Patents Represented by Attorney E. Eugene Innis
  • Patent number: 4481250
    Abstract: An emulsion composition is disclosed which provides a binder having good wet tensile strength and low heat seal temperature for nonwoven products which comprises an aqueous dispersion of a mixture consisting essentially of 50 to 95 wt % of a vinyl acetate-ethylene copolymer and 5 to 50 wt % of a vinyl acetate-ethylene-crosslinking monomer copolymer.
    Type: Grant
    Filed: July 29, 1983
    Date of Patent: November 6, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Gerald R. Cook, Phillip A. Mango
  • Patent number: 4479350
    Abstract: Power is recovered from the vaporization of natural gas by warming the natural gas against a multicomponent stream which is cooled and liquefied. The liquefied multicomponent stream is pumped to an elevated pressure and is warmed against one or more streams of propane which are cooled and liquefied. The warmed multicomponent stream is heated, expanded through a generator loaded expander and recycled. The liquefied propane is pumped to an elevated pressure in single or multi-staged streams, vaporized, expanded through a second generator loaded expander and recycled.
    Type: Grant
    Filed: March 6, 1981
    Date of Patent: October 30, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Charles L. Newton, Dennis L. Fuini
  • Patent number: 4479362
    Abstract: The present invention is an improved process for cooling cement which comprises injecting liquid nitrogen into a pneumatic transport line used to convey the cement.
    Type: Grant
    Filed: December 10, 1982
    Date of Patent: October 30, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Thomas E. McWhorter, Barry J. Halper
  • Patent number: 4478959
    Abstract: Amino and amido carboxylates of divalent tin, zinc, cobalt and nickel which are useful as catalysts for polyurethane formulations. Such compounds correspond to either of the formulae: ##STR1## wherein R.sub.1 and R.sub.2 are independently C.sub.1 -C.sub.20 alkyl, C.sub.6 -C.sub.20 cyclohydrocarbyl, C.sub.2 -C.sub.20 hydroxyalkyl or alkoxyalkyl, or R.sub.1 and R.sub.2 together with N form a nitrogen-containing heterocyclic ring of 5 or 6 atoms;R.sub.3 is a --CH.sub.2).sub.n group where n is an integer from 2 to 6 or a ##STR2## group where R.sub.4 is an alkyl, cycloalkyl or aryl group of up to 6 carbon atoms;A is ##STR3## wherein R.sub.5 and R.sub.6 are independently hydrogen, C.sub.1 -C.sub.4 alkyl or R.sub.5 and R.sub.6 together form part of a six-member cyclohydrocarbyl ring, andM is divalent tin, zinc, cobalt or nickel.
    Type: Grant
    Filed: September 29, 1983
    Date of Patent: October 23, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Ibrahim S. Bechara, Rocco L. Mascioli
  • Patent number: 4477264
    Abstract: A simplified low-cost system designed for home use in the direct administration of high purity oxygen to a patient, utilizes a single adsorption column containing successive layers of adsorbent. The first layer is composed of a molecular sieve adsorbent for removal of water and CO.sub.2 from the air feed stream. The second layer is a molecular sieve adsorbent which preferentially retains nitrogen. The sequence and conditions of the several steps of the operating cycle are designed to recover a therapeutic gas stream of about 90% oxygen content.
    Type: Grant
    Filed: March 30, 1983
    Date of Patent: October 16, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Wilbur C. Kratz, Shivaji Sircar
  • Patent number: 4477265
    Abstract: Argon is recovered from a gas stream comprising the same in admixture with oxygen and nitrogen, by a vacuum swing adsorption (VSA) process wherein the mixed gas is passed through an adsorbent bed having thermodynamic selectivity for adsorption of nitrogen and the unadsorbed portion then passed through a second adsorbent bed having kinetic selectivity for retaining oxygen. Both adsorbent beds are regenerated by vacuum desorption, applied to the first bed for a longer time period than that of the second bed. Further purification of the recovered argon may be carried out, if desired, by catalytic hydrogenation of residual oxygen therein. The mixed gas stream fed to the VSA unit may be that obtained from the crude argon column associated with a cryogenic air separation plant and the waste gas from the VSA unit may be recycled to the main column of the cryogenic air separation plant, thus enhancing argon recovery.
    Type: Grant
    Filed: August 5, 1982
    Date of Patent: October 16, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Ravi Kumar, Shivaji Sircar, Thomas R. White, Eugene J. Greskovich
  • Patent number: 4475351
    Abstract: Products to be frozen are conveyed through an insulated horizontal tunnel having a plurality of individual cooling zones, each equipped with a radial fan rotating in a horizontal plane. Cryogenic liquid refrigerant is sprayed into one or more of the cooling zones in the central region of the tunnel, upwardly into the rotating fans and the thus vaporized refrigerant caused to flow in a downward direction in a recirculating pattern into contact with the conveyed products by vertical partitions between contiguous zones. The vaporized refrigerant flows from the supercold zone of liquid introduction beneath the edges of the partitions in two directions, outwardly towards the opposite ends of the tunnel in substantially equal amounts.
    Type: Grant
    Filed: August 9, 1983
    Date of Patent: October 9, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventor: David J. Klee
  • Patent number: 4475347
    Abstract: A process is described for the separation of an off-gas from a synthetic fuels production process, such as oil shale retorting, coal gasification, oxygen fireflooding or carbon dioxide miscible flood enhanced oil recovery, into an essentially sulfur-free, light fuel gas and a sulfur containing carbon dioxide gas. The off-gas is contacted with methanol to remove the sulfur containing gases and is then cooled to separate out a light fuel gas from a predominantly carbon dioxide gas. The carbon dioxide gas is again contacted with the same methanol to scrub the latter of sulfur-containing gas and reabsorb the sulfur onto the carbon dioxide gas. The carbon dioxide gas can then be recycled to the synthetic fuels production process with deposition of the sulfur therein or the gas can be delivered for export with downstream sulfur treatment.
    Type: Grant
    Filed: September 16, 1982
    Date of Patent: October 9, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: William P. Hegarty, William P. Schmidt
  • Patent number: 4472263
    Abstract: A process is disclosed for the solvent refining of non-anthracitic coal at elevated temperatures and pressure in a hydrogen atmosphere using a hydrocarbon solvent which before being recycled in the solvent refining process is subjected to chemical treatment to extract substantially all nitrogenous and phenolic constituents from the solvent so as to improve the conversion of coal and the production of oil in the solvent refining process. The solvent refining process can be either thermal or catalytic. The extraction of nitrogenous compounds can be performed by acid contact such as hydrogen chloride or fluoride treatment, while phenolic extraction can be performed by caustic contact or contact with a mixture of silica and alumina.
    Type: Grant
    Filed: July 19, 1982
    Date of Patent: September 18, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Diwakar Garg, Edwin N. Givens, Frank K. Schweighardt
  • Patent number: 4472177
    Abstract: A system and method of controlling a vacuum swing adsorption process. During an adsorption step, the percent composition of the gas being processed is sensed as it is introduced into at least one train of beds which comprises a pretreatment bed and an air fractionation bed. The control system terminates the adsorption step when a predetermined high level oxygen composition is detected. During a rinse step the percent composition of the high purity nitrogen in the train is sensed. The control system terminates the rinse step when a predetermined low level oxygen composition is detected. During an evacuation step, the level of pressure in the train is sensed and predetermined subatmospheric pressure levels are detected for terminating evacuation in first, the air fractionation bed, and second, the pretreatment bed.
    Type: Grant
    Filed: September 9, 1982
    Date of Patent: September 18, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Shivaji Sircar
  • Patent number: 4472178
    Abstract: A process is set forth for the removal of carbon dioxide from air in an adsorption bed wherein the regeneration energy is reduced by the use of a heat recuperator and a purge sequence which avoids the removal of heat from the adsorption bed during regeneration.
    Type: Grant
    Filed: July 5, 1983
    Date of Patent: September 18, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Ravi Kumar, Shivaji Sircar, Wilbur C. Kratz
  • Patent number: 4467089
    Abstract: Novel carbamic and carbonic acid derivatives are provided by simultaneous reaction of a secondary amine and a tertiary amine with carbon dioxide. These derivatives correspond in general to the formula ##STR1## in which R.sub.1 and R.sub.2 may be individual substituents attached to the N or together form with N a heterocyclic moiety; R.sub.3, R.sub.4, R.sub.5 may be individual short chain alkyl or hydroxyalkyl substituents on the N or form therewith a monocyclic or bicyclic heterocyclic moiety. These described compounds find particular use as heat activatable delayed action catalysts especially for use in polyurethane formulations.
    Type: Grant
    Filed: March 4, 1982
    Date of Patent: August 21, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Ibrahim S. Bechara
  • Patent number: 4465587
    Abstract: A process is set forth for the solvent extraction and hydroliquefaction of heavy hydrocarbon oils and residua having an API gravity at 60.degree. F. of less than 20.degree. in the presence of a hydrogen atmosphere and a hydrogen donor solvent at elevated temperature and pressure. Alternately, the hydrocarbon feed can be subjected to a vacuum distillation before solvent extraction or the liquefaction can be catalyzed in-situ. The process results in improved oil production and greater denitrogenation desulfurization and demetallization.
    Type: Grant
    Filed: February 28, 1983
    Date of Patent: August 14, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Diwakar Garg, Robert N. Miller
  • Patent number: 4465876
    Abstract: In a process for nitrating aromatics using lower valent nitrating agents in trifluoroacetic acid, the product yield of nitroarenes can be significantly increased by maintaining an excess of nitrating agent over the stoichiometric amount during the reaction.
    Type: Grant
    Filed: February 7, 1983
    Date of Patent: August 14, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Barton Milligan
  • Patent number: 4464519
    Abstract: Vinyl chloride-propylene copolymer resin having improved porosity as shown by an increased irreversible plasticizer take-up is produced by the suspension polymerization of vinyl chloride and propylene in the presence of a binary suspension system of a hydroxypropylmethyl cellulose having 19-30% methoxyl and 4-12% hydroxypropoxyl substitution and a 30-50 mole % hydrolyzed polyvinyl alcohol.
    Type: Grant
    Filed: June 7, 1982
    Date of Patent: August 7, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Phillip A. Mango
  • Patent number: 4464188
    Abstract: A process and apparatus is set forth for the separation of air by cryogenic distillation in a rectification column using two nitrogen recycle streams and a sidestream of the feed air stream to reboil the column. One of the nitrogen recycle streams is expanded to provide refrigeration and to provide power to compress the feed air sidestream.
    Type: Grant
    Filed: September 27, 1983
    Date of Patent: August 7, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Rakesh Agrawal, Thomas E. Cormier
  • Patent number: 4464490
    Abstract: Amino and amido dialkyltin dicarboxylates and stannoxy carboxylates are prepared by first reacting an amine or amino alcohol with a dicarboxylic acid anhydride, followed by reaction of the resulting product with a dialkyltin oxide. The obtained compounds are useful as catalysts for promoting reaction of organic isocyanates with organic compounds having one or more active hydrogen-containing groups.
    Type: Grant
    Filed: March 18, 1983
    Date of Patent: August 7, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Ibrahim S. Bechara, Rocco L. Mascioli
  • Patent number: 4463193
    Abstract: A process for preparing predominantly noncyclic polyalkylene polyamine compounds is disclosed wherein an alkanolamine compound is reacted with an alkyleneamine compound and ammonia or a primary or secondary amine in the presence of a catalytically effective amount of a Group IIIB metal acid phosphate at a temperature from about 175.degree. to 400.degree. C. under a pressure sufficient to maintain a substantial amount of the ammonia or amine in the reaction zone.
    Type: Grant
    Filed: July 19, 1983
    Date of Patent: July 31, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Thomas A. Johnson, Michael E. Ford
  • Patent number: 4457329
    Abstract: A safety pressure regulator employing a diaphragm actuator that upon exposure to high temperature an element melts to release the valve from the actuator to effect its automatic closing.
    Type: Grant
    Filed: December 4, 1981
    Date of Patent: July 3, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Barry L. Werley, Richard H. Snyder, Joseph E. McQuillen, Keith A. Miller
  • Patent number: 4458096
    Abstract: A process is described for producing ethylene and propylene in high selectivity from feed streams containing ethane and propane. The process involves separating the feed into ethane and propane fractions and subsequently cracking the ethane fraction to produce ethylene and dehydrogenating the propane fraction to produce propylene. The fractions are then combined and purified, and the ethylene and propylene products are recovered. Any unreacted ethane or propane is recycled back to the cracking or dehydrogenation units respectively.
    Type: Grant
    Filed: May 26, 1983
    Date of Patent: July 3, 1984
    Assignee: Air Products and Chemicals, Inc.
    Inventors: David J. Phillips, Jerome L. Glazer