Abstract: An improved multifilament polyethylene terephthalate yarn is prepared by first applying to the yarn a liquid composition comprising hexadecyl stearate, refined coconut oil, ethoxylated tallow amine, ethoxylated lauryl alcohol, sodium salt of alkylarylsulfonate, dinonyl-sodium-sulfosuccinate, and a mineral oil, and then applying to the yarn a liquid composition which is an oil-in-water emulsion, the oil portion of which comprises coconut oil, polyoxyethylene hydrogenated castor oil, and phosphated polyoxyethylated tridecyl alcohol neutralized with potassium hydroxide. The yarn is preferably used in tire cords for the construction of pneumatic passenger tires and results in excellent adhesion of tire cord to rubber.

Abstract: High molecular weight linear condensation polyesters are stabilized against deterioration by heat by reacting the polyester in molten form with certain polycarbonates in the presence of a catalytic amount of a phosphonium compound selected from the group consisting of tetra-n-alkylphosphonium acetates and tetra-n-alkylphosphonium halides. For the purpose of this disclosure, polycarbonates are defined as linear polyesters of carbonic acid in which the carbonate groups recur in the polymer chain. In continuous production of the improved polyesters, it is preferred that the polycarbonate and catalyst be added to the process stream with mixing at a point to give 2 to 15 minutes reaction time under superatmospheric pressure before the polyester enters the last polycondensation reactor.

Abstract: A computer controlled process for preparation of cyclohexanone by liquid phase, catalytic hydrogenation of phenol in three or more hydrogenation stages by using a computer control system interrelated with a phenol hydrogenation system in such a manner that it is capable of correlating a predetermined mole ratio of phenol to cyclohexanone with a predetermined maximum temperature in each of the hydrogenation stages, whereby intrinsic safety of operation is achieved by operating at temperatures at or below the atmospheric boiling point in each reactor.

Abstract: A controlled process for preparation of cyclohexanone by liquid phase, catalytic hydrogenation of phenol in two or more hydrogenation stages by correlating a predetermined mole ratio of phenol to cyclohexanone with a predetermined maximum temperature in each of the hydrogenation stages, whereby intrinsic safety of operation is achieved by operating at temperatures at or below the atmospheric boiling point in each reactor. The process provided improved control by use of a hydrogenation gas comprising hydrogen and nitrogen and recycling unreacted gas to the reaction zone to promote flashing overhead of product cyclohexanone. At least part of the recycling gas is treated by a cryogenic hydrogen recovery process to remove inerts from the system.

Abstract: High molecular weight linear condensation polyesters are stabilized against deterioration by heat by reacting the polyester in molten form with an epoxy compound having 5 to 25 carbon atoms in the molecule and selected from the group consisting of ##STR1## where R represents the radical remaining after removal of the carboxyl group from a monocarboxylic acid, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent hydrogen or hydrocarbon radicals, and n is an integer that can be 0 to 3.

Abstract: Fibers are produced from synthetic polymeric materials having randomly produced sections of high and low orientation and varying cross-section areas. The varied orientation and cross-section areas are produced by quickly cooling the fiber and drawing said fiber below its natural draw ratio.

Abstract: High molecular weight linear condensation polyesters are stabilized against deterioration by heat with a stabilizer comprising an N-epoxyalkyl imide of a dicarboxylic acid, having 5 to 20 carbon atoms in the imide molecule and composed of carbon, hydrogen, carbonyl and epoxy oxygen, and imide nitrogen atoms, said epoxy oxygen being linked to adjacent carbon atoms.

Abstract: A soil resistant spin finish particularly for polyamide feeder yarn to be processed at high temperature into bulked textile yarn, comprising a first oil in water emulsion wherein the oil portion consists essentially of sorbitan monooleate, polyoxyethylene tallow amine, and an alkyl stearate, said first oil in water emulsion being mixed with a second oil in water emulsion wherein the oil portion consists essentially of an alkanol amide which is a reaction product of coco fatty acid and diethanol amine, and a fluorochemical compound consisting of a polycarboxybenzene esterified with certain partially fluorinated alcohols and with hydroxyl-containing organic radicals such as glyceryl, 2-hydroxyethyl, chlorohydryl or bromohydryl. Textiles prepared from the bulked yarn show excellent resistance to soiling by oily materials.

Abstract: High molecular weight linear condensation polyesters are stabilized against deterioration by heat by reacting the polyester in molten form with an epoxy compound having 5 to 25 carbon atoms in the molecule and selected from the group consisting of ##STR1## where R represents the radical remaining after removal of the carboxyl group from a monocarboxylic acid, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent hydrogen or hydrocarbon radicals, and n is an integer that can be 0 to 3.

Abstract: An improved spin finish particularly for polyamide yarn to be processed into tire cord, comprising an oil in water emulsion, said oil portion consisting essentially of specified proportions of an oxidized polyethylene wax, a white mineral oil having a viscosity of 300 to 500 S.U.S. at 100.degree. F., a polyoxyethylene oleyl phosphate, and a sulfonated succinic acid ester of decyl alcohol, said oil in water emulsion being adjusted to pH 7.1 to 8.0 with sodium hydroxide.

Abstract: An antistatic pile carpet having a relatively pliable primary backing and a tufted surface, said surface being comprised of fibers selected from the group consisting of polyester and polyamide fibers having grafted thereon from 1 to 5 percent by weight of a conductive polymeric salt of a polyethylenimine having a molecular weight of 200 to 10,000 and a sulfonic acid compound of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are individually hydrogen or a lower alkyl radical having 1-3 carbon atoms.

Abstract: A spin finish composition for polyamide yarn to be processed into plied, bulked, continuous filament carpet yarn, comprising coconut oil, polyoxyethylene hydrogenated castor oil and the potassium salt of polyoxyethylene tridecyl alcohol phosphate. This finish improves processing of the yarn at high temperature, as by steam jet texturing, and prevents excessive tension build-up during subsequent cabling operations.

Abstract: High molecular weight linear condensation polyesters are stabilized against deterioration by heat by reacting the polyester in molten form with an epoxy compound having 5 to 25 carbon atoms in the molecule and selected from the group consisting of ##STR1## where R represents the radical remaining after removal of the carboxyl group from a monocarboxylic acid, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent hydrogen or hydrocarbon radicals, and n is an integer that can be 0 to 3.

Abstract: Preparation of improved yarns from synthetic linear polymer filaments by melt spinning followed by substantially immediately heating said filaments above their second order transition temperature and drawing said filaments substantially instantly at a temperature in the range of from about above their second order transition temperature to within about 5.degree. C. of their melting point, said heating being preceded by pretensioning of said filaments at a constant tension level greater than about 0.005 gram per denier and less than a tension level required to draw said filaments.

Abstract: In a process for producing polyethylene terephthalate yarn wherein a liquid finish is applied to the yarn, said process involving spinning and drawing steps, the improvement comprising first applying to the yarn prior to said drawing step a liquid finish composition consisting essentially of a polyalkylene glycol compound which is a mixed polyoxyethylated-polyoxypropylated monoether prepared in accordance with the equation: ##STR1## where R is an alkyl group having 1 to 8 carbon atoms, x and y are the number of moles of propylene oxide and ethylene oxide respectively and wherein ethylene oxide comprises 40 to 60 percent by weight of the combined total of ethylene oxide and propylene oxide and x+y has a value to produce a molecular weight of from 300 to 1,000, and then applying to said yarn after said drawing step a liquid finish composition consisting essentially of about 70 to 95 parts by weight of said mixed polyoxyethylated-polyoxypropylated monoether, about 5 to 30 parts by weight of a silane having the s

Abstract: A computer controlled apparatus for the preparation of high molecular weight, high quality polyethylene terephthalate polyester suitable for processing into fibers, films, and other shaped articles. The computer is interrelated with a hardware system in such a manner that it is capable of initiating process changes capable of producing a predetermined intrisic viscosity polymer during the polycondensation reaction stages.

Abstract: Synthetic filamentary yarn comprised of polyethylene terephthalate filaments which are first treated with from about 0.3 to about 0.6 weight percent based on the weight of the yarn of a liquid composition consisting essentially of about 10 to about 20 weight percent of said composition of refined coconut oil, about 10 to 20 weight percent of said composition of a stearic acid ester of a branched chain alcohol having 14-15 carbon atoms, about 3.0 to about 6.0 weight percent of said composition of ethoxylated tallow amine, about 10 to about 20 weight percent of said composition of ethoxylated lauryl alcohol, about 8.0 to about 12.0 weight percent of said composition of sodium salt of alkylarylsulfonate, about 1.0 to about 3.0 weight percent of said composition of dinonyl-sodium-sulfosuccinate, and about 35 to 50 weight percent of said composition of white mineral oil having a boiling point of between 510.degree. F. and 620.degree. F., and then treated with from about 0.7 to about 1.

Abstract: Synthetic filamentary yarn comprised of polyethylene terephthalate filaments which are first treated with a liquid composition consisting essentially of refined coconut oil, about 10 to 20 weight percent of said composition of a stearic acid ester of a branched chain alcohol having 14-15 carbon atoms, ethoxylated tallow amine, ethoxylated lauryl alcohol, sodium salt of alkylarylsulfonate, dinonyl-sodium-sulfosuccinate, and white mineral oil having a boiling point of between 510.degree. and 620.degree. F., and then treated with a liquid composition consisting essentially of a compound selected from the group consisting of glycerol monooleate and decaglycerol tetraoleate with ethoxylated tall oil fatty acids, a compound selected from the group consisting of sulfated glycerol trioleate and ethoxylated tallow amine, and a stearic acid ester of a branched chain alcohol having 14-15 carbon atoms.

Abstract: In a process for the preparation of high molecular weight linear polyesters of terephthalic acid which comprises partially esterifying terephthalic acid with an alkylene glycol under direct esterification conditions and then further esterifying and polycondensing the partially esterified product, the molecular weight distribution of the polyester is narrowed by correlating the carboxyl conversion with the reacted glycol to terephthalic acid mol ratio in various steps of a multistep process.

Abstract: A flame-retardant pile carpet having a relatively pliable primary backing and a tufted surface, said surface being comprised of fibers selected from the group consisting of polyester and polyamide fibers having incorporated therein from 0.1 to 15 percent by weight of a compound selected from the group consisting of zinc oxide and zinc hydroxide, said fibers being bonded to said backing with a bonding substance comprising a latex material and a hydrate material, said latex material being selected from the group consisting of polymers and copolymers of vinylidene chloride, and said hydrate material being selected from the group consisting of aluminum hydroxide and hydrated aluminum oxide, the ratio by weight of said latex material to said hydrate material being within the range 1:2 to 1:4.5.