Abstract: A sprayable, solvent-borne, primer composition for use as a first coat on light-sensitive, automotive plastic parts. The primer serves as a barrier to block ultraviolet light penetration to the underlying substrate and to prevent migration of substrate degradation and by-products up into the topcoat finishes. The primer is a solvent blend of a film-forming crosslinkable polymer resin, a crosslinker for the resin, a catalyst, carbon black pigments surface modified with a polymer dispersant and an organic pigment derivative co-dispersant, crosslinked polymer microgel particles, and U.V. absorbers and optional antioxidants. The surface modification on the carbon black pigments results in higher pigment loadings, which, in turn, imparts U.V. light protection at exceptionally low dry film builds.

Abstract: A silicone resin for forming a coating powder has organic substitutents selected from the group consisting of phenyl, methyl, C.sub.2 through C.sub.6 alkyl and mixtures thereof; a viscosity of between about 500 and about 10,000 cps at 150.degree. C.; a condensable hydroxyl content of between about 2.0 and about 4.5 wt %; a glass transition temperature of about 55.degree. C. or above; and about 0.2% or less of organic solvent.

Abstract: Markers which are soluble in petroleum fuel and are extractable from petroleum fuel by either acidic aqueous solutions or basic solutions and develop a color in the presence of the extracting acidic or basic aqueous solution, are identified by passing a specimen putatively containing the marker through an acidic resin column or a basic resin column, as the case may be.

Abstract: An asphalt release agent for preventing hot road asphalt, especially polymer-modified asphalt, from sticking to surfaces of delivery truck beds is provided. The release agent includes a water-based mixture of polycycloaliphatic amines and polyalkylene glycols. The release agent is applied onto the truck beds to create a slippery non-stick surface so that the road asphalt which comes in contact with such truck bed surfaces will not adhere.

Abstract: A negative-acting photoimageable composition useful as a photoresist comprises an acid-functional binder, a photopolymerizable component, a photoinitiator chemical system comprising 9-phenyl acridine or a homologue thereof, and a dibenzoate plasticizer.

Abstract: The invention provides a negative-acting photoimageable composition comprising A) between about 30 and about 80 wt % based on total weight of A) plus B) of a binder polymer having acid functionality sufficient to render said photoimageable composition developable in alkaline aqueous solution, B) between about 20 and about 70 wt % based on total weight of A) plus B) of an addition-polymerizeable, non-gaseous .alpha.,.beta.-ethylenically unsaturated compound(s) capable of forming a high polymer by free-radical initiated chain-propagating addition polymerization, at least about 50 mole percent of the .alpha.,.beta.-ethylenically unsaturated moieties of B) being methacrylic moieties, and C) between about 0.1 and about 20 wt % based on total weigh of A) plus B) of a photoinitiator chemical system. Photopolymerizable component B comprises, at between about 1 and about 70 wt. % relative to total of A) plus B), a urethane oligomer having, in addition to .alpha.,.beta.

Abstract: In a negative acting photoimageable composition comprising an acid functional binder polymer, photopolymerizable .alpha.,.beta.-ethylenically unsaturated compounds, and photoinitiator, at least a portion of the photopolymerizable compounds are isocyanate trimers having tri-acrylate functionality. Further, the composition contains a dibenzoate plasticizer.

Abstract: The invention provides a negative-acting photoimageable composition comprising A) between about 30 and about 80 wt % based on total weight of A) plus B) of a binder polymer having acid functionality sufficient to render said photoimageable composition developable in alkaline aqueous solution, B) between about 20 and about 70 wt % based on total weight of A) plus B) of an addition-polymerizeable, non-gaseous .alpha.,.beta.-ethylenically unsaturated compound(s) capable of forming a high polymer by free-radical initiated chain-propagating addition polymerization, at least about 50 mole percent of the .alpha.,.beta.-ethylenically unsaturated moieties of B) being methacrylic moieties, and C) between about 0.1 and about 20 wt % based on total weight of A) plus B) of a photoinitiator chemical system, the photoinitiator chemical system comprising between about 0.005 and about 3 wt % relative to total weight of A) plus B) of triphenyphosphine and between about 0.

Abstract: A water soluble dicarboxylic acid or an alkali metal salt thereof acts as a mold release agent for salt pellets when a salt-contacting surface of a roll-type briquetting press is coated with from about 0.02 to about 5 mg/cm.sup.2 of a powder of the acid or alkali metal salt just prior to a charge of salt. The coating is achieved by spraying an air stream entraining the powder onto the press rolls or by spraying a solution of the release agent onto the rolls and evaporating the solvent to leave the powder on the rolls. The acid has from 6 to 10 carbon atoms; adipic acid being preferred. Salt pellets having a layer of the powder on their surface may be used in water softening systems wherein the pellets sit in a brine reservoir and supply salt for the recharging of an ion exchange resin. There is no formation of an unsightly scum on the surface of the brine and on the sides of the reservoir.

Abstract: An epoxy coating powder composition and a method for controlling the denseness of cured wrinkle finish patterns are provided by the use of a curing agent mixture comprising a blocked Lewis acid, methylenedisalicylic acid and a ring-substituted homolog thereof having the formula ##STR1## wherein x and y are from 1 to 3, and R.sup.1 and R.sup.2 are, independently, hydrogen, alkyl groups having from 1 to 20 carbon atoms, aryl groups having from 6 to 10 carbon atoms, or aryl-substituted methylene groups; with the proviso that when x=y=3, R.sup.1 and R.sup.2 .noteq.hydrogen;wherein the ratio of methylene disalicylic acid and the ring-substituted homolog is from about 50:50 to about 2:98 by weight.

Abstract: In a process for fabricating a multilayer printed circuit board with permanent innerlayers of photoresist, the photoimageable composition used to form the hard permanent layer comprises a polymerizable acrylate monomer; an oligomer formed by the reaction of an epoxy resin and an acrylic or methacrylic acid; a photosensitive, free radical generating initiator for polymerization of the acrylic monomer and oligomer; a curable epoxy resin; a curing agent for the epoxy resin; and, optionally, a crosslinking agent reactive with hydroxyl groups. After exposure and development of a layer of the photoimageable composition and etching of the underlying metal layer on a board, the resultant photoresist is left on the circuitry traces. The innerlayers of photoresist are stacked in a press where it initially conforms under heat and pressure to fill voids between the innerlayers and then cures to permanence.

Abstract: A composition and method for stripping tin or tin-lead alloys, and any underlying copper-tin intermetallic, from a copper surface. The composition includes an aqueous solution of approximately 5-60% nitric acid by weight, approximately 0.5-30% ferric nitrate by weight, and a nitric acid stabilizer selected from the group consisting of an amino-triazole, an amino-isoxazole, and a linear amino sulfone in the form H.sub.2 N-SO.sub.2 -R, where R is any alkyl or benzene group, wherein the stabilizer is present at a concentration sufficient to inhibit exothermic conditions, emission of toxic NOx gas, and copper attack. A soluble source of halogen ion, such as hydrochloric acid, can be added to the composition to yield a uniform, reflective, bright pink copper appearance, and to further reduce sludge formation. In addition, sludge formation can be eliminated by adding a soluble source of sulfate ion (SO.sub.4.sup.-2) to the composition.

Abstract: A waterborne photoimageable composition, developable in alkaline aqueous solution, which is hardenable to form a hard, permanent layer suitable as a solder mask, comprisesA) between about 25 and about 40 wt % of a latex acrylic binder polymer having an acid number between about 125 and about 200 and a number average molecular weight of between about 20,000 and about 80,000,B) between about 13 and about 30 wt % of a waterborne epoxy resin having an epoxy equivalent weight of between about 100 and about 700,C) between about 20 and about 35 wt % of photopolymerizable, multi-functional .alpha.,.beta.-ethylenically unsaturated monomer and/or short-chain oligomer having a molecular weight between about 500 and about 2000,D) between about 4 and about 20 wt % of a free-radical generating chemical system,E) between about 0.5 and about 10 wt % of an epoxy curative and/or cure catalyst, andF) between about 3 and about 12 wt % surfactant(s), the weight percentages being based on total weight of A)-F).

Abstract: As a means of providing a patterned coating on a substrate, either decorative or functional, coating powder is applied to a substrate. Then the coating powder is fused or fused and cured in selected portions by computer-guided laser. One application of the invention is to fuse coating powder into a resist pattern for the production of printed circuitry.

Abstract: Opaquely pigmented or thick filmed powder coatings for heat sensitive substrates, such as wood, wood composites, for example, medium density fiber board, and plastics, that can be fully cured, especially near the substrate, through the incorporation of a dual cure system in the powder comprising a thermal initiator, such as a peroxide, along with a UV initiator. The UV initiator cures the surface, while the thermal initiator cures at the substrate. Surprisingly, virtually no pregelation occurs during the heated melt and flow out step prior to UV curing. Consequently, the hardened film finish formed on the surface exhibits exceptional smoothness which is comparable to that of traditional UV curable powders. The hardened film finish is also fully cured throughout and exhibits exceptional adhesion to the substrate which cannot be achieved with traditional UV curable powders that have been pigmented.

Abstract: A negative-acting photoimageable composition useful as a photoresist comprises an acid-functional binder polymer, a photopolymerizable component, and a photoinitiator chemical system, in which the binder polymer has a multi-modal molecular weight distribution used to promote faster photoresist stripping times and a smaller stripped particle size. The combination of faster stripping times and smaller stripped particle size allows for fully aqueous, environmentally friendly, stripping of the photoresist from overplated circuit boards.

Abstract: An alkaline aqueous developing solution for developing photoresists or the like contains, as an anti-scum agent, an ethoxylated surfactant having the general formula:R--?O--(AO).sub.n !.sub.m --X (I)where AO are alkylene oxide units selected from ethylene oxide units (CH.sub.2 --CH.sub.2 --O) and propylene oxide units (CH(CH.sub.3)--CH.sub.2 --O) or (CH.sub.2 --CH(CH.sub.3)--O), where R is a hydrophobic group, X is H or an anionic group, m is from 1 to 3, and n is at least about 8, and the molar ratio of total ethylene oxide units to total propylene oxide units is between about 1:4 and about 4:1, preferably between about 2:3 and about 3:2.

Abstract: A polyurethane prepared from a functionalized polyol has superior hydrolytic stability and dispersive capacity which makes it useful as a binder for magnetic particles in a magnetic recording medium. The functionalized polyol may be one of the group consisting of a polyesterdiol, a polyetherdiol, a polycaprolactone diol and a polycarbonate diol, each of which which incorporates a functional group having the formula: ##STR1## wherein M is a methylene group or nitrogen, R and R.sup.1 are the same or different alkylene groups having from 1 to 7 carbon atoms, R.sup.2 is an alkylene group having from 1 to 7 carbon atoms, and R.sup.3 and R.sup.4 are the same or different alkyl groups having from 1 to 7 carbon atoms, and X is an anion of a Br.o slashed.nsted acid in an amount such that the polyurethane contains from about 8 to about 32 gram moles of the functional group per 1.times.10.sup.6 grams of the polyurethane. The polyurethane may be made by heating a mixture of a Br.o slashed.

Abstract: Wood is electrostatically coated with a thermosetting powder coating system in which a mixture of a self-curing epoxy resin and a catalyst therefore is extruded and a low temperature curing agent are both pulverized and the powders are blended with conventional additives to make a coating powder which is deposited on a wooden substrate and heated to cure. The mixture of resin and catalyst does not cure within the extruder but it is made to cure at low temperatures by the separate addition of the curing agent. A small amount of the low temperature curing agent, insufficient to cause substantial curing during extrusion may be used in place of the catalyst.

Abstract: A water-immiscible organic fluid is tagged and identified by tagging the organic fluid with between about 0.25 and about 100 ppm of a marker compound having the formula: ##STR1## where the OH groups are either ortho or para to the diazo moieties, and the Xs are the same or different and are selected from C.sub.1 -C.sub.12 -alkyl, Cl, Br, F, NH.sub.2, CN, NO.sub.2, NH(C.sub.1-3 -alkyl) and N(C.sub.1-3 -alkyl).sub.2, and the fluid is identified by extracting the tagged fluid with an alkaline aqueous extractant having a pH above about 12 and containing, based on 100 parts by weight of said extractant, between about 10 and about 60 parts by weight of an organic cosolvent having the formula:R.sup.1 --O--R.sup.2 --NH.sub.2 (II)where R.sup.1 is C.sub.1 -C.sub.3 -alkyl, and R.sup.2 is C.sub.2 -C.sub.6 -alkylene.