Abstract: A coating hood adapted to uniformly apply protective coatings to the exterior of hot glass containers is disclosed. The hood comprises a tunnel for allowing the containers to pass therethrough, and an adjustable top for accommodating containers of various sizes. At least two jet slots are located in each side wall, and at least two receiver slots in the opposite side wall are aligned therewith. The jet slots and the suction slots are interspersed opposite to each other in each side wall. The coating compound is introduced through at least one feedpoint, and blowers secured to the side walls furnish high velocity air containing the coating compound. Baffles are situated in the flow path of the high velocity air so that the jets issuing from the jet slots are well defined. Two or more closed recirculating loops are defined by the judicious selection of blowers, jet slots and receivers.
Abstract: Monoalkyl tin derivatives of mercaptoacetic acid esters, such as mono-n-octyltin-S,S', S"-tris(isooctyl mercaptoacetate), are useful as food-grade stabilizers for vinyl halide polymers.
Abstract: The invention is concerned with the electrodeposition of copper from an aqueous acidic bath containing the following additives:a. An alkylated polyalkyleneimine obtained as the reaction product of a polyalkyleneimine represented by the formula :H.sub.2 N--(CH.sub.2).sub.n NH--Rwherein R is H or (CH.sub.2).sub.n NH.sub.2 and n=1 to 6 with an epihalohydrin and an alkylating agent; an organic sulfo sulfonate; a polyether; and optionally a thioorganic compound.
Abstract: Sterically-hindered triorganotin compounds of the general formula ##STR1## effectively combat fungi and mites when applied to objects, particularly plants, that are susceptible to attack by these organisms. The present compounds are particularly advantageous in that they are considerably less phytotoxic than homologous triorganotin compounds wherein the hydrocarbon radicals contain between 4 and 6 carbon atoms (e.g. n-butyl and n-hexyl radicals). In the foregoing formulae X is selected from the group consisting of a chlorine, bromine, fluorine, hydroxyl, cyanide, carbamate, thiocarbamate, amide (NH.sub.2), amino (NR.sub.2.sup.1 or NR.sup.1 H), nitrate, enolate, carboxylate ##STR2## phenoxy, alkoxy (--OR.sup.1) and mercaptide (--SR.sup.1) radical wherein R.sup.1 represents an alkyl or aryl radical containing between 1 and 12 carbon atoms, inclusive, Y is an oxygen, sulfur, or a sulfate radical and n is an integer between 0 and 4, inclusive.
Abstract: A nonionic composition that exhibits activity as a surface active agent is provided which comprises the alkylene oxide-sulfur dioxide copolymer adducts of a water soluble alcohol.
Abstract: Poly(alkylene oxide) compositions are provided which exhibit excellent resistance to oxidative degradation and inhibit the corrosion of ferrous metals, which compositions have incorporated therein an effective amount of a mononuclear aromatic compound having at least one substituent nitro group.
Abstract: Organic amine compositions which are substantially free of nitrosamine contaminants are provided which comprise an organic amine and an inhibiting amount of an inhibitor additive selected from the group consisting of 1,4-naphthoquinone, 1,4-naphthohydroquinone, alkyl-derivatives of said quinones, and mixtures of the same.
Abstract: Poly(alkylene oxide) compositions are provided which exhibit excellent resistance to oxidative degradation and inhibit the corrosion of ferrous metals, which compositions have incorporated therein a small effective amount of a bridged dimer of a hydroxyl-substituted aromatic carboxylic acid and salts thereof of the general formula: ##STR1## wherein X is a chemically stable group selected from lower alkylene, sulfonyl, and amino groups, and a sulfur atom, and Y and Y' may be the same or different, and are a hydrogen atom, hydroxyl group, amino group, alkyl group, or sulfonyl group.
Abstract: A novel catalyst and process for the manufacture of polyhydric alcohol(s) from synthesis gas. This novel catalyst is a rhodium carbonyl phosphido cluster compound. In particular, the anion cluster of the rhodium carbonyl phosphido compound is of the following empirical formula:[Rh.sub.9 P (CO).sub.21 ].sup.
Abstract: A spin finish for synthetic fibers has been developed consisting essentially of a thermally stable lubricant and a surfactant derived from an ethylene oxide/propylene oxide block co-polymer adduct of an alkylated phenol.
Type:
Grant
Filed:
March 30, 1979
Date of Patent:
February 24, 1981
Assignee:
Union Carbide Corporation
Inventors:
Quintin W. Decker, Erich Marcus, Harvey S. Koenig
Abstract: Production of lower molecular weight poly(ethylene oxide) by controlled degradation of higher molecular weight poly(ethylene oxide) initiated by a free radical source in contact with oxygen.
Type:
Grant
Filed:
September 28, 1978
Date of Patent:
April 29, 1980
Assignee:
Union Carbide Corporation
Inventors:
Priscilla B. Stanley, Donald F. Anderson
Abstract: Polymers which comprise polymer chains along which the proportion of mer units provided by a first heterocyclic monomer gradually increases in a given chain length as the proportion of mer units provided by a second heterocyclic monomer gradually decreases along said chain length. In one form, the portions of the polymers adjacent one end of the given chain lengths have about 100% of mer units provided by the first monomer and about 0% of mer units provided by the second monomer and the portions adjacent the other end of the given chain lengths have about 0% of mer units provided by the first monomer and about 100% of mer units provided by the second monomer. Additional forms of polymers are disclosed.
Abstract: There is disclosed a thermosetting phenolic resin composition, suitable for use in injection molding, which resin composition contains a molding grade phenolic resin and an effective amount of a reactive compound (e.g., para-t-butylphenol) that is capable of reducing the viscosity of molding compositions containing said phenolic resin compositon to a processable viscosity at a temperature at which the period of time within which said molding composition cures to a thermoset state is longer than the period of time that said molding composition is in the runner during a normal injection molding operation. There is also disclosed molding compositions containing said phenolic resin composition, and an injection molding process utilizing the same.
Abstract: A process for the reductive alkylation of secondary amines with either aliphatic aldehydes or aliphatic ketones in contact with hydrogen, a water-segregating agent and a hydrogenation catalyst to form tertiary amines.
Abstract: A coating and adhesive composition that may be in finely divided powder form is provided comprising a solid phenolic resole (one-step) resin having a gel time of between 150 seconds to about 250 seconds at 150.degree. C., said resin being the reaction product of bisphenol-A and formaldehyde at a mole ratio between about 2.11 to 2.64 moles of formaldehyde per mole of bisphenol-A in the presence of a catalytic quantity of a condensation catalyst at a temperature of at least about 70.degree. C. that is acidified to a pH from about 3 up to 7 and dehydrated.
Abstract: Particulate, solid, heat-reactive, filler-containing resole molding compositions are directly produced by reacting a phenol, formaldehyde, and an amine in an aqueous medium containing a water-insoluble filler material having reactive sites on the surface thereof which chemically bond with a phenolic resin and protective colloid to produce an aqueous suspension of a particulate filler-containing resole, and recovering the filler-containing resole from said suspension.
Abstract: The wetting rates of polyurethane hydrogels comprising lightly crosslinked polymers of isocyanate terminated prepolymers which are the reaction product of (i) poly(alkyleneoxy) polyols with (ii) organic diisocyanates that has been lightly crosslinked with (iii) water or an organic polyamine are enhanced by treating the surface of the solid hydrogel with certain ketones, alcohols, organic amines, aromatic hydrocarbons or aqueous alkali metal hydroxide solutions.
Abstract: A process is provided for producing a mixture of aromatic sulfonyl chlorides and aromatic sulfones substantially free of the corresponding aromatic sulfonic acids and their anhydrides, which comprises the steps of (a) reacting a monosubstituted benzene such as monochlorobenzene with sulfur trioxide in the presence of at least about 15 mole percent to about 50 mole percent of thionyl chloride, based on the sulfur trioxide, at a temperature from about the freezing point of the reactants to about 40.degree. C.; (b) adding to the reaction mixture of step (a) at least about 60 mole percent thionyl chloride, based on the sulfur trioxide, and preferably a small catalytic amount of dimethylformamide, wherein the total thionyl chloride in the reaction mixture is at least about 110 mole percent, based on the sulfur trioxide, while maintaining the reaction mixture at a temperature between about 25.degree. C. and 70.degree. C.; and then (c) continuing the reaction up to a temperature of about 160.degree. C.
Type:
Grant
Filed:
August 15, 1977
Date of Patent:
October 30, 1979
Assignee:
Union Carbide Corporation
Inventors:
Wong F. Ark, James H. Kawakami, Ulrich A. Steiner