Patents Represented by Attorney Edward McC. Roberts
  • Patent number: 5218021
    Abstract: Co-oligmers of the formula R.sub.f --E.sub.m --(S).sub.n --[M.sub.1 ].sub.x --[M.sub.2 ].sub.y --H and mixtures thereof, wherein R.sub.f is a perfluoroalkyl group, E is a linkage group, M.sub.1 represents a non-ionic hydrophilic monomer unit, M.sub.2 represents an anionic hydrophilic monomer unit, n and m are optionally 0 or 1, and x and y represent the number of monomer units present in the novel co-oligomers, the sum of x and y being between 5 and 200, and y/(x+y) being between 0.01 and 0.98; are useful as additives in polar-solvent fire-fighting compositions when used in conjunction with polysaccharides and other adjuvants. They improve dynamic foam stability and vapor suppressing ability of the foam, thereby reducing the flammability of polar solvent contaminated foams and consequently improving extinguishment and burnback resistance.
    Type: Grant
    Filed: February 6, 1992
    Date of Patent: June 8, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Kirtland P. Clark, Michael Jacobson, Chang H. Jho
  • Patent number: 5216016
    Abstract: A novel synergistic insectidical composition that comprises, in addition to carriers and/or other adjuvants or diluents, a componentA consisting of an insecticidal compound of formula I ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.3 alkyl, R.sub.2 is halogen and R.sub.3 is hydrogen or halogen, and also a componentB consisting of one or more insecticidal compounds selected from the group consisting of the compounds of formulae II to XV ##STR2## wherein R.sub.1 is hydrogen, methyl or ethyl and R.sub.2 is hydrogen or methyl; ##STR3## The composition is suitable especially for controlling sucking insects.
    Type: Grant
    Filed: March 6, 1992
    Date of Patent: June 1, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: William Vorley, Friedrich Karrer, Francois Bourgeois
  • Patent number: 5215570
    Abstract: The N-acylsulfamoylphenylureas of formula I below are suitable as counter-agents (antidotes or safeners) for protecting cultivated plants from the phytotoxic action of herbicides. Suitable crops are preferably cereals, soybeans, sorghum, maize and rice, and suitable herbicides are sulfonylureas, chloroacetanilides and aryloxyphenoxypropionic acid derivatives.The N-acylsulfamoylphenylureas have the formula I ##STR1## wherein A is a radical selected from the group ##STR2## R.sub.1 is C.sub.1 -C.sub.4 -alkoxy or each of R.sub.1 and R.sub.2, independently of the other, is hydrogen, C.sub.1 -C.sub.8 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, ##STR3## or C.sub.1 -C.sub.4 alkyl substituted by C.sub.1 -C.sub.4 alkoxy or by ##STR4## or R.sub.1 and R.sub.2 together form a C.sub.4 -C.sub.6 alkylene bridge, or a C.sub.4 -C.sub.6 alkylene bridge interrupted by oxygen, sulfur, SO, SO.sub.2, NH or by --N(C.sub.1 -C.sub.4 alkyl)-, R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.
    Type: Grant
    Filed: January 3, 1991
    Date of Patent: June 1, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Urs Burckhardt, Raafat Soliman, Werner Topfl, Hans-Rudolf Waespe
  • Patent number: 5214452
    Abstract: The invention relates to a hydrogel which is a copolymer of a polymerizable monomer mixture which containsa) 2-85 mol-% of a hydrophobic vinyl monomer with at least three fluorine atoms,b) 2-80 mol-% of a hydrophobic polyhydroxy vinyl monomer whose hydroxyl groups are in protected form,c) 2-70 mol-% of a hydrophilic vinyl monomer and,d) based on the total amount of monomers a)-c), 0-5 mol-% of a crosslinker, in which hydrogel the hydroxyl groups of the segments formed by the monomers b) are in protected or in free form.These hydrogels can be used, for example, as contact lenses, intraocular lenses or in other areas of application where biologically tolerated materials are required.
    Type: Grant
    Filed: July 17, 1992
    Date of Patent: May 25, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Kossmehl, Horst Schafer, Norbert Klaus, Jurgen Volkheimer, Madjid Rezaii-Djafari
  • Patent number: 5214121
    Abstract: Diols containing perfluoroalkyl radicals are produced by reacting compounds of the formulaR.sub.f --(E).sub.m --X'--H(R.sub.f =perfluoroalkyl radical, E is an alkylene group optionally interrupted by certain groups and/or substituted at the end, m=0 or 1, X'--H=--CONRH, --SO.sub.2 NRH or --SH) in a first step with diols containing at least 2 halogen atoms. Preferably the obtained products are reacted in a second reaction step with polyvalent isocyanates to prepolymers with free --NCO-- or free --OH--groups and these prepolymers are reacted in a third step with compounds containing isocyanate groups and/or hydroxyl groups. The first reaction step is carried out in an aprotic solvent which is insoluble in water, in the presence of an aqueous solution of an alkali metal carbonate. Intermediate products have not to be isolated.The obtained polyurethanes can be used in form of aqueous dispersions for the oil- and water repellent finishing of textiles.
    Type: Grant
    Filed: May 17, 1991
    Date of Patent: May 25, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Franz Mosch, LuSimpert, Michael Bernheim
  • Patent number: 5211719
    Abstract: Concentrated aqueous solutions are described comprising specific anionic disazo dyes and polyglycol amines, which are highly suitable as commercial forms.
    Type: Grant
    Filed: September 27, 1991
    Date of Patent: May 18, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Adolf Kaser
  • Patent number: 5209771
    Abstract: N-Phenylsulfonyl N'-triazinylureas and -thioureas of formula I ##STR1## in which X is oxygen, sulfur, SO or SO.sub.2 ; W is oxygen or sulfur; R.sub.1 is hydrogen or methyl; R.sub.2 is hydrogen, fluorine, chlorine, bromine, iodine, (X).sub.n R.sub.3, NO.sub.2, NR.sub.4 R.sub.5, --C.tbd.CR.sub.6, ##STR2## or cyano; n is the number 0 or 1; R.sub.3 is C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkyl which is substituted by 1-4 halogen atoms, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkylthio; or C.sub.2 -C.sub.4 alkenyl or C.sub.2 -C.sub.4 alkenyl which is substituted by 1-4 halogen atoms; R.sub.4 is hydrogen, CH.sub.3 O, CH.sub.3 CH.sub.2 O or C.sub.1 -C.sub.3 alkyl; R.sub.5 is hydrogen or C.sub.1 -C.sub.3 alkyl; R.sub.6 is hydrogen, methyl or ethyl; R.sub.7 is hydrogen or methyl; Z is ##STR3## E is nitrogen; R.sub.8 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkylthio, C.sub.1 -C.sub.4 alkylthio, halogen, C.sub.2 -C.sub.
    Type: Grant
    Filed: January 21, 1992
    Date of Patent: May 11, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Willy Meyer
  • Patent number: 5210205
    Abstract: Compounds of formula V ##STR1## and C.sub.1 -C.sub.6 carboxylic acid esters thereof, wherein R.sub.1 is selected from the group consisting of CH.sub.3, C.sub.2 H.sub.5, n-C.sub.3 H.sub.7, isoC.sub.3 H.sub.7, CH.sub.2 --O--CH.sub.3, CH.sub.2 --O--C.sub.2 H.sub.5, CH.sub.2 --O--CHF.sub.2 and cyclopropyl and R.sub.2 is cyclopropyl or C.sub.1 -C.sub.3 alkyl.
    Type: Grant
    Filed: March 18, 1992
    Date of Patent: May 11, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Adolf Hubele
  • Patent number: 5209832
    Abstract: The invention relates to a process for the preparation of a metal complex dye under production conditions, which comprises reacting at least one dye with a metal donor, adding said metal donor or said dye discontinuously before the end point of the metallizing is reached, and determining the end of the metallizing voltametrically.The process makes it possible to prepare metal complex dyes in good yield and purity.
    Type: Grant
    Filed: December 11, 1991
    Date of Patent: May 11, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Wilhelm Schmidt, Gerhard Beck
  • Patent number: 5207799
    Abstract: A process is described for fibre- and surface-level dyeing of wool and blends thereof with other fibers using a compound of formula (1) ##STR1## in which n is 0 or 1, and if n is 1, A is a radical of the formula ##STR2## and B is an alkylene or alkenylene group or a direct bond, or if n is zero, A is a compound of the formula ##STR3## Fibre- and surface-level dyeings, in particular in light to medium color shades are obtained by the dyeing process according to the invention. The dyeing aid according to this invention can be used to substitute formaldehyde containing wool dyeing aids.
    Type: Grant
    Filed: August 27, 1991
    Date of Patent: May 4, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Back, Klaus Hannemann, Josef Koller
  • Patent number: 5207801
    Abstract: The invention relates to reactive dye mixtures comprising the reactive dyes of the formulae ##STR1## in which X.sub.1, X.sub.2 and X.sub.3 are reactive radicals bonded via a diaminoalkylene bridge and the other substituents are as defined in claim 1.The reactive dye mixtures are suitable for dyeing and printing cellulosic fibre materials and give wet- and light-fast dyeings in luminous blue shades.
    Type: Grant
    Filed: November 5, 1991
    Date of Patent: May 4, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Aeschlimann, Paul Herzig, Athanassios Tzikas
  • Patent number: 5206390
    Abstract: Compounds of the formula I ##STR1## in which R.sup.1 to R.sup.8 independently of one another are H and at least one of R.sup.1 to R.sup.8 is a substituent belonging to the group --F, --Si(C.sub.1 -C.sub.4 alkyl).sub.3 or --COOR.sup.10 ; or each pair of adjacent radicals of R.sup.1 to R.sup.8 is --CO--O--CO--; or at least one of R.sup.1 to R.sup.8 is C.sub.1 -C.sub.20 alkyl--(X).sub.p --, C.sub.2 -C.sub.20 alkenyl--(X).sub.p --, C.sub.2 -C.sub.20 -alkynyl--(X).sub.p --, C.sub.3 -C.sub.8 cycloalkyl--(X).sub.p --, (C.sub.1 -C.sub.12 alkyl--C.sub.3 -C.sub.8 cycloalkyl--(X).sub.p --, C.sub.3 -C.sub.8 -cycloalkyl--CH.sub.2 --(X).sub.p --, C.sub.1 -C.sub.12 alkyl--C.sub.3 -C.sub.8 cycloalkyl--CH.sub.2 --(X).sub.p --, C.sub.6 -C.sub.10 aryl--X--, C.sub.7 -C.sub.20 alkaryl--X--, C.sub.7 -C.sub.12 aralkyl--(X).sub.p -- or C.sub.8 -C.sub.20 --alkaralkyl--(X).sub.p -- or --Y--(C.sub.m H.sub.2m --O)--.sub.n R.sup.10 each of which is unsubstituted or substituted by --F, --OH, --CN, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.
    Type: Grant
    Filed: May 24, 1989
    Date of Patent: April 27, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Marcus Baumann, Carl W. Mayer, Wolfgang Wernet, Walter Fischer
  • Patent number: 5206395
    Abstract: Compounds of the formula I or V, or mixtures thereof, ##STR1## wherein R is unsubstituted C.sub.6 -C.sub.14 aryl or C.sub.6 -C.sub.14 aryl which is substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 alkylthio, phenyl, benzyl, --CN, --CF.sub.3, halogen or --COOR.sub.5, and R.sub.5 is H, C.sub.16 l-C.sub.18 alkyl, cyclohexyl, cyclopentyl, phenyl, C.sub.1 -C.sub.12 alkylphenyl, benzyl or C.sub.1 -C.sub.12 alkylbenzyl, and at least one of the substituents R.sub.1 to R.sub.4 is an organic thio, sulfoxyl or sulfonyl group, and the other members R.sub.1 to R.sub.4 are H, F, Cl or Br, are reversible photochromic systems which can be used for contrast formation or light absorption.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: April 27, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Walter Fischer, Evelyn Fischer, Ernst Minder, Manfred Hofmann, Jurgen Finter, Heinz Spahni
  • Patent number: 5206388
    Abstract: The reaction of 5,6,11,12-tetrachlorotetracene with thiourea and sulfur in a polar aprotic solvent yields 5,6,11,12-tetrathiotetracene in high yield and purity. This compound is an electron donor for forming electrically conductive radical cation salts with electron donors.
    Type: Grant
    Filed: April 22, 1992
    Date of Patent: April 27, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Alex Alder
  • Patent number: 5203876
    Abstract: The dyes of formula ##STR1## wherein R, M and n are as defined in claim 1, are preeminently suitable for dyeing paper in blue shades.
    Type: Grant
    Filed: February 22, 1991
    Date of Patent: April 20, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Adolf Kaser
  • Patent number: 5204453
    Abstract: The invention relates to a process for the preparation of 1:2 chromium, 1:2 cobalt, 1:2 nickel or 1:2 iron complex azo dyes diazotisation, coupling and metallizing, without isolation of the coupling product, which process comprises diazotizing at least one amine of the benzene or naphthalene series in aqueous solution and coupling the diazonium compound so obtained to at least one coupling component of the benzene or naphthalene series or of the heterocyclic series, such that the azo dye obtained as intermediate contains groups suitable for metal complex formation, and carrying out the diazotization or coupling in the presence of a chromium, cobalt, nickel or iron donor.The dyes obtained by the process of the invention are suitable for dyeing in particular wool or synthetic textile polyamide fibre materials as well as leather, and for use as wood mordant dyes.
    Type: Grant
    Filed: December 30, 1991
    Date of Patent: April 20, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Bernard Chambon, Horst H. Jager, Rudiger Oxenius, Alois Puntener
  • Patent number: 5201998
    Abstract: Sizing agents of which some are novel and which have at least one anionic or acidic group which is optionally in the form of a salt and at least two hydrophobic substituents which each have at least 5 carbon atoms, at least two of the most adjacent hydrophobic substituents being bonded to each other with a linking member which has at least 2 hetero atoms, are particularly suitable for use, together with commercially available polymeric, cationic retention aids, in a process for sizing paper or cardboard.
    Type: Grant
    Filed: February 28, 1990
    Date of Patent: April 13, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Rosemarie Topfl, Michael Bernheim, Hubert Meindl, Hans Wegmuller, Peter Rohringer, Dieter Werthemann
  • Patent number: 5202240
    Abstract: Asporous mutants of Bacillus thuringiensis serovar. israelensis, a process for their perparation and their use for the isolation of bacterial toxins for controlling insects of the order Diptera.
    Type: Grant
    Filed: April 6, 1992
    Date of Patent: April 13, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans Zaehner, Konrad Bernhard, Harald Weisser
  • Patent number: 5200121
    Abstract: In the process described, a limited number of shaping tools (T.sub.1, T.sub.2, . . . , T.sub.N) having standardized parameters (for the production of the following contact lens parameters: contact lens diameter, radius of curvature of the rear face of the contact lens, vertex refraction) is used for the manufacture of standardized moulds (M.sub.1, M.sub.2, . . . , M.sub.N). Preferably by material-removing machining of the moulds, moulds are produced that have additional altered parameters. The multiplicity of moulds produced in that manner is used for the one-step manufacture (F) of contact lenses (L) having different parameters that largely do not have to be finished.
    Type: Grant
    Filed: April 22, 1991
    Date of Patent: April 6, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Hagmann, Peter Hofer
  • Patent number: 5199956
    Abstract: Polyester textile material can be dyed from supercritical CO.sub.2 with special disperse dyes.
    Type: Grant
    Filed: August 28, 1991
    Date of Patent: April 6, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Wolfgang Schlenker, Dieter Werthemann, Peter Liechti, Angelo D. Casa