin prepolymers in combination with optionally blocked polyisocyanates or aminoplast resins.
Type:
Grant
Filed:
March 11, 1997
Date of Patent:
December 22, 1998
Assignee:
Bayer Corporation
Inventors:
E. Haakan Jonsson, Douglas A. Wicks, Philip E. Yeske, Lyuba K. Gindin
Abstract: The present invention relates to a powder coating composition for the production of non-yellowing flexible coatings which is solid below 30.degree. C. and liquid above 120.degree. C. and contains a mixture ofA) a polyisocyanate component whichi) has a content of blocked isocyanate groups (expressed as NCO, molecular weight=42) of 3.0 to 14.0% by weight,ii) has a functionality, based on the blocked isocyanate groups, of 1.9 to 2.3 andiii) and contains at least one .epsilon.
Type:
Grant
Filed:
October 27, 1997
Date of Patent:
December 22, 1998
Assignee:
Bayer Aktiengesellschaft
Inventors:
Reinhard Halpaap, Christian Wamprecht, Hans-Joachim Kreuder, Wolfgang Schultz, Manfred Bock, Rainer Rettig
Abstract: A method for imparting dry strength to paper by adding to a pulp slurry during a paper-making process a mixed resin solution containing (i) an aminopolyamide-epichlorohydrin resin and (ii) a glyoxylated acrylamide-dimethyl diallyl ammonium chloride resin, in combination with (iii) a high charge density cationic polymer.
Abstract: A stable, fluid alkaline earth metal tallate dispersion is prepared by (i) forming a pre-emulsion of fatty acids derived from tall oil, water, and a surfactant; (ii) forming an alkaline earth metal salt dispersion from an alkaline earth metal oxide and/or hydroxide, a lower carboxylic acid, and water; and (iii) incorporating the pre-emulsion into the alkaline earth metal salt dispersion under high shear and low pressure.
Type:
Grant
Filed:
June 20, 1996
Date of Patent:
June 9, 1998
Assignee:
High Point Chemical Corp.
Inventors:
Peter M. Robinson, Robert E. Brooks, Terry E. Singleton
Abstract: A transportation safety apparatus and method for the detection of obstacles which lie off the line-of-sight or beyond the field of view of a moving vehicle entails shooting a laser beam through the air from a moving vehicle, capturing the beam and passing it to a fiberoptic relay which transmits a laser pulse to a distant site, and receiving a reflection thereof if the site is clear of obstacles. The pulses are received within about 10-20 microseconds per kilometer of relay length from the time of launching, permitting monitoring of the probe-site in real-time.
Abstract: A method for imparting strength to paper by adding to a pulp slurry during a paper-making process a mixed resin solution containing (i) an aminopolyamide-epichlorohydrin resin and (ii) a glyoxylated acrylamide-dimethyl diallyl ammonium chloride resin.
Type:
Grant
Filed:
February 16, 1996
Date of Patent:
October 7, 1997
Assignee:
Callaway Corp.
Inventors:
Richard T. Underwood, Robert J. Jasion, Stephen P. Hoke, Gavin G. Spence
Abstract: Pharmaceutical composition for immunomodulating and adjuvant therapy containing a metabolic stressor, 2-deoxy-D-ribose and further active components, i.e. ribose, DL-alanine, nicotonic acid, L-ascorbic acid, thiamin and glutamic acid amide is intended for immunomodulating and adjuvant therapy and for prevention of weakening of the immunity system.
Abstract: Broad spectrum glycosidase inhibitors are produced from monosaccharide lactams by conversion to amidines, amidrazones or amidoximes. The inhibitors have the general formula: ##STR1## wherein the N and C are joined as part of a monosaccharide azaanalog ring and wherein --NRQ, together with the nitrogen and carbon atoms, form a chemical group selected from amidines, amidrazones, and amidoximes.
Type:
Grant
Filed:
January 19, 1995
Date of Patent:
September 2, 1997
Assignee:
Cornell Research Foundation, Inc.
Inventors:
Bruce Ganem, Michael K. Tong, George Papandreou
Abstract: A method for repelling insects from plants with non-cyclic esters is disclosed. The esters are prepared from a non-cyclic polyhydroxyl compound having from about 3 to about 5 carbon atoms and at least three hydroxyl groups and a carboxylic acid. In the esters at least two of the hydroxyl groups are esterified and the total number of carbon atoms in all of the ester groups is from about 9 to about 19.
Abstract: A nozzle assembly for forming hollow fibers, particularly a "Z-fiber" having longitudinally oriented trabeculae with the fiber wall, is disclosed. The nozzle assembly contains a replaceable nozzle cap, a replaceable seal-guide, and a retractable central bore used to supply core material for the hollow fibers. The Z-fibers are particularly useful in enabling cells, solutes, or the like, to enter the fiber wall and move longitudinally into the center of the fiber wall.
Type:
Grant
Filed:
June 1, 1995
Date of Patent:
August 12, 1997
Assignee:
Brown University Research Foundation, Inc.
Inventors:
Frank T. Gentile, Michael J. Lysaght, Nicholas F. Warner
Abstract: A method of pore-size selective chemical modification of materials having pores of about 1 to 1,500 nm is disclosed. The resulting novel porous materials are particularly useful as separation media in chromatography, for selective isolation, adsorption and catalysis.
Abstract: A process for improving the rate of metal production and FeO utilization in a steelmaking process or a process combining iron-making and steelmaking in a single reactor that uses or generates Fe-C metal alloy droplets submerged in an FeO-containing slag. The process involves discharging a charge build-up (electron accumulation) in the slag at the slag-metal alloy interface by means of an electron conductor connected between the metal alloy droplets and a gas at a gas-slag interface, said gas having an oxygen partial pressure of at least about 0.01 atmosphere.